US3749673A - Bleach-fabric softener compositions - Google Patents

Bleach-fabric softener compositions Download PDF

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US3749673A
US3749673A US00117590A US3749673DA US3749673A US 3749673 A US3749673 A US 3749673A US 00117590 A US00117590 A US 00117590A US 3749673D A US3749673D A US 3749673DA US 3749673 A US3749673 A US 3749673A
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bleaching
compositions
chloride
composition
solution
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J Jones
C Nicol
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Procter and Gamble Co
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Procter and Gamble Co
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • A61Q11/02—Preparations for deodorising, bleaching or disinfecting dentures
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/08—Preparations for bleaching the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3945—Organic per-compounds

Definitions

  • h m is provide eornsatihle hlseshiah'ric softener co hinatios which is m d in the form oi s ls shit i ls i it is further onset of the i mvenon is provide 2 catalyzed hlashiah q when which has he 'l sd at low so he was alien and wh' h is eiieciive a law tsiiies hires and. after short is M Whi e b each and fab.
  • compositions can contain from about 1% to 15% by weight of an alkali metal or alkaline earth metal chloride to provide all or part of the ionizable chlorine.
  • all of the ionizable chlorine can be provided by the quaternary ammonium compound as hereinafter detailed.
  • a preferred embodiment of the invention contains, in addition to the above components, from about 0.08% to about 8% by weight of a watersoluble salt of a transition metal element.
  • compositions are dissolved in water to provide fabric softening and catalyzed bleaching of both colored and white fabrics.
  • aqueous solutions may also be used as hard surface or denture cleaners and as agents for restoring natural color to artificially colored hair.
  • the drawing provides a graphical representation of the elfect of time and temperature upon the bleaching activity of the compositions of the instant invention relative to the prior art.
  • the horizontal axis represents time in minutes.
  • the vertical axis represents AW, a measure of stain removal performancedescribed in column 9, lines 73-75, hereof.
  • Each curve represents a particular bleaching composition of Table I (col. 9) identified by number and utilized at the indicated temperature.
  • R is an alkylene or arylene group
  • bianionic dimers during the bleaching process.
  • such complexes are formed from the combination of (l) the above compounds which have lost one proton upon dissolution and/or (2) the above compounds which have lost both protons.
  • these bianionic complexes for example, can have the general formulas,
  • a micelle' is a highly charged colloidal aggregate. It is believed that such positively charged aggregates, as well as positive transition metal ions, serve as rallying points for the S0 and HSO anions and their organic peroxyacid counterparts, thereby facilitating formation of the indispensible transition complex of the bleaching reaction. Quaternary ammonium salts are employed in order to form the necessary miceslles in solution. In addition, bleaching catalysis may be enhanced by addition of a transition metal salt such as copper sulfate, to provide more complex-creating cations in solution.
  • a transition metal salt such as copper sulfate
  • compositions of the present invention must contain enough of a water-soluble chloride compound or mixtures thereof to provide from about 5 to about grams of ionizable chlorine per kilogram of dry composition.
  • Ionizable chloride is that portion of any compound of the present invention which when dissolved contributes chloride ions to the aqueous solutions.
  • Ionizable chlorine is, of course, provided by chloridesalts.
  • the necessary ionizable chlorine content of the instant composition can be provided in the form of the quaternary ammonium chloride, an added alkali metal or alkaline earth metal chloride and/or by the transition metal chlorides.
  • hypochlorite is formed in solution from the compositions of the instant invention, it is formed over an extended period of time and at a lower concentration than the directly added hypochlorite of the prior art. Performance loss due to this indirect method of hypochlorite bleaching is more than adequately compensated for by the effectiveness of the rnicelle-cattalyzed oxygen bleaching. Overall bleaching performance thus compares favorably with harsh concentrated hypochlorite with little hypochlorite-type color damage occurring.
  • compositions of the instant invention should contain no more bromide than would be present if the optional transition metal salt is a bromide. This is so since large amounts of bromide ions in solution with some peroxygen bleaches can cause severe color damage to fabrics. Consequently, the quaternary ammonium compound (which can be present in a relatively high concentration in the composition) cannot be a bromide salt, i.e. bromide is an interfering anion.
