US3822312A - Creamy rinsing agent composition - Google Patents
Creamy rinsing agent composition Download PDFInfo
- Publication number
- US3822312A US3822312A US00301103A US30110372A US3822312A US 3822312 A US3822312 A US 3822312A US 00301103 A US00301103 A US 00301103A US 30110372 A US30110372 A US 30110372A US 3822312 A US3822312 A US 3822312A
- Authority
- US
- United States
- Prior art keywords
- carbon atoms
- creamy
- rinsing agent
- wig
- iii
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract description 44
- 239000003795 chemical substances by application Substances 0.000 abstract description 39
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract description 19
- 210000004209 hair Anatomy 0.000 abstract description 14
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 11
- 239000000194 fatty acid Substances 0.000 abstract description 11
- 229930195729 fatty acid Natural products 0.000 abstract description 11
- 150000004665 fatty acids Chemical class 0.000 abstract description 11
- 150000001875 compounds Chemical class 0.000 abstract description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract description 9
- 239000002216 antistatic agent Substances 0.000 abstract description 7
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract description 7
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract description 6
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 abstract description 6
- 150000003839 salts Chemical class 0.000 abstract description 6
- 239000000600 sorbitol Substances 0.000 abstract description 6
- 150000001298 alcohols Chemical class 0.000 abstract description 3
- 150000002334 glycols Chemical class 0.000 abstract description 3
- 239000002736 nonionic surfactant Substances 0.000 abstract description 3
- 229920000233 poly(alkylene oxides) Polymers 0.000 abstract description 3
- 230000000630 rising effect Effects 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 5
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 125000004432 carbon atom Chemical group C* 0.000 description 21
- MAUMSNABMVEOGP-UHFFFAOYSA-N (methyl-$l^{2}-azanyl)methane Chemical compound C[N]C MAUMSNABMVEOGP-UHFFFAOYSA-N 0.000 description 19
- 239000000835 fiber Substances 0.000 description 16
- 125000000217 alkyl group Chemical group 0.000 description 15
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- -1 alkyl dimethyl ammonium chloride Chemical compound 0.000 description 12
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 9
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 8
- 238000011282 treatment Methods 0.000 description 8
- 239000012209 synthetic fiber Substances 0.000 description 7
- 229920002994 synthetic fiber Polymers 0.000 description 7
- 239000003760 tallow Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 229960003237 betaine Drugs 0.000 description 6
- 239000006071 cream Substances 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 230000003068 static effect Effects 0.000 description 5
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 4
- BXHBTSNIMKXATC-UHFFFAOYSA-N C(C)OS(=O)(=O)[O-].C(CC)[NH2+]CC Chemical compound C(C)OS(=O)(=O)[O-].C(CC)[NH2+]CC BXHBTSNIMKXATC-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 125000005907 alkyl ester group Chemical group 0.000 description 4
- ACZVSMNFVFBOTM-UHFFFAOYSA-N beta-alanine betaine Chemical compound C[N+](C)(C)CCC([O-])=O ACZVSMNFVFBOTM-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004166 Lanolin Substances 0.000 description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229940039717 lanolin Drugs 0.000 description 3
- 235000019388 lanolin Nutrition 0.000 description 3
- 239000001632 sodium acetate Substances 0.000 description 3
- 235000017281 sodium acetate Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 2
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 2
- GHEZBHAGHAJHIT-UHFFFAOYSA-N 2,2-dihydroxyethyl-di(docosyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[NH+](CC(O)O)CCCCCCCCCCCCCCCCCCCCCC GHEZBHAGHAJHIT-UHFFFAOYSA-N 0.000 description 2
- HVYJSOSGTDINLW-UHFFFAOYSA-N 2-[dimethyl(octadecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O HVYJSOSGTDINLW-UHFFFAOYSA-N 0.000 description 2
