US3807965A - Contact material for vacuum switch of wc with co-cu binder and method of making - Google Patents

Contact material for vacuum switch of wc with co-cu binder and method of making Download PDF

Info

Publication number
US3807965A
US3807965A US00338568A US33856873A US3807965A US 3807965 A US3807965 A US 3807965A US 00338568 A US00338568 A US 00338568A US 33856873 A US33856873 A US 33856873A US 3807965 A US3807965 A US 3807965A
Authority
US
United States
Prior art keywords
tungsten carbide
contact material
percent
set forth
vacuum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00338568A
Other languages
English (en)
Inventor
K Tazaki
K Nagami
H Shinohara
A Kikuchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuji Electric Co Ltd
Original Assignee
Fuji Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Electric Co Ltd filed Critical Fuji Electric Co Ltd
Application granted granted Critical
Publication of US3807965A publication Critical patent/US3807965A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/0203Contacts characterised by the material thereof specially adapted for vacuum switches
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/067Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds comprising a particular metallic binder
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/021Composite material
    • H01H1/023Composite material having a noble metal as the basic material
    • H01H1/0233Composite material having a noble metal as the basic material and containing carbides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9265Special properties
    • Y10S428/929Electrical contact feature

Definitions

  • a contact material for a vacuum switch having a composition comprising from 50 to 75 percent of tungsten carbide, from 0.3 to 5 percent of cobalt, and a remainder of copper, said tungsten carbide having a finely pulverized structure of a grain size of less than 1.2 microns.
  • W-Cu alloys can be used as contacts in vacuum switches, and that contacts made of these alloys exhibit high resistance against welding of the contacts. It is also found that the contacts made of such materials can minimize the erosion of the contacts due to arcing in the vacuum switch.
  • the tungsten-copper alloys have advantageous features as described above, the material has a drawback in that its so-called chopping level is considerably high.
  • W-Cu alloys containing bismuth have been proposed.
  • the W-Cu- Bi alloys were found to be inferior in workability in brazing.
  • a primary object of the present invention is to provide a contact material to be used in a vacuum switch, which is operable with high reliability and has a low chopping level.
  • Another object of the invention is to provide a contact material for a vacuum switch, which has a minimumrange of variation in the chopping level.
  • Still another object of the invention is to provide a contact material for a vacuum switch, wherein the value of current above which the contacts tend to be welded is comparable to those in the W-Cu alloys.
  • a contact material for a vacuum switch at a composition comprising from 50 to 75 percent of tungsten carbide, from 0.3 to 5 percent of cobalt, and a remainder of copper, said tungsten carbide having a minute pulverized structure of less than 1.2 microns.
  • the present invention contemplates the provision of a contact material for a vacuum switch of greater capacities than 10 MVA at 3.3 KV, whereby the composition of the WC-Co-Cu alloy according to the present invention is adapted to be used for such an application.
  • Pulverized tungsten carbide of approximately 1.2 microns in grain size was molded under a pressure of 0. l 5
  • the percentage of voids in the presintered material was 55 percent by volume.
  • the material was thereafter impregnated with 2 percent of Co-Cu alloy in vacuum at 1,300C.
  • the material thus obtained was machined into contacts of approximately 24 mm in diameter, and
  • the chopping level of the contacts was 3.5A, and the interruptable current was more than 4.8 KA.
  • the contacts were not fused toelectricalperformancetests were carried out theregi gether under a current of 20KA flowing therethrougl EXAMPLE 2.
  • Tungsten carbide powder of 0.7-micron grain size with the material according to the present invention. and cobalt powder of 2-micron gram size were mixed Table Composition Grain size lnterruptable Chopping Gas content by weight) of WC (or W) Current level As will be apparent from the above table, the interruptable current increases when cobalt is added, when the percentage of tungsten carbide becomes low, or
  • the resulting mixture was press-formed under a pressure of 0.2 ton/cm and presintered in vacuum at 1,300C.
  • the eentie of voids of the presintered material was 42 percent by volume.
  • the presintered material was impregnated with Cu at l,300C in vacuum.
  • the contact material thus obtained was formed into contacts as described in Example I, and electrical performance tests were carried out thereon. As a result, the chopping level was found to be 2.6A, the interruptable current was 4.5 KA, and the current fusing the contacts together was found to be 30 KA.
  • finely pulverized tungsten carbide is used as the principal component, to which an appropriate amount of Co-Cu alloy is added, and the resulting mixture is formed into desired contacts, whereby interrupters and circuit breakers of high performance and reliability can be produced.
  • a contact material for a vacuum switch consisting essentially of from about 50 to 75 percent of tungsten carbide having a finely pulverized structure of a grain size of less than 1.2 microns, from 0.3 to 5 percent of cobalt, and a remainder of copper.
  • a method of producing a contact material for a vacuum switch in which a component of tungsten carbide having a finely pulverized structure of a grain size of less than 1.2 microns is press-formed and presintered into a porous structure, which is thereafter impregnated with another components of Co-Cu alloy, the ratio in amount of said components being from about 50 to percent of tungsten carbide, from 0.3 to 5 percent of cobalt, and a remainder of copper.
  • a method of producing a contact material for a vacuum switch in which a component of tungsten carbide having a finely pulverized structure of grain size of less than 1.2 microns is mixed with a component of cobalt to form a mixture thereof, then press-formed and presintered into a porous structure, and is thereafter impregnated with a component of copper, the ratio of said components being from about 50 to 75 percent of tungsten carbide, from 0.3 to 5 percent of cobalt, and a remainder of copper.
US00338568A 1972-03-07 1973-03-06 Contact material for vacuum switch of wc with co-cu binder and method of making Expired - Lifetime US3807965A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP47023320A JPS5140940B2 (ja) 1972-03-07 1972-03-07

