US3789647A - Method of surface-conditioning heat-treating-furnace hearth rolls having sleeves of rebonded fused silica thereon by processing silicon steel strip - Google Patents

Method of surface-conditioning heat-treating-furnace hearth rolls having sleeves of rebonded fused silica thereon by processing silicon steel strip Download PDF

Info

Publication number
US3789647A
US3789647A US00299533A US3789647DA US3789647A US 3789647 A US3789647 A US 3789647A US 00299533 A US00299533 A US 00299533A US 3789647D A US3789647D A US 3789647DA US 3789647 A US3789647 A US 3789647A
Authority
US
United States
Prior art keywords
furnace
steel strip
strip
rolls
silicon steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00299533A
Other languages
English (en)
Inventor
J Milberger
J Hamilton
J Jenks
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
United States Steel Corp
Original Assignee
United States Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United States Steel Corp filed Critical United States Steel Corp
Application granted granted Critical
Publication of US3789647A publication Critical patent/US3789647A/en
Assigned to USX CORPORATION, A CORP. OF DE reassignment USX CORPORATION, A CORP. OF DE MERGER (SEE DOCUMENT FOR DETAILS). Assignors: UNITED STATES STEEL CORPORATION (MERGED INTO)
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/54Furnaces for treating strips or wire
    • C21D9/56Continuous furnaces for strip or wire
    • C21D9/562Details
    • C21D9/563Rolls; Drums; Roll arrangements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49544Roller making

