US3829295A - Sintered iron based articles infiltrated with copper based metals - Google Patents
Sintered iron based articles infiltrated with copper based metals Download PDFInfo
- Publication number
- US3829295A US3829295A US00297363A US29736372A US3829295A US 3829295 A US3829295 A US 3829295A US 00297363 A US00297363 A US 00297363A US 29736372 A US29736372 A US 29736372A US 3829295 A US3829295 A US 3829295A
- Authority
- US
- United States
- Prior art keywords
- copper
- sintered
- infiltrated
- article
- skeleton
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000010949 copper Substances 0.000 title abstract description 39
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title abstract description 38
- 229910052802 copper Inorganic materials 0.000 title abstract description 38
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title abstract description 16
- 229910052751 metal Inorganic materials 0.000 title abstract description 13
- 239000002184 metal Substances 0.000 title abstract description 13
- 229910052742 iron Inorganic materials 0.000 title abstract description 8
- 150000002739 metals Chemical class 0.000 title description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 11
- 229910052799 carbon Inorganic materials 0.000 abstract description 9
- 229910052759 nickel Inorganic materials 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 7
- 229910052710 silicon Inorganic materials 0.000 abstract description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 5
- 239000005864 Sulphur Substances 0.000 abstract description 5
- 239000012535 impurity Substances 0.000 abstract description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 5
- 239000011574 phosphorus Substances 0.000 abstract description 5
- 239000010703 silicon Substances 0.000 abstract description 5
- 239000011573 trace mineral Substances 0.000 abstract description 5
- 235000013619 trace mineral Nutrition 0.000 abstract description 5
- 239000000956 alloy Substances 0.000 description 20
- 229910045601 alloy Inorganic materials 0.000 description 20
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 6
- 229910052750 molybdenum Inorganic materials 0.000 description 6
- 239000011733 molybdenum Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000005256 carbonitriding Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- 244000208235 Borassus flabellifer Species 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/02—Making ferrous alloys by powder metallurgy
- C22C33/0242—Making ferrous alloys by powder metallurgy using the impregnating technique
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/1216—Continuous interengaged phases of plural metals, or oriented fiber containing
- Y10T428/12167—Nonmetal containing
Definitions
- a sintered metal article including a sintered skeleton having the composition 1.5-2.0% Nickel, 0.30.7% Molybdenum, 1-2% Copper, 0.1-0.3% Carbon, not more than 2% of Manganese, Silicon, Sulphur, and Phosphorus together (percentages being by weight), the remainder (apart from impurities and trace elements) being Iron, the sintered skeleton being infiltrated with Copper or Copper-based alloy, and the article being case-hardened.
- This invention relates to sintered metal articles and to processes for their manufacture.
- a sintered metal article includes a sintered skeleton having the composition 1.5-2.0% Nickel, 0.3-0.7% Molybdenum, 1-2% Copper, 0.10.3% Carbon, not more than 2% of Manganese, Silicon, Sulphur and Phosphorus together (percentages being by weight), the remainder (apart from impurities and trace elements) being Iron, the sintered skeleton being infiltrated with Copper, or Copper-based alloy, and the article being case hardened.
- the skeleton has substantially 1.75% Nickel, 0.5% Molybdenum. 1.5% Copper, 0.25% Combined Carbon.
- a process for the manufacture of sintered metal articles includes the steps of producing a sintered skeleton having the composition l.5-2.0% Nickel, 0.30.7% Molybdenum, 12% Copper, 0.l0.3% Carbon, not more than 2% of Manganese, Silicon, Sulphur and Phosphorus together, the remainder (apart from impurities and trace elements) being Iron, infiltrating the skeleton with Copper or Copper-based alloy in an amount between 8% and 25% of the skeleton, and then case-hardening the infiltrated article.
- the sintered skeleton is infiltrated with 14% Copper or Copper-based alloy.
- This pre-alloy or partial pre-alloy powder is mixed with 01-03% (of the weight of the pre-alloy powder) of Carbon, in the form of graphite, and preferably with a small percentage e.g. 1% of a suitable lubricant such as Zinc Stearate.
- a suitable lubricant such as Zinc Stearate.
- the sintered article or skeleton is then infiltrated with Copper or Copper-based alloy in an amount equal to between 8 and 25 of the weight of the article, for example, by placing the article in a suitable mould having walls which extend above the article and placing Copper or Copper-based alloy powder on the article, between the walls.
- the article is then heated in an oven to a temperature significantly above the melting point of Copper or its alloy, so that all the molten Copper or Copper-based alloy infiltrates into the pores of the article; the time of heating is such as to allow the Copper or Copper-based alloy to infiltrate the article uniformly.
- Suitable Copper-based alloys are Copper plus 3% Cobalt, or Copper plus 5% Iron and 5% Manganese.
