US3493425A - Lubricated fibers - Google Patents
Lubricated fibers Download PDFInfo
- Publication number
- US3493425A US3493425A US613105A US3493425DA US3493425A US 3493425 A US3493425 A US 3493425A US 613105 A US613105 A US 613105A US 3493425D A US3493425D A US 3493425DA US 3493425 A US3493425 A US 3493425A
- Authority
- US
- United States
- Prior art keywords
- fiber
- fibers
- weight
- oil
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000835 fiber Substances 0.000 title description 35
- 239000003921 oil Substances 0.000 description 19
- -1 polysiloxane copolymer Polymers 0.000 description 19
- 229920001296 polysiloxane Polymers 0.000 description 15
- 239000000314 lubricant Substances 0.000 description 8
- 239000002480 mineral oil Substances 0.000 description 7
- 235000010446 mineral oil Nutrition 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229920001059 synthetic polymer Polymers 0.000 description 5
- 229920001778 nylon Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000009991 scouring Methods 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 3
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-dichloroethene Chemical group ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 229920000793 Azlon Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002821 Modacrylic Polymers 0.000 description 1
- 229920002544 Olefin fiber Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 101000941926 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) Carboxypeptidase Y inhibitor Proteins 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003901 ceryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 125000000755 henicosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000002463 lignoceryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000001802 myricyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004767 olefin fiber Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002460 pentacosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 229920006298 saran Polymers 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000002469 tricosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6433—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing carboxylic groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/653—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain modified by isocyanate compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/46—Textile oils
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2962—Silane, silicone or siloxane in coating
Definitions
- the present invention relates to a process for lubricating synthetic and natural fibers which comprises applying to the fiber a coning oil which has incorporated therein a polysiloxane copolymer consisting of units of the unit formulae a)zSiO, (B) (C 3)(C11 2u+l) O, and
- This invention relates to a process of applying a lubricant to a fiber and more particularly to a lubricant that effectively facilitates processing and which possesses the unique and added advantage of being easily and readily removed from the fiber prior to subsequent operations or ultimate use.
- the fiber when natural or numerous synthetic fibers are processed prior to knitting or the like, the fiber must be immersed in a coning oil such as mineral oil, butyl stearate, and fatty acids among others to insure an efiicient and productive capacity.
- a coning oil such as mineral oil, butyl stearate, and fatty acids among others to insure an efiicient and productive capacity.
- the fiber following the initial or early processing stages, the fiber is wound about conical containers.
- the use of the coning oil serves a dual purpose; (1) it provides lubricity to increase the rate of processing, and (2) it imparts to the fiber, a surface tackiness of a consistency such that the fiber will remain in position upon the conical container and will not tend to sag or drop to the lower portion of the container which may disrupt production.
- the coning oil cannot provide too great a surface tackiness or when the fiber is unwound for further processing or use, it will stick and interfere with normal operations. Following the above processing stage and prior to ultimate use or subsequent operations, e.g., dying, the residual coning oil must be removed from the fiber. Removal of the coning oil is generally achieved by scouring and other cumbersome methods, however, an inherent disadvantage exists in that the coning oil is sufliciently diificult to remove so that 3,493,425 Patented Feb. 3, 1970 much of it remains on the fiber resulting in countless problems. Also, because the coning oil is especially difficult to remove, considerable expense is encountered due to the fact that removal of the coning oil requires a tremendous increase in labor costs and the like.
- This invention relates to a process for lubricating fibers which comprises applying to the fiber a coning oil, the improvement comprising as an additive to the coning oil, a polysiloxane copolymer consisting of units of the unit formulae 3)3 (B) (CH3) (C H2n+1)SiO, and (C) (CHQSIQ I (C2 4 l )x in which R is a member selected from the group consisting of a hydrogen atom, a hydrocarbon radical containing less than 9 carbon atoms,
- 3 0R radical, and alCN R radical n has a value of at least 9, x has a value of at least 6, and
- (B) Is present in an amount of from 32 to 38 weight percent based on the weight of (A) +(B) +(C), and
- (C) Is present in an amount of from 36 to 44 weight percent based on the weight of (A) +(B)+(C).
- R radical when it is a hydrocarbon radical containing less than 9 carbon atoms are the methyl, ethyl, propyl, isopropyl, butyl, hexyl, phenyl, tolyl, and allyl radicals, etc.
- n has a value of at least 9, hence that radical can be represented as an alkyl radical such as the nonyl, decyl, hendecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, heneicosyl, docosyl, tricosyl, tetracosyl, pentacosyl, hexacosyl, triacontyl, tetracontyl, pentacontyl, and hexacontyl radical, among others.
