US3781202A - Spin finish for polyamide yarn processed at high temperature - Google Patents
Spin finish for polyamide yarn processed at high temperature Download PDFInfo
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- US3781202A US3781202A US00221828A US3781202DA US3781202A US 3781202 A US3781202 A US 3781202A US 00221828 A US00221828 A US 00221828A US 3781202D A US3781202D A US 3781202DA US 3781202 A US3781202 A US 3781202A
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- yarn
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- high temperature
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Links
- 239000004952 Polyamide Substances 0.000 title description 5
- 229920002647 polyamide Polymers 0.000 title description 5
- 239000000203 mixture Substances 0.000 abstract description 10
- 239000003209 petroleum derivative Substances 0.000 abstract description 7
- 239000003240 coconut oil Substances 0.000 abstract description 6
- 235000019864 coconut oil Nutrition 0.000 abstract description 6
- 239000004677 Nylon Substances 0.000 abstract description 2
- 229920001778 nylon Polymers 0.000 abstract description 2
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 description 11
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 11
- 125000005456 glyceride group Chemical group 0.000 description 10
- 239000003921 oil Substances 0.000 description 10
- 235000019198 oils Nutrition 0.000 description 10
- 239000003760 tallow Substances 0.000 description 10
- 239000002480 mineral oil Substances 0.000 description 9
- 235000010446 mineral oil Nutrition 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- 239000004359 castor oil Substances 0.000 description 8
- 235000019438 castor oil Nutrition 0.000 description 8
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- -1 polyoxyethylene Polymers 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 235000013162 Cocos nucifera Nutrition 0.000 description 4
- 244000060011 Cocos nucifera Species 0.000 description 4
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical class FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 3
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 244000208734 Pisonia aculeata Species 0.000 description 3
- NGHUOSKIZOQGBY-PMDAXIHYSA-N [3-[3-[3-[3-[3-[3-[3-[3-[3-[2,3-bis[[(Z)-octadec-9-enoyl]oxy]propoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-[(Z)-octadec-9-enoyl]oxypropyl] (Z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(COC(=O)CCCCCCC\C=C/CCCCCCCC)OC(=O)CCCCCCC\C=C/CCCCCCCC)OC(=O)CCCCCCC\C=C/CCCCCCCC NGHUOSKIZOQGBY-PMDAXIHYSA-N 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- RZRNAYUHWVFMIP-HXUWFJFHSA-N glycerol monolinoleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-HXUWFJFHSA-N 0.000 description 3
- 239000007764 o/w emulsion Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 3
- 229920000053 polysorbate 80 Polymers 0.000 description 3
- 238000009732 tufting Methods 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- WOKDXPHSIQRTJF-UHFFFAOYSA-N 3-[3-[3-[3-[3-[3-[3-[3-[3-(2,3-dihydroxypropoxy)-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]propane-1,2-diol Chemical compound OCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)COCC(O)CO WOKDXPHSIQRTJF-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000001593 sorbitan monooleate Substances 0.000 description 2
- 235000011069 sorbitan monooleate Nutrition 0.000 description 2
- 229940035049 sorbitan monooleate Drugs 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical class CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 description 1
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IZEKFCXSFNUWAM-UHFFFAOYSA-N dipyridamole Chemical compound C=12N=C(N(CCO)CCO)N=C(N3CCCCC3)C2=NC(N(CCO)CCO)=NC=1N1CCCCC1 IZEKFCXSFNUWAM-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Definitions
- This invention relates to a yarn finish. More specifically, this invention relates to a spin finish for polyamide feeder yarn to be processed at high temperature into carpet yarn such as by steam jet texturing.
- the spin finish composition shown below improves processing and gives better quality yarn.
- This finish composition has a unique combination of coconut oil and sulfonated petroleum product which provides an unusually even distribution of finish on the fiber in the yarn. In this way, more consistent frictional and physical properties of the yarn results.
- the unique spin finish of this invention is for high temperature carpet yarn processing, and is specifically designed for steam jet texturing processes. A level of 0.5 to 1.2 percent weight of oil on textured yarn can be achieved even though the finish is applied prior to steam jet texturizing, i.e. when the yarn is spun.