  • Bleaching agents sodium or potassium monopersulfate (NaHSO and KHSO and the organic monoand diperoxyacids (or water-soluble salts thereof) having respectively the following formulas:
  • the organic peroxyacids or salts thereof of the invention can contain either one or two peroxy groups and can be either aliphatic or aromatic.
  • the organic peroxyacid is aliphatic
  • the alkylene linkage between the anionic groups can contain halogen or othe non-interfering groups.
  • the unsubstituted acid has the general formula Where Y is for example.
  • YH groupings can be in any relative position around the aromatic ring.
  • the ring can contain any noninterfering substituent such as halogen groups.
  • suitable aromatic peroxy acids include monoperoxyphthalic acid, dip-eroxyterephthalic acid, 4-chlorodiperoxyphthalic acid and the monosodium salt of diperoxyterephthalic acid.
  • the preferred aromatic peroxyacids are the monoand diperoxyisophthalic acids.
  • the bleaching compositions can contain from about 8% to about 60% by weight of the bleaching agent.
  • the preferred monopersulfate weight range is from about 25% to about 30% by weight.
  • a preferred organic peroxyacid weight range is from about 16% to about 35% by weight.
  • Mixtures of the monpersulfate compounds and the peroxyacids can be employed in the instant invention.
  • These bleaching compositions are, of course, dissolved in aqueous solutions for actual use on fabrics, sinks, dentures or hair.
  • the bleaching composition is added in quantities suflicient to yield from about 5 to ppm. available oxygen in solution from either the persulfate or organic peroxyacid bleach actives.
  • the above bleaching actives when employed in the catalyzed compositions of the present invention provide effective bleaching at all practical bleaching solution temperatures and bleach effectively after a. very short contact time with the material to be bleached. As noted, color and fabric damage is minimal.
  • Quaternary ammonium compounds-Quaternary ammonium compounds useful herein have the general formulas and Ilia lla Rr-III-Ih-III-Rg R: R5
  • R is an alkyl group containing from about 12 to 20 carbon atoms
  • R is an alkyl group of about 1 to 14 carbon atoms, a cycloalkyl group of about 5 to 8 carbon atoms, a carboxymethyl group, a 6 to 8 carbon aryl group, an alkaryl group of 7 to 10 carbon atoms, a pyridyl group, or a group of the general formula either a 1 to 3 carbon atom alkylene group, a 5 to 8 carbon arylene group or a group of the formula
  • X is any non-interfering anion such as chloride, nitrate, fluoride, sulfate, methylsulfate, carbonate, hydrogen phosphate, dihydrogen phosphate, chlorate or hydroxide; and n is 1 when X is monovalent and n is 2 when X is divalent.
  • quaternary ammonium compounds employable in the compositions include tetradecyltrimethylammonium chloride; tetradecyltrimethylammonium methylsulfate; tetradecyltrimethylammonium nitrate; cetyltrimethylammonium hydrogen phosphate;
  • cetyltrirnethylammonium nitrate octadecyltrimethylammonium chloride; octadecyltrimethylammonium chlorate; octadecyltrimethylammonium nitrate; eicosyltrimethylammonium chloride; eicosyltrimethylammonium hydroxide; eicosyltrimethylammonium nitrate;
  • the quaternary ammonium constituent serves two purposes in the instant compositions. These surface active compounds form the micelles for catalysis of the peroxygen bleaching, and in addition they impart fabric softening characteristics to the bleaching solutions. In solutions prepared from the compositions of this invention the quaternary ammonium salt concentration should range from about 100 p.p.m. to about 500 p.p.m.
  • quaternary ammonium compounds of the type herein employed function as fabric softeners. They have heretofore been utilized alone in laundry rinse water since they are incompatible with anionic detergents. It has been discovered, however, that these compounds are compatible with the bianionic, complex-forming bleach agents of the present invention and, in fact, act as micelle catalysts while retaining their fabric softening properties.
  • a preferred embodiment of the invention is a dry composition which contains about 2% to about 30% by weight of a carbon chain quaternary ammonium salt and about 8% to 30% by weight of 14, 16 or 18 carbon chain quaternary ammonium salts.
  • aqueous solution prepared from this preferred composition there should be from about 20 p.p.m. to about 80 p.p.m. of the C1840 quaternary ammonium salt to provide softening capability.
  • the quaternary ammonium compound if a chloride salt, can contribute to the total required ionizable chlorine content of the composition.
  • any noninterfering compound which can alter and maintain pH such as any standard buffering agent or combination is employed.
  • phosphates, carbonates or bicarbonates which buffer within the 7-10 pH range are useful.
  • suitable buffering agents include sodium bicarbonate, sodium carbonate, disodium hydrogen phosphate and sodium dihydrogen phosphate.