- TYIOVYZMKITKRO-UHFFFAOYSA-N 2-[hexadecyl(dimethyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O TYIOVYZMKITKRO-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 2
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- REVKSDVMARYEDI-UHFFFAOYSA-N 2-[di(docosyl)amino]ethane-1,1-diol Chemical compound CCCCCCCCCCCCCCCCCCCCCCN(CC(O)O)CCCCCCCCCCCCCCCCCCCCCC REVKSDVMARYEDI-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 229940001447 lactate Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- XCVNDBIXFPGMIW-UHFFFAOYSA-N n-ethylpropan-1-amine Chemical compound CCCNCC XCVNDBIXFPGMIW-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Definitions
- An aqueous creamy rinsing agent composition for wig and hair comprising as essential components (I) 1-7% of a quaternary ammonium salt having two long-chain alkyl groups having 16 to 22 carbon atoms; (II) 0.1- of an antistatic agent expressed by the following formula wherein R stands for an alkyl group having 16 to 22 carbon atoms, R and R designate independently an alkyl group having 1 to 3 carbon atoms, and m is a number of from 1 to 4: (III) 05-10% of at least one compound selected from the group consisting of alcohols having up to 3 carbon atoms, glycols having up to 3 carbon atoms, glycerol, sorbitol, non-ionic surfactants containing no ethylene oxide units in the molecule or containing up to moles of ethylene oxide units in the molecule, polyalkylene oxide compounds having a molecular weight of greater
- This invention relates to a creamy rinsing agent composition having an excellent effect for finishing wigs made from synthetic fibers or human hairs, or hairs.
- the creamy rinsing agent composition of this invention exhibits a very excellent finishing effect particularly when it is used for finishing treatment of wigs made from synthetic fibers.
- the direct rinse can be easily applied to a wig.
- An antistatic property can be imparted to a wig.
- Wigs made from synthetic fibers are, in particular, readily statically charged.
- fibers of the wig 3,822,312 Patented July 2, 1974 is statically charged, they are entangled or bristled, resulting in a great damage on the wig.
- it is a great defect of a wig of synthetic fibers that it is readily statically charged in the winter season when the wig is used more frequently.
- Wigs can be combed smoothly. In other words, it is desired that a good smoothness can be imparted to wig fibers.
- the rinsing agent is in the form of a stable emulsion having a relatively high viscosity.
- the rinsing agent having such property is called creamy rinsing agent for convenience.
- the creamy rinsing agent to be used for treatment of wigs has the above properties (2), (3) and (4).
- the creamy rinsing agent should give a suitable softness to wig fibers and decrease unnatural feeling in wigs.
- the rinsing agent is stable at a relatively high viscosity.
- an aqueous creamy rinsing agent composition for wig and hair which comprises the following four ingredients (I) to (IV):
- the balance is water.
- quaternary ammonium salt (I) there may be exemplified distearyl dimethyl ammonium chloride, dipalmityl dimethyl ammonium chloride, di-hydrogenatedbeef-tallow-alkyl dimethyl ammonium chloride, dibehenyl dihydroxyethyl ammonium chloride, dipalmityl propylethyl ammonium ethylsulfate, etc.
- antistatic agent (II) there may be mentioned stearyl dimethyl betaine [C H -(CH N+CH COO-] (structural formulae will be omitted below), cetyl dimethyl propiobetaine, cetyl dimethyl betaine, behenyl dipropyl betaine, behenyl dimethyl betaine, behenyl dimethyl propiobetaine, palmityl dimethyl betaine, etc.
- methanol, ethanol, propanol, ethylene glycol, propylene glycol, glycerol, sorbitol compounds expressed by the formula RO (C H O) H in which m is to 10, and R is an alkyl or alkenyl group of 12-22 carbon atoms, a lanolin alcohol alkyl residue or an alkylphenyl group having an alkyl group of 8 to 12 carbon atoms, monoglycerides of higher fatty acids, sorbitan esters of higher fatty acids, adducts of 1 to moles of ethylene oxides to sorbitan esters of higher fatty acids, OH(CH CH O) OH,
- inorganic and organic salts (IV having an electrolytic property there may be mentioned salts of alkali metals, ammonium, halogens, sulfuric acid, boric acid, phosphoric acid and organic acids having up to 6 carbon atoms.
