US3661642A - Method of cleaning battery terminals and the like - Google Patents

Method of cleaning battery terminals and the like Download PDF

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Publication number
US3661642A
US3661642A US879599A US3661642DA US3661642A US 3661642 A US3661642 A US 3661642A US 879599 A US879599 A US 879599A US 3661642D A US3661642D A US 3661642DA US 3661642 A US3661642 A US 3661642A
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Prior art keywords
solution
water
cleaning
battery terminals
parts
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Expired - Lifetime
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US879599A
Inventor
Joseph Pisaturo
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State Battery Co Inc
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State Battery Co Inc
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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/571Methods or arrangements for affording protection against corrosion; Selection of materials therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D9/00Chemical paint or ink removers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/12Carbonates bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/268Carbohydrates or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/40Products in which the composition is not well defined
    • C11D7/44Vegetable products
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/24Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
    • C23G1/26Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/16Metals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • ABSTRACT UNITED STATES PATENTS A method for cleaning corrosion off battery terminals and the like consisting of applying an aqueous solution having therein 152,697 6/1874 Short ..200/21 pure fruit dye sucrose sodium bicarbonate benzoate of Soda, 2,603,569 7/1952 Alther and vitamin D to the terminal and then flushing with water.
  • the cleaning solution of the present invention consists of an aqueous solution having therein pure fruit dye, sucrose, sodium bicarbonate, benzoate of soda, and vitamin D.
  • Another object of the present invention is to teach a method of cleaning battery terminals and the like by using a solution that includes a mixture of pure fruit dye, sucrose, sodium bicarbonate, benzoate of soda, and vitamin D with water.
  • a color solution is first formulated by mixing one part of a color additive to 128 parts of water, said water being maintained at a temperature of approximately 130 F.
  • the color additive consists of a mixture comprising 24 percent by weight of a pure fruit dye, which is derived from a coal tar derivative, and 76 percent sucrose.
  • An example of a suitable color additive is Food and Drug certified shamrock green shade food coloring.
  • a second aqueous solution is then blended consisting of 42 parts of sodium bicarbonate (baking soda), which is mixed in 384 parts of water, said water being maintained at approximately 95 F.
  • One part of the aforesaid color solution is then of vitamin I) per 50 allons of solution is sufficient. After the resultant mixture has een well blended, it is allowed to stand for approximately 12 hours at normal room temperatures.
  • One ounce of Food and Drug certified shamrock green shade food coloring is dissolved in one gallon of water that is maintained at approximately 130 F. and mixed thoroughly therein.
  • a second solution is formulated by adding 14 ounces of sodium bicarbonate (NaHCO to 1 gallon of water that is maintained at approximately F. After this second solution has been well blended, approximately 8 cc. of the aforesaid color solution is added thereto and mixed therein.
  • a small quantity of benzoate of soda is added, namely, 227 milligrams and additionally, a minute quantity of vitamin D is added, namely 0.0044 milligrams. After being thoroughly mixed, the solution was allowed to stand at ordinary room temperatures for approximately 12 hours.
  • the above solution is brushed, sprayed or poured over the corrosive material appearing on a battery terminal, clamp or the like.
  • a boiling action commences that causes the corrosive material to start to disintegrate and dissolve.
  • clear water may be applied to wash away the solution and the corrosive material that has been dissolved, this latter step being desirable, but not absolutely essential.
  • the battery terminal or clamp will then be substantially free and clear of any accumulation of corrosion, without the necessity of rubbing, scrubbing, or scouring, although in some cases it may be desirable to repeat the application of cleaning solution to the corrosive area.
  • the aforesaid cleaning solution is in no way harmful to the battery, to any paint that it may come in contact with, or to the person who is handling it, even if it comes in direct contact with a persons skin.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Emergency Medicine (AREA)
  • Electrochemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

A method for cleaning corrosion off battery terminals and the like consisting of applying an aqueous solution having therein pure fruit dye, sucrose, sodium bicarbonate, benzoate of soda, and vitamin D3 to the terminal and then flushing with water.