Publications (1)

Publication Number Publication Date
US3807965A true US3807965A (en) 1974-04-30

Family

ID=12107281

Family Applications (1)

Application Number Title Priority Date Filing Date
US00338568A Expired - Lifetime US3807965A (en) 1972-03-07 1973-03-06 Contact material for vacuum switch of wc with co-cu binder and method of making

Country Status (2)

Country Link
US (1) US3807965A (ja)
JP (1) JPS5140940B2 (ja)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4514321A (en) * 1983-08-25 1985-04-30 E. I. Du Pont De Nemours And Company Thick film conductor compositions
US4540604A (en) * 1983-08-25 1985-09-10 E. I. Du Pont De Nemours And Company Thick film conductor compositions
WO1987002711A1 (en) * 1985-11-05 1987-05-07 Smith International, Inc. Tungsten carbide cobalt chip matrix, bearing material
US4933240A (en) * 1985-12-27 1990-06-12 Barber Jr William R Wear-resistant carbide surfaces
EP0488083A2 (en) * 1990-11-28 1992-06-03 Kabushiki Kaisha Toshiba Contact material for a vacuum interrupter
US5149362A (en) * 1988-08-19 1992-09-22 Kabushiki Kaisha Toshiba Contact forming material for a vacuum interrupter
US6461401B1 (en) * 1999-08-12 2002-10-08 Smith International, Inc. Composition for binder material particularly for drill bit bodies
CN111996432A (zh) * 2020-09-02 2020-11-27 四川大学 超粗硬质合金材料制备方法