- each of the above four ingredients is an essential and indispensable component
- the creamy rinsing agent of this invention should comprise all of the above four ingredients. More specifically, a mere blend of the quaternary ammonium salt (I) and the antistatic agent (II) cannot exhibit a stable creamy state, and a blend of any three ingredients of the above four indispensable ingredients cannot possess a stable creamy state or a good combination of properties intended in this invention. In short, only the rinsing agent composition comprising the four indispensable ingredients specified in this invention can possess a stable cream state and a good combination of intended properties.
- the creamy rinsing agent composition according to this invention is especially suitable for the treatment of wigs made from synthetic fibers which are readily statically charged, but it may of course be effectively used for the finishing treatment of wigs made from human hairs or human hairs per se. Furthermore, the creamy rinsing agent composition of this invention may further comprise small amounts of known additives such as perfumes, fungicides, pigments, etc.
- Example 1 Viscosity, antistatic property and other properties required of a rinsing agent were measured with respect to each of the compositions illustrated below. In the following, the compositions tested are shown first, and then the results of the measurement and evaluation in those compositions are shown. In each of compositions, symbols (I) to (IV) are those used throughout the instant specification to clearly indicate the four ingredients.
- Composition 1 Percent (I) Di-hydrogenated-beef-tallow-alkyl dimethyl ammonium chloride 4
- Water Balance Composition 2 Percent (I) Di-hydrogenated beef-tallow-alkyl ammonium (I) Dibehenyl dihydroxyethyl ammonium bro- 6 mide 6 (II) C H -(CH 'N+CH COO- 3 (IV) Sodium acetate 0.5
- Water Balance Composition 13 (example): Percent (I) Dipalmityl propyl ethyl ammonium ethylsulfate 6 C22H45' 2N+CH2COO 1 (III) C H COO(C H O) H 5 (IV) Sodium phosphate 0.2
- the measurement was carried out according to Rtider method.
- the fibers there were used Kanekalon wig fibers (fibers of a copolymer of acrylonitrile and vinyl chloride manufactured by Kanegafuchi Kagaku Kogyo K.K.).
- the fibers were dipped for 3 minutes in an aqueos solution containing 5% of the rinsing agent composition and then squeezed so that the aqueous solution was contained in an amount of 50% based on the fibers.
- the fibers were dried and allowed to stand at a temperature of 25 C. under a relative humidity of 45% for 48 hours.
- the treated fibers were used as test samples.
- the fiber running velocities adopted in the measurement according to Roder method were 2 cm./min. (static friction) or cm./min. (dynamic friction).
- Rinsing agents of compositions 9 to can fully meet all the necessary requirements and have an excellent creamy appearance.
- An aqueous creamy rinsing agent composition for wigs consisting essentially of (I) 1 to 7% by weight of a quaternary ammonium salt having two long-chain alkyl groups having 16 to 22 carbon atoms and two short chain alkyl or hydroxyalkyl groups having 1 to 3 carbon atoms;
- an anion selected from the group consisting of halogens, sulfate, borate, phosphate, acetate and lactate;
- composition according to claim 1 in which said two short chain alkyl or hydroxy alkyl groups are selected from the group consisting of dimethyl, dihydroxyethyl and propylethyl.
- composition according to claim 1 in which said quaternary ammonium salt *(I) is selected from the group consisting of distearyl dimethyl ammonium chloride, dipalmityl dimethyl ammonium chloride, di-hydrogenatedbeef-tallow-alkyl dimethyl ammonium chloride, dibehenyl dihydroxyethyl ammonium chloride and dipalmityl propylethyl ammonium ethylsulfate.