Description

I United States Patent [151 3,661,642 Pisaturo 5] May 9, 1972 [54] METHOD OF CLEANING BATTERY FOREIGN PATENTS OR APPLICATIONS TERMINALS AND THE LIKE 18,247 1903 Great Britain ..252/86 7 I t P' P 2] nven or Joseph lsaturo rovtdence R I OTHER PUBLICATIONS 73 A' :SttBt .,I., l 1 ss'gnee a e a my C0 provdeme RI Bennet, The Chem. Formulary v01. 1 1933) Van Mostrand [22] Filed: Nov. 24, 1969 Co. Inc. p. 458. [2]] APPL No: 879,599 gzngetgz'ghe Chem. Formulary Vol. IX (1953) Chem. Publ. Rose, The Cond. Chem. Dict. 6th Ed. (1960) Reinhold Dahl. [52] US. Cl ..134/28, 134/42, 136/63, C0. p. 339.
252/86, 252/89 [51 1 Int. Cl ..B08b 30/00 Primary ExaminerLeon D. Rosdol [58] Field of Search ..252/89, 82, 86; 134/3, 26, Assistant Examiner-William E. Schulz 134/27, 28, 34, 4], 42; 136/63 Attorney-Salter8t Michaelson [56] References Cited [57] ABSTRACT UNITED STATES PATENTS A method for cleaning corrosion off battery terminals and the like consisting of applying an aqueous solution having therein 152,697 6/1874 Short ..200/21 pure fruit dye sucrose sodium bicarbonate benzoate of Soda, 2,603,569 7/1952 Alther and vitamin D to the terminal and then flushing with water. 2,988,450 6/1961 Bulatkin ..99/79 3,491,027 1]] 970 Baber et a1 ..252/86 1 Claim, N0 Drawings METHOD OF CLEANING BATTERY TERMINALS AND THE LIKE BACKGROUND OF THE INVENTION A problem normally encountered with a conventional automobile battery is the accumulation of corrosive material around the battery terminals and clamps that results from the oxidizing of the materials associated with these parts. The acids normally associated with batteries further add to the accumulation of corrosion on the terminals and clamps thereof. This corrosion, if allowed to accumulate, may cause malfunction of the battery and the component parts thereof.
SUMMARY OF THE INVENTION This invention is directed to a solution, and a method of making same, which when applied to battery terminals and clamps, as by being poured thereover, is effective to break down, dissolve, and remove any accumulated corrosion thereon, without the necessity of rubbing or scouring. Generally speaking, the cleaning solution of the present invention consists of an aqueous solution having therein pure fruit dye, sucrose, sodium bicarbonate, benzoate of soda, and vitamin D. It has been found that when this solution is applied to the terminals and cables of a battery, a reaction takes place with the accumulated corrosion that is present at these areas, which results in a boiling action that quickly results in the disintegration of the accumulated corrosion, although it is sometimes desirable to employ a subsequent water rinse to help wash away the down corrosion particles.
It is therefore an object of the present invention to provide a cleaning solution that is adapted to readily clean battery terminals, clamps and the like by the simple application of the solution thereto and, in some cases, the rinsing of water after the application of the cleaning solution.
Another object of the present invention is to teach a method of cleaning battery terminals and the like by using a solution that includes a mixture of pure fruit dye, sucrose, sodium bicarbonate, benzoate of soda, and vitamin D with water.
DESCRIPTION OF THE INVENTION It has been found in accordance with the present invention that when one part of a food color solution consisting of one part color additive and 128 parts water is mixed with a second solution comprising 42 parts sodium bicarbonate (baking soda) and 384 parts of water and then small quantities of benzoate of soda and vitamin D are added thereto a cleaning solution results that has remarkable advantages in the removal of corrosion from battery terminals, clamps, and the like so as to effect cleaning thereof. The mixing and blending of the materials comprised in the cleaning solution of the present invention is effectively carried out without the necessity of resorting to complicated mixing procedures or blending apparatus. Thus with the required ingredients available, a quantity of the cleaning solution may easily be formulated, as hereinafter set forth.