- composition has excellent stability to high temperature process conditions, provides lubrication, static protection and plasticity to the yarn for subsequent drawing and steam jet texturing or other high temperature processing.
- the yarn has more consistent physical and frictional properties from package to package and within the same package.
- This invention is a finish of an oil in water emulsion of about 10 to 20 percent by weight of the oil portion.
- the oil portion is made up of from about 55 to 65 percent by weight of coconut oil, about 3 to 8 percent of polyoxyethylene castor oil, about 5 to 10 percent by weight of decaglycerol tetraoleate, about 2 to 5 percent of glycerol monooleate, about 2 to 7 percent by weight of polyoxyethylene sorbitan monooleate, about 9 to 11 percent by weight of polyoxyethylene tallow glyceride, and about 8 to 12 percent by weight of sulfonated petroleum prod-. uct.
- the coconut oil is refined coconut glyceride
- the ethoxylated castor oil contains about 25 moles of ethylene oxide per mole of castor oil
- the ethoxylated sorbitan monooleate contains about 20 moles of ethylene oxide per mole of sorbitan monooleate
- the ethoxylated tallow glyceride contains about 15 moles of ethylene oxide per mole of tallow glyceride
- the sulfonated petroleum product is sodium petroleum sulfonate present as about 60 to 62 percent by weight atcive ingredient in mineral oil.
- the sodium petroleum sulfonate is based on an alkyl-aryl petroleum sulfonate having a typical formula (C 'H )SO Na where n is between about 20 and about 30. Even more preferably, the average molecular weight of the above chemical formula is about 430 and 30 percent of the petroleum product remains unsulfonated mineral oil.
- Table I shows the finish composition of the preferred embodiment of this invention.
- Table II shows the criticality of the ingredients and the amounts of ingredients necessary in order to provide a stable emulsion. Note that only the finish identified as A provides excellent emulsion stability after 48 hours. Varying the amounts or leaving out various components results in only fair or poor emulsion stability.
- Table III shows criticality of the amounts and the presence of various components in the processing of yarn. Note that only the composition labeled A has excellent texturing performance, tuftability, loses only 0.01 percent of the finish after steam jet texturing, and has by far the lowest yarn to metal friction reading.
- Formula of sulfonated petroleum product Alkyl-aryl petroleum sulfonate typical formula n 2n1o) 3 5 r z 20, 30 with 30% mineral oil content average molecular weight 430; sulfonate (S0 Na) 62% by weight.
- E ExcelentTrans1ucent bluish-white particle size less than 1 micron. No separation.
- F Fair-Milky white, particle size up to 4 microns. Slight ring of oil separation on surface.
- P PoorChalky white, particle size above 4 microns. Creaming on surface.
- Ethoxylated castor oil (25120) a 5. 5 Do. Decaglycerol tetraoleate- 7. 5 Do. Glycerol mono0leate 3- 0 Do. Ethoxylated sorbltan monooleate (ZOEO) 5. 0 Do Ethoxylated tallow glyceride (15E0) 10.0 Do. sodium petroleum sulfonate 60-62'7 active on mineral oil 10. 0 Antistat-emulsifiet. Sullated glycerol trioleate 18 0 15 0 Do. Ethoxylated tallow amine (20EO 0 D0.
- a spin finish for polyamide yarn to be processed at high temperature said finish being an oil in water emulsion of about 10 to 20 percent by weight of said oil portion, said oil portion consisting essentially of about to percent by weight of coconut oil, about 3 to 8 percent by weight of polyoxyethylene castor oil, about 5 to 10 percent by weight of decaglycerol tetraoleate, about 2 to 5 percent by weight of glycol monooleate, about 2 to 7 perecnt by weight of polyoxyethylene sorbitan monooleate, about 9 to 11 percent by weight of polyoxyethylene tallow glyceride, and about 8 to 12 percent by weight of sodium alkyl aryl petroleum sulfonate having a formula (C H- )SO Na Where n is between about 20 and about 30.