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5218445A (en) * 1975-08-04 1977-02-12 Teikoku Sanso Kk Consumable electrode type arc welding equipment
JPS5521849A (en) * 1978-08-04 1980-02-16 Tokyo Shibaura Electric Co Electrode for gas switch
CN111411280A (zh) * 2020-03-03 2020-07-14 福达合金材料股份有限公司 一种铜碳化钨金刚石复合电触头材料及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1822426A (en) * 1929-09-27 1931-09-08 Firth Sterling Steel Co Composition of matter and method of making the same
GB459854A (en) * 1934-07-15 1937-01-13 Jean Mayor Process for the preparation by melting of moulded bodies of a difficultly fusible alloy, and a product obtained by this process
GB503995A (en) * 1937-04-02 1939-04-18 British Thomson Houston Co Ltd Improvements in and relating to hard alloys
US3301673A (en) * 1964-04-24 1967-01-31 Exxon Production Research Co Liquid phase sintering process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1822426A (en) * 1929-09-27 1931-09-08 Firth Sterling Steel Co Composition of matter and method of making the same
GB459854A (en) * 1934-07-15 1937-01-13 Jean Mayor Process for the preparation by melting of moulded bodies of a difficultly fusible alloy, and a product obtained by this process
GB503995A (en) * 1937-04-02 1939-04-18 British Thomson Houston Co Ltd Improvements in and relating to hard alloys
US3301673A (en) * 1964-04-24 1967-01-31 Exxon Production Research Co Liquid phase sintering process

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4514321A (en) * 1983-08-25 1985-04-30 E. I. Du Pont De Nemours And Company Thick film conductor compositions
US4540604A (en) * 1983-08-25 1985-09-10 E. I. Du Pont De Nemours And Company Thick film conductor compositions
WO1987002711A1 (en) * 1985-11-05 1987-05-07 Smith International, Inc. Tungsten carbide cobalt chip matrix, bearing material
US4933240A (en) * 1985-12-27 1990-06-12 Barber Jr William R Wear-resistant carbide surfaces
US5149362A (en) * 1988-08-19 1992-09-22 Kabushiki Kaisha Toshiba Contact forming material for a vacuum interrupter
EP0488083A2 (en) * 1990-11-28 1992-06-03 Kabushiki Kaisha Toshiba Contact material for a vacuum interrupter
EP0488083A3 (en) * 1990-11-28 1993-04-14 Kabushiki Kaisha Toshiba Contact material for a vacuum interrupter
US5420384A (en) * 1990-11-28 1995-05-30 Kabushiki Kaisha Toshiba Contact material for a vacuum interrupter
US6461401B1 (en) * 1999-08-12 2002-10-08 Smith International, Inc. Composition for binder material particularly for drill bit bodies
CN111996432A (zh) * 2020-09-02 2020-11-27 四川大学 超粗硬质合金材料制备方法
CN111996432B (zh) * 2020-09-02 2021-02-12 四川大学 超粗硬质合金材料制备方法

Also Published As

Publication number Publication date
JPS5140940B2 (ja) 1976-11-06
JPS4891596A (ja) 1973-11-28

Similar Documents

Publication Publication Date Title
US3807965A (en) Contact material for vacuum switch of wc with co-cu binder and method of making
US4743718A (en) Electrical contacts for vacuum interrupter devices
US3385677A (en) Sintered composition material
US4640999A (en) Contact material of vacuum interrupter and manufacturing process therefor
EP0031159B1 (en) Electrical contact
US4299889A (en) Contact for vacuum interrupter
US4147909A (en) Sintered composite material as contact material for medium-voltage vacuum power circuit breakers
US2664618A (en) Electrical contact
US6027821A (en) Contact material for vacuum interrupter and method for producing the same
US3819897A (en) Vacuum switch with contact material containing a minor percentage of aluminum
US2818633A (en) Electrical contact
US2180826A (en) Electric contact
JPS6059691B2 (ja) 真空しや断器用接点及びその製造方法
US3669634A (en) Metal composites
EP0460680A2 (en) Contact for a vacuum interrupter
US2300558A (en) Contact alloys
US4784829A (en) Contact material for vacuum circuit breaker
US3128540A (en) Electrical contact
JPS5914218A (ja) 真空しや断器用接点材料
CA1082268A (en) Contact alloy for a vacuum circuit breaker
JP3790055B2 (ja) 真空バルブ用接点材料
SU561459A1 (ru) Материал дл контактов вакуумных выключателей
JPH04132127A (ja) 真空バルブ用接点
JPS6196621A (ja) 真空しや断器接触子の製造方法
KR0171607B1 (ko) 진공회로 차단기용 전극 및 진공회로 차단기