- composition according to claim 1 in which said antistatic agent (II) is selected from the group consisting of stearyl dimethyl betaine, cetyl dimethyl propiobetaine, cetyl dimethyl betaine, "behenyl dipropyl betaine, behenyl dimethyl betaine, behenyl dimethyl propiobetaine and palmityl dimethyl betaine.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Engineering & Computer Science (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP46087388A JPS519012B2 (en, 2012) | 1971-11-02 | 1971-11-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3822312A true US3822312A (en) | 1974-07-02 |
Family
ID=13913494
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00301103A Expired - Lifetime US3822312A (en) | 1971-11-02 | 1972-10-26 | Creamy rinsing agent composition |
Country Status (8)
Country | Link |
---|---|
US (1) | US3822312A (en, 2012) |
JP (1) | JPS519012B2 (en, 2012) |
AU (1) | AU467621B2 (en, 2012) |
DE (1) | DE2252669A1 (en, 2012) |
ES (1) | ES408173A1 (en, 2012) |
FR (1) | FR2158383B1 (en, 2012) |
GB (1) | GB1410789A (en, 2012) |
IT (1) | IT1001509B (en, 2012) |
Cited By (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3975313A (en) * | 1974-06-19 | 1976-08-17 | Shelmire Jr Jesse Bedford | Solid amphoteric skin cleanser |
DE2704343A1 (de) * | 1976-02-09 | 1977-08-18 | Bristol Myers Co | Chemische zusammensetzung zur konditionierung, zur aufhellung oder zum faerben von menschlichem haar |
US4102825A (en) * | 1976-10-01 | 1978-07-25 | Kao Soap Co., Ltd. | Liquid light-duty detergent composition |
US4144326A (en) * | 1975-05-19 | 1979-03-13 | American Cyanamid Company | Oil free, water-soluble, clear creme rinse for hair |
US4148762A (en) * | 1976-04-15 | 1979-04-10 | Henkel Kommanditgesellschaft Auf Aktien | Cosmetic cleaning agents containing betaines and process |
US4149551A (en) * | 1977-03-28 | 1979-04-17 | The Procter & Gamble Company | Method of conditioning hair using a flexible substrate |
US4165369A (en) * | 1975-09-11 | 1979-08-21 | Kao Soap Co., Ltd. | Liquid hair rinse containing quaternary ammonium salts and a synthetic secondary alcohol |
US4166048A (en) * | 1975-09-22 | 1979-08-28 | Kao Soap Co., Ltd. | High foaming detergent composition having low skin irritation properties |
US4187289A (en) * | 1976-12-03 | 1980-02-05 | Ciba-Geigy Corporation | Softening agents containing diester/amine adducts and quaternary ammonium salts, valuable for use as after-rinse softeners and after-shampoo hair conditioners |
US4220168A (en) * | 1978-06-05 | 1980-09-02 | Helene Curtis Industries, Inc. | Method of moisturizing and maintaining normal moisture level in hair having a normal moisture content |
US4220166A (en) * | 1978-06-05 | 1980-09-02 | Helene Curtis Industries, Inc. | Method of restoring normal moisture level to hair with severe moisture deficiency |
US4220167A (en) * | 1978-06-05 | 1980-09-02 | Helene Curtis Industries, Inc. | Method of restoring normal moisture level to hair with slight to moderate moisture deficiency |
US4261869A (en) * | 1977-07-01 | 1981-04-14 | Lever Brothers Company | Detergent compositions |
US4374125A (en) * | 1978-06-05 | 1983-02-15 | Helene Curtis Industries, Inc. | Hair moisturizing compositions |
US4421740A (en) * | 1976-07-09 | 1983-12-20 | S. C. Johnson & Son, Inc. | Hair conditioning composition and process for producing the same |
