US3883356A - Rinse-wax formulation - Google Patents
Rinse-wax formulation Download PDFInfo
- Publication number
- US3883356A US3883356A US349165A US34916573A US3883356A US 3883356 A US3883356 A US 3883356A US 349165 A US349165 A US 349165A US 34916573 A US34916573 A US 34916573A US 3883356 A US3883356 A US 3883356A
- Authority
- US
- United States
- Prior art keywords
- weight
- rinse
- carbon atoms
- cationic surfactant
- formulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 78
- 238000009472 formulation Methods 0.000 title claims abstract description 59
- 239000002480 mineral oil Substances 0.000 claims abstract description 23
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 20
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 19
- 239000000344 soap Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 125000003118 aryl group Chemical group 0.000 claims abstract description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 10
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 7
- 238000004900 laundering Methods 0.000 claims abstract description 6
- 239000003643 water by type Substances 0.000 claims abstract description 6
- 238000010348 incorporation Methods 0.000 claims abstract description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 150000001412 amines Chemical class 0.000 claims description 14
- 150000004668 long chain fatty acids Chemical class 0.000 claims description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 12
- -1 amine acetate Chemical class 0.000 claims description 11
- 125000002947 alkylene group Chemical group 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- 239000007795 chemical reaction product Substances 0.000 claims description 8
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 7
- 230000003381 solubilizing effect Effects 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 229910021529 ammonia Inorganic materials 0.000 claims description 6
- 239000007859 condensation product Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 229920000768 polyamine Polymers 0.000 claims description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 5
- 239000012736 aqueous medium Substances 0.000 claims description 5
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 4
- 244000060011 Cocos nucifera Species 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000002334 glycols Chemical class 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 4
- 239000002253 acid Substances 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000003599 detergent Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 1
- HSEMFIZWXHQJAE-UHFFFAOYSA-N Amide-Hexadecanoic acid Natural products CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- VUFOSBDICLTFMS-UHFFFAOYSA-M ethyl-hexadecyl-dimethylazanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)CC VUFOSBDICLTFMS-UHFFFAOYSA-M 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 235000001055 magnesium Nutrition 0.000 description 1
- 229940091250 magnesium supplement Drugs 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/002—Non alkali-metal soaps
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
Definitions
- This invention relates to a rinsing formulation for treating cleaned surfaces. More particularly it relates to a so-called rinse-wax formulation for rinsing previously cleaned cars and automobiles.
- Automobiles and the like are generally washed and cleaned with alkaline built detergents or anionic detergents. After application of the detergent the automobile finish is rinsed and dried in the conventional manner, i.e., with a cloth or by means of an air blast.
- a rinsing formulation is generally added to the last rinsing water to facilitate the rinsing and drying of the cleaned surfaces and provide a deposit of a waterrepellent film on the treated surface.
- Still another object of this invention is to provide a clear liquid rinse-wax formulation which has satisfactory cold-stability.
- the present invention provides an improved rinse-wax formulation, which comprises essentially a cationic surfactant, a metal soap, a mineral oil, and water.
- an improved rinse-wax formulation suitable for incorporation into rinse-waters during the laundering of cars and automobiles comprising a cationic surfactant, a mineral oil and water, can be prepared by the addition of low levels of a nonalkalimetal soap of long chain fatty acids in combination with a mixed paraffinic and aromatic/naphthenic mineral oil.
- the rinse-wax formulation of the present invention comprises a cationic surfactant, a mineral oil constituting a mixture of paraffinic and aromatic/naphthenic material. a non-alkalimetal soap of long chain fatty acids, and water.
- the cationic surfactants which can be used in the formulation of the invention are known and generally will be nitrogen-containing compounds which are reaction products of long-chain fatty acids containing from 8 to 22 carbon atoms with alkylene polyamines, alkylol amines or ammonia; the condensation products of a primary fatty amine containing from 8 to 22 carbon atoms with alkylene oxide, such as ethylene oxide or other active epoxides, such as propylene oxide and the like; and the quaternary ammonium salts of fatty amines having at least one alkyl substituent containing from 8 to 22 carbon atoms such as fatty amine acetates, fatty amine chlorides, fatty amine bromides and the like.
