US3756805A - Method of producing lead bead bearing steel - Google Patents
Method of producing lead bead bearing steel Download PDFInfo
- Publication number
- US3756805A US3756805A US00079529A US3756805DA US3756805A US 3756805 A US3756805 A US 3756805A US 00079529 A US00079529 A US 00079529A US 3756805D A US3756805D A US 3756805DA US 3756805 A US3756805 A US 3756805A
- Authority
- US
- United States
- Prior art keywords
- lead
- steel
- ladle
- stream
- bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 title abstract description 50
- 239000010959 steel Substances 0.000 title abstract description 50
- 238000000034 method Methods 0.000 title description 27
- 239000011324 bead Substances 0.000 title 1
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 abstract description 9
- 229910000464 lead oxide Inorganic materials 0.000 abstract description 8
- 230000008018 melting Effects 0.000 abstract description 8
- 238000002844 melting Methods 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 4
- 239000001301 oxygen Substances 0.000 abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 238000007599 discharging Methods 0.000 abstract description 2
- 239000002184 metal Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000005266 casting Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000005204 segregation Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000005587 bubbling Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000007970 homogeneous dispersion Substances 0.000 description 2
- 241000478574 Eleutherodactylus parabates Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 101100350775 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) prr-5 gene Proteins 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0037—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by injecting powdered material
- C21C7/0043—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by injecting powdered material into the falling stream of molten metal
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
Definitions
- the present invention relates to an improved method of making steel and a product produced thereby.
- the present invention relates particularly to the manufacture of lead-bearing steels, having a lead content of between 0.10 and 0.8% which is distributed finely and homogeneously throughout the entire mass of the steel.
- lead-bearing steels have a greater machinability, when worked on chip-producing machinetools, than steels of the same basic composition that do not contain lead.
- FIG. 1 is a schematic vertical longitudinal section through a melting furnace, a ladle and the means for adding the lead at the moment at which the metal is poured into the ladle and the addition of lead is made;
- FIG. 2 is a schematic vertical longitudinal section through the ladle showing one construction thereof according to the present invention of the ladle outlet;
- FIG. 3 is a schematic vertical longitudinal section through the ladle showing another ladle outlet construc tion.
- FIG. 1 there is shown a melting furnace 1, from which a stream of molten steel 2 passes from the melting furnace 1 to a ladle 3.
- a feed means 4 feeds a solid or liquid lead into a duct 5 which carries the lead to the molten stream of metal with which it joins up at point 6.
- the ladle outlet 7 is more particularly disclosed in FIGS. 2 and 3QFIG. 2 shows an arrangement in which a base 8 of the ladle has a projecting portion orupstanding rim9, whereby it israised above the opening ofitheladle outlet.
- FIG. 3 there is shownianotherarrangement in which a sleeve 7 defining the ladle outlethas one end thereof raised above theflatnbase 8 of the ladle.
- a plug 10 is providedforopening and closing the'ladle outlet:
- the lead-oxide formed has a low boiling point and causes bubbling of the steel bath which becomes saturated with this compound.
- Table No. 1 shows the solubility of lead-oxide as a function of the temperature of the bath, as established on the basis of numerous tests:
- the solubility of lead in steel is independent of the composition of the steel and is determined solely by temperature.
- the temperature at which the metal is poured into the ladle should be greater than 1600 C. and is governed by the percentage of lead required in the steel, as shown in Table No. 1.
- the quantity of lead added in solid or liquid form should be greater than that theoretically required, and preferably should be 40% greater than the quantity that it is desired to incorporate in the steel.
- the lead is added at the feed point via means 4 (FIG. 1) at a rate equal to that required at the upper part 6 of the stream of molten steel.
- the rate of supply of the lead needed at the feed point 4 in FIG. 1 can be determined by simple tests, the aim being to have a supply of solid or liquid lead reaching the stream of molten metal during practically the entire period during which pouring takes place. Nevertheless, the system does not call for a high degree of co-ordination in this operation, since, as previously indicated, if too much lead is added this does not become incorporated in the bath but is deposited on the base of the ladle.
- the method of the present invention does not require any high capital cost equipment.
- the only requirement is that of positioning the ladle outlet 7 or a rim 9 in such a way that it projects upward of or beyond the plane of the base 8 of the ladle 3, thus preventing the lead, deposited on the base, from being entrained by the stream of steel which emerges through the mouth-piece 7 when casting takes place.
- the method to which the present invention relates can be applied to all kinds of steel compositions and can be adopted in present-day steel-producing techniques.
- the method of the present invention can be used in all the usual steel-making processes, for example, Siemens- Martin, electric furnace, L.D., continuous casting, or mold-casting by the siphon or direct methods.
- ingots manufactured by the method of the present invention do not need to be end-cropped, as is the case with ingots manufactured by the classical methods.
- the lead particles form a fine, homogeneous dispersion, the grain-size of which is often less than one micron.
