US3519419A - Superplastic nickel alloys - Google Patents

Superplastic nickel alloys Download PDF

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Publication number
US3519419A
US3519419A US563630A US3519419DA US3519419A US 3519419 A US3519419 A US 3519419A US 563630 A US563630 A US 563630A US 3519419D A US3519419D A US 3519419DA US 3519419 A US3519419 A US 3519419A
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US
United States
Prior art keywords
alloy
alloys
chromium
gamma
alpha
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US563630A
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English (en)
Inventor
Robert Cameron Gibson
Howard Wayne Hayden Jr
John R Mihalisin
Jere Hall Brophy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntington Alloys Corp
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International Nickel Co Inc
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Publication date
Application filed by International Nickel Co Inc filed Critical International Nickel Co Inc
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Publication of US3519419A publication Critical patent/US3519419A/en
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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005—Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C19/00—Alloys based on nickel or cobalt
    • C22C19/03—Alloys based on nickel or cobalt based on nickel
    • C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/052—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 40%
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
    • C22C27/06—Alloys based on chromium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S420/00—Alloys or metallic compositions
    • Y10S420/902—Superplastic

Definitions

  • the alloys can also contain up to 3% molybdenum and up to about 1.5% tungsten for enhancing corrosion resistance and room temperature strength, but the total molybdenum plus one half the percentage of tungsten should not exceed about 3% in order to avoid detrimental phases such as the sigma phase and to avoid adversely affecting hot workability.
  • the alloys can contain up to about 0.1% carbon, up to about 0.5% silicon, up to about 0.5 manganese, up to 4% tantalum, provided the sum of the percent columbium plus one half the percent tantalum in the alloy does not exceed about 2.5% of the alloy, up to about 1% beryllium and up to about 0.2% vanadium.
  • Gamma grain size 3/2 (1/N microns
  • (l/N is an average intragranular dimension, in microns per grain, obtained by averaging the intragranular distances between a representative number of gamma grain boundaries intersecting one or more randomly oriented lines on a micrograph.
  • a micron grain size microstructure of an alloy of the invention can be differentiated by optical microscopy from other alloys having larger grain sizes, the very fine grain sizes of 5 microns and less, often present in the alloy of the invention, are so fine as not to be easily resolvable by optical microscopy. Electron micrographs are usually needed if such very fine grain sizes are to be accurately measured.
  • An example of a fine grain gamma-alpha microstructure having an average grain size of about 1 to 2 microns in accordance with the invention is illustrated by FIG. 5.
  • alloy 37 of the invention has the important advantage of being hot workable with low rolling loads which are similar to the rolling loads for alloy I and which are very substantially lower than the loads for rolling alloy K, both of which are much lower in chromium.
  • a corroison resistant, unfired pressure vessel can be produced by providing a tube of the fine grain gamma-alpha alloy, welding one end of the tube closed gas-tight, heating a portion of the'tube to about 1800 F., connecting the open end of the tube to a gas pressure source and expanding the heated portion to a predetermined size by fluid pressure exerted at the interior of the tube. Thereafter, the pressure is released, the article cooled to room temperature and the open end of the tube shortened to desired length.
  • Another illustration is the production from a flat plate, of a dished, dimpled or grooved article, by a procedure wherein a heated portion of the plate is bulged and expanded by gas pressure on one side to force the opposite side into contact with an open-faced forming die.
  • An alloy as set forth in claim 1 containing 34% to about 43% chromium, about 7% to 34% iron, about 0.55% to 2.5 titanium, up to about 0.08% carbon, up to about 1.4% aluminum, with at least 0.36% effective titanium and a titanium-to-aluminum ratio of at least about 1.5 :1 characterized by superplastic deformability enabling the alloy to be elongated at least 500% in tension at 1800 F. at a constant elongation rate from an initial strain rate of at least about 0.16 inch per inch per minute.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Nonferrous Metals Or Alloys (AREA)
  • Paints Or Removers (AREA)
US563630A 1966-06-21 1966-06-30 Superplastic nickel alloys Expired - Lifetime US3519419A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US55918566A 1966-06-21 1966-06-21
US56363066A 1966-06-30 1966-06-30
US63851967A 1967-05-15 1967-05-15

Publications (1)

Publication Number Publication Date
US3519419A true US3519419A (en) 1970-07-07

Family

ID=27415788

Family Applications (1)

Application Number Title Priority Date Filing Date
US563630A Expired - Lifetime US3519419A (en) 1966-06-21 1966-06-30 Superplastic nickel alloys

Country Status (12)