US4464272A (en) * | 1982-02-10 | 1984-08-07 | Lever Brothers Company | Fabric softening composition |
US4464273A (en) * | 1982-02-10 | 1984-08-07 | Lever Brothers Company | Fabric softening composition |
US4532127A (en) * | 1976-02-09 | 1985-07-30 | Clairol Incorporated | Composition for lightening or coloring hair containing an oxidizing agent and certain quaternary amines |
US4534877A (en) * | 1982-07-30 | 1985-08-13 | The Procter & Gamble Company | Shampoo compositions comprising specific betaine surfactants and a quaternary compound |
US4537762A (en) * | 1983-11-14 | 1985-08-27 | Bernel Chemical Co. | Hair compositions containing mixtures of quaternary ammonium compounds and tertiary amine salts of long-chain acids |
US4548810A (en) * | 1979-05-03 | 1985-10-22 | Albert Zofchak | Method of lubricating the skin |
US4636329A (en) * | 1983-06-22 | 1987-01-13 | The Procter & Gamble Company | Shampoo compositions comprising quaternary imidazolinium compound and alkylamido betaine having low pH range |
US4749411A (en) * | 1986-03-14 | 1988-06-07 | M. D. Stetson Company | Disinfecting and high-speed buffing composition comprising polyethylene glycol and quaternary ammonium germicide, and method of use |
US4917842A (en) * | 1988-02-12 | 1990-04-17 | The Standard Oil Company | Process of making ceramics |
US4979993A (en) * | 1989-03-27 | 1990-12-25 | Loctite Corporation | Trialkylammonium alkyl carboxylate primer for cyanoacrylate bonding of polymeric substrates |
US4986983A (en) * | 1989-04-03 | 1991-01-22 | Revlon, Inc. | Superfatted betaine and zwitterionic hair and skin conditioner compositions |
US5034218A (en) * | 1990-07-13 | 1991-07-23 | Helene Curtis, Inc. | Stable conditioning shampoo containing compatible anionic surfactant/cationic conditioning agent-non-volatile silicone emulsion |
US5066743A (en) * | 1989-03-27 | 1991-11-19 | Loctite Corporation | Two-part composition comprising a cyanoacrylate adhesive and a primer comprising a tertiary ammonium carboxylate compound |
US5078990A (en) * | 1990-07-13 | 1992-01-07 | Helene Curtis, Inc. | Shampoos and conditioning shampoos having increased capacity for incorporation of conditioning agents and removal of hair soil |
WO1992005234A1 (en) * | 1990-09-21 | 1992-04-02 | The Procter & Gamble Company | Cleansing compositions |
US5334376A (en) * | 1993-08-13 | 1994-08-02 | Colgate-Palmolive Company | Compositions for conditioning hair |
US5733536A (en) * | 1995-06-05 | 1998-03-31 | Whitehill Oral Technologies, Inc. | Ultramulsion based hair care compositions |
US20030125212A1 (en) * | 2000-04-10 | 2003-07-03 | Katsuhiko Yamaguchi | Wetting agent composition for agricultural chemicals |
US8277788B2 (en) | 2005-08-03 | 2012-10-02 | Conopco, Inc. | Quick dispersing hair conditioning composition |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5129233A (en) * | 1974-09-03 | 1976-03-12 | Kao Corp | Heaarinsuzai soseibutsu |
JPS5272834A (en) * | 1975-12-15 | 1977-06-17 | Kao Corp | Clear hair rinse |
JPS559016A (en) * | 1978-07-04 | 1980-01-22 | Kao Corp | Rinse |
US4375421A (en) * | 1981-10-19 | 1983-03-01 | Lever Brothers Company | Viscous compositions containing amido betaines and salts |
