US3640749A - Method of fixing images consisting of dry powders on paper - Google Patents
Method of fixing images consisting of dry powders on paper Download PDFInfo
- Publication number
- US3640749A US3640749A US806271A US3640749DA US3640749A US 3640749 A US3640749 A US 3640749A US 806271 A US806271 A US 806271A US 3640749D A US3640749D A US 3640749DA US 3640749 A US3640749 A US 3640749A
- Authority
- US
- United States
- Prior art keywords
- paper
- dispersion
- synthetic resin
- powder
- dry powders
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 16
- 239000000843 powder Substances 0.000 title abstract description 26
- 239000006185 dispersion Substances 0.000 claims abstract description 30
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 12
- 239000000057 synthetic resin Substances 0.000 claims abstract description 12
- 238000000576 coating method Methods 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 230000019612 pigmentation Effects 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000007639 printing Methods 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G11/00—Selection of substances for use as fixing agents
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G13/00—Electrographic processes using a charge pattern
- G03G13/20—Fixing, e.g. by using heat
Definitions
- ABSTRACT 521 US. (:1. ..117/2ls1,71/1,75/l1 7.l51, 71/12/5251, Dry powderimagesm fixed on paperby eating the powder Int Cl 344d U094 g 844d l image igat ad paper withanaqueous dispersion of afilm formu 5s FieldofSearch ..117/l7.5,28,29,33,76P, mgsy e 117/155, 13 5Claims,No Drawings METHOD ()F FIXING IMAGES CONSISTING F DRY POWDERS 0N PAPER
- the invention relates to a method of fixing images of dry powders on paper.
- Dry colored powders are used in different printing methods, particularly silk screening and electrostatic printing.
- the adhesion of such a powder to paper is only small.
- the image obtained by a dry powder must always be fixed in a separate operation. Several methodsof fixation are known.
- the powder contains a thermoplastic component and/or the paper to be printed is provided with a coating of material which softens upon heating. Upon softening of the resin component, the powder and the paper are permanently connected together.
- Heat can be applied to the material provided with an image of dry powder, for example, by hot air, infrared radiators, heated plates or drums.
- the paper surface bearing an image is provided by means of spraying, rolling or dipping, with a film consisting of a solvent having a low boiling point, which dissolves a certain component of the powder and/or the paper surface, and hence establishes an adhesion between paper and powder, after evaporation.
- Solvents suitable for this purpose are, however, either inflammable (for example toluene) poisonous (for example, trichloroethylene) or only slowly dissolve the active component in the powder or the paper and evaporate slowly (for example, water).
- the image powder does not contain components which can be softened by heat or can be dissolved in manageable solvents and if the paper does not include coatings which possess these properties, then it is alternatively possible to coat the paper provided with a powder image with a solution of a transparent substance which forms a film in the solid state. It must also in this case be possible for the solvent to be evaporated by heating.
- a lacquer solution which is commercially indicated as a fixative. All solvents usable for this purpose have, however, the previously mentioned drawbacks.
- the said methods of fixation have great drawbacks which impede particularly their use in electrostatic high-speed printing machines which must cooperate with data-processing machines. Temperatures above 100 C. must be used for fixation by means of heating. The required heat is therefore 10-20 kw. per sq. m. of paper in which up to 5 g. of water per sq. m. of paper is simultaneously evaporated. When printing quantities of 0.5 to 1.0 sq. m. of paper per second, the working space is generally loaded to an inadmissibly great extent by exhausted heat and water vapors including decomposition products of the adhesive in the paper. Separate devices for removing the decomposition products require additional investments.
- An object of the present invention is to provide a simple method of fixing images consisting of dry powders on paper, by which the described drawbacks are obviated and in which, as a rule, no special devices for the removal of possible decomposition products are required.
- the method according to the invention is characterized in that the paper provided with a dry powder image is coated with a dispersion of a synthetic resin in water.
- an aqueous dispersion of a synthetic resin is preferably used which forms a film at a low temperature.
- a synthetic resin film of approximately 2-4 pm. thick on the paper is generally amply sufficient for fixation.