Country Link
US (1) US3519419A (xx)
JP (1) JPS512413B1 (xx)
AT (3) AT295176B (xx)
BE (3) BE700250A (xx)
CH (1) CH524685A (xx)
DE (3) DE1558519A1 (xx)
ES (3) ES342038A1 (xx)
FR (1) FR1550996A (xx)
GB (2) GB1192934A (xx)
NL (3) NL6708309A (xx)
NO (2) NO122157B (xx)
SE (2) SE346121B (xx)

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3640777A (en) * 1968-02-08 1972-02-08 Int Nickel Co Heat treatment of high-chromium alloys to improve ductility
US3816106A (en) * 1972-08-25 1974-06-11 Int Nickel Co Strong, corrosion resistant alloy
US3837846A (en) * 1971-04-08 1974-09-24 Ver Deutsche Metallwerke Ag Austenitic steel alloy adapted to be welded without cracking
US3975219A (en) * 1975-09-02 1976-08-17 United Technologies Corporation Thermomechanical treatment for nickel base superalloys
US4025314A (en) * 1975-12-17 1977-05-24 The International Nickel Company, Inc. Nickel-chromium filler metal
US4065302A (en) * 1975-12-29 1977-12-27 The International Nickel Company, Inc. Powdered metal consolidation method
US4066448A (en) * 1976-04-07 1978-01-03 The International Nickel Company, Inc. Nickel-chromium-cobalt containing alloys
US4492672A (en) * 1982-04-19 1985-01-08 The United States Of America As Represented By The Secretary Of The Navy Enhanced microstructural stability of nickel alloys
US4529452A (en) * 1984-07-30 1985-07-16 United Technologies Corporation Process for fabricating multi-alloy components
US4613388A (en) * 1982-09-17 1986-09-23 Rockwell International Corporation Superplastic alloys formed by electrodeposition
US5413752A (en) * 1992-10-07 1995-05-09 General Electric Company Method for making fatigue crack growth-resistant nickel-base article
FR2722510A1 (fr) * 1994-07-13 1996-01-19 Societe Nationale D Etude Et De Construction De Mo Procede d'elaboration de toles en alliage 718 et de formage superplastique de ces toles
US20080110534A1 (en) * 2002-12-25 2008-05-15 Manabu Kanzaki Method for manufacturing nickel alloy
US20090038717A1 (en) * 2005-11-07 2009-02-12 Huntington Alloys Corporation Process for Manufacturing High Strength Corrosion Resistant Alloy For Oil Patch Applications
US20110011500A1 (en) * 2007-11-19 2011-01-20 Huntington Alloys Corporation Ultra high strength alloy for severe oil and gas environments and method of preparation
US20120027607A1 (en) * 2010-07-27 2012-02-02 General Electric Company Nickel alloy and articles
US20130224068A1 (en) * 2010-03-23 2013-08-29 Siemens Aktiengesellschaft Metallic bondcoat with a high gamma/gamma' transition temperature and a component
US20160015384A1 (en) * 2013-04-04 2016-01-21 Merete Medical Gmbh Staple Implant for Influencing the Growth in Bone Regions Bordering an Epiphyseal Plate
US20160067834A1 (en) * 2014-09-05 2016-03-10 Ametek, Inc. Nickel-chromium alloy and method of making the same
CN108699635A (zh) * 2016-02-24 2018-10-23 日立金属株式会社 热锻性优异的高强度高耐腐蚀性Ni基合金
US10184166B2 (en) 2016-06-30 2019-01-22 General Electric Company Methods for preparing superalloy articles and related articles
US10253382B2 (en) 2012-06-11 2019-04-09 Huntington Alloys Corporation High-strength corrosion-resistant tubing for oil and gas completion and drilling applications, and process for manufacturing thereof
US10458005B2 (en) 2016-03-15 2019-10-29 Hitachi Metals, Ltd. Heat-resistant and corrosion-resistant high-chromium nickel-based alloy with superior hot forgeability
US10640858B2 (en) 2016-06-30 2020-05-05 General Electric Company Methods for preparing superalloy articles and related articles
CN112157122A (zh) * 2020-11-10 2021-01-01 贵州大学 提高3003铝合金板材强度和塑性的深冷加工方法
EP3757241A4 (en) * 2018-02-20 2021-10-20 Hitachi, Ltd. CR-FE-NI ALLOY PRODUCT

