US3668133A - Detergent oily agent adapted to be well adsorbed in fabrics and having detergency - Google Patents
Detergent oily agent adapted to be well adsorbed in fabrics and having detergency Download PDFInfo
- Publication number
- US3668133A US3668133A US51377A US3668133DA US3668133A US 3668133 A US3668133 A US 3668133A US 51377 A US51377 A US 51377A US 3668133D A US3668133D A US 3668133DA US 3668133 A US3668133 A US 3668133A
- Authority
- US
- United States
- Prior art keywords
- fabrics
- active agent
- agent
- mineral oil
- oily
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/07—Organic amine, amide, or n-base containing
Definitions
- This invention relates to a novel oily agent for cotton and other fabrics. More specifically, the invention relates to a new and better oily agent capable of imparting both adsorbency and detergency to such fabrics, thereby to make them fit for the manual cleaning of various articles and typically for household or office use as mops.
- the fabrics when fabrics are immersed and stirred in emulsified water solutions of oils, the fabrics may absorb oils both efficiently and uniformly, but there is a positive drawback such that the fabrics need an acid pretreatment which causes processing trouble and impairment of cotton and other fabrics and the successful oil adsorption of the fabrics depends largely upon the skill regarding to dosages of acid, water and other additives.
- Another object of the invention is to provide novel oily agents that canbe readily adsorbed in the fabrics at a low temperature and in a comparatively short time, without need for any preor aftertreatments of the fabrics.
- Yet another object of the invention is to provide novel oily agents which contain an excellent detergent surface-active ability so that the fabrics treated therewith have a longsustained self-cleansing quality.
- Still another object of the invention is to provide novel oily agents each consisting essentially of a mineral oil containing a surface-active agent which becomes adsorbable when activated, and another surface-active agent capable of completely emulsifying the mineral oil in a neutral solution so that the mineral oil is adsorbed efficiently in the fabrics along with the other ingredients.
- the fabric was removed from the solution, dehydrated and desiccated by use of apparatuses available conventionally for the purposes, and then its weight was measured.
- the nearly complete absence of organic matter from the remaining water proves the fact that the fabric took up almost the whole of the other ingredients of the oily agent, too.
- C machine oil was used for the mineral oil; diethanol amide of the fatty acid of coconut oil for the particular nonionic surface-active agent; stearyl dimethylbenzil ammonium chloride for the cationic surface-active agent; and polyoxyethylene alkyl phenol ether for the normal nonionic surface-active agent.
- the most important matter of the present invention resides in the above-mentioned performance characteristics, that is, in that an adsorbent is activated in its neutral state, thereby to cause effective adsorption of the mineral oils, adsorptive substances and detergent substances in the fabric to be processed.
- oily agent of the present invention resides in the activation (by means of an emulsifier) of adsorbents contained therein in neutral solutions, so that not only the oils, but the adsorbent and detergent ingredients, too, of the oily agent are wastelessly adsorbed in fabrics treated therein.
- the oily agents according to the invention have various advantages such that preparation of the oily agent is very simple because of being able to be prepared at a low temperature and in a comparatively short period of time without necessity of any acid treatment, adsorbency of the oily agent is strong and uniform; damage of the fabric treated with the oily agent is avoided because of using no acid-treatment; and detergency of the fabric treated with the oily agent becomes excellent and effectively sustained, owing to well adsorption of any detergent in said fabric.
- An oil composition for impregnation of cellulosic wipes, fabrics or mops at substantially neutral pH comprising a neutral aqueous blend of mineral oil with a first nonionic surface-active agent, a cationic surface-active agent and a second nonionic surface-active agent; wherein said first nonionic surface-active agent is the diethanolamide of coconut oil fatty acids; said second nonionic surface-active agent is polyoxyethylene alkylphenol ether and said cationic surface-active agent is the quaternary, stearyl dimethylbenzyl ammonium chloride.
