US3773502A - Aluminum-zinc-alloy - Google Patents
Aluminum-zinc-alloy Download PDFInfo
- Publication number
- US3773502A US3773502A US00094175A US3773502DA US3773502A US 3773502 A US3773502 A US 3773502A US 00094175 A US00094175 A US 00094175A US 3773502D A US3773502D A US 3773502DA US 3773502 A US3773502 A US 3773502A
- Authority
- US
- United States
- Prior art keywords
- aluminum
- alloy
- zinc
- manganese
- hardness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001297 Zn alloy Inorganic materials 0.000 title claims abstract description 15
- 239000011701 zinc Substances 0.000 claims abstract description 22
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 19
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 19
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000010949 copper Substances 0.000 claims abstract description 16
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 16
- 239000011572 manganese Substances 0.000 claims abstract description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052802 copper Inorganic materials 0.000 claims abstract description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 13
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 8
- 239000011651 chromium Substances 0.000 claims abstract description 8
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 7
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 49
- 239000000956 alloy Substances 0.000 abstract description 49
- 239000000463 material Substances 0.000 abstract description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 7
- 238000005266 casting Methods 0.000 abstract description 6
- 230000002045 lasting effect Effects 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 238000004898 kneading Methods 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 238000000137 annealing Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 238000007493 shaping process Methods 0.000 description 6
- FJMNNXLGOUYVHO-UHFFFAOYSA-N aluminum zinc Chemical group [Al].[Zn] FJMNNXLGOUYVHO-UHFFFAOYSA-N 0.000 description 4
- 239000001996 bearing alloy Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 229910000951 Aluminide Inorganic materials 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 229910000746 Structural steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000007712 rapid solidification Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/10—Alloys based on aluminium with zinc as the next major constituent
Definitions
- ALUMINUM-ZINC-ALLOY Inventors: Gilbert l-lorvath, Linz, Austria;
- the invention relates to an aluminum-zinc-alloy consisting of 50 to 75 aluminum, 0.3 to 1.5 manganese and, if desired, copper, nickel, silicium, lithium and chromium, remainder zinc.
- these new alloys are provided with an increased red hardness, high load sustaining capacity at sliding movement, lasting accuracy to gauge, high mechanical strength, adequate resistance to corrosion, essentially increased resistance to creeping, increased applicability as casting and kneading material, and may be hot shaped at high working speeds with temperatures of the range 275 to 450 C.
- the invention relates to an aluminum-zinc-alloy containing manganese and, if desired, further alloy elements such as copper, nickel, silicium, lithium and chromium.
- Aluminum-zinc-alloys consisting of aluminum and zinc in various contents, manganese and, if desired, further alloy elements, which are used as materials for slide bearings are already known.
- the invention is aimed at avoiding the described disadvantages and difficulties by creating an alloy which unites the following properties: increased red hardness (that is, hardness at elevated temperatures) as compared to known bearing alloys on aluminum-zinc-basis, high load sustaining capacity at sliding movement, lasting accuracy to gauge, high mechanical strength, adequate resistance to corrosion, essentially increased resistance to creeping as compared to known aluminumzinc bearing alloys, increased applicability both as material for casting and kneading (re-shaping operations). Further, the alloy should be hot shapeable at high working speeds, similar as this is the case with bronzes.
- the alloy according to the invention with which these aims are reached is an aluminum-zinc-alloy containing 50 to 75 preferably 55 to 65 aluminum, 0.3 to l .5 preferably 0.5 to 0.8 manganese, and, if desired,
- This alloy differs from other known alloys having a comparably high aluminum content in that its manganese content is limited at a maximum of
- the effect of the manganese content in the aluminum-zinc-alloy is based on the high inclination of the aluminum-zinc solid solution to be oversaturated with manganese during the rapid solidification under normal production conditions (particularly chill casting). Owing to this capacity (of the aluminum-zinc solid solution) to be oversaturated, it is e.g. effected that the manganese remains in solution but only to a particular, low percentage which again depends on the content of other alloy elements and does not form hard aluminides.
- manganese increase of tensile strength, yield point, elongation, resistance to wear, red hardness and resistance to corrosion.