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2708448A1 (de) * 1976-03-01 1977-10-13 Kubota Ltd Verfahren zur herstellung von rostfreien stahlprodukten
US4410489A (en) * 1981-07-17 1983-10-18 Cabot Corporation High chromium nickel base alloys
JPS6059291B2 (ja) * 1982-02-23 1985-12-24 株式会社クボタ 製紙サクションロ−ル用高腐食疲労強度二相ステンレス鋳鋼
JPS6052523A (ja) * 1983-09-01 1985-03-25 Nippon Stainless Steel Co Ltd フエライト−オ−ステナイト二相ステンレス鋼の製造方法
CA1242095A (en) * 1984-02-07 1988-09-20 Akira Yoshitake Ferritic-austenitic duplex stainless steel
JPS60211028A (ja) * 1984-04-03 1985-10-23 Daido Steel Co Ltd 排気バルブ用合金
JPS61119640A (ja) * 1984-11-16 1986-06-06 Honda Motor Co Ltd 排気バルブ用合金
US4721600A (en) * 1985-03-28 1988-01-26 Sumitomo Metal Industries, Ltd. Superplastic ferrous duplex-phase alloy and a hot working method therefor
ES2885758T3 (es) 2012-01-20 2021-12-15 Solu Stainless Oy Procedimiento para la fabricación de un producto de acero inoxidable austenítico
WO2017168640A1 (ja) * 2016-03-30 2017-10-05 株式会社日立製作所 クロム基二相合金製造物およびその製造方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2809139A (en) * 1952-10-24 1957-10-08 Research Corp Method for heat treating chromium base alloy
US3015558A (en) * 1959-09-16 1962-01-02 Grant Nickel-chromium-aluminum heat resisting alloy
US3212886A (en) * 1961-10-03 1965-10-19 Armco Steel Corp High temperature alloy
US3340101A (en) * 1965-04-02 1967-09-05 Ibm Thermoforming of metals

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2809139A (en) * 1952-10-24 1957-10-08 Research Corp Method for heat treating chromium base alloy
US3015558A (en) * 1959-09-16 1962-01-02 Grant Nickel-chromium-aluminum heat resisting alloy
US3212886A (en) * 1961-10-03 1965-10-19 Armco Steel Corp High temperature alloy
US3340101A (en) * 1965-04-02 1967-09-05 Ibm Thermoforming of metals

