Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B44—DECORATIVE ARTS
  • B44D—PAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
  • B44D3/00—Accessories or implements for use in connection with painting or artistic drawing, not otherwise provided for; Methods or devices for colour determination, selection, or synthesis, e.g. use of colour tables
  • B44D3/18—Boards or sheets with surfaces prepared for painting or drawing pictures; Stretching frames for canvases
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
  • B05D5/04—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a surface receptive to ink or other liquid
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
  • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
  • B05D7/04—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
  • B05D5/02—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a matt or rough surface
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
  • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
  • Y10T428/24372—Particulate matter
  • Y10T428/24413—Metal or metal compound
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
  • Y10T428/256—Heavy metal or aluminum or compound thereof
  • Y10T428/257—Iron oxide or aluminum oxide
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/31507—Of polycarbonate
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
  • Y10T428/3179—Next to cellulosic
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/31855—Of addition polymer from unsaturated monomers
  • Y10T428/3188—Next to cellulosic
  • Y10T428/31884—Regenerated or modified cellulose
  • Y10T428/31891—Where addition polymer is an ester or halide
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/31855—Of addition polymer from unsaturated monomers
  • Y10T428/31935—Ester, halide or nitrile of addition polymer

Definitions

• the present invention relates to a mat film for writing. More particularly, it relates to obtaining a mat film suitable for drafting by arranging a mat layer on a plastic film as a support.
• a mat film for drafting using polyester film, polyvinyl chloride film, or polycarbonate film as a support is usually employed, one having arranged a mat layer containing a matting agent such as glass powder, silica powder, clay powder, and titanium oxide on a plastic film as a support.
• a matting agent such as glass powder, silica powder, clay powder, and titanium oxide
• the mat layer must be so rigid that it can be smoothly written by a hard pencil of 7 to 9H; in case of writing by a hard pencil (7, 8 and 9H), the mat layer should not become dented nor rubbing marks lie thereon as they are in conventional film. And the mat layer must not peel off even is case of rubbing out with an eraser and the same place must be smooth for writing.
• the conventional mat film has had the defect that the mat layer and carbon of pencil are poor in adaptability and, when written places are lightly rubbed by fingers, they are contaminated by carbon; conventional mat film has been so unsatisfactory in workability that thick writing cannot be obtained for carbon does not adhere to the mat.
• the present invention provides a mat film for recording having a mat layer comprising fine powder of fused alumina and cellulose acetate resin on a plastic film support.
• fine powder of fused alumina for example, there is used fine powder of fused alumina grinding stone.
• One which contains above 75% of A1 0 and, in addition, SiO Fe O and TiO and is below 20 microns in particle size is preferable; one which contains above 90% of A1 0 below 5.0% of TiO below 0.3% of SiO and above 0.1% of Fe 0 is above 3.85 in specific gravity and below 14,14 in maximum particle size (average particle size about p.) is particularly preferable.
• the mat layer is formed by dispersing cellulose acetate and the above fine powder in an organic solvent such as tetrachloroethane, methylene chloride, methanol, acetone, methyl ethyl ketone, ethylene chloride, cyclohexanone, methyl acetate, ethyl acetate, dioxane, nitromethane, dimethylformamide, acetic acid, and formic acid, coating the resulting dispersion on a film support and thereafter layer may be carried out by any conventional method.
• an organic solvent such as tetrachloroethane, methylene chloride, methanol, acetone, methyl ethyl ketone, ethylene chloride, cyclohexanone, methyl acetate, ethyl acetate, dioxane, nitromethane, dimethylformamide, acetic acid, and formic acid
• the organic solvent is selected depending upon the solubility of cellulose acetate and the amount of solvent used is not particularly limited.
• the relationship between the quantities of the finely divided alumina powder and cellulose acetate is preferably 1 to 15 parts, by weight, of powder per 10 parts, by weight of binder.
• the amount of binder in solution is preferably 4 to 11 parts, by weight, per parts, by weight, of solution.
• the cellulose acetate may be either cellulose diacetate or cellulose triacetate, and these acetates are used as a binder for the fine powder; if the amount of acetate used is too little, the mat layer tends to become brittle.
• the drying temperature of the organic solvent may be above its boiling point and the higher the temperature is, the shorter the drying time is.
• a plastic film such as polyvinyl chloride resin, polycarbonate resin, polyester resin, etc., is employed.
• the mat layer of the present invention contain fine powder of fused alumina grinding stone and cellulose acetate; however, of course, it can contain other additions.
• the mat layer does not become dented by Writing pressure even in the case of using a hard pencil of 7 to 9H; therefore, rubbing marks do not occur thereon even in case of rubbing out by an eraser since the layer is high in hardness.
• the adhesion of pencil carbon to the mat layer is so excellent that it can be thick and clearly written even by light touch. Furthermore, it is not stained even by rubbing a written place, so a clear and correct writing can be obtained. That an erasure does not remain is advantageous in that, in case of applying the mat to a diazofilm, a printing thickness is even.
• a mat layer of cellulose acetate resin mixed with other matting agents for example, glass powder, silica powder, etc.
• another mat layer of synthetic resin other than cellulose acetate resin for example, polyester, acrylic acid-butadiene-styrene copolymer, polyvinyl acetate, etc.
• fused alumina grinding fine powder satisfactory results could not be obtained.
• the above-mentioned remarkable effects were obtained only in case of mixing a fused alumina grinding fine powder in cellulose acetate resin.
• EXAMPLE 1 A mixture of 25 parts of nitro cellulose (RS /2"), 2.5 parts of Ester Resin #20 (manufactured by Toyobo Co., Ltd), 50 parts of ethylene chloride and 45 parts of methyl ethyl ketone was undercoated on a polyester film of 100,41. in thickness and, after drying at 80 C. for 5 minutes, a dispersion of 10 g. of diacetyl cellulose resin (acetylation value 55.5, polymerization degree 30 g. of methylene chloride, 10 g. of methanol and 5 g. of a fine powder of fused alumina for grinding, WA (white Alundum) grain was coated thereon and, after drying, a mat layer of 10 in thickness was coated thereon.
• the writing property and erasing property of this surface were excellent.
• EXAMPLE 2 A mixed solution of 205 parts of Ester Resin #20, 45 parts of methylene chloride and 50 parts of methyl ethyl ketone was undercoated on a polyvinyl chloride film of 200 in thickness and, after drying at 80 C. for 5 minutes, a dispersion of 12 g. of tri-acetyl cellulose resin (acetylation value 60.8, polymerization degree 370), 30
• a mat film for writing having a mat layer comprising a cellulose acetate resin and a fine powder of fused alumina on a plastic film support.
• the mat film of claim 1 wherein the cellulose acetate is cellulose diacetate or cellulose triacetate.
• plastic support comprises a polyvinyl chloride resin, 6. polycarbonate resin, or a polyester resin.

Landscapes

• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Wood Science & Technology (AREA)
• Laminated Bodies (AREA)
• Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)

Applications Claiming Priority (1)

Publications (1)

Family

ID=13097029

Family Applications (1)

Country Status (2)

Cited By (5)

• 1970
  • 1970-07-06 JP JP45058879A patent/JPS4948843B1/ja active Pending
• 1971
  • 1971-07-02 US US00159520A patent/US3746566A/en not_active Expired - Lifetime

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