Definitions

  • ABSTRACT Primary Examiner-Hyland Bizot Assistant ExaminerW. R. Satterfield Attorney, Agent, or Firm-Donald S. Ferito 5 7] ABSTRACT Generally, the method of the invention involves surface-conditioning new and used rebonded fused silica sleeved hearth rolls of a continuous silicon steel strip heat-treating furnace while the furnace is in production Operation.
  • Method consists of scheduling the furnace, when new rolls are to be conditioned, to process silicon steel strip product requiring dry annealing in an atmosphere having a maximum dew point of 30F at a temperature the range of approximately 1,400 to 2,000F (preferably 1,500F) and processing such silicon steel strip through the furnace with the strip applying a Sustained force normal to the peripheral surfaces of the rolls for a period of 24 to 72 hours.
  • used rolls are surface-conditioned to remove oxide roll-pickup by scheduling the processing of silicon strip product having rough surfaces through the furnace which requires a dry anneal in an atmosphere having a maximum dew point of 30F at a temperature ranging from 1,400 to 2,000F (preferably 1,500F) and processing such Strip through the furnace for approximately 16 hours.
  • the present invention relates generally to the heat treating of steel strip and more particularly to a method of surface-conditioning rolls having sleeves thereon of rebonded fused silica especially suitable for use in continuous silicon steel strip heat-treating furnaces.
  • Steel strip can be annealed in either coil form, commonly referred to as batch annealing or by passing the uncoiled strip through a continuous annealing furnace.
  • the present invention addresses itself to the continuous annealing of steel strip.
  • Continuous annealing furnaces are of two types, namely, vertical or horizontal. Vertical or horizontal refers to the strip alignment in the furnace during the heat treatment operation. The major affect on product quality in comparing the two types is the capability of the horizontal furnace to produce a stress-free strip product.
  • a typical horizontal continuous heat-treating furnace roller hearth line consists of an entry section including coil-payoff reels, strip welder, horizontal looping equipment, electrolytic cleaning, scrubbing and drying units.
  • the entry section is joined to a contiguous horizontal heat-treating section consisting of a gas-fired heating zone (72 feet long), and an electrically-heated holding zone (600 feet long), a controlled cooling zone (200 feet long), and a jet-cooling zone (90 feet long).
  • the dimensions cited pertain to a typical unit now in operation. The dimensions are stated to illustrate 'the comparative lengths of the various elements of a typical horizontal continuous annealing furnace. These dimensions may vary as desired or necessary.
  • the exit section of the furnace consists of a horizontal looping unit and tension reel.
  • the strip is supported as it passes through the heat-treating, section of the furnace in catenary fashion by individually-motor-driven alloy steel rolls having sleeves of rebonded fused silica thereon.
  • This type of roll is described and claimed in pending US patent application Ser. No. 172,947, now US. Pat. No. 3,75 1,195, which is assigned to the assignee of the present application.
  • oxides of silicon and carbon are given off as gases (C0, C while the silicon oxide (SiO is retained on the strip surface.
  • This silicon oxide is very much like a thin glass coating which is in a viscous state. Small portions of this oxide are sometimes picked up from the steel strip by the roll sleeve surfaces at various points on the periphery thereof. This spotty buildup on the roll sleeve surfaces causes a depression or dimple to form on strip subsequently passing over the roll surface. Such depressions or dimples are particularly objectionable on silicon steel strip since a major end use of this product is the forming of stator and rotor laminations of electrical equipment or devices.
  • a specific number of laminations is required, for example, for building up the armature of an electric motor in order to attain certain desired electrical characteristics. Specifically, a fixed number of laminationsis required for each lineal inch of cross section of the armature in order to attain certain electrical characteristics. Therefore, distortions of the surface of silicon steel strip used for making these laminations cannot be tolerated.
  • the susceptibility of silicon steel strip to surface deformation or marking is related to its silicon content.
  • Low silicon steel strip one-half to 1% silicon content
  • medium silicon steel strip (1 to 3% silicon content) has a lesser, but still objectionable, susceptibility to surface marking and deformation
  • high silicon steel strip (above 3% silicon content) has the greatest resistance to surface marking or deformation by roll-pickup accretions on annealing furnace rolls.
  • the amount of roll-pickup and subsequent strip marking has been found to be related to annealing temperature and moisture content of the atmosphere in the continuous annealing furnace.
  • a normal operating cycle to anneal silicon strip in a typical horizontal continuous annealing furnace would be in a range of 1 ,400 to 2,000lF with steam being introduced in the electrically-heated holding zone to decarburize the strip.
  • a normal decarburization atmosphere would have a minimum F dew point.
  • high silicon approximately 3% silicon content
  • Such a fast oxide pickup occurs because of the surface condition of the sleeves of the newly manufactured or newly ground rolls.
  • the roll sleeves not only have grinding marks resulting from the pre-service conditioning of the sleeve surface, but the nature of the rebonded fused silica surface is such that it is also somewhat porous. Therefore, if the fresh roll is initially exposed to conditions of high temperature and high dew point, the glutinous oxide produced on the silicon strip being heat treated is picked up in the sleeve pores and the imperfections resulting from pre-service surfaceconditioning. Although the amounts of oxide pickup are minute, the oxide penetrates the porous surfaces of the sleeves and then serve as a base for further cumulative pickup. The sleeved roll must, therefore, be initially conditioned to form a compact peripheral surface which will not readily permit oxide adherence.
  • the method of our invention utilizes the normal catenary disposition of the strip between hearth rolls to an advantage.
  • the weight of the strip while operating in the dry annealing atmosphere applies a sustained force normal to the peripheral surface of the roll which. results in a polished peripheral surface on the sleeved roll which is essentially free of pores which, if present, would later attract strip oxides.
  • the annealing line will operate free of oxide pickup for at least fourteen days.
  • This modified embodiment of the invention includes two alternatives depending upon the severity of oxide pickup on the rolls.
  • the first alternative comprises scheduling the annealing furnace to anneal high silicon (3% or more silicon content, by weight) strip which has'been previously box annealed at high temperature.
  • a coating of magnesium oxide is applied to the strip prior to box annealing to prevent spot welding of concentric wraps of the strip coil at the high temperature used during box annealing.
  • the magnesium in this coating and the silicon in the strip combine to form a magnesium silicate on the strip surface. This magnesium silicate imparts an abrasive surface to the strip. Processing this type of silicon strip through the annealing furnace for approximately sixteen hours at a low temperature of approximately 1,500F and in a dry atmosphere (30F maximum dew point) will effectively remove oxide pickup from the hearth rolls with no detrimental effect on productivity.
  • the furnace could be scheduled to process high silicon strip which has been given a rough temper mill finish during its previous processing.
  • a method for surface-conditioning newly installed continuous silicon steel strip heat-treating-furnace rolls having sleeves of rebonded fused silica thereon during production operation of said furnace which comprises the step of processing production silicon steel strip through said furnace in a relativelydry atmosphere having a maximum dew point of approximately 30F at a temperature in the range of substantially l,400 to 2,000F for a period of approximately 24 to 72 hours with the weight of said silicon steel strip applying a sustained force normal to the peripheral surfaces of said rolls whereby a polished surface free of pores is produced on said furnace rolls.
  • a method for removing roll-pickup fron continuous silicon steel strip heat-treating-furnace rolls having sleeves of rebonded fused silica thereon during production operation of said furnace which comprises the step of processing rough-surfaced silicon steel strip through said furnace in a relatively dry atmosphere having a maximum dew point of approximately 30F at a temperature in the range of substantially 1,400" to 2,000F for a period of approximately 16 hours with the weight of said silicon steel strip applying a sustained force normal to the peripheral surfaces of said rolls whereby a polished surface free of roll-pickup is produced on said furnace rolls.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Manufacturing Of Steel Electrode Plates (AREA)
  • Heat Treatments In General, Especially Conveying And Cooling (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Rolls And Other Rotary Bodies (AREA)
US00299533A 1972-10-20 1972-10-20 Method of surface-conditioning heat-treating-furnace hearth rolls having sleeves of rebonded fused silica thereon by processing silicon steel strip Expired - Lifetime US3789647A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US29953372A 1972-10-20 1972-10-20

Publications (1)

Publication Number Publication Date
US3789647A true US3789647A (en) 1974-02-05

Family

ID=23155223

Family Applications (1)

Application Number Title Priority Date Filing Date
US00299533A Expired - Lifetime US3789647A (en) 1972-10-20 1972-10-20 Method of surface-conditioning heat-treating-furnace hearth rolls having sleeves of rebonded fused silica thereon by processing silicon steel strip