- the solidv substance content of dispersions suitable for this purpose is. generally more than 40 percent. Since the synthetic resin in the dispersion is present in the form of small particles of at least 0.2 gm. diameter the viscosity of even a very highly concentrated dispersion only differs little from that of pure water.
- the paper is not soaked by the dispersion as in the case of a solution, and therefore not only a fraction but the entire solid substance content of the coating provided is available for the formation of a film. Quantities of provided coatings of 4 to 8 g. of dispersion per sq. m. of paper are therefore amply sufiicient.
- the fixation process takes some tenths of a second, and the porous structure of the paper greatly contributes thereto.
- the water is sucked away from the dispersion in the paper under the influence of capillary forces, so thatthe dispersion breaks.
- the dispersed particles are, as it were, filtered off.
- the particles form a loose network on the paper in the pores of the surface and above the powder image provided, which network, however, flows together to a coherent transparent film when the lowest temperature at which a film is formed by the dispersed substance is below the operation temperature.
- the lowest temperature at which a film is formed is dependent on the kind of synthetic resin used, but by suitable choice this temperature is substantially arbitrarily adjustable between +3 C. and C.
- the added quantity of water is only approximately 24 g. per sq. m. of paper surface, that is to say, 5 to 10 percent of the quantity of paper.
- This quantity of water is approximately as large as the quantity which is normally present in the paper at the usual air hunridities.
- the additional load of the paper by water caused by the fixation can therefore be accepted without further drying steps. If nevertheless an immediately dry paper provided with an image would be desired, then there is the possibility to use predried paper which not until fixing reaches a moisture content which is balanced by the air humidity.
- the dispersions may efficiently be provided with the aid of a follower roller.
- Auxiliary rollers may apply the suitable quantity of dispersion to the roller by means of which the dispersion is provided. Spraying on the dispersions is only possible at a great mechanical stability of the dispersions, for otherwise the dispersion breaks in the spraying nozzle. Due to the low viscosity of dispersions which substantially corresponds to that of water the provision of the dispersion presents few difficulties. When providing the dispersion of occurrence of stripping forces must be avoided as much as possible in order that the powder image is not wiped out. An equalization of the film provided is, however, not necessary because freedom from pores is not required and because the thickness is very small anyway.
- the properties of the transparent coatings are adjustable with respect to color tone, gloss, writing possibility and smoothness
- auxiliary substances such as substances suppressing the formation of foam, wetting agents and thickening agents can be added to the dispersions.
- a method of fixing dry powder images on paper comprising coating the side of a paper on which a dry powder image is present with an aqueous dispersion of a filmforming synthetic resin, said coating step being carried out at a temperature sufficiently high to cause the synthetic resin to form a film on the paper.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Paper (AREA)
- Printing Methods (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP0044238 | 1968-03-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3640749A true US3640749A (en) | 1972-02-08 |
Family
ID=7380167
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US806271A Expired - Lifetime US3640749A (en) | 1968-03-14 | 1969-03-11 | Method of fixing images consisting of dry powders on paper |
Country Status (8)
Country | Link |
---|---|
US (1) | US3640749A (enrdf_load_html_response) |
BE (1) | BE729761A (enrdf_load_html_response) |
CA (1) | CA939567A (enrdf_load_html_response) |
CH (1) | CH489840A (enrdf_load_html_response) |
FR (1) | FR2014112A1 (enrdf_load_html_response) |
GB (1) | GB1221615A (enrdf_load_html_response) |