JPS5885810A (ja) * | 1981-11-17 | 1983-05-23 | Kao Corp | 毛髪処理剤組成物およびその製造方法 |
US4526781A (en) * | 1984-04-25 | 1985-07-02 | Revlon, Inc. | Hair care compositions |
JP3431737B2 (ja) * | 1995-10-25 | 2003-07-28 | サンスター株式会社 | 高分子配合乳化型頭髪処理剤 |
-
1971
- 1971-11-02 JP JP46087388A patent/JPS519012B2/ja not_active Expired
-
1972
- 1972-10-26 US US00301103A patent/US3822312A/en not_active Expired - Lifetime
- 1972-10-27 DE DE2252669A patent/DE2252669A1/de active Pending
- 1972-10-30 AU AU48323/72A patent/AU467621B2/en not_active Expired
- 1972-10-31 GB GB5012572A patent/GB1410789A/en not_active Expired
- 1972-10-31 FR FR7238563A patent/FR2158383B1/fr not_active Expired
- 1972-10-31 ES ES408173A patent/ES408173A1/es not_active Expired
- 1972-10-31 IT IT31154/72A patent/IT1001509B/it active
Cited By (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3975313A (en) * | 1974-06-19 | 1976-08-17 | Shelmire Jr Jesse Bedford | Solid amphoteric skin cleanser |
US4144326A (en) * | 1975-05-19 | 1979-03-13 | American Cyanamid Company | Oil free, water-soluble, clear creme rinse for hair |
US4165369A (en) * | 1975-09-11 | 1979-08-21 | Kao Soap Co., Ltd. | Liquid hair rinse containing quaternary ammonium salts and a synthetic secondary alcohol |
US4166048A (en) * | 1975-09-22 | 1979-08-28 | Kao Soap Co., Ltd. | High foaming detergent composition having low skin irritation properties |
US4119399A (en) * | 1976-02-09 | 1978-10-10 | Clairol Incorporated | Composition for coloring hair containing an oxidizing agent and certain quaternary amines |
US4532127A (en) * | 1976-02-09 | 1985-07-30 | Clairol Incorporated | Composition for lightening or coloring hair containing an oxidizing agent and certain quaternary amines |
US4096243A (en) * | 1976-02-09 | 1978-06-20 | Clairol Incorporated | Composition for lightening hair containing an oxidizing agent and certain quaternary amines |
DE2704343A1 (de) * | 1976-02-09 | 1977-08-18 | Bristol Myers Co | Chemische zusammensetzung zur konditionierung, zur aufhellung oder zum faerben von menschlichem haar |
US4148762A (en) * | 1976-04-15 | 1979-04-10 | Henkel Kommanditgesellschaft Auf Aktien | Cosmetic cleaning agents containing betaines and process |
US4421740A (en) * | 1976-07-09 | 1983-12-20 | S. C. Johnson & Son, Inc. | Hair conditioning composition and process for producing the same |
US4102825A (en) * | 1976-10-01 | 1978-07-25 | Kao Soap Co., Ltd. | Liquid light-duty detergent composition |
US4187289A (en) * | 1976-12-03 | 1980-02-05 | Ciba-Geigy Corporation | Softening agents containing diester/amine adducts and quaternary ammonium salts, valuable for use as after-rinse softeners and after-shampoo hair conditioners |
US4149551A (en) * | 1977-03-28 | 1979-04-17 | The Procter & Gamble Company | Method of conditioning hair using a flexible substrate |
US4261869A (en) * | 1977-07-01 | 1981-04-14 | Lever Brothers Company | Detergent compositions |
US4220167A (en) * | 1978-06-05 | 1980-09-02 | Helene Curtis Industries, Inc. | Method of restoring normal moisture level to hair with slight to moderate moisture deficiency |
US4374125A (en) * | 1978-06-05 | 1983-02-15 | Helene Curtis Industries, Inc. | Hair moisturizing compositions |
US4220166A (en) * | 1978-06-05 | 1980-09-02 | Helene Curtis Industries, Inc. | Method of restoring normal moisture level to hair with severe moisture deficiency |