- a spin finish for polyarnide yarn to be processed at high temperature said finish being an oil in water emulsion of about 10 to 20 percent by weight of said oil portion, said oil portion consisting essentially of about 55 to 65 percent by weight of refined coconut glyceride, about 3 to 8 percent by weight of polyoxyethylene castor oil containing about 25 moles of ethylene oxide per mole of castor oil, about 5 to 10 percent by weight of decaglycerol tetraoleate, about 2 to 5 percent by weight of glycerol monooleate, about 2 to 7 percent by weight of polyoxyethylene sorbitan monooleate containing about 20 moles of ethylene oxide per mole of sorbitan monooleate, about 9 to 11 percent by weight of polyoxyethylene tallow glyceride containing about 15 moles of ethylene oxide per mole of tallow glyceride, and about 8 to 12 percent by weight of sodium petroleum sulfonate present as about 60 to 62% by weight active ingredient in mineral oil.
- the spin finish of claim 2 wherein the sodium petroleum sulfonate is based on an alkyl-aryl petroleum sulfonate having a formula (C H )SO Na where n is between about 20 and about 30.
- the spin finish of claim 3 is wherein the average molecular weight of the (C H )SO Na is about 430, and 30% of the petroleum product remains unsulfonated mineral oil.
- Colfimn 2 line 19, "atcive” should be --active-- Column 2, in Table I, add footnote (a) after "weight”, moles of ethylene oxide permole of base material- Table III, Footnote 3 11nder.item “F'f after "Less-than”, :the numeral "5" should bei50-- ColuI nn claim 4, line 1, "is” shouldbe deleted. after "claim 3" Signed and Sealed this 18th day June 1974,
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A SPIN FINISH COMPOSITION FOR NYLON FEEDER YARN TO BE PROCESSED AT HIGH TEMPERATURE INTO CARPET YARN, SUCH AS BY STEAM JET TEXTURING, COMPRISING COCONUT OIL, SULFONATED NATURAL PETROLEUM PRODUCT AND OTHER ESSENTIAL COMPONENTS RESULTS IN IMPROVED PROCESSING AND BETTER QUALITY YARN.
Description
United States Patent 3,781,202 SPIN FINISH FOR POLYAMIDE YARN PROCESSED AT HIGH TEMPERATURE Robert Moore Marshall, Chesterfield County, and Kimon Constantine Dardoufas, Richmond, Va., assignors to Allied Chemical Corporation, New York, N.Y. No Drawing. Filed Jan. 28, 1972, Ser. No. 221,828 Int. Cl. D06m 13/30 US. Cl. 2528.7 4 Claims ABSTRACT OF THE DISCLOSURE A spin finish composition for nylon feeder yarn to be processed at high temperature into carpet yarn, such as by steam jet texturing, comprising coconut oil, sulfonated natural petroleum product and other essential components results in improved processing and better quality yarn.
BACKGROUND OF THE INVENTION This invention relates to a yarn finish. More specifically, this invention relates to a spin finish for polyamide feeder yarn to be processed at high temperature into carpet yarn such as by steam jet texturing.
Various finishes for synthetic filaments are disclosed in the prior art for high temperature processing. However, none of the prior art teach a specific combination of ingredients to achieve the specific beneficial results of the composition of this invention. The critical amounts and ingredients are shown in the discussion below. Many of the prior art finishes flash olf in high temperature processing such as steam jet texturing for yarn. Others fail to have emulsion stability or have insufficient yarn lubrication.
SUMMARY OF THE INVENTION For treating polyamide feeder yarn to be processed at high temperature, such as in steam jet texturizing processes, the spin finish composition shown below improves processing and gives better quality yarn. This finish composition has a unique combination of coconut oil and sulfonated petroleum product which provides an unusually even distribution of finish on the fiber in the yarn. In this way, more consistent frictional and physical properties of the yarn results. The unique spin finish of this invention is for high temperature carpet yarn processing, and is specifically designed for steam jet texturing processes. A level of 0.5 to 1.2 percent weight of oil on textured yarn can be achieved even though the finish is applied prior to steam jet texturizing, i.e. when the yarn is spun. The composition has excellent stability to high temperature process conditions, provides lubrication, static protection and plasticity to the yarn for subsequent drawing and steam jet texturing or other high temperature processing. The yarn has more consistent physical and frictional properties from package to package and within the same package. Following is a list of the benefits of the composition of this invention.
(1) It is nonfuming, that is, it does not flash olf in high temperature processing such as steam jet texturing.