- composition according to claim 1 wherein said second nonionic surface-active agent is present in an amount by weight substantially equal to the combined weights of said first nonionic surface-active agent and said cationic surfaceactive agent and is sufficient to substantially completely em ulsify said mineral oil in neutral aqueous solutions.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP44051934A JPS4830039B1 (ja) | 1969-06-30 | 1969-06-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3668133A true US3668133A (en) | 1972-06-06 |
Family
ID=12900683
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US51377A Expired - Lifetime US3668133A (en) | 1969-06-30 | 1970-06-30 | Detergent oily agent adapted to be well adsorbed in fabrics and having detergency |
Country Status (2)
Country | Link |
---|---|
US (1) | US3668133A (ja) |
JP (1) | JPS4830039B1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3740191A (en) * | 1971-08-23 | 1973-06-19 | Sun Oil Co | Antibacterial laundry oil and dust control oil composition |
EP0000234A1 (en) * | 1977-06-29 | 1979-01-10 | THE PROCTER & GAMBLE COMPANY | Low-phosphate detergent composition for fabric washing |
EP0000235A1 (en) * | 1977-06-29 | 1979-01-10 | THE PROCTER & GAMBLE COMPANY | Low-phosphate detergent composition for fabric washing |
EP0000595A1 (en) * | 1977-06-29 | 1979-02-07 | THE PROCTER & GAMBLE COMPANY | Low-phosphate detergent composition for fabric washing |
FR2400585A1 (fr) * | 1977-07-12 | 1979-03-16 | Procter & Gamble Europ | Compositions pour le traitement des textiles en milieu aqueux |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3105500A (en) * | 1959-08-04 | 1963-10-01 | American Cyanamid Co | Soil retaining finish for textiles |
US3175949A (en) * | 1962-01-08 | 1965-03-30 | Bristol Myers Co | Emulsion of mineral oil, lauric diethanolamide, and water |
US3200036A (en) * | 1962-08-17 | 1965-08-10 | Talb Ind Inc | Oiled dust cloth composition |
US3311659A (en) * | 1963-11-21 | 1967-03-28 | Rayette Faberge | Process for preparing higher fatty alkyl diloweralkyl benzyl ammonium halides |
US3391079A (en) * | 1964-06-10 | 1968-07-02 | Greenblatt Joseph | Treatment of cellulosic fabrics |
-
1969
- 1969-06-30 JP JP44051934A patent/JPS4830039B1/ja active Pending
-
1970
- 1970-06-30 US US51377A patent/US3668133A/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3105500A (en) * | 1959-08-04 | 1963-10-01 | American Cyanamid Co | Soil retaining finish for textiles |
US3175949A (en) * | 1962-01-08 | 1965-03-30 | Bristol Myers Co | Emulsion of mineral oil, lauric diethanolamide, and water |
US3200036A (en) * | 1962-08-17 | 1965-08-10 | Talb Ind Inc | Oiled dust cloth composition |
US3311659A (en) * | 1963-11-21 | 1967-03-28 | Rayette Faberge | Process for preparing higher fatty alkyl diloweralkyl benzyl ammonium halides |
US3391079A (en) * | 1964-06-10 | 1968-07-02 | Greenblatt Joseph | Treatment of cellulosic fabrics |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3740191A (en) * | 1971-08-23 | 1973-06-19 | Sun Oil Co | Antibacterial laundry oil and dust control oil composition |
US3740190A (en) * | 1971-08-23 | 1973-06-19 | Sun Oil Co | Antibacterial laundry oil and dust control oil composition |
EP0000234A1 (en) * | 1977-06-29 | 1979-01-10 | THE PROCTER & GAMBLE COMPANY | Low-phosphate detergent composition for fabric washing |
EP0000235A1 (en) * | 1977-06-29 | 1979-01-10 | THE PROCTER & GAMBLE COMPANY | Low-phosphate detergent composition for fabric washing |
EP0000595A1 (en) * | 1977-06-29 | 1979-02-07 | THE PROCTER & GAMBLE COMPANY | Low-phosphate detergent composition for fabric washing |
FR2400585A1 (fr) * | 1977-07-12 | 1979-03-16 | Procter & Gamble Europ | Compositions pour le traitement des textiles en milieu aqueux |
Also Published As
Publication number | Publication date |
---|---|
JPS4830039B1 (ja) | 1973-09-17 |
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