NL (1) | NL6903627A (enrdf_load_html_response) |
SE (1) | SE352751B (enrdf_load_html_response) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3911160A (en) * | 1974-03-19 | 1975-10-07 | Shamrock Chemicals Corp | Method of using resin powders to cure solvent-free inks |
US4063530A (en) * | 1975-03-06 | 1977-12-20 | Xerox Corporation | Image fixing |
US4259429A (en) * | 1974-04-03 | 1981-03-31 | Agfa-Gevaert N.V. | Protection of toner images |
US4312268A (en) * | 1979-12-10 | 1982-01-26 | The Standard Register Company | Apparatus and method for coating of inks applied at high speed |
US4337303A (en) * | 1980-08-11 | 1982-06-29 | Minnesota Mining And Manufacturing Company | Transfer, encapsulating, and fixing of toner images |
EP0221451A1 (en) * | 1985-10-24 | 1987-05-13 | Stork Colorproofing B.V. | Method of image fixing in colour electrostatography |
US5208093A (en) * | 1991-03-29 | 1993-05-04 | Minnesota Mining And Manufacturing Company | Film construction for use in a plain paper copier |
US5298309A (en) * | 1991-11-05 | 1994-03-29 | Minnesota Mining And Manufacturing Company | Film construction for use in a plain paper copier |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2297691A (en) * | 1939-04-04 | 1942-10-06 | Chester F Carlson | Electrophotography |
US2751315A (en) * | 1953-01-02 | 1956-06-19 | Eastman Kodak Co | Method of applying a protective coating over a photographic print |
US2933416A (en) * | 1960-04-19 | Process for fixing figments on | ||
US3157546A (en) * | 1960-04-19 | 1964-11-17 | Xerox Corp | Image transfer |
US3468692A (en) * | 1963-09-12 | 1969-09-23 | Renker Belipa Gmbh Fa | Transcriptive material for making copies without use of carbon paper |
-
1969
- 1969-03-08 NL NL6903627A patent/NL6903627A/xx unknown
- 1969-03-10 CH CH353069A patent/CH489840A/de not_active IP Right Cessation
- 1969-03-11 US US806271A patent/US3640749A/en not_active Expired - Lifetime
- 1969-03-11 GB GB02765/69A patent/GB1221615A/en not_active Expired
- 1969-03-11 SE SE03333/69A patent/SE352751B/xx unknown
- 1969-03-12 BE BE729761D patent/BE729761A/xx unknown
- 1969-03-14 FR FR6907317A patent/FR2014112A1/fr not_active Withdrawn
- 1969-03-14 CA CA045,669A patent/CA939567A/en not_active Expired
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2933416A (en) * | 1960-04-19 | Process for fixing figments on | ||
US2297691A (en) * | 1939-04-04 | 1942-10-06 | Chester F Carlson | Electrophotography |
US2751315A (en) * | 1953-01-02 | 1956-06-19 | Eastman Kodak Co | Method of applying a protective coating over a photographic print |
US3157546A (en) * | 1960-04-19 | 1964-11-17 | Xerox Corp | Image transfer |
US3468692A (en) * | 1963-09-12 | 1969-09-23 | Renker Belipa Gmbh Fa | Transcriptive material for making copies without use of carbon paper |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3911160A (en) * | 1974-03-19 | 1975-10-07 | Shamrock Chemicals Corp | Method of using resin powders to cure solvent-free inks |
US4259429A (en) * | 1974-04-03 | 1981-03-31 | Agfa-Gevaert N.V. | Protection of toner images |
US4063530A (en) * | 1975-03-06 | 1977-12-20 | Xerox Corporation | Image fixing |
US4312268A (en) * | 1979-12-10 | 1982-01-26 | The Standard Register Company | Apparatus and method for coating of inks applied at high speed |
US4337303A (en) * | 1980-08-11 | 1982-06-29 | Minnesota Mining And Manufacturing Company | Transfer, encapsulating, and fixing of toner images |
EP0221451A1 (en) * | 1985-10-24 | 1987-05-13 | Stork Colorproofing B.V. | Method of image fixing in colour electrostatography |
US5208093A (en) * | 1991-03-29 | 1993-05-04 | Minnesota Mining And Manufacturing Company | Film construction for use in a plain paper copier |
US5298309A (en) * | 1991-11-05 | 1994-03-29 | Minnesota Mining And Manufacturing Company | Film construction for use in a plain paper copier |
Also Published As
Publication number | Publication date |
---|---|
SE352751B (enrdf_load_html_response) | 1973-01-08 |
FR2014112A1 (enrdf_load_html_response) | 1970-04-17 |
NL6903627A (enrdf_load_html_response) | 1969-09-16 |
GB1221615A (en) | 1971-02-03 |
BE729761A (enrdf_load_html_response) | 1969-09-12 |
CA939567A (en) | 1974-01-08 |
CH489840A (de) | 1970-04-30 |
DE1671644B2 (de) | 1975-10-23 |
DE1671644A1 (de) | 1971-10-07 |
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