- a method of producing lead-bearing steel, containing a uniform distribution of lead comprising the steps of discharging a stream of molten steel from a melting furnace into a ladle,
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES376188A ES376188A1 (es) | 1970-02-03 | 1970-02-03 | Perfeccionamientos introducidos en el proceso de fabrica- cion de aceros. |
Publications (1)
Publication Number | Publication Date |
---|---|
US3756805A true US3756805A (en) | 1973-09-04 |
Family
ID=8455007
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00079529A Expired - Lifetime US3756805A (en) | 1970-02-03 | 1970-10-09 | Method of producing lead bead bearing steel |
Country Status (11)
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3917240A (en) * | 1971-08-02 | 1975-11-04 | Sumitomo Metal Ind | Apparatus for projecting pieces of a deoxidizing agent into molten steel |
US4203763A (en) * | 1977-12-21 | 1980-05-20 | Scandinavian Lancers Aktiebolag | Method of manufacturing a lead alloy steel and a steel made according to the method |
US4371395A (en) * | 1981-07-06 | 1983-02-01 | Southwire Company | Technique for adding lead to steel |
US4751047A (en) * | 1987-05-26 | 1988-06-14 | Nippon Steel Corporation | Method of adding low-melting-point metal to molten steel |
US4781887A (en) * | 1986-11-14 | 1988-11-01 | Nippon Steel Corporation | Production of steels containing low melting point metals |
US4849167A (en) * | 1988-03-18 | 1989-07-18 | Inland Steel Company | Method and appartus for adding liquid alloying ingredient to molten steel |
US4848755A (en) * | 1988-03-18 | 1989-07-18 | Inland Steel Company | Apparatus for adding liquid alloying ingredient to molten steel |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT345491B (de) * | 1976-12-10 | 1978-09-25 | Voest Ag | Einrichtung zur zugabe von zusatzstoffen in einen metallgiessstrahl |
DE2730045C2 (de) * | 1977-07-02 | 1984-11-08 | Krupp Stahl Ag, 4630 Bochum | Verfahren zum Herstellen verschleißbeständiger Schienen und/oder Radwerkstoffen |
FR3153592A1 (fr) | 2023-09-28 | 2025-04-04 | Saipem S.A. | Procédé de ballastage actif et centralisé d’un flotteur semi-submersible pour éolienne offshore et flotteur |
FR3153593A1 (fr) | 2023-09-28 | 2025-04-04 | Saipem S.A. | Procédé de ballastage actif et individualisé d’un flotteur semi-submersible pour éolienne offshore et flotteur |
-
1970
- 1970-02-03 ES ES376188A patent/ES376188A1/es not_active Expired
- 1970-03-17 DE DE19702012668 patent/DE2012668A1/de active Pending
- 1970-03-17 DE DE2065802*A patent/DE2065802A1/de active Pending
- 1970-05-28 GB GB2574570A patent/GB1311156A/en not_active Expired
- 1970-07-06 SE SE7009355A patent/SE382829B/xx unknown
- 1970-10-09 US US00079529A patent/US3756805A/en not_active Expired - Lifetime
-
1971
- 1971-01-22 AT AT53371A patent/AT322598B/de not_active IP Right Cessation
- 1971-01-26 LU LU62493D patent/LU62493A1/xx unknown
- 1971-02-02 NL NL7101331A patent/NL7101331A/xx unknown
- 1971-02-02 FR FR7103348A patent/FR2079204A1/fr not_active Withdrawn
- 1971-02-03 CH CH156271A patent/CH545855A/xx not_active IP Right Cessation
- 1971-02-03 BE BE762489A patent/BE762489A/xx not_active IP Right Cessation
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3917240A (en) * | 1971-08-02 | 1975-11-04 | Sumitomo Metal Ind | Apparatus for projecting pieces of a deoxidizing agent into molten steel |
US4203763A (en) * | 1977-12-21 | 1980-05-20 | Scandinavian Lancers Aktiebolag | Method of manufacturing a lead alloy steel and a steel made according to the method |
US4371395A (en) * | 1981-07-06 | 1983-02-01 | Southwire Company | Technique for adding lead to steel |
US4781887A (en) * | 1986-11-14 | 1988-11-01 | Nippon Steel Corporation | Production of steels containing low melting point metals |
US4751047A (en) * | 1987-05-26 | 1988-06-14 | Nippon Steel Corporation | Method of adding low-melting-point metal to molten steel |
US4849167A (en) * | 1988-03-18 | 1989-07-18 | Inland Steel Company | Method and appartus for adding liquid alloying ingredient to molten steel |
US4848755A (en) * | 1988-03-18 | 1989-07-18 | Inland Steel Company | Apparatus for adding liquid alloying ingredient to molten steel |
AU616921B2 (en) * | 1988-03-18 | 1991-11-14 | Inland Steel Company | Method and apparatus for adding liquid alloying ingredient to molten steel |
Also Published As
Publication number | Publication date |
---|---|
BE762489A (fr) | 1971-07-16 |
SE382829B (sv) | 1976-02-16 |
NL7101331A (enrdf_load_stackoverflow) | 1971-08-05 |
ES376188A1 (es) | 1972-03-16 |
DE2012668A1 (de) | 1971-08-12 |
DE2065802A1 (de) | 1976-03-11 |
CH545855A (enrdf_load_stackoverflow) | 1974-02-15 |
AT322598B (de) | 1975-05-26 |
LU62493A1 (enrdf_load_stackoverflow) | 1971-08-11 |
GB1311156A (en) | 1973-03-21 |
FR2079204A1 (enrdf_load_stackoverflow) | 1971-11-12 |
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