- Typical illustrative nitrogen-containing compounds which are the reaction products of long-chain fatty acids with alkylene polyamines are l-(2-amino ethyl)- 2-heptadecenyl-2-imidazoline; l-(2-amino ethyl)-2- heptadecadienyl-2-imidazoline, and the like.
- Typical reaction products of long-chain fatty acids with alkylol amines are l-(2-hydroxyethyl)-2- heptadecenyl-2-imidazoline; l-(2-hydroxyethyl)-2- heptadecadienyl-Z-imidazoline, and the like.
- Typical reaction products of long-chain fatty acids with ammonia are octadecylamide, hexadecylamide, docosylamide, octylamide, and the like.
- Typical condensation products of a primary fatty amine with an alkylene oxide or the like are the N,N-di- (monoand polyalkylene-oxyalkylol)- octadecylamines, the N,N-di-(monoand polyalkyleneoxyalkylol)-heptadecylamines, the N,N-di(mono-and polyalkylene-oxyalkylol)-hexadecylamines, the N,N- di-(monoand polyalkylene-oxyalkylol)- tetradecylamines, the N,N-di(monoand polyalkyleneoxyalkylol)-dodecylamines, and the like.
- Typical quaternary ammonium salts are the coconut oil quaternary amine acetates, octadecyltrimethylammonium chloride, octadecylbenzyldimethylammonium chloride, hexadecyldimethylethylammonium bromide, dodecyl trimethylammonium chloride, and the like.
- the preferred cationic surfactants for the instant for mulations are the quaternary ammonium salts of fatty amines having at least one alkyl substituent containing from 8 to 22 carbon atoms. Particularly preferred are the coconut fatty amine acetates.
- metal soap as used herein is meant the non-alkali metal salts of long-chain fatty acids having about 12-22 carbon atoms. It has been established that by the presence of small amounts of metal soap the properties of rinse-wax formulations are greatly improved.
- Suitable metal soaps for the formulation of the invention are the fatty acid salts of metals of Group IIA, HE and IIIA of the periodic system, such as the Mg-, Ca-, Sr-, Ba-, Zn-, Cdand Al-soaps, of which the stearates are particularly preferred.
- Metal stearates are for example derived from hardened tallow fatty acids, and technical or pure grade stearic acid, comprising a mixture of predominantly C -C saturated fatty acids.
- the mineral oils suitable for the formulation of the invention are the mixed paraffinic and aromatic/naphthenic mineral oils. It is essential that the mineral oil used in the invention contains a certain proportion of aromatic/naphthenic constituents, to get the benefit'of the effect from the metal soap constituent in the formulation. Surprisingly it has been observed that either pure paraffine mineral oil or pure aromatic/naphthenic mineral oil is not suitable for the purpose of the invention, since compositions with or without metal soaps comprising these oils would have substantially equal performance. The combined effect of mixed oils and metal soap is quite surprising.
- Preferred mineral oils are those having an aromatic/naphthenic content within the range of from about 5-70% by weight, more preferably from 15-50%. In practice the mineral oil employed will have a boiling point of at least 100C, since lower boiling oils would be too volatile.
- the formulation contains a solubilizing nonionic substance. Whereas this latter is not essential to the technical performance of the product, it does promote the solubilization of the mineral oil and other essential ingredients in the aqueous medium, thus making the formulation more manageable and more suitable for use.
- the rinse-wax formulation according to the invention therefore comprises an effective amount of cationic surfactant, a non-alkali metal soap derived from long chain fatty acids, a mineral oil constituting a mixture of paraffinic and aromatic/naphthenic material and water.