- alkyl radical such as the nonyl, decyl, hendecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl,
- coning oil as used herein, it is simply meant a lubricant which is applied to both natural and synthetic yarns which assists in the further processing of yarns to piece goods, i.e., knitting and weaving.
- the term coning oil includes material such as mineral oil, butyl stearate, polyethylene oxides, glycol esters, fatty acids and fatty amides, etc. However, for practical considerations and the like, for most operations, mineral oil is generally preferred.
- the polysiloxane copolymers of the present invention can be endblocked by various groups including triorganosiloxy groups wherein the organo groups are the methyl, phenyl, ethyl, vinyl, and trifluoropropyl group; hydroxyl groups, and methyl radicals bonded to the termial silicon atoms through an Si-C bond, among many others.
- the weight percentages of (A), (B), and (C) are especially critical if the objects of this invention are to be achieved. Since very specific properties are of prime importance, the weight percentages heretofore related are of particular significance.
- the above combination provides a polysiloxane cpolymer which exhibits both lubricity and self-emulsifiable characteristics.
- it when added to the coning oil, it enhances lubricity for purposes of processing and since it is also self-emulsifiable, it can be easily removed upon simple contact with water, thus precluding the cumbersome scouring procedures which were previously necessary.
- this very specific additive in effect, lifts the coning oil off the surface of the fiber when subjected to water and acts as an internal scouring agent itself; thus making its use both beneficial and attractive to the textile industry.
- the synthetic fibers that can be so treated include acrylic fibers in which the fiber-forming substance is any long chain synthetic polymer composed of at least 85 percent by weight of acrylonitrile units; modacrylic fibers in which the fiber-forming substance is any long chain synthetic polymer composed of less than 85 percent but at least 35 percent by weight of acrylonitrile units; polyester fibers in which the fiber-forming substance is any long chain synthetic polymer composed of at least 85 percent by weight of an ester of a dihydric alcohol and terephthalic acid; Saran fibers in which the fiber-forming substance is any long chain synthetic polymer composed of at least 80 percent by Weight of vinylidene chloride units; azlon fibers in which the fiber-forming substance is composed of any regenerated, naturally occurring proteins; nytril fibers in which there is at least 85 percent of a long chain polymer of vinlyidene dinitrile where the vinylidene dinitrile content is no less than every other unit in the polymer chain; nylon fibers in which the fiber-forming substance is
- natural fibers such as cotton, wool, etc. can be so treated to derive the aforementioned advantages.
- the amount of the polysiloxane additive incorporated in the coming oil is not particularly critical with the exception that it be present in a sufficient quantity to impart the desired properties. Therefore, it has been found that approximately 0.5 percent to percent of the polysiloxane additive based on the weight of the coning oil is a perfectly satisfactory amount to achieve the desired effects.
- polysiloxane additive of this invention is also potentially useful when employed alone as a fiber finish where unique compatibility is required. For example, to finish tire cord yarns where the cord is placed in the rubber and the finish does not affect subsequent adhesion.
- the yarns were then subjected to simple washing by merely spraying the fibers with water. Subsequent analysis of the fiber confirmed that virtually no residual lubricant remained.
- a fiber having on its surface a lubricant comprising (1) a coming oil, and (2) from 0.5 percent to 20 percent based upon the Weight of 1) a polysiloxane copolymer consisting in which R is a member selected from the group consisting of a hydrogen atom, a hydrocarbon radical containing less than 9 carbon 40 atoms, a
- (C) is present in an amount of from 36 to 44 weight percent based upon the weight of (A)'+(B)I(C).