- the article is then case-hardened either by Carburising, Carbo-Nitriding or any other known or convenient method of Carbon case-hardening.
- the pre-alloy powder contained 1.75% Nickel, 0.5% Molybdenum, 1.5% Copper, which was mixed with 0.25% Graphite and 1% Zinc Stearate. After sintering in the above manner the skeleton was impregnated with 14% Copper.
- a sintered metal article consisting of a sintered skeleton infiltrated with copper or copper-based alloy, the skeleton having the composition, in percentages by weight:
- a sintered metal article, according to Claim 1, in whi h th skeleton has substantially 1.75% Nickel, 0.5% 3414391 12/1968 Brab 29' 182'1 Mo1ybdenum,1 5% COpper0 25% Carbon 3,694,173 9/1972 Farmer et al. 29182.1
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4934571A GB1399812A (en) | 1971-10-23 | 1971-10-23 | Sintered metal articles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3829295A true US3829295A (en) | 1974-08-13 |
Family
ID=10452051
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00297363A Expired - Lifetime US3829295A (en) | 1971-10-23 | 1972-10-13 | Sintered iron based articles infiltrated with copper based metals |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3829295A (enrdf_load_stackoverflow) |
| JP (1) | JPS5323761B2 (enrdf_load_stackoverflow) |
| AU (1) | AU466216B2 (enrdf_load_stackoverflow) |
| DE (1) | DE2251909C2 (enrdf_load_stackoverflow) |
| FR (1) | FR2157563A5 (enrdf_load_stackoverflow) |
| GB (1) | GB1399812A (enrdf_load_stackoverflow) |
| IT (1) | IT966411B (enrdf_load_stackoverflow) |
| SE (1) | SE391951B (enrdf_load_stackoverflow) |
| ZA (1) | ZA727376B (enrdf_load_stackoverflow) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3983615A (en) * | 1973-02-09 | 1976-10-05 | Toyo Kogyo Co., Ltd. | Sliding seal member for an internal combustion engine |
| US4271239A (en) * | 1977-07-20 | 1981-06-02 | Brico Engineering Limited | Sintered metal articles and process for their manufacture |
| US4327156A (en) * | 1980-05-12 | 1982-04-27 | Minnesota Mining And Manufacturing Company | Infiltrated powdered metal composite article |
| US5145504A (en) * | 1991-07-08 | 1992-09-08 | The Dow Chemical Company | Boron carbide-copper cermets and method for making same |
| US5507336A (en) * | 1995-01-17 | 1996-04-16 | The Procter & Gamble Company | Method of constructing fully dense metal molds and parts |
| US5906781A (en) * | 1996-10-24 | 1999-05-25 | The Procter & Gamble Company | Method of using thermally reversible material to form ceramic molds |
| US5918293A (en) * | 1994-05-27 | 1999-06-29 | Hoganas Ab | Iron based powder containing Mo, P and C |
| US5927373A (en) * | 1996-10-24 | 1999-07-27 | The Procter & Gamble Company | Method of constructing fully dense metal molds and parts |
| US20060180251A1 (en) * | 2005-02-11 | 2006-08-17 | Paul Rivest | Copper-based alloys and their use for infiltration of powder metal parts |
| US20080107558A1 (en) * | 2004-02-04 | 2008-05-08 | Gkn Sinter Metals, Inc. | Sheet Material Infiltration of Powder Metal Parts |
| WO2010074627A1 (en) * | 2008-12-22 | 2010-07-01 | Höganäs Ab (Publ) | Machinability improving composition |
| CN114367662A (zh) * | 2021-12-13 | 2022-04-19 | 西安理工大学 | 微纳双连续孔道的多孔铜的制备方法 |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3984158A (en) * | 1973-09-10 | 1976-10-05 | Dresser Industries, Inc. | Journal and pilot bearings with alternating surface areas of wear resistant and anti-galling materials |
| JPS5224613A (en) * | 1975-08-19 | 1977-02-24 | Nippon Piston Ring Co Ltd | Sliding move part material made of ferrous system sintered alloy for i nternal combustion engine and forming method of its sliding move surfa ce |
| GB2087929B (en) | 1980-11-19 | 1985-01-09 | Brico Eng | Sintered metal articles and their manufacture |
| DE3683428D1 (de) * | 1985-07-15 | 1992-02-27 | Scm Metal Products Inc | Pulvermetallkoerper mit hoher kerbschlagzaehigkeit und verfahren zu seiner herstellung. |