In making the cleaning solution of the instant invention, a color solution is first formulated by mixing one part of a color additive to 128 parts of water, said water being maintained at a temperature of approximately 130 F. The color additive consists of a mixture comprising 24 percent by weight of a pure fruit dye, which is derived from a coal tar derivative, and 76 percent sucrose. An example of a suitable color additive is Food and Drug certified shamrock green shade food coloring. A second aqueous solution is then blended consisting of 42 parts of sodium bicarbonate (baking soda), which is mixed in 384 parts of water, said water being maintained at approximately 95 F. One part of the aforesaid color solution is then of vitamin I) per 50 allons of solution is sufficient. After the resultant mixture has een well blended, it is allowed to stand for approximately 12 hours at normal room temperatures.
SPECIFIC EXAMPLE The following is a specific example of a cleaning solution formulated in accordance with the present invention:
One ounce of Food and Drug certified shamrock green shade food coloring is dissolved in one gallon of water that is maintained at approximately 130 F. and mixed thoroughly therein. A second solution is formulated by adding 14 ounces of sodium bicarbonate (NaHCO to 1 gallon of water that is maintained at approximately F. After this second solution has been well blended, approximately 8 cc. of the aforesaid color solution is added thereto and mixed therein. To this solution a small quantity of benzoate of soda is added, namely, 227 milligrams and additionally, a minute quantity of vitamin D is added, namely 0.0044 milligrams. After being thoroughly mixed, the solution was allowed to stand at ordinary room temperatures for approximately 12 hours.
In use, the above solution is brushed, sprayed or poured over the corrosive material appearing on a battery terminal, clamp or the like. In a short period of time, usually about 2 or 3 seconds, a boiling action commences that causes the corrosive material to start to disintegrate and dissolve. In approximately another 20 or 30 seconds clear water may be applied to wash away the solution and the corrosive material that has been dissolved, this latter step being desirable, but not absolutely essential. The battery terminal or clamp will then be substantially free and clear of any accumulation of corrosion, without the necessity of rubbing, scrubbing, or scouring, although in some cases it may be desirable to repeat the application of cleaning solution to the corrosive area. The aforesaid cleaning solution is in no way harmful to the battery, to any paint that it may come in contact with, or to the person who is handling it, even if it comes in direct contact with a persons skin.
As this invention may be embodied in several forms without departing from the spirit or essential characteristics thereof, the present embodiment is therefore illustrative and not restrictive, since the scope of the invention is defined by the appended claims rather than by the description preceding them, and all changes that fall within the metes and bounds of the claims or that form their functional as well as conjointly cooperative equivalents, are therefore intended to be em braced by these claims.
What is claimed is:
1. The method of cleaning corrosion off of battery terminals and the like consisting of the following steps:
A. applying a solution consisting of 1. one part of a color solution consisting of one part color additive to 128 parts of water, said color additive consisting of 24 percent pure fruit dye and 76 percent sucrose;
2. 42 parts of sodium bicarbonate;
3. 384 parts ofwater;
4. 0.005 of 1 percent by weight of the cleaning solution of benzoate of soda; and
5. 22 mg. of vitamin D for each 50 gallons of cleaning solution;
to the battery terminal; and.
B. flushing the terminal with water.

