US3689941A - Method of fabricating and soldering stainless steel parts - Google Patents

Method of fabricating and soldering stainless steel parts Download PDF

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Publication number
US3689941A
US3689941A US49154A US3689941DA US3689941A US 3689941 A US3689941 A US 3689941A US 49154 A US49154 A US 49154A US 3689941D A US3689941D A US 3689941DA US 3689941 A US3689941 A US 3689941A
Authority
US
United States
Prior art keywords
sheets
lead
stainless steel
molten
bath
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US49154A
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English (en)
Inventor
Andre Chartet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chausson Usines SA
Original Assignee
Chausson Usines SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chausson Usines SA filed Critical Chausson Usines SA
Application granted granted Critical
Publication of US3689941A publication Critical patent/US3689941A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/08Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
    • F28F21/081Heat exchange elements made from metals or metal alloys
    • F28F21/082Heat exchange elements made from metals or metal alloys from steel or ferrous alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D53/00Making other particular articles
    • B21D53/02Making other particular articles heat exchangers or parts thereof, e.g. radiators, condensers fins, headers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/0008Soldering, e.g. brazing, or unsoldering specially adapted for particular articles or work
    • B23K1/0012Brazing heat exchangers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/001Interlayers, transition pieces for metallurgical bonding of workpieces
    • B23K35/004Interlayers, transition pieces for metallurgical bonding of workpieces at least one of the workpieces being of a metal of the iron group
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/10Lead or alloys based thereon
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
    • F28D1/02Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
    • F28D1/03Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with plate-like or laminated conduits
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/02Header boxes; End plates
    • F28F9/04Arrangements for sealing elements into header boxes or end plates
    • F28F9/16Arrangements for sealing elements into header boxes or end plates by permanent joints, e.g. by rolling
    • F28F9/18Arrangements for sealing elements into header boxes or end plates by permanent joints, e.g. by rolling by welding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S29/00Metal working
    • Y10S29/037Stamping with other step
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4935Heat exchanger or boiler making
    • Y10T29/49393Heat exchanger or boiler making with metallurgical bonding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4998Combined manufacture including applying or shaping of fluent material
    • Y10T29/49982Coating