US4220168A (en) * | 1978-06-05 | 1980-09-02 | Helene Curtis Industries, Inc. | Method of moisturizing and maintaining normal moisture level in hair having a normal moisture content |
US4548810A (en) * | 1979-05-03 | 1985-10-22 | Albert Zofchak | Method of lubricating the skin |
US4464273A (en) * | 1982-02-10 | 1984-08-07 | Lever Brothers Company | Fabric softening composition |
US4464272A (en) * | 1982-02-10 | 1984-08-07 | Lever Brothers Company | Fabric softening composition |
US4534877A (en) * | 1982-07-30 | 1985-08-13 | The Procter & Gamble Company | Shampoo compositions comprising specific betaine surfactants and a quaternary compound |
US4636329A (en) * | 1983-06-22 | 1987-01-13 | The Procter & Gamble Company | Shampoo compositions comprising quaternary imidazolinium compound and alkylamido betaine having low pH range |
US4537762A (en) * | 1983-11-14 | 1985-08-27 | Bernel Chemical Co. | Hair compositions containing mixtures of quaternary ammonium compounds and tertiary amine salts of long-chain acids |
US4749411A (en) * | 1986-03-14 | 1988-06-07 | M. D. Stetson Company | Disinfecting and high-speed buffing composition comprising polyethylene glycol and quaternary ammonium germicide, and method of use |
US4917842A (en) * | 1988-02-12 | 1990-04-17 | The Standard Oil Company | Process of making ceramics |
US5066743A (en) * | 1989-03-27 | 1991-11-19 | Loctite Corporation | Two-part composition comprising a cyanoacrylate adhesive and a primer comprising a tertiary ammonium carboxylate compound |
US4979993A (en) * | 1989-03-27 | 1990-12-25 | Loctite Corporation | Trialkylammonium alkyl carboxylate primer for cyanoacrylate bonding of polymeric substrates |
US4986983A (en) * | 1989-04-03 | 1991-01-22 | Revlon, Inc. | Superfatted betaine and zwitterionic hair and skin conditioner compositions |
US5034218A (en) * | 1990-07-13 | 1991-07-23 | Helene Curtis, Inc. | Stable conditioning shampoo containing compatible anionic surfactant/cationic conditioning agent-non-volatile silicone emulsion |
US5078990A (en) * | 1990-07-13 | 1992-01-07 | Helene Curtis, Inc. | Shampoos and conditioning shampoos having increased capacity for incorporation of conditioning agents and removal of hair soil |
WO1992005234A1 (en) * | 1990-09-21 | 1992-04-02 | The Procter & Gamble Company | Cleansing compositions |
US5334376A (en) * | 1993-08-13 | 1994-08-02 | Colgate-Palmolive Company | Compositions for conditioning hair |
US5733536A (en) * | 1995-06-05 | 1998-03-31 | Whitehill Oral Technologies, Inc. | Ultramulsion based hair care compositions |
US20030125212A1 (en) * | 2000-04-10 | 2003-07-03 | Katsuhiko Yamaguchi | Wetting agent composition for agricultural chemicals |
US8277788B2 (en) | 2005-08-03 | 2012-10-02 | Conopco, Inc. | Quick dispersing hair conditioning composition |
Also Published As
Publication number | Publication date |
---|---|
GB1410789A (en) | 1975-10-22 |
AU467621B2 (en) | 1975-12-04 |
FR2158383B1 (en, 2012) | 1975-11-07 |
FR2158383A1 (en, 2012) | 1973-06-15 |
DE2252669A1 (de) | 1973-05-10 |
AU4832372A (en) | 1974-05-02 |
ES408173A1 (es) | 1975-11-16 |
JPS519012B2 (en, 2012) | 1976-03-23 |
JPS4852947A (en, 2012) | 1973-07-25 |
IT1001509B (it) | 1976-04-30 |
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