Country Status (10)

Country Link
US (1) US3789647A (cs)
JP (1) JPS5858408B2 (cs)
BG (1) BG21376A3 (cs)
CA (1) CA992439A (cs)
DE (1) DE2352611C2 (cs)
FR (1) FR2208982B1 (cs)
GB (1) GB1450957A (cs)
IT (1) IT998803B (cs)
RO (1) RO67729A (cs)
YU (1) YU273573A (cs)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4000015A (en) * 1975-05-15 1976-12-28 Allegheny Ludlum Industries, Inc. Processing for cube-on-edge oriented silicon steel using hydrogen of controlled dew point
CN103320737A (zh) * 2013-06-26 2013-09-25 上海大学 热浸镀硅法制备高硅硅钢薄带的方法及硅钢带连续制备装置

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115323126B (zh) * 2022-07-27 2023-05-23 攀钢集团西昌钢钒有限公司 快速减轻连续退火炉炉辊结瘤及延长其使用周期的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3130094A (en) * 1959-06-11 1964-04-21 Armco Steel Corp Manufacture of silicon-iron having cubic texture
US3333579A (en) * 1964-06-29 1967-08-01 Reynolds Metals Co Formation of low friction glass-like surface on aluminum silicon alloy for engine operation

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3130094A (en) * 1959-06-11 1964-04-21 Armco Steel Corp Manufacture of silicon-iron having cubic texture
US3333579A (en) * 1964-06-29 1967-08-01 Reynolds Metals Co Formation of low friction glass-like surface on aluminum silicon alloy for engine operation

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4000015A (en) * 1975-05-15 1976-12-28 Allegheny Ludlum Industries, Inc. Processing for cube-on-edge oriented silicon steel using hydrogen of controlled dew point
CN103320737A (zh) * 2013-06-26 2013-09-25 上海大学 热浸镀硅法制备高硅硅钢薄带的方法及硅钢带连续制备装置
CN103320737B (zh) * 2013-06-26 2016-01-13 上海大学 热浸镀硅法制备高硅硅钢薄带的方法及硅钢带连续制备装置

Also Published As

Publication number Publication date
YU273573A (en) 1982-02-28
IT998803B (it) 1976-02-20
DE2352611A1 (de) 1974-05-02
GB1450957A (en) 1976-09-29
FR2208982A1 (cs) 1974-06-28
CA992439A (en) 1976-07-06
DE2352611C2 (de) 1985-06-27
RO67729A (ro) 1980-04-15
FR2208982B1 (cs) 1976-05-14
JPS4999922A (cs) 1974-09-20
JPS5858408B2 (ja) 1983-12-24
BG21376A3 (bg) 1976-05-20

Similar Documents

Publication Publication Date Title
US2867557A (en) Method of producing silicon steel strip
US3941623A (en) Method for producing a grain-oriented electrical steel sheet using separators comprising metal nitrides
US3789647A (en) Method of surface-conditioning heat-treating-furnace hearth rolls having sleeves of rebonded fused silica thereon by processing silicon steel strip
US3180767A (en) Process for making a decarburized low carbon, low alloy ferrous material for magnetic uses
US2113537A (en) Method of rolling and treating silicon steel
HU177279B (en) Process for producing boron-doped silicon steel having goss-texture
US4213804A (en) Processing for cube-on-edge oriented silicon steel
JPS58120733A (ja) 電磁鋼板の連続焼鈍方法
JPS5846531B2 (ja) 無方向性電磁鋼帯の製造方法
RU2002820C1 (ru) Способ производства анизотропной электротехнической стали
US2283109A (en) Bluing steel
KR100347575B1 (ko) 마르텐사이트발생을억제하기위한고탄소선재의단계냉각법
US3830023A (en) Dry descaling
JPS5922771B2 (ja) 繰返し曲げ特性の優れた方向性珪素鋼板の製造方法
JPS5830936B2 (ja) 繰返し曲げ特性の優れた方向性珪素鋼板の製造方法
US3228810A (en) Method for producing highly ductile metallic coated ferrous sheet and strip
JPS60221521A (ja) 一方向性珪素鋼板の仕上焼鈍方法
JPS6372832A (ja) 成形性の良い酸化皮膜を有するオイルテンパ−線の製造方法
US1873659A (en) Process of treating silicon steel
JPS6253578B2 (cs)
JPS63190123A (ja) シヤフト用ステンレス鋼線の製造方法
JPS5852009B2 (ja) 磁性金属線の連続焼鈍方法
JPS61243124A (ja) 加工性にすぐれたぶりき原板の製造方法
RU2203967C2 (ru) Способ производства анизотропной электротехнической стали
JPS6315328B2 (cs)

Legal Events

Date Code Title Description
AS Assignment

Owner name: USX CORPORATION, A CORP. OF DE, STATELESS

Free format text: MERGER;ASSIGNOR:UNITED STATES STEEL CORPORATION (MERGED INTO);REEL/FRAME:005060/0960

Effective date: 19880112