  • Sodium carbonate is the preferred buffering agent for monopersulfate systems.
  • Disodium hydrogen phosphate and sodium dihydrogen phosphate are preferred for peroxy acid systems.
  • Buffering agents comprise from about 10% to about 75% by weight of the compositions.
  • Alkali metal or alkaline earth metal chl0ride Addition of a compound of this type to the concentrated bleaching composition of this invention is optional if the quaternary ammonium compound is a chloride and is present in the dry compositions in sufiicient amount to provide the necessary 5 to grams of ionizable chlorine per kilogram of the total composition. If, however, the quaternary ammonium compound is not a chloride or is not present in an amount sufiicient to provide the proper ionizable chlorine content, this alkali metal or alkaline earth metal chloride is a necessary component. Suitable chlorides include, for example, NaCl, KCl, C-aCl and Mgclg.
  • the alkali metal or alkaline earth metal chloride When employed, it should comprise from about 1% to 15% by weight of the total composition.
  • preferred embodiments of the present invention employ enough chloride compound of any type so that in solution the chloride ion, (although as noted above, the chloride ion as such probably does not exist in the bleaching solution) is present from whatever source in a theoretical p.p.m. amount equal to the p.p.m. of available oxygen (av. 0 from the oxygen bleaching actives.
  • a more specific preferred embodiment of the present invention would employ a quaternary ammonium chloride of the type defined above in an amount of from about 15 to about 25% by weight with an alkali metal or alkaline earth metal chloride compound being present in a concentration of from about 2% to about 10% by weight.
  • Transistion metal salt.Improved bleaching can also be obtained by the optional addition to the compositions of a source of transition metal ions. Any soluble salts which yield such ions in bleaching solution are useful in this invention. Such ions are believed to further catalyze the formation of the active peroxy compound and chlorine species to provide synergistic bleaching enhancement.
  • Transition metal salts which can be used in the instant compositions include copper sulfate, copper chloride, cobalt chloride, manganese bromide, nickel nitrate, copper nitrate, chromium chloride, manganese nitrate and chromium bromide. It should be noted that if chloride transition metal salts are employed, they also can contribute to the necessaary ionizable chlorine content of the compositions.
  • Such transition metal salts can be employed in the present compositions in a concentration range of from about 0.08% to about 8% by weight.
  • the salts are preferably present in an amount efifective to provide a transition metal ion concentration in bleaching solution of from about 5 10- M to about 3 10 M.
  • additives such as builders, perfumes, coloring agents, fillers, etc., .can be added to the dry bleaching and softening compositions.
  • Composition 8 contains dihydroanowedtoalgefrthreedaysat120,, F genated tallow ammonium monoperoxysulfate.
  • Composition No. 11 is a hypochlorite formulation.
  • Composition Gravy No. 16 is a potassium dichloroisocyanurate composition. The others are compositions with one or more of the essenoneounce Package of Durkees brown Y miX is tial components of the instant invention omitted. These Wlth 1 P of Water and brought t0 a boil With compositions are employed in the following Bleaching stirring. Tllfl mixture is removed Il'Om the heat and stirred Performance Test.
  • the buffering agent s sodium carbonate.
  • the bufien'ng agent is a mixture of dlsodium hydrogen phosphate and sodium dihydrogen phosphate in a NazHPO; to N8H2PO4 ratio of approximately 5:1.
  • Table II provides the concentration in bleaching solution of components of the various compositions. Table II also summarizes the AW value of each composition, thereby indicating their relativ bleaching performance.
  • compositions were used after or as the cloths were washed'in Tide" at 125 F. with 7 grain/gallon hardness water.
  • compositionsof the instant invention provide stain removal superior to the other prior art compositions at comparable strength in solution and superior to compositions not containing all of the essential components of the instant invention.
  • Preferred Composition No. performs at a very low strength about as well as a highly concentrated NaOCl bleaching solution (No. 11).- Substantially similar AW results are obtained with the compositions of the present invention not appearing in Table 11 (Nos. 5 and 9).
  • diperoxyisophthalic acid of Composition 9 When the diperoxyisophthalic acid of Composition 9 is replaced with diperoxyterephthalic acid, 4-chlorodiperoxyphthalic acid, the monosodium salt of diperoxymonium fluoride, sulfate, methylsulfate, hydrogen phosphate, dihydrogen phosphate, chlorate, carbonate or hydroxide substantially similar performance of the compositions is obtained.