Cited By (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3640777A (en) * 1968-02-08 1972-02-08 Int Nickel Co Heat treatment of high-chromium alloys to improve ductility
US3837846A (en) * 1971-04-08 1974-09-24 Ver Deutsche Metallwerke Ag Austenitic steel alloy adapted to be welded without cracking
US3816106A (en) * 1972-08-25 1974-06-11 Int Nickel Co Strong, corrosion resistant alloy
US3975219A (en) * 1975-09-02 1976-08-17 United Technologies Corporation Thermomechanical treatment for nickel base superalloys
US4025314A (en) * 1975-12-17 1977-05-24 The International Nickel Company, Inc. Nickel-chromium filler metal
DE2656929A1 (de) * 1975-12-17 1977-07-07 Inco Europ Ltd Nickel-chrom-legierung
US4065302A (en) * 1975-12-29 1977-12-27 The International Nickel Company, Inc. Powdered metal consolidation method
US4066448A (en) * 1976-04-07 1978-01-03 The International Nickel Company, Inc. Nickel-chromium-cobalt containing alloys
US4492672A (en) * 1982-04-19 1985-01-08 The United States Of America As Represented By The Secretary Of The Navy Enhanced microstructural stability of nickel alloys
US4613388A (en) * 1982-09-17 1986-09-23 Rockwell International Corporation Superplastic alloys formed by electrodeposition
US4529452A (en) * 1984-07-30 1985-07-16 United Technologies Corporation Process for fabricating multi-alloy components
US5413752A (en) * 1992-10-07 1995-05-09 General Electric Company Method for making fatigue crack growth-resistant nickel-base article
FR2722510A1 (fr) * 1994-07-13 1996-01-19 Societe Nationale D Etude Et De Construction De Mo Procede d'elaboration de toles en alliage 718 et de formage superplastique de ces toles
US6328827B1 (en) 1994-07-13 2001-12-11 Societe Nationale d'Etude et de Construction de Moteurs d'Aviation “SNECMA” Method of manufacturing sheets made of alloy 718 for the superplastic forming of parts therefrom
US7799152B2 (en) * 2002-12-25 2010-09-21 Sumitomo Metal Industries, Ltd. Method for manufacturing nickel alloy
US20080110534A1 (en) * 2002-12-25 2008-05-15 Manabu Kanzaki Method for manufacturing nickel alloy
US20090038717A1 (en) * 2005-11-07 2009-02-12 Huntington Alloys Corporation Process for Manufacturing High Strength Corrosion Resistant Alloy For Oil Patch Applications
US8133334B2 (en) * 2005-11-07 2012-03-13 Huntington Alloys Corporation Process for manufacturing high strength corrosion resistant alloy for oil patch applications
US20110011500A1 (en) * 2007-11-19 2011-01-20 Huntington Alloys Corporation Ultra high strength alloy for severe oil and gas environments and method of preparation
US10100392B2 (en) 2007-11-19 2018-10-16 Huntington Alloys Corporation Ultra high strength alloy for severe oil and gas environments and method of preparation
US9017490B2 (en) 2007-11-19 2015-04-28 Huntington Alloys Corporation Ultra high strength alloy for severe oil and gas environments and method of preparation
US9074268B2 (en) * 2010-03-23 2015-07-07 Siemens Aktiengesellschaft Metallic bondcoat with a high gamma/gamma' transition temperature and a component
US20130224068A1 (en) * 2010-03-23 2013-08-29 Siemens Aktiengesellschaft Metallic bondcoat with a high gamma/gamma' transition temperature and a component
US20120027607A1 (en) * 2010-07-27 2012-02-02 General Electric Company Nickel alloy and articles
US9562276B2 (en) 2010-07-27 2017-02-07 General Electric Company Nickel alloy and articles
US8608877B2 (en) * 2010-07-27 2013-12-17 General Electric Company Nickel alloy and articles
US10253382B2 (en) 2012-06-11 2019-04-09 Huntington Alloys Corporation High-strength corrosion-resistant tubing for oil and gas completion and drilling applications, and process for manufacturing thereof
US20160015384A1 (en) * 2013-04-04 2016-01-21 Merete Medical Gmbh Staple Implant for Influencing the Growth in Bone Regions Bordering an Epiphyseal Plate
US10085743B2 (en) * 2013-04-04 2018-10-02 Aristotech Industries Gmbh Staple implant for influencing the growth in bone regions bordering an epiphyseal plate
US20160067834A1 (en) * 2014-09-05 2016-03-10 Ametek, Inc. Nickel-chromium alloy and method of making the same
US11130201B2 (en) * 2014-09-05 2021-09-28 Ametek, Inc. Nickel-chromium alloy and method of making the same
CN108699635A (zh) * 2016-02-24 2018-10-23 日立金属株式会社 热锻性优异的高强度高耐腐蚀性Ni基合金
US10450635B2 (en) 2016-02-24 2019-10-22 Hitachi Metals, Ltd. High strength and high corrosion-resistance nickle-based alloy with superior hot forgeability
US10458005B2 (en) 2016-03-15 2019-10-29 Hitachi Metals, Ltd. Heat-resistant and corrosion-resistant high-chromium nickel-based alloy with superior hot forgeability
US10640858B2 (en) 2016-06-30 2020-05-05 General Electric Company Methods for preparing superalloy articles and related articles
US10184166B2 (en) 2016-06-30 2019-01-22 General Electric Company Methods for preparing superalloy articles and related articles
EP3757241A4 (en) * 2018-02-20 2021-10-20 Hitachi, Ltd. CR-FE-NI ALLOY PRODUCT
US11466347B2 (en) 2018-02-20 2022-10-11 Hitachi, Ltd. Cr—Fe—Ni-based alloy product
CN112157122A (zh) * 2020-11-10 2021-01-01 贵州大学 提高3003铝合金板材强度和塑性的深冷加工方法

Also Published As

Publication number Publication date
GB1192945A (en) 1970-05-28
DE1558521C3 (de) 1973-10-31
AT296636B (de) 1972-02-25
BE700250A (xx) 1967-12-31
ES342040A1 (es) 1968-10-16
GB1192934A (en) 1970-05-28
CH524685A (fr) 1972-06-30
SE346121B (xx) 1972-06-26
NL6708309A (xx) 1967-12-22
AT295176B (de) 1971-12-27
SE346122B (xx) 1972-06-26
BE700251A (xx) 1967-12-21
JPS512413B1 (xx) 1976-01-26
NL6709130A (xx) 1968-01-02
NL6708496A (xx) 1967-12-22
FR1550996A (xx) 1968-12-27
ES342038A1 (es) 1968-10-01
ES342039A1 (es) 1968-10-16
DE1558521A1 (de) 1970-04-02
NO121050B (xx) 1971-01-11
AT295872B (de) 1972-01-25
DE1533976A1 (de) 1970-06-18
DE1558521B2 (de) 1973-04-12
DE1558519A1 (de) 1970-04-09
BE700752A (xx) 1968-01-02
NO122157B (xx) 1971-05-24

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