- the manganese addition within the limits according to the invention furnishes an alloy on aluminum-zinc-basis with properties which are otherwise not obtainable or only with essentially more expensive alloys. Owing to the high content of aluminum of the alloy according to the invention and the therefore only very small change in volume during the eutectic transformation of the aluminumzinc mixed crystal it is possible and advantageous to carry out heat treatments also above a temperature of 275 C without the occurrence of an embrittlement in the material.
- the copper content of the alloy according to the invention may amount to up to 3
- the nickel content of the alloy according to the invention may amount to up to 1
- the silicium content of the alloy according to the invention may amount to up to 0.6
- the lithium content of the alloy according to the invention may amount to up to 0.1
- the chromium content of the alloy according to the invention may amount to up to 0.5
- a preferred embodiment for producing shaped bodies from alloys of the described kind by hot shaping resides in that a shaping temperature of 275 to 450 C, preferably of 330 to 350 C, is applied. Owing to the higher temperature for hot shaping it is possible to work with an essentially higher shaping speed than may be employed with known alloys. Shaping may also be effected by extrusion, traction and rolling.
- the shaped bodies may also be produced from the described alloys by casting and subsequent heat treatment, the heat treatment being carried out at a temperature of 290 to 380 C, preferably 330 to 350 C.
- the duration of the heat treatment may amount to several hours up to 48 hours.
- an alloy of the following composition is produced which is used for manufacturing a bearing bushing with an inner diameter of 30 mm and an outer diameter of 40 mm.
- the alloy is composed of:
- composition of an alloy is the following:
- composition of an alloy is the following:
- composition of an alloy is the following:
- composition of an alloy is the following:
- composition of an alloy is the following:
- the mechanical data of the alloy in the as-cast condition are the following:
- composition of an alloy is the following:
- manganese content amounts to from 0.5 to
- OHM PC4050 uscoMM-oc 60376-P69 9 U.S. GOVERNMENT fIUNTING OFFICE II! O3-33l.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Sliding-Contact Bearings (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT1127269A AT294439B (de) | 1969-12-03 | 1969-12-03 | Aluminium-Zink-Legierung |
Publications (1)
Publication Number | Publication Date |
---|---|
US3773502A true US3773502A (en) | 1973-11-20 |
Family
ID=3627799
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00094175A Expired - Lifetime US3773502A (en) | 1969-12-03 | 1970-12-01 | Aluminum-zinc-alloy |
Country Status (15)
Country | Link |
---|---|
US (1) | US3773502A (en)) |
JP (1) | JPS512408B1 (en)) |
AT (1) | AT294439B (en)) |
BE (1) | BE759746A (en)) |
CH (3) | CH547863A (en)) |
DE (1) | DE2058212A1 (en)) |
DK (1) | DK141374B (en)) |
FR (1) | FR2072592A5 (en)) |
GB (1) | GB1328125A (en)) |
IL (1) | IL35776A (en)) |
LU (1) | LU62141A1 (en)) |
NL (1) | NL7017608A (en)) |
NO (1) | NO126032B (en)) |
SE (1) | SE357004B (en)) |
YU (1) | YU33810B (en)) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5133931A (en) * | 1990-08-28 | 1992-07-28 | Reynolds Metals Company | Lithium aluminum alloy system |
US5198045A (en) * | 1991-05-14 | 1993-03-30 | Reynolds Metals Company | Low density high strength al-li alloy |
