US3668133A - Detergent oily agent adapted to be well adsorbed in fabrics and having detergency - Google Patents

Detergent oily agent adapted to be well adsorbed in fabrics and having detergency Download PDF

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Publication number
US3668133A
US3668133A US51377A US3668133DA US3668133A US 3668133 A US3668133 A US 3668133A US 51377 A US51377 A US 51377A US 3668133D A US3668133D A US 3668133DA US 3668133 A US3668133 A US 3668133A
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US
United States
Prior art keywords
fabrics
active agent
agent
mineral oil
oily
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US51377A
Other languages
English (en)
Inventor
Yoshinobu Ijiri
Yoshiaki Yano
Hiroshi Yoshida
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HIROSHIMA KAGO MINAMIKANON KK
Original Assignee
HIROSHIMA KAGO MINAMIKANON KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HIROSHIMA KAGO MINAMIKANON KK filed Critical HIROSHIMA KAGO MINAMIKANON KK
Application granted granted Critical
Publication of US3668133A publication Critical patent/US3668133A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46Compounds containing quaternary nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01Wetting, emulsifying, dispersing, or stabilizing agents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01Wetting, emulsifying, dispersing, or stabilizing agents
    • Y10S516/07Organic amine, amide, or n-base containing

Definitions

  • This invention relates to a novel oily agent for cotton and other fabrics. More specifically, the invention relates to a new and better oily agent capable of imparting both adsorbency and detergency to such fabrics, thereby to make them fit for the manual cleaning of various articles and typically for household or office use as mops.
  • the fabrics when fabrics are immersed and stirred in emulsified water solutions of oils, the fabrics may absorb oils both efficiently and uniformly, but there is a positive drawback such that the fabrics need an acid pretreatment which causes processing trouble and impairment of cotton and other fabrics and the successful oil adsorption of the fabrics depends largely upon the skill regarding to dosages of acid, water and other additives.
  • Another object of the invention is to provide novel oily agents that canbe readily adsorbed in the fabrics at a low temperature and in a comparatively short time, without need for any preor aftertreatments of the fabrics.
  • Yet another object of the invention is to provide novel oily agents which contain an excellent detergent surface-active ability so that the fabrics treated therewith have a longsustained self-cleansing quality.
  • Still another object of the invention is to provide novel oily agents each consisting essentially of a mineral oil containing a surface-active agent which becomes adsorbable when activated, and another surface-active agent capable of completely emulsifying the mineral oil in a neutral solution so that the mineral oil is adsorbed efficiently in the fabrics along with the other ingredients.
  • the fabric was removed from the solution, dehydrated and desiccated by use of apparatuses available conventionally for the purposes, and then its weight was measured.
  • the nearly complete absence of organic matter from the remaining water proves the fact that the fabric took up almost the whole of the other ingredients of the oily agent, too.
  • C machine oil was used for the mineral oil; diethanol amide of the fatty acid of coconut oil for the particular nonionic surface-active agent; stearyl dimethylbenzil ammonium chloride for the cationic surface-active agent; and polyoxyethylene alkyl phenol ether for the normal nonionic surface-active agent.
  • the most important matter of the present invention resides in the above-mentioned performance characteristics, that is, in that an adsorbent is activated in its neutral state, thereby to cause effective adsorption of the mineral oils, adsorptive substances and detergent substances in the fabric to be processed.
  • oily agent of the present invention resides in the activation (by means of an emulsifier) of adsorbents contained therein in neutral solutions, so that not only the oils, but the adsorbent and detergent ingredients, too, of the oily agent are wastelessly adsorbed in fabrics treated therein.
  • the oily agents according to the invention have various advantages such that preparation of the oily agent is very simple because of being able to be prepared at a low temperature and in a comparatively short period of time without necessity of any acid treatment, adsorbency of the oily agent is strong and uniform; damage of the fabric treated with the oily agent is avoided because of using no acid-treatment; and detergency of the fabric treated with the oily agent becomes excellent and effectively sustained, owing to well adsorption of any detergent in said fabric.
  • An oil composition for impregnation of cellulosic wipes, fabrics or mops at substantially neutral pH comprising a neutral aqueous blend of mineral oil with a first nonionic surface-active agent, a cationic surface-active agent and a second nonionic surface-active agent; wherein said first nonionic surface-active agent is the diethanolamide of coconut oil fatty acids; said second nonionic surface-active agent is polyoxyethylene alkylphenol ether and said cationic surface-active agent is the quaternary, stearyl dimethylbenzyl ammonium chloride.
  • composition according to claim 1 wherein said second nonionic surface-active agent is present in an amount by weight substantially equal to the combined weights of said first nonionic surface-active agent and said cationic surfaceactive agent and is sufficient to substantially completely em ulsify said mineral oil in neutral aqueous solutions.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
US51377A 1969-06-30 1970-06-30 Detergent oily agent adapted to be well adsorbed in fabrics and having detergency Expired - Lifetime US3668133A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP44051934A JPS4830039B1 (ja) 1969-06-30 1969-06-30