Claims (4)

  1. 2. 42 parts of sodium bicarbonate;
  2. 3. 384 parts of water;
  3. 4. 0.005 of 1 percent by weight of the cleaning solution of benzoate of soda; and
  4. 5. 22 mg. of vitamin D3 for each 50 gallons of cleaning solution; to the battery terminal; and B. flushing the terminal with water.
US879599A 1966-02-28 1969-11-24 Method of cleaning battery terminals and the like Expired - Lifetime US3661642A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53253266A 1966-02-28 1966-02-28
US87959969A 1969-11-24 1969-11-24

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US532532A Expired - Lifetime US3491027A (en) 1966-02-28 1966-02-28 Composition and method for cleaning salt residues from metal surfaces
US879599A Expired - Lifetime US3661642A (en) 1966-02-28 1969-11-24 Method of cleaning battery terminals and the like

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4055687A (en) * 1976-01-26 1977-10-25 Blue Maurice R Battery terminal post cleaner
US5270136A (en) * 1992-04-24 1993-12-14 Noland E Bruce Acid-neutralizing battery mat

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3491027A (en) * 1966-02-28 1970-01-20 Us Navy Composition and method for cleaning salt residues from metal surfaces
US4116755A (en) * 1977-09-06 1978-09-26 Mcdonnell Douglas Corporation Chem-milling of titanium and refractory metals
FR2501357B1 (en) * 1981-03-04 1988-01-15 Permo PROCESS FOR CLEARING CIRCUITS IN THERMAL EXCHANGE PLANTS USING WATER
US4808235A (en) * 1987-01-20 1989-02-28 The Dow Chemical Company Cleaning gas turbine compressors
AT392285B (en) * 1989-08-11 1991-02-25 Lang Chem Tech Prod CLEANER FOR COMPRESSORS
DE10200727C1 (en) * 2002-01-11 2003-06-12 Clariant Gmbh External cleaner for means of transport, e.g. car, lorry, train, tram and especially aircraft, contains tertiary amine oxide and alkali metal polyaspartate and/or polyglutamate

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US152697A (en) * 1874-06-30 Improvement in compounds for cleaning paints
GB190318247A (en) * 1903-08-24 1904-08-18 Georges Giraudet Improvements in the Manufacture of Detergent and other Preparations for Toilet use.
US2603569A (en) * 1950-01-23 1952-07-15 Joseph G Alther Effervescent drink concentrate
US2988450A (en) * 1958-06-25 1961-06-13 Crown Cork & Seal Co Beverage manufacture
US3491027A (en) * 1966-02-28 1970-01-20 Us Navy Composition and method for cleaning salt residues from metal surfaces

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2802788A (en) * 1957-08-13 Cleaning composition for automotive
US2399134A (en) * 1943-02-24 1946-04-23 Aluminum Co Of America Method of removing oxide coating from aluminum surfaces
US2943058A (en) * 1956-10-15 1960-06-28 Diamond Alkali Co Liquid detergent compositions
US3110684A (en) * 1959-12-22 1963-11-12 Leo D Miller Humidifier preservative
US3166444A (en) * 1962-04-26 1965-01-19 Lubrizol Corp Method for cleaning metal articles

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US152697A (en) * 1874-06-30 Improvement in compounds for cleaning paints
GB190318247A (en) * 1903-08-24 1904-08-18 Georges Giraudet Improvements in the Manufacture of Detergent and other Preparations for Toilet use.
US2603569A (en) * 1950-01-23 1952-07-15 Joseph G Alther Effervescent drink concentrate
US2988450A (en) * 1958-06-25 1961-06-13 Crown Cork & Seal Co Beverage manufacture
US3491027A (en) * 1966-02-28 1970-01-20 Us Navy Composition and method for cleaning salt residues from metal surfaces

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Bennet, The Chem. Formulary Vol. I (1933) Van Mostrand Co. Inc. p. 458. *
Bennet, The Chem. Formulary Vol. IX (1953) Chem. Publ. Co. p. 528. *
Rose, The Cond. Chem. Dig. 6th Ed. (1960) Reinhold Dahl. Co. p. 339. *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4055687A (en) * 1976-01-26 1977-10-25 Blue Maurice R Battery terminal post cleaner
US5270136A (en) * 1992-04-24 1993-12-14 Noland E Bruce Acid-neutralizing battery mat

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