Definitions

  • the present invention is directed to a new method for manufacturing heat exchangers and, more particularly, cooling or heating radiators for vehicles, which has the great advantage of enabling the use of stainless steel for making the entire radiator or parts thereof so that the radiator may still, if necessary, comprise parts of cupreous metals. Furthermore, existing manufacturing equipment, such as the shaping tools and the assembling machines, may be used and with the certainty that the radiators thus produced will retain not only the same qualities, but also'improved qualities with respect to those made of brass and copper. This result is obtained while greatly reducing the manufacturing cost.
  • the method comprises the steps of taking a sheet or strip of stainless steel as the basic material, treating said sheet or strip to cover the faces thereof with a coating of non-ferrous metal or lead alloy and adapted to be wet by soldering alloys containing tin and lead, shaping said parts from the sheet or strip of coated stainless steel and assembling the parts of the radiator through a conventional soldering process.
  • a satisfactory procedure is to submit the stainless steel to an initial treatment comprising degreasing in an alkaline or acid bath, the composition of which may be variable. Baths used for degreasing ordinary iron sheets are perfectly satisfactory. Stainless steel is then submitted to a chemical pickling in a fluonitric aqueous bath which may contain from 2 to 10 percent of hydrofluoric acid and from 5 to 30 percent of nitric acid, this pickling being performed at ambient temperature. The sheets or strips of stainless steel thus depassivated may be stored in a dry room for a very long time.
  • the sheets or strips of stainless steel are submitted to a second pickling operation in a bath of the same kind asthe bath of the initial treatment, or preferably this second pickling is made by dipping in an aqueous bath containing 100 to g/liter of hydrochloric acid, i.e., a tri or quadrimolar bath.
  • the stainless steel is rinsed with fresh water, then immediately submitted to a fluxing operation by introduction into a molten salt bath containing 85 to parts by weight of zinc chloride and 15 to 25 parts by weight of ammonium chloride.
  • the steel As soon as the steel leaves the fluxing salt bath, it is passed or dipped into a molten bath containing from 8 to 40 parts per weight of tin and from 60 to 92 parts per weight of lead.
  • the sheets or strips are submitted to a powerful wiping action while the tin-lead alloy is still molten. This wiping action may be carried out by blowing hot air or by means of rolls or by a combination of these two opera tions.
  • the thickness of the alloy with a high percentage of lead which is thus deposited must be as thin as possible because it is only desired to form on the stainless steel surface a dependent coat suitable for subsequent wetting by soft solder. As the lower limit, a molecular coat is sufficient but in practice for convenience in manufacturing, this coat may be between about 0.5g. and in thickness.
  • the constitutive parts of the radiator are shaped by rolling with regard to the ducts, or by stamping with regard to collectors and water-boxes, only after the basic metal has been coated on the two faces thereof.
  • stamping it has been found that it is much easier to coat strips or continuous sheets of stainless steel with an added metal when said strips or sheets are not previously mechanically worked.
  • the stamping of stainless coated steel is made considerably easier by said coating alloy, the stamping operations particularly, can be made in a manner as simple and with the same tooling used for working non-ferrous alloys such as brass. This is generally not the case when parts are stamped from a non-coated stainless steel sheet.
  • the parts of coated stainless steel, made according to the invention may be fitted together, or with parts of other metals such as copper or brass, with exactly the same procedure as for assembling said parts of non-ferrous metals. Therefore, the parts are submitted to fluxing, then they are joined with a soft solder comprising a tin-lead alloy, the dependent coat covering both faces of the element of stainless steel thus ensuring the intimate connection with the soft solder.
  • the invention thus enables the manufacture of radiators of which all the elements may be made of stainless steel, thereby providing radiators having improved mechanical characteristics and making possible operation under higher pressure conditions for the water circuits. Moreover, this result is obtained at a lesser cost than for analogous radiators made of non-ferrous metals, for example brass.
  • a method of making products of which at least some parts are made from sheets of stainless steel which method includes the steps of providing a sheet of stainless steel containing no nickel and at least 13 percent by weight of chromium,
  • Method according to claim 1 comprising the further step of submitting the sheet, before deoxidizing, to degreasing, then to pickling in a fluonitric bath whereby the steel is depassivated.
  • step of deoxidizing the sheets includes subjecting the depassivated sheets to a pickling bath containing from three to four moles of acid by liter, then to a fluxing step in a molten bath containing zinc and ammonium chlorides.
  • step of covering includes dipping the fluxed sheet in a molten bath of a high lead percentage alloy, and wiping the sheet whereby the coating has a thickness between 0.541. and 201.1
  • a method of making products comprising at least some parts made from sheets of stainless steel and some portions of copper alloys, said stainless steel containing no nickel and at least 13 percent by weight of chromiurn, which method includes the steps of pickling the sheets of stainless steel in a fluonitric bath; keeping the pickled sheet in a dry atmosphere before use; at the moment of use;

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
US49154A 1969-06-30 1970-06-23 Method of fabricating and soldering stainless steel parts Expired - Lifetime US3689941A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR696922044A FR2045742B1 (enrdf_load_stackoverflow) 1969-06-30 1969-06-30

Publications (1)

Publication Number Publication Date
US3689941A true US3689941A (en) 1972-09-12

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ID=9036647

Family Applications (1)

Application Number Title Priority Date Filing Date
US49154A Expired - Lifetime US3689941A (en) 1969-06-30 1970-06-23 Method of fabricating and soldering stainless steel parts

Country Status (9)

Country Link
US (1) US3689941A (enrdf_load_stackoverflow)
JP (1) JPS502869B1 (enrdf_load_stackoverflow)
BE (1) BE752422A (enrdf_load_stackoverflow)
DE (1) DE2030925A1 (enrdf_load_stackoverflow)
ES (1) ES381193A1 (enrdf_load_stackoverflow)
FR (1) FR2045742B1 (enrdf_load_stackoverflow)
GB (1) GB1306835A (enrdf_load_stackoverflow)
NL (1) NL165669C (enrdf_load_stackoverflow)
SE (1) SE379946B (enrdf_load_stackoverflow)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3838495A (en) * 1971-03-26 1974-10-01 Bayerische Motoren Werke Ag Method of forming closed sheet metal structures with an internal corrosion-resistant coating
US3963162A (en) * 1973-08-13 1976-06-15 Senju Metal Industry Co. Ltd. Method of soldering stainless steel pipes by using soft solders
FR2703282A1 (fr) * 1993-03-31 1994-10-07 Lorraine Laminage Procédé d'assemblage de tôles d'acier revêtues d'une couche d'alliage comprenant principalement du plomb.
USRE35098E (en) * 1979-12-20 1995-11-28 Modine Manufacturing Co. Method of making a heat exchanger
US5822854A (en) * 1994-07-22 1998-10-20 Mitsubishi Denki Kabushiki Kaisha Method of fabricating a heat exchanger for an air conditioner
US10010984B2 (en) 2013-10-31 2018-07-03 MAHLE Behr GmbH & Co. KG Method for the production of a heat exchanger, particularly a sorption heat exchanger