- a substantially clear liquid rinse-wax formulation is provided, containing a solubilizing nonionic substance.
- solubilizing nonionic substance is used herein to indicate a non-detergent organic nonionic material having solubilizing properties.
- the lower ethyloxylated nonionics containing 2-4 ethylene oxide groups per molecule
- the glycols and their derivatives such as ethylene glycol, diethylene glycol, butyldiglycol, and the like
- the low-molecular weight monohydroxy alcohols such as butanol and isobutanol, and mixtures thereof.
- the cationic surfactant may be present in amounts in the range of l20% by weight, the preferred range being from 210% by weight.
- the metal soap is present in the formulation usually in an amount in the range of 0.0 l2.0% by weight and preferably in an amount from about 0.050.75% by weight.
- the mineral oil as hereinbefore defined is present usually in an amount of at least 10%. by weight up to about 30% by weight of the formulation.
- the formulation of the invention contains aromatic/naphthenic oil material within from 0.5-6.0% by weight, based on the total composition prior to dilution.
- the amount of solubilizing nonionics preferably employed in the formulation is about 515% by weight.
- ingredients may also be added in the formulation, if desirable, such as for example low-foaming nonionic surfactants, perfume, colouring substances, etc.
- the rinse-wax formulation according to the invention is applied to the cars in the conventional manner by diluting it with water in a ratio of the order of about 111,000 and spraying it onto the cars after they have been washed and rinsed, or while they are being rinsed.
- rinse-wax compositions formulated as herein described according to the invention show remarkably better properties and performance on use as compared with the conventional compositions, particularly with respect to water-breakand hydrophobing effect, and film stability.
- a further improvement is that rinse-wax formulations of the invention maintain their effectiveness irrespective of the type of detergents used in the cleaning and washing stage of the vehicle, i.e., not susceptible to anionic detergents.
- Formulation in by weight "Expressed as number of drops of a rinse wax solution (cone. 2 g/l) from a burette necessary for water break on a lacquered surface being wettcd before with a solution of 0.2 g/l sodium-alkylbenzene sulphonatc.
- the above formulations 1 111 can be diluted with water in a ratio of about 1-2 parts of the formulation to about 1,000 parts of water and sprayed on cleaned cars prior to drying.
- a rinse-wax formulation suitable for incorporation into rinse waters during the laundering of cars or automobiles comprising an aqueous medium having therein solubilized a cationic surfactant selected from the group consisting of reaction products of long-chain fatty acids containing from 8-22 carbon atoms with alkylene polyamines, alkylolamines or ammonia, the condensation products of primary fatty amines containing from 8-22 carbon atoms with an alkylene oxide, the quaternary ammonium salts of fatty amines having at least one alkyl substituent containing from 8-22 carbon atoms; and mixtures thereof; a mineral oil having an aromatic material content of from about -70% by weight; and a non-alkalimetal salt of long chain fatty acids having from about 12-22 carbon atoms in the chain, selected from the group consisting of magne sium, calcium, strontium, barium, zinc, cadmium, aluminum salts and mixtures thereof; said formulation comprising essentially about l-% by weight