  • compositions of the instant invention are compared to each other and to the other compositions of Table I. Color damage is ascertained and evaluated by the following procedures. Thirtytwo difierent articles of clothing having characteristics summarized in Table III are first washed in Tide, a representative commercially available laundering detergent, with water of 7 grain hardnessat 125 F. Compositions 11 and 16 were employed in the wash water itself. The other compositions were utilized in 7 grain hardness rinse water at 100 F. All compositions were employed at the concentrations of Table II.
  • composition number 10 11 13 Component-solution concentration, p.p.m.:
  • Potassium monopersuliate (ppm. av. 02).-. 53 45 Sodium hypochlorite (p.p.m. av. C12) 200 Cetyltrimethylammonium chloride (pipini. i
  • FABRIC SOFT ENING TEST Softening was tested under standard U.S. conditions of 125 F. wash (7 gr./gal. hardness) followed by 100 F. rinse with 7 gr./gal. hardness. Loads were washed in the automatic mini washer using 0.9 cup Tide, 1 /2 gallons of water and a 5 /2 pound load equivalent. The standard load contained 4 terry wash cloths. Compositions were tested for two cycles, and the terry cloths were graded by a panel of 5 expert judges using the method of round robin paired comparisons.
  • a dry bleach and fabric-softening composition consisting essentially of:
  • A from about 8% to about 60% by weight of a bleaching agent selected from the group consisting of (1) sodium monopersulfate, (2) potassium monopersulfate, (3) an organic peroxyacid or water-soluble salt thereof, said peroxyacid having the general formula wherein R is selected from the group consisting of alkylene groups containing from 1 to about 16 carbon atoms and arylene groups containing from 6 to about 8 carbon atoms and Y is a group providing an anionic moiety in aqueous solution, and (4) mixtures thereof; (B) from about 10% to about 60% by weight of a quaternary ammonium compound selected from the group consisting of i Br fillband of alkyl groups containing from about 1 to 3 carbon atoms, aryl groups containing from about 6 to 8 carbon atoms, cycloalkyl groups containing from about 5 to 8 carbon atoms, carboxymethyl groups, alkaryl groups containing from about 7 to 10 carbon atoms, pyridyl, and groups of the general formula wherein
  • (C) from about 10% to about by weight of a buffering agent effective to maintain a solution pH of from about 7 to about 10 when said composition is dissolved in water for bleaching;
  • composition containing sufiicient chloride sa to provide from about 5 to about grams of ioniza le chlorine per kilogram of the total composition.
  • composition of claim 1 wherein the bleaching agent is potassium monopersulfate.
  • a composition in accordance with claim 1 wherein the bleaching agent is selected from the group consisting of monoperazelaic acid and diperazelaic acid.
  • composition in accordance with claim 1 which contains in addition from about 0.08% to about 8% by weight of a water-soluble salt of a transition metal element.
  • a composition in accordance with claim 1 which contains from about 2% to about 10% of a water-soluble alkali metal or alkaline earth metal chloride.
  • a composition in accordance with claim 1 wherein the quaternary ammonium compound is a mixture containing from about 2% to about 10% by weight of the total composition of an eicosyltrimethylammonium 'compound and about 8% to about 30% by weight of the total composition of a cetyltrimethylor octadecyltrimethyl-ammonium compound.
  • a concentrated, dry bleach and fabriosoftening composition consisting essentially of:
  • R is an alkyl group containing from 12 to about 20 carbon atoms
  • R is selected from the group consisting of alkyl groups containing from about 1 to 14 carbon atoms, cycloalkyl groups containing from about to 8 carbon atoms, carboxymethyl groups, aryl groups containing from about 6 to 8 carbon atoms, alkaryl groups containing from about 7 to carbon atoms, pyridyl and groups of the general formula --(C H O) (C H O) I-l wherein a and b are integers and a+b is 1 to 50; R R and R are each selected from the group consisting of alkyl groups containing from about 1 to 3 carbon atoms, cycloalkyl groups containing from about 5 to 8 carbon atoms, carboxymethyl groups, aryl groups containing from about 6 to 8 carbon atoms, alkaryl groups containing from about 7 to
  • (E) from about 10% to about by Weight of a buffering agent effective to maintain a solution pH of from about 7 to about 10 when said composition is dissolved in water for bleaching; said composition containing suflicient chloride salt to provide from about 5 to about 100 grams of ionizable chlorine per kilogram of the total composition.
  • bleaching agent is selected from the group consisting of diperazelaic acid, diperoxyisophthalic acid, diperoxyterephthalic acid, 4 chlorodiperoxyphthalic acid, the monosodium salt of diperoxyterephthalic acid and a monoperoxy compound of the general formula wherein R is an alkyl group of from about 8 to about 18 carbon atoms and wherein X and Y are each selected from the group of cations consisting of hydrogen, sodium, potassium, ammonium and substituted ammonium cations.