Publications (1)

Publication Number Publication Date
US3668133A true US3668133A (en) 1972-06-06

Family

ID=12900683

Family Applications (1)

Application Number Title Priority Date Filing Date
US51377A Expired - Lifetime US3668133A (en) 1969-06-30 1970-06-30 Detergent oily agent adapted to be well adsorbed in fabrics and having detergency

Country Status (2)

Country Link
US (1) US3668133A (ja)
JP (1) JPS4830039B1 (ja)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3740191A (en) * 1971-08-23 1973-06-19 Sun Oil Co Antibacterial laundry oil and dust control oil composition
EP0000234A1 (en) * 1977-06-29 1979-01-10 THE PROCTER & GAMBLE COMPANY Low-phosphate detergent composition for fabric washing
EP0000235A1 (en) * 1977-06-29 1979-01-10 THE PROCTER & GAMBLE COMPANY Low-phosphate detergent composition for fabric washing
EP0000595A1 (en) * 1977-06-29 1979-02-07 THE PROCTER & GAMBLE COMPANY Low-phosphate detergent composition for fabric washing
FR2400585A1 (fr) * 1977-07-12 1979-03-16 Procter & Gamble Europ Compositions pour le traitement des textiles en milieu aqueux

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3105500A (en) * 1959-08-04 1963-10-01 American Cyanamid Co Soil retaining finish for textiles
US3175949A (en) * 1962-01-08 1965-03-30 Bristol Myers Co Emulsion of mineral oil, lauric diethanolamide, and water
US3200036A (en) * 1962-08-17 1965-08-10 Talb Ind Inc Oiled dust cloth composition
US3311659A (en) * 1963-11-21 1967-03-28 Rayette Faberge Process for preparing higher fatty alkyl diloweralkyl benzyl ammonium halides
US3391079A (en) * 1964-06-10 1968-07-02 Greenblatt Joseph Treatment of cellulosic fabrics

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3105500A (en) * 1959-08-04 1963-10-01 American Cyanamid Co Soil retaining finish for textiles
US3175949A (en) * 1962-01-08 1965-03-30 Bristol Myers Co Emulsion of mineral oil, lauric diethanolamide, and water
US3200036A (en) * 1962-08-17 1965-08-10 Talb Ind Inc Oiled dust cloth composition
US3311659A (en) * 1963-11-21 1967-03-28 Rayette Faberge Process for preparing higher fatty alkyl diloweralkyl benzyl ammonium halides
US3391079A (en) * 1964-06-10 1968-07-02 Greenblatt Joseph Treatment of cellulosic fabrics

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3740191A (en) * 1971-08-23 1973-06-19 Sun Oil Co Antibacterial laundry oil and dust control oil composition
US3740190A (en) * 1971-08-23 1973-06-19 Sun Oil Co Antibacterial laundry oil and dust control oil composition
EP0000234A1 (en) * 1977-06-29 1979-01-10 THE PROCTER & GAMBLE COMPANY Low-phosphate detergent composition for fabric washing
EP0000235A1 (en) * 1977-06-29 1979-01-10 THE PROCTER & GAMBLE COMPANY Low-phosphate detergent composition for fabric washing
EP0000595A1 (en) * 1977-06-29 1979-02-07 THE PROCTER & GAMBLE COMPANY Low-phosphate detergent composition for fabric washing
FR2400585A1 (fr) * 1977-07-12 1979-03-16 Procter & Gamble Europ Compositions pour le traitement des textiles en milieu aqueux

Also Published As

Publication number Publication date
JPS4830039B1 (ja) 1973-09-17

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