- a substantially clear liquid rinse-wax formulation suitable for incorporation into rinse waters during the laundering of cars or automobiles comprising an aqueous medium having therein solubilized a cationic surfactant selected from the group consisting of reaction products of long-chain fatty acids containing from 8-22 carbon atoms with alkylene polyamines, alkylolamines or ammonia, the condensation products of primary fatty amines containing from 8-22 carbon atoms with an alkylene oxide, the quaternary ammonium salts of fatty amines having at least one alkyl substituent containing from 8-22 carbon atoms; and mixtures thereof; said formulation comprising essentially about 1-20% by weight of said cationic surfactant, about 10-30% by weight of said mineral oil, about 0.0l2.0% by weight of said non-alkali metal soap, about 5-15% by weight of a solubilizing nonionic substance, selected from the group consisting of non-detersive lower ethoxylated nonionic compounds having from
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1659172A GB1368540A (en) | 1972-04-11 | 1972-04-11 | Rinse-wax formulation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3883356A true US3883356A (en) | 1975-05-13 |
Family
ID=10080096
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US349165A Expired - Lifetime US3883356A (en) | 1972-04-11 | 1973-04-09 | Rinse-wax formulation |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3883356A (enrdf_load_stackoverflow) |
| AT (1) | AT329724B (enrdf_load_stackoverflow) |
| CA (1) | CA977503A (enrdf_load_stackoverflow) |
| DE (1) | DE2317741A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1368540A (enrdf_load_stackoverflow) |
| NL (1) | NL7304707A (enrdf_load_stackoverflow) |
| SE (1) | SE387652B (enrdf_load_stackoverflow) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5827451A (en) * | 1993-03-17 | 1998-10-27 | Witco Corporation | Microemulsion useful as rinse aid |
| WO2000063331A1 (en) * | 1999-04-20 | 2000-10-26 | Ecolab Inc. | Composition and method for road-film removal |
| US6339054B1 (en) | 1999-04-20 | 2002-01-15 | Ecolab, Inc. | Composition and method for road-film removal |
| US6551974B1 (en) | 1999-04-20 | 2003-04-22 | Ecolab Inc. | Polish compositions for gloss enhancement, and method |
| WO2004065505A1 (en) * | 2003-01-13 | 2004-08-05 | Vahid Ghodoussi | Water based protectant containing a reaction product of two ionic surfactants |
| US20060011223A1 (en) * | 2002-10-31 | 2006-01-19 | Ronald Peterson | Automatic vehicle wash and wax system |
| US20080085253A1 (en) * | 2006-10-06 | 2008-04-10 | L'oreal | Aqueous polyamine-containing anti-frizz composition for hair |
| US20090074683A1 (en) * | 2007-09-14 | 2009-03-19 | L'oreal | Compositions and methods for treating keratinous substrates |
| US20090071493A1 (en) * | 2007-09-14 | 2009-03-19 | L'oreal | Compositions and methods for conditioning hair |
| US7699897B2 (en) | 2007-09-14 | 2010-04-20 | L'oreal | Method of coloring hair |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1090056A (en) * | 1976-06-04 | 1980-11-25 | Pierre C.E. Goffinet | Textile treating compositions |
| GB2127841B (en) * | 1982-09-10 | 1986-10-15 | Arwyn Oswald Thomas Charles | Inclusion of oil emulsion in gramophone record cleaning fluids |
| DE4243476A1 (de) * | 1992-12-22 | 1994-06-23 | Henkel Ecolab Gmbh & Co Ohg | Neutrales Wischpflegemittel (II) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2765255A (en) * | 1948-10-25 | 1956-10-02 | Shell Dev | Insecticidal emulsion concentrates |
| US2956971A (en) * | 1958-01-13 | 1960-10-18 | Francys C Bresee | Defoaming compositions and method and products containing the same |
| US3222201A (en) * | 1962-12-28 | 1965-12-07 | Union Carbide Corp | Cleaning and coating formulation |
| US3497365A (en) * | 1965-04-14 | 1970-02-24 | Armour Ind Chem Co | Protective polish |
-
1972