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US00117590A 1971-02-22 1971-02-22 Bleach-fabric softener compositions Expired - Lifetime US3749673A (en)

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AU (1) AU458447B2 (enrdf_load_stackoverflow)
BE (1) BE779600A (enrdf_load_stackoverflow)
CA (1) CA972505A (enrdf_load_stackoverflow)
DE (1) DE2207988A1 (enrdf_load_stackoverflow)
ES (1) ES399763A1 (enrdf_load_stackoverflow)
FR (1) FR2126255B1 (enrdf_load_stackoverflow)
GB (1) GB1378672A (enrdf_load_stackoverflow)
IT (1) IT959548B (enrdf_load_stackoverflow)
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Cited By (15)

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Publication number Priority date Publication date Assignee Title
US3876551A (en) * 1972-02-14 1975-04-08 Int Flavors & Fragrances Inc Perfumed aqueous hypochlorite composition and method for preparation of same
US3996151A (en) * 1975-02-18 1976-12-07 Basf Aktiengesellschaft Alkaline peroxide bleach liquor
US4113645A (en) * 1977-07-26 1978-09-12 Polak's Frutal Works, Inc. Bleach compositions containing perfume oils
US4170453A (en) * 1977-06-03 1979-10-09 The Procter & Gamble Company Peroxyacid bleach composition
US4203852A (en) * 1974-03-01 1980-05-20 Colgate-Palmolive Company Softener, bleach and anti-cling composition
US4445901A (en) * 1981-10-09 1984-05-01 Lever Brothers Company Fabric conditioning composition
US4800036A (en) * 1985-05-06 1989-01-24 The Dow Chemical Company Aqueous bleach compositions thickened with a viscoelastic surfactant
US5597791A (en) * 1994-10-13 1997-01-28 Fmc Corporation Stable peracid sols, gels and solids
US6143088A (en) * 1996-03-14 2000-11-07 Etat Francais represented by the Delegue General pour l ' Armement Peracid-based composition for decontamination of materials soiled by toxic agents
US6262013B1 (en) 1999-01-14 2001-07-17 Ecolab Inc. Sanitizing laundry sour
US6436445B1 (en) * 1999-03-26 2002-08-20 Ecolab Inc. Antimicrobial and antiviral compositions containing an oxidizing species
US6534075B1 (en) 1999-03-26 2003-03-18 Ecolab Inc. Antimicrobial and antiviral compositions and treatments for food surfaces
US20030185902A1 (en) * 2002-03-28 2003-10-02 Ecolab Inc. Antimicrobial and antiviral compositions containing an oxidizing species
WO2007009618A1 (de) * 2005-07-16 2007-01-25 Henkel Kommanditgesellschaft Auf Aktien Alkalimetallhalogenide als tracer
WO2011160864A3 (de) * 2010-06-22 2012-03-01 Henkel Ag & Co. Kgaa Ammoniumsalz-haltige blondierpulver