CN101906562A (zh) * | 2010-08-20 | 2010-12-08 | 江油恒俊机电有限公司 | 高强度轻型耐磨高锌铝基轴承实体保持架材料 |
CN101985709A (zh) * | 2010-11-08 | 2011-03-16 | 西安晟金新材料科技有限公司 | 一种耐磨高锌铝基代青铜材料 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2616158B1 (fr) * | 1987-06-05 | 1990-10-19 | Pechiney | Alliage metallique a grand parametre de maille |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2166495A (en) * | 1936-12-15 | 1939-07-18 | Sumitomo Metal Ind | Aluminum alloys |
US2226594A (en) * | 1939-10-27 | 1940-12-31 | Aluminum Co Of America | Aluminum alloy |
US2870008A (en) * | 1954-11-18 | 1959-01-20 | Main Alloy Company Establishme | Zinc-aluminium alloys and the method for producing same |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE975916C (de) * | 1943-06-09 | 1962-12-06 | Fr Nielsen & Co G M B H | Verwendung von Aluminium-Zink-Legierungen |
-
1969
- 1969-12-03 AT AT1127269A patent/AT294439B/de not_active IP Right Cessation
-
1970
- 1970-11-18 SE SE15632/70A patent/SE357004B/xx unknown
- 1970-11-26 LU LU62141D patent/LU62141A1/xx unknown
- 1970-11-26 DE DE19702058212 patent/DE2058212A1/de active Pending
- 1970-11-27 FR FR7042864A patent/FR2072592A5/fr not_active Expired
- 1970-11-30 CH CH1442673A patent/CH547863A/xx not_active IP Right Cessation
- 1970-11-30 CH CH1769370A patent/CH545854A/xx not_active IP Right Cessation
- 1970-11-30 CH CH1442573A patent/CH547862A/xx not_active IP Right Cessation
- 1970-12-01 GB GB5710270A patent/GB1328125A/en not_active Expired
- 1970-12-01 US US00094175A patent/US3773502A/en not_active Expired - Lifetime
- 1970-12-02 JP JP45105974A patent/JPS512408B1/ja active Pending
- 1970-12-02 YU YU2921/70A patent/YU33810B/xx unknown
- 1970-12-02 NO NO4621/70A patent/NO126032B/no unknown
- 1970-12-02 BE BE759746D patent/BE759746A/xx not_active IP Right Cessation
- 1970-12-02 NL NL7017608A patent/NL7017608A/xx not_active Application Discontinuation
- 1970-12-02 IL IL35776A patent/IL35776A/en unknown
- 1970-12-03 DK DK616670AA patent/DK141374B/da unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2166495A (en) * | 1936-12-15 | 1939-07-18 | Sumitomo Metal Ind | Aluminum alloys |
US2226594A (en) * | 1939-10-27 | 1940-12-31 | Aluminum Co Of America | Aluminum alloy |
US2870008A (en) * | 1954-11-18 | 1959-01-20 | Main Alloy Company Establishme | Zinc-aluminium alloys and the method for producing same |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5133931A (en) * | 1990-08-28 | 1992-07-28 | Reynolds Metals Company | Lithium aluminum alloy system |
US5198045A (en) * | 1991-05-14 | 1993-03-30 | Reynolds Metals Company | Low density high strength al-li alloy |
CN101906562A (zh) * | 2010-08-20 | 2010-12-08 | 江油恒俊机电有限公司 | 高强度轻型耐磨高锌铝基轴承实体保持架材料 |
CN101985709A (zh) * | 2010-11-08 | 2011-03-16 | 西安晟金新材料科技有限公司 | 一种耐磨高锌铝基代青铜材料 |
CN101985709B (zh) * | 2010-11-08 | 2012-08-08 | 西安晟金新材料科技有限公司 | 一种耐磨高锌铝基代青铜材料 |
Also Published As
Publication number | Publication date |
---|---|
DK141374C (en)) | 1980-08-18 |
NO126032B (en)) | 1972-12-11 |
SE357004B (en)) | 1973-06-12 |
DE2058212A1 (de) | 1971-06-09 |
LU62141A1 (en)) | 1971-05-11 |
DK141374B (da) | 1980-03-03 |
CH547863A (de) | 1974-04-11 |
IL35776A0 (en) | 1971-02-25 |
BE759746A (fr) | 1971-05-17 |
NL7017608A (en)) | 1971-06-07 |
FR2072592A5 (en)) | 1971-09-24 |
YU33810B (en) | 1978-05-15 |
CH545854A (en)) | 1974-02-15 |
JPS512408B1 (en)) | 1976-01-26 |
CH547862A (de) | 1974-04-11 |
IL35776A (en) | 1973-08-29 |
AT294439B (de) | 1971-11-25 |
GB1328125A (en) | 1973-08-30 |
YU292170A (en) | 1977-10-31 |
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