US1574407A - Cleaning composition for granite, stone, etc - Google Patents
Cleaning composition for granite, stone, etc Download PDFInfo
- Publication number
- US1574407A US1574407A US736790A US73679024A US1574407A US 1574407 A US1574407 A US 1574407A US 736790 A US736790 A US 736790A US 73679024 A US73679024 A US 73679024A US 1574407 A US1574407 A US 1574407A
- Authority
- US
- United States
- Prior art keywords
- stone
- composition
- granite
- cleaning composition
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 14
- 239000004575 stone Substances 0.000 title description 5
- 238000004140 cleaning Methods 0.000 title description 4
- 239000010438 granite Substances 0.000 title description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229940116315 oxalic acid Drugs 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 235000006408 oxalic acid Nutrition 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 239000004579 marble Substances 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C11D2111/24—
Definitions
- composition of matter in general and particularly to a cleansing compound for stone, marble, tile and similar material as described and claimed in my co-pending application filed June 12, 1923, Serial No. 644,944: for composition matter, and of which the present case is a division.
- the objectof my invention is to provide a simple, effective and inexpensive composition for cleaning tombstones, granite aces of buildings and marble and stone articles of various kinds, and tile, which may be readily prepared and applied, and which will be very effective in cleansing and bleaching such articles.
- composition I comprises a composition comprising technical ammonium fluoride, hydro-chloride, mixed with a certain portion of oxalic acid and carbonate of sodium, which ingredients when compounded in proper proportions are mixed with a certain quantity of water and are applied to the surface to be cleaned or bleached.
- This composition is applied to the surface of the article to be cleansed and permitted-to adhere thereto and then, washed off with pure water.
- the composition when applying the composition to rub the surface with either a rag saturated with the compound or with a brush, so as to reach the crevices in the In order to give the surface of the cleaned article a, glossyappearanc e, the same may be smoothedwith pulverized pumice stone or any other polishing material. Hereafter the composition may be again applied and rinsed with water. a s
- This cleansing process may be repeated until the desired degree of bleaching is ob tained.
- a composition matter for cleaning granite, stone, marble, tile, etc comprising 75% ammonium fluoride, 10% oxalicacid 15% carbonate of sodium, compounded to about the weight of one and a half pounds, and
Description
Patented Feb. 23, 1926.
UNITED STATES PATENTHOFFICE.
GUSTAF A. NELSON, or NEW YORK, N. Y.
CLEANING COMPOSITION FOR GRANITE, STONE, ETC.
No Drawing.
. filed September 9, 1924. Serial No. 736,790.
To all whom it may concern: 7
Be it known that I, GUs'rAr A. NELSON,
citizen of the United States, and resident of New York, in the county of New'York and State of New York, have invented certain new and useful Improvements in a Cleaning Composition for Granite, Stone, Etc, of which the following is a specification.
This invention relates to composition of matter in general and particularly to a cleansing compound for stone, marble, tile and similar material as described and claimed in my co-pending application filed June 12, 1923, Serial No. 644,944: for composition matter, and of which the present case is a division.
The objectof my invention is to provide a simple, effective and inexpensive composition for cleaning tombstones, granite aces of buildings and marble and stone articles of various kinds, and tile, which may be readily prepared and applied, and which will be very effective in cleansing and bleaching such articles.
\Vhile I have made various experiments, the most effective composition I have found comprises a composition comprising technical ammonium fluoride, hydro-chloride, mixed with a certain portion of oxalic acid and carbonate of sodium, which ingredients when compounded in proper proportions are mixed with a certain quantity of water and are applied to the surface to be cleaned or bleached.
I have found that very good results are also obtainable when the carbonate of sodium is omitted and a composition of ammonium fluoride and-oxalic acid is employed.
The were found to be obtainable by mixing 95% technical ammonium fluoride with 570' surface;
best results in the latter composition Original application filed June 12, 1923, Serial No. M4344. Divided and this application oxalic acid to the quantity of about one and i a half pounds, which is mixed with approximately one gallon of water.
When carbonate of sodium is employed the composition is about as follows,75%
technical ammonium fluoride, 10% oxalic acid, 15% carbonate of sodium, mixed to the weight of about one and ahalf'pounds, which is dissolved in one gallon of water.
This composition is applied to the surface of the article to be cleansed and permitted-to adhere thereto and then, washed off with pure water. a
It is preferable, when applying the composition to rub the surface with either a rag saturated with the compound or with a brush, so as to reach the crevices in the In order to give the surface of the cleaned article a, glossyappearanc e, the same may be smoothedwith pulverized pumice stone or any other polishing material. Hereafter the composition may be again applied and rinsed with water. a s
This cleansing process may be repeated until the desired degree of bleaching is ob tained.
"While I have mentioned a certain propoi tion of each ingredient, be it understood that such proportions may be varied when stronger or weaker compounds are desired.
Having thus described my invention, I claim: I
A composition matter for cleaning granite, stone, marble, tile, etc, comprising 75% ammonium fluoride, 10% oxalicacid 15% carbonate of sodium, compounded to about the weight of one and a half pounds, and
mixed with about one gallon of water.
Signed at New York in the county of New York and State: of New YorkthisQ-ird day of August A. D. 1924.
GUSTAF A. NELSON.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US736790A US1574407A (en) | 1923-06-12 | 1924-09-09 | Cleaning composition for granite, stone, etc |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US644944A US1574406A (en) | 1923-06-12 | 1923-06-12 | Composition for cleaning stone |
| US736790A US1574407A (en) | 1923-06-12 | 1924-09-09 | Cleaning composition for granite, stone, etc |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1574407A true US1574407A (en) | 1926-02-23 |
Family
ID=27094588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US736790A Expired - Lifetime US1574407A (en) | 1923-06-12 | 1924-09-09 | Cleaning composition for granite, stone, etc |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1574407A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3150007A (en) * | 1954-08-02 | 1964-09-22 | Julius M Kovachy | Process for cleaning stone |
| US4897213A (en) * | 1988-10-14 | 1990-01-30 | Brink Douglas F | Granite cleaning agent and preparation thereof |
| US6090766A (en) * | 1999-10-12 | 2000-07-18 | Brink; Douglas F. | Stone cleaning agent and preparation thereof |
-
1924
- 1924-09-09 US US736790A patent/US1574407A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3150007A (en) * | 1954-08-02 | 1964-09-22 | Julius M Kovachy | Process for cleaning stone |
| US4897213A (en) * | 1988-10-14 | 1990-01-30 | Brink Douglas F | Granite cleaning agent and preparation thereof |
| US6090766A (en) * | 1999-10-12 | 2000-07-18 | Brink; Douglas F. | Stone cleaning agent and preparation thereof |
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