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1130790A (en) * 1979-12-20 1982-08-31 Zalman P. Saperstein Heat exchanger
ES487463A0 (es) * 1980-01-04 1980-11-01 Puma Chausson Radiadores Procedimiento para la fabricacion de cambiadores de calor,en particular radiadores
FR2549494B1 (fr) * 1983-07-19 1989-03-24 Vaillant Sarl Procede de plombage d'elements de construction presentant des surfaces en cuivre et en acier
DE102007038217A1 (de) 2007-08-13 2009-02-19 Behr Gmbh & Co. Kg Verfahren zum Beloten eines Werkstückes, Vorrichtung zur Durchführung des Verfahrens und Werkstück, belotet nach dem Verfahren

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2498827A (en) * 1945-10-01 1950-02-28 Young Radiator Co Oval oil cooler construction
US2937438A (en) * 1958-07-14 1960-05-24 Lloyd C Lemon Method for joining aluminum to stainless steel
US3128546A (en) * 1960-02-01 1964-04-14 Pennsalt Chemicals Corp Method and flux for soldering chromium oxide coated steel members
US3242565A (en) * 1963-02-06 1966-03-29 Robert E North Fluxless joining of stainless steel to aluminum
US3465424A (en) * 1967-01-26 1969-09-09 Smith Corp A O Method of forming glass coated steel articles

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2498827A (en) * 1945-10-01 1950-02-28 Young Radiator Co Oval oil cooler construction
US2937438A (en) * 1958-07-14 1960-05-24 Lloyd C Lemon Method for joining aluminum to stainless steel
US3128546A (en) * 1960-02-01 1964-04-14 Pennsalt Chemicals Corp Method and flux for soldering chromium oxide coated steel members
US3242565A (en) * 1963-02-06 1966-03-29 Robert E North Fluxless joining of stainless steel to aluminum
US3465424A (en) * 1967-01-26 1969-09-09 Smith Corp A O Method of forming glass coated steel articles

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3838495A (en) * 1971-03-26 1974-10-01 Bayerische Motoren Werke Ag Method of forming closed sheet metal structures with an internal corrosion-resistant coating
US3963162A (en) * 1973-08-13 1976-06-15 Senju Metal Industry Co. Ltd. Method of soldering stainless steel pipes by using soft solders
USRE35098E (en) * 1979-12-20 1995-11-28 Modine Manufacturing Co. Method of making a heat exchanger
FR2703282A1 (fr) * 1993-03-31 1994-10-07 Lorraine Laminage Procédé d'assemblage de tôles d'acier revêtues d'une couche d'alliage comprenant principalement du plomb.
US5822854A (en) * 1994-07-22 1998-10-20 Mitsubishi Denki Kabushiki Kaisha Method of fabricating a heat exchanger for an air conditioner
US5964284A (en) * 1994-07-22 1999-10-12 Mitsubishi Denki Kabushiki Kaisha Heat exchanger for air conditioner and method of fabricating the heat exchanger
US10010984B2 (en) 2013-10-31 2018-07-03 MAHLE Behr GmbH & Co. KG Method for the production of a heat exchanger, particularly a sorption heat exchanger

Also Published As

Publication number Publication date
SE379946B (enrdf_load_stackoverflow) 1975-10-27
ES381193A1 (es) 1972-12-01
NL165669C (nl) 1981-05-15
JPS502869B1 (enrdf_load_stackoverflow) 1975-01-29
GB1306835A (en) 1973-02-14
NL165669B (nl) 1980-12-15
FR2045742A1 (enrdf_load_stackoverflow) 1971-03-05
BE752422A (fr) 1970-12-01
FR2045742B1 (enrdf_load_stackoverflow) 1974-02-22
DE2030925A1 (de) 1971-01-14
NL7009673A (enrdf_load_stackoverflow) 1971-01-04

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