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Silicon Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB30989/66A GB1175208A (en) | 1967-01-09 | 1967-01-09 | Application of Finishing Agents to Shaped Articles |
| US61310567A | 1967-02-01 | 1967-02-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3493425A true US3493425A (en) | 1970-02-03 |
Family
ID=26236528
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US613105A Expired - Lifetime US3493425A (en) | 1967-01-09 | 1967-02-01 | Lubricated fibers |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3493425A (is") |
| BE (1) | BE710156A (is") |
| DE (2) | DE1719356A1 (is") |
| FR (2) | FR1559763A (is") |
| GB (2) | GB1175208A (is") |
| NL (2) | NL6801319A (is") |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4076672A (en) * | 1975-08-11 | 1978-02-28 | Wacker-Chemie Gmbh | Lubricants for organic fibres |
| US4105569A (en) * | 1977-02-07 | 1978-08-08 | George A. Goulston Co., Ltd. | Yarn finish formulation |
| DE2900396A1 (de) * | 1978-02-23 | 1979-09-06 | Goldschmidt Ag Th | Textilfaserpraeparationen |
| US4169905A (en) * | 1976-11-30 | 1979-10-02 | Rhone-Poulenc Industries | Process for lubricating textile threads |
| US4394414A (en) * | 1981-05-29 | 1983-07-19 | Ppg Industries, Inc. | Aqueous sizing composition for glass fibers for use on chopped glass fibers |
| US4455400A (en) * | 1978-09-28 | 1984-06-19 | Owens-Corning Fiberglas Corporation | Migratin-free size for glass fibers |
| US4477524A (en) * | 1981-05-29 | 1984-10-16 | Ppg Industries, Inc. | Aqueous sizing composition for glass fibers for use on chopped glass fibers |
| US4530860A (en) * | 1980-06-25 | 1985-07-23 | Owens-Corning Fiberglas Corporation | Migration-free size for glass fibers |
| US4552671A (en) * | 1984-04-06 | 1985-11-12 | Takemoto Yushi Kabushiki Kaisha | Spin finish compositions for polyester and polyamide yarns |
| US5387467A (en) * | 1991-12-11 | 1995-02-07 | Th. Goldschmidt Ag | Method for modifying the surface of finely divided particles by the application of organofunctional polysiloxanes |
| US5672641A (en) * | 1995-01-23 | 1997-09-30 | Ppg Industries, Inc. | Secondary coating compositions for glass fibers, glass fibers coated with the same and composites reinforced therewith |
| US11345847B2 (en) | 2016-08-01 | 2022-05-31 | Schlumberger Technology Corporation | Treatment fluid, method for formation treatment, method for reducing the proppant settling rate in the formation treatment fluid |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1273546A (en) * | 1968-06-25 | 1972-05-10 | Ici Ltd | Treatment of textile materials |
| JPS6018352B2 (ja) | 1978-12-22 | 1985-05-09 | 旭化成株式会社 | 繊維製品からの溶剤回収方法 |
| US4532132A (en) * | 1983-04-11 | 1985-07-30 | Dow Corning Corporation | Skin care formulations comprising a water-in-mineral oil emulsion and siloxane compositions therefor |
| DE3622571A1 (de) * | 1986-07-04 | 1988-01-21 | Goldschmidt Ag Th | Verwendung von polyoxyalkylen-polysiloxan-blockmischpolymerisaten als demulgatoren fuer wasser enthaltendes erdoel |
| KR101130885B1 (ko) * | 2006-03-24 | 2012-04-12 | 칼라렙, 인코포레이티드 | 승화 프린팅 장치 작동 방법 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1945959A (en) * | 1929-03-25 | 1934-02-06 | Celanese Corp | Treatment of yarn |
| US2664409A (en) * | 1949-10-13 | 1953-12-29 | British Nylon Spinners Ltd | Textile treating composition and method |
| US3288622A (en) * | 1964-10-02 | 1966-11-29 | Nathan M Weiss | Method to impart suppleness to monofilament thread |
| US3423235A (en) * | 1964-11-23 | 1969-01-21 | Dow Corning | Organosiloxane-containing finishes for organic fibers |
-
0
- NL NL132213D patent/NL132213C/xx active
-
1967
- 1967-01-09 GB GB30989/66A patent/GB1175208A/en not_active Expired
- 1967-02-01 US US613105A patent/US3493425A/en not_active Expired - Lifetime
-
1968
- 1968-01-02 GB GB219/68A patent/GB1194111A/en not_active Expired
- 1968-01-05 DE DE19681719356 patent/DE1719356A1/de active Pending
- 1968-01-09 FR FR1559763D patent/FR1559763A/fr not_active Expired
- 1968-01-30 NL NL6801319A patent/NL6801319A/xx unknown
- 1968-01-30 DE DE19681719365 patent/DE1719365A1/de not_active Withdrawn
- 1968-01-30 FR FR1552577D patent/FR1552577A/fr not_active Expired
- 1968-01-31 BE BE710156D patent/BE710156A/xx not_active IP Right Cessation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1945959A (en) * | 1929-03-25 | 1934-02-06 | Celanese Corp | Treatment of yarn |