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Publication number Priority date Publication date Assignee Title
AU497498B2 (en) * 1973-06-04 1978-12-14 Colgate-Palmolive Pty. Ltd. Perpthalic acid bleach fabric softening composition
ZA75747B (en) * 1974-03-01 1976-09-29 Colgate Palmolive Co Softener, bleach and anti-cling composition
US4096243A (en) * 1976-02-09 1978-06-20 Clairol Incorporated Composition for lightening hair containing an oxidizing agent and certain quaternary amines
US4532127A (en) * 1976-02-09 1985-07-30 Clairol Incorporated Composition for lightening or coloring hair containing an oxidizing agent and certain quaternary amines
US4402700A (en) * 1976-02-09 1983-09-06 Clairol Incorporated Composition for coloring hair containing an oxidizing agent and certain quaternary amines
GB1557568A (en) * 1976-09-20 1979-12-12 Procter & Gamble Laundry composition comprising an agglomerate of a cationic surfactant and a bleach activator
GB9213059D0 (en) * 1992-06-19 1992-08-05 Laporte Esd Ltd Compositions

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AU293991B2 (en) * 1963-05-28 1969-09-09 Colgate-Palmolive Company Laundering compositions
DE1619081B2 (de) * 1966-12-21 1977-03-03 Henkel & Cie GmbH, 4000 Düsseldorf Avivagemittel fuer textilien
DE1617126C3 (de) * 1967-03-01 1975-06-19 Henkel & Cie Gmbh, 4000 Duesseldorf Maschinenwaschmittel

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3876551A (en) * 1972-02-14 1975-04-08 Int Flavors & Fragrances Inc Perfumed aqueous hypochlorite composition and method for preparation of same
US4203852A (en) * 1974-03-01 1980-05-20 Colgate-Palmolive Company Softener, bleach and anti-cling composition
US3996151A (en) * 1975-02-18 1976-12-07 Basf Aktiengesellschaft Alkaline peroxide bleach liquor
US4170453A (en) * 1977-06-03 1979-10-09 The Procter & Gamble Company Peroxyacid bleach composition
US4113645A (en) * 1977-07-26 1978-09-12 Polak's Frutal Works, Inc. Bleach compositions containing perfume oils
US4445901A (en) * 1981-10-09 1984-05-01 Lever Brothers Company Fabric conditioning composition
US4800036A (en) * 1985-05-06 1989-01-24 The Dow Chemical Company Aqueous bleach compositions thickened with a viscoelastic surfactant
US5597791A (en) * 1994-10-13 1997-01-28 Fmc Corporation Stable peracid sols, gels and solids
US6143088A (en) * 1996-03-14 2000-11-07 Etat Francais represented by the Delegue General pour l ' Armement Peracid-based composition for decontamination of materials soiled by toxic agents
US6262013B1 (en) 1999-01-14 2001-07-17 Ecolab Inc. Sanitizing laundry sour
US6436445B1 (en) * 1999-03-26 2002-08-20 Ecolab Inc. Antimicrobial and antiviral compositions containing an oxidizing species
US6534075B1 (en) 1999-03-26 2003-03-18 Ecolab Inc. Antimicrobial and antiviral compositions and treatments for food surfaces
US20030185902A1 (en) * 2002-03-28 2003-10-02 Ecolab Inc. Antimicrobial and antiviral compositions containing an oxidizing species
US6855328B2 (en) 2002-03-28 2005-02-15 Ecolab Inc. Antimicrobial and antiviral compositions containing an oxidizing species
WO2007009618A1 (de) * 2005-07-16 2007-01-25 Henkel Kommanditgesellschaft Auf Aktien Alkalimetallhalogenide als tracer
WO2011160864A3 (de) * 2010-06-22 2012-03-01 Henkel Ag & Co. Kgaa Ammoniumsalz-haltige blondierpulver

Also Published As

Publication number Publication date
ES399763A1 (es) 1974-12-01
BE779600A (fr) 1972-08-21
FR2126255B1 (enrdf_load_stackoverflow) 1975-03-21
DE2207988A1 (de) 1973-09-27
NL7202292A (enrdf_load_stackoverflow) 1972-08-24
GB1378672A (en) 1974-12-27
AU458447B2 (en) 1975-02-27
CA972505A (en) 1975-08-12
FR2126255A1 (enrdf_load_stackoverflow) 1972-10-06
IT959548B (it) 1973-11-10
AU3909772A (en) 1973-08-23

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