| US6676894B2 (en) * | 2002-05-29 | 2004-01-13 | Ntn Corporation | Copper-infiltrated iron powder article and method of forming same |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1071863A (en) * | 1965-03-15 | 1967-06-14 | Mitsubishi Kinzoku Kogyu Kabus | Lead-impregnated,iron-base,sintered alloy materials for current-collecting slider shoes |
-
1971
- 1971-10-23 GB GB4934571A patent/GB1399812A/en not_active Expired
-
1972
- 1972-10-13 US US00297363A patent/US3829295A/en not_active Expired - Lifetime
- 1972-10-17 ZA ZA727376A patent/ZA727376B/xx unknown
- 1972-10-17 AU AU47821/72A patent/AU466216B2/en not_active Expired
- 1972-10-18 FR FR7236886A patent/FR2157563A5/fr not_active Expired
- 1972-10-19 IT IT53478/72A patent/IT966411B/it active
- 1972-10-20 SE SE7213594A patent/SE391951B/xx unknown
- 1972-10-20 JP JP10458472A patent/JPS5323761B2/ja not_active Expired
- 1972-10-23 DE DE2251909A patent/DE2251909C2/de not_active Expired
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3983615A (en) * | 1973-02-09 | 1976-10-05 | Toyo Kogyo Co., Ltd. | Sliding seal member for an internal combustion engine |
| US4271239A (en) * | 1977-07-20 | 1981-06-02 | Brico Engineering Limited | Sintered metal articles and process for their manufacture |
| DK155982B (da) * | 1977-07-20 | 1989-06-12 | Brico Eng | Sintret metalemne samt fremgangsmaade til fremstilling af dette og dets anvendelse. |
| US4327156A (en) * | 1980-05-12 | 1982-04-27 | Minnesota Mining And Manufacturing Company | Infiltrated powdered metal composite article |
| US5145504A (en) * | 1991-07-08 | 1992-09-08 | The Dow Chemical Company | Boron carbide-copper cermets and method for making same |
| US5918293A (en) * | 1994-05-27 | 1999-06-29 | Hoganas Ab | Iron based powder containing Mo, P and C |
| US5507336A (en) * | 1995-01-17 | 1996-04-16 | The Procter & Gamble Company | Method of constructing fully dense metal molds and parts |
| US5906781A (en) * | 1996-10-24 | 1999-05-25 | The Procter & Gamble Company | Method of using thermally reversible material to form ceramic molds |
| US5927373A (en) * | 1996-10-24 | 1999-07-27 | The Procter & Gamble Company | Method of constructing fully dense metal molds and parts |
| US20080107558A1 (en) * | 2004-02-04 | 2008-05-08 | Gkn Sinter Metals, Inc. | Sheet Material Infiltration of Powder Metal Parts |
| US7341093B2 (en) | 2005-02-11 | 2008-03-11 | Llc 2 Holdings Limited, Llc | Copper-based alloys and their use for infiltration of powder metal parts |
| US20060180251A1 (en) * | 2005-02-11 | 2006-08-17 | Paul Rivest | Copper-based alloys and their use for infiltration of powder metal parts |
| US20080138237A1 (en) * | 2005-02-11 | 2008-06-12 | Paul Rivest | Copper-based alloys and their use for infiltration of powder metal parts |
| WO2010074627A1 (en) * | 2008-12-22 | 2010-07-01 | Höganäs Ab (Publ) | Machinability improving composition |
| CN102325614A (zh) * | 2008-12-22 | 2012-01-18 | 霍加纳斯股份有限公司 | 改进可机械加工性的组合物 |
| US8795407B2 (en) | 2008-12-22 | 2014-08-05 | Hoganas Ab (Publ) | Machinability improving composition |
| US9393617B2 (en) | 2008-12-22 | 2016-07-19 | Hoganas Ab (Publ) | Machinability improving composition |
| CN106735165A (zh) * | 2008-12-22 | 2017-05-31 | 霍加纳斯股份有限公司 | 改进可机械加工性的组合物 |
| CN106735165B (zh) * | 2008-12-22 | 2019-09-27 | 霍加纳斯股份有限公司 | 改进可机械加工性的组合物 |
| CN114367662A (zh) * | 2021-12-13 | 2022-04-19 | 西安理工大学 | 微纳双连续孔道的多孔铜的制备方法 |
| CN114367662B (zh) * | 2021-12-13 | 2024-01-26 | 西安理工大学 | 微纳双连续孔道的多孔铜的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU466216B2 (en) | 1975-10-23 |
| JPS5323761B2 (enrdf_load_stackoverflow) | 1978-07-17 |
| ZA727376B (en) | 1973-06-27 |
| FR2157563A5 (enrdf_load_stackoverflow) | 1973-06-01 |
| JPS4850907A (enrdf_load_stackoverflow) | 1973-07-18 |
| IT966411B (it) | 1974-02-11 |
| GB1399812A (en) | 1975-07-02 |
| DE2251909A1 (de) | 1973-04-26 |
| DE2251909C2 (de) | 1983-10-27 |
| AU4782172A (en) | 1974-04-26 |
| SE391951B (sv) | 1977-03-07 |
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