| US2664409A (en) * | 1949-10-13 | 1953-12-29 | British Nylon Spinners Ltd | Textile treating composition and method |
| US3288622A (en) * | 1964-10-02 | 1966-11-29 | Nathan M Weiss | Method to impart suppleness to monofilament thread |
| US3423235A (en) * | 1964-11-23 | 1969-01-21 | Dow Corning | Organosiloxane-containing finishes for organic fibers |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4076672A (en) * | 1975-08-11 | 1978-02-28 | Wacker-Chemie Gmbh | Lubricants for organic fibres |
| US4169905A (en) * | 1976-11-30 | 1979-10-02 | Rhone-Poulenc Industries | Process for lubricating textile threads |
| US4105569A (en) * | 1977-02-07 | 1978-08-08 | George A. Goulston Co., Ltd. | Yarn finish formulation |
| DE2900396A1 (de) * | 1978-02-23 | 1979-09-06 | Goldschmidt Ag Th | Textilfaserpraeparationen |
| US4455400A (en) * | 1978-09-28 | 1984-06-19 | Owens-Corning Fiberglas Corporation | Migratin-free size for glass fibers |
| US4530860A (en) * | 1980-06-25 | 1985-07-23 | Owens-Corning Fiberglas Corporation | Migration-free size for glass fibers |
| US4394414A (en) * | 1981-05-29 | 1983-07-19 | Ppg Industries, Inc. | Aqueous sizing composition for glass fibers for use on chopped glass fibers |
| US4477524A (en) * | 1981-05-29 | 1984-10-16 | Ppg Industries, Inc. | Aqueous sizing composition for glass fibers for use on chopped glass fibers |
| US4552671A (en) * | 1984-04-06 | 1985-11-12 | Takemoto Yushi Kabushiki Kaisha | Spin finish compositions for polyester and polyamide yarns |
| US5387467A (en) * | 1991-12-11 | 1995-02-07 | Th. Goldschmidt Ag | Method for modifying the surface of finely divided particles by the application of organofunctional polysiloxanes |
| US5672641A (en) * | 1995-01-23 | 1997-09-30 | Ppg Industries, Inc. | Secondary coating compositions for glass fibers, glass fibers coated with the same and composites reinforced therewith |
| US11345847B2 (en) | 2016-08-01 | 2022-05-31 | Schlumberger Technology Corporation | Treatment fluid, method for formation treatment, method for reducing the proppant settling rate in the formation treatment fluid |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6801319A (is") | 1968-08-02 |
| GB1194111A (en) | 1970-06-10 |
| GB1175208A (en) | 1969-12-23 |
| FR1559763A (is") | 1969-03-14 |
| FR1552577A (is") | 1969-01-03 |
| DE1719365A1 (de) | 1970-10-29 |
| BE710156A (is") | 1968-07-31 |
| NL132213C (is") | |
| DE1719356A1 (de) | 1971-01-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3493425A (en) | Lubricated fibers | |
| US3853607A (en) | Synthetic filaments coated with a lubricating finish | |
| US3983272A (en) | Method for improving the lubricating properties and imparting antistatic properties to organic fibers | |
| US3423314A (en) | Antistatic lubricant as a process finish for synthetic fibers | |
| EP0132910B1 (en) | Lubricating agents for processing fibres and method of processing thermoplastic synthetic fibre filaments therewith | |
| US3306850A (en) | Composition | |
| US2695270A (en) | Oil soluble cationic textile antistatic agent | |
| US3781202A (en) | Spin finish for polyamide yarn processed at high temperature | |
| US5241042A (en) | Finish for textile fibers containing polyalphaolefin and nonionic emulsifiers having a plurality of hydrocarbon chains | |
| US3423235A (en) | Organosiloxane-containing finishes for organic fibers | |
| US3896032A (en) | Diorganopolysiloxane-based lubricant for organic fibers | |
| US3717575A (en) | Spandex lubricant | |
| US3009830A (en) | Finishing polyolefin filamentary textile article and the article obtained therefrom | |
| US3653955A (en) | Antistatic fiber treatments | |
| US3844826A (en) | Dressing sewing thread to reduced friction | |
| US3634236A (en) | Spandex lubricant composition | |
| US2385423A (en) | Treatment of textile materials | |
| US4014800A (en) | Fiber-lubricating compositions | |
| US2197930A (en) | Method of treating cellulose organic derivative cut staple fibers | |
| US2865855A (en) | Textile treating composition | |
| US2182323A (en) | Treatment of textile materials | |
| Brown | A preliminary study of the fiber-length distribution in fly produced during the weft knitting of cotton yarns | |
| US3193407A (en) | Finished polyolefin fibers and method of preparation | |
| US5288416A (en) | Finish for textile fibers containing silahydrocarbon lubricants and nonionic emulsifiers having a plurality of hydrocarbon chains | |
| US2067174A (en) | Manufacture and treatment of textile materials |