- 1972-04-11 GB GB1659172A patent/GB1368540A/en not_active Expired
-
1973
- 1973-04-05 NL NL7304707A patent/NL7304707A/xx unknown
- 1973-04-09 US US349165A patent/US3883356A/en not_active Expired - Lifetime
- 1973-04-09 DE DE2317741A patent/DE2317741A1/de active Pending
- 1973-04-10 SE SE7305071A patent/SE387652B/xx unknown
- 1973-04-10 AT AT313673A patent/AT329724B/de not_active IP Right Cessation
- 1973-04-10 CA CA169,236A patent/CA977503A/en not_active Expired
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2765255A (en) * | 1948-10-25 | 1956-10-02 | Shell Dev | Insecticidal emulsion concentrates |
| US2956971A (en) * | 1958-01-13 | 1960-10-18 | Francys C Bresee | Defoaming compositions and method and products containing the same |
| US3222201A (en) * | 1962-12-28 | 1965-12-07 | Union Carbide Corp | Cleaning and coating formulation |
| US3497365A (en) * | 1965-04-14 | 1970-02-24 | Armour Ind Chem Co | Protective polish |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5827451A (en) * | 1993-03-17 | 1998-10-27 | Witco Corporation | Microemulsion useful as rinse aid |
| US7223722B2 (en) | 1999-04-20 | 2007-05-29 | Ecolab Inc. | Polish compositions for gloss enhancement, and method |
| US20090188533A1 (en) * | 1999-04-20 | 2009-07-30 | Ecolab Inc. | Composition and method for road-film removal |
| US6350725B1 (en) | 1999-04-20 | 2002-02-26 | Ecolab, Inc. | Composition and method for road-film removal |
| US6551974B1 (en) | 1999-04-20 | 2003-04-22 | Ecolab Inc. | Polish compositions for gloss enhancement, and method |
| US6602350B2 (en) | 1999-04-20 | 2003-08-05 | Ecolab Inc. | Composition and method for road-film removal |
| US6864220B2 (en) | 1999-04-20 | 2005-03-08 | Ecolab Inc. | Composition and method for road-film removal |
| US20050199272A1 (en) * | 1999-04-20 | 2005-09-15 | Ecolab Inc. | Composition and method for road-film removal |
| WO2000063331A1 (en) * | 1999-04-20 | 2000-10-26 | Ecolab Inc. | Composition and method for road-film removal |
| US6339054B1 (en) | 1999-04-20 | 2002-01-15 | Ecolab, Inc. | Composition and method for road-film removal |
| US7482315B2 (en) | 1999-04-20 | 2009-01-27 | Ecolab Inc. | Composition and method for road-film removal |
| US7951245B2 (en) | 1999-04-20 | 2011-05-31 | Ecolab Usa Inc. | Composition and method for road-film removal |
| US20060011223A1 (en) * | 2002-10-31 | 2006-01-19 | Ronald Peterson | Automatic vehicle wash and wax system |
| US7494547B2 (en) * | 2002-10-31 | 2009-02-24 | Car Wash Partners, Inc. | Automatic vehicle wash and wax system |
| WO2004065505A1 (en) * | 2003-01-13 | 2004-08-05 | Vahid Ghodoussi | Water based protectant containing a reaction product of two ionic surfactants |
| US20080085253A1 (en) * | 2006-10-06 | 2008-04-10 | L'oreal | Aqueous polyamine-containing anti-frizz composition for hair |
| US8475778B2 (en) | 2006-10-06 | 2013-07-02 | L'oreal | Aqueous polyamine-containing anti-frizz composition for hair |
| US20090071493A1 (en) * | 2007-09-14 | 2009-03-19 | L'oreal | Compositions and methods for conditioning hair |
| US20090074683A1 (en) * | 2007-09-14 | 2009-03-19 | L'oreal | Compositions and methods for treating keratinous substrates |
| US7699897B2 (en) | 2007-09-14 | 2010-04-20 | L'oreal | Method of coloring hair |
| US8658140B2 (en) | 2007-09-14 | 2014-02-25 | L'oreal | Compositions and methods for treating keratinous substrates |
Also Published As
| Publication number | Publication date |
|---|---|
| CA977503A (en) | 1975-11-11 |
| NL7304707A (enrdf_load_stackoverflow) | 1973-10-15 |
| ATA313673A (de) | 1975-08-15 |
| AT329724B (de) | 1976-05-25 |
| GB1368540A (en) | 1974-09-25 |
| DE2317741A1 (de) | 1973-10-18 |
| SE387652B (sv) | 1976-09-13 |
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