(2) It has excellent emulsion stability.
(3) This spin finish lubricates the yarn even after passing through high temperature processing such as steam jet.
(4) The finish improves texturing performance.
(5) An even distribution of the finish is achieved.
(6) The finish prevents static buildup.
(7) Plasticity is imparted to the yarn.
(8) Tuftability of the carpet yarn is improved.
"ice
This invention is a finish of an oil in water emulsion of about 10 to 20 percent by weight of the oil portion. The oil portion is made up of from about 55 to 65 percent by weight of coconut oil, about 3 to 8 percent of polyoxyethylene castor oil, about 5 to 10 percent by weight of decaglycerol tetraoleate, about 2 to 5 percent of glycerol monooleate, about 2 to 7 percent by weight of polyoxyethylene sorbitan monooleate, about 9 to 11 percent by weight of polyoxyethylene tallow glyceride, and about 8 to 12 percent by weight of sulfonated petroleum prod-. uct. Preferably, the coconut oil is refined coconut glyceride, the ethoxylated castor oil contains about 25 moles of ethylene oxide per mole of castor oil, the ethoxylated sorbitan monooleate contains about 20 moles of ethylene oxide per mole of sorbitan monooleate, the ethoxylated tallow glyceride contains about 15 moles of ethylene oxide per mole of tallow glyceride and the sulfonated petroleum product is sodium petroleum sulfonate present as about 60 to 62 percent by weight atcive ingredient in mineral oil. More preferably, the sodium petroleum sulfonate is based on an alkyl-aryl petroleum sulfonate having a typical formula (C 'H )SO Na where n is between about 20 and about 30. Even more preferably, the average molecular weight of the above chemical formula is about 430 and 30 percent of the petroleum product remains unsulfonated mineral oil.
Since, as shown in the data in the preferred embodiments, very little of this finish flashes off in high temperature processing, about 0.5 to 1.2% by weight of yarn, of oil is applied as spin finish, and about 0.5 to 1.2%, by weight, of the oil remains on the yarn after high temperature processing.
DESCRIPTION OF THE PREFERRED EMBODIMENTS Table I shows the finish composition of the preferred embodiment of this invention. Table II shows the criticality of the ingredients and the amounts of ingredients necessary in order to provide a stable emulsion. Note that only the finish identified as A provides excellent emulsion stability after 48 hours. Varying the amounts or leaving out various components results in only fair or poor emulsion stability.
Table III shows criticality of the amounts and the presence of various components in the processing of yarn. Note that only the composition labeled A has excellent texturing performance, tuftability, loses only 0.01 percent of the finish after steam jet texturing, and has by far the lowest yarn to metal friction reading.
Formula of sulfonated petroleum product Alkyl-aryl petroleum sulfonate typical formula n 2n1o) 3 5 r z 20, 30 with 30% mineral oil content average molecular weight 430; sulfonate (S0 Na) 62% by weight.
TABLE II.FINISH COMPOSITIONS Finish components Finish identities A B C D E F G H I J Refined coconut glyceride- 59. 59. 0 59. 0 60. 0 59. 0 60. 0 60. 0 60. 0 58. 0 59. 0 Lubricant. Ethoxylated castor oil (25150)- 5. 3. 0 6.0 5. 5 8.0 13. O 16.0 5. 0 Emulsifier. Decaglycerol tetraoleate- 7. 5 9. 0 7. 0 6. 0 7. 5 8. 0 6. O 9. 0 4. 0 4. 0 Do. Glycerol monooleate 3. 0 3. 0 4. 0 3. 0 7. 0 5. 0 5. 0 10. 0 5 0 Do. Ethoxylated sorbitan mo le 5. 0 7. 0 6. 0 5. 0 7. 0 6. 0 0. 0 4. Do. Ethoxylated tallow glyceride (EO) 10. 0 7. 0 13. 0 10. 0 10. 0 Do. Sodium petroleum sulfonate 60-62% active in mineral oil. 10. 0 12. 0 11. 0 Antistat emulsifier. Sulfated glycerol trloleate 0 Do. Ethoxylated tallow amine (20150). 0 Do. Emulsion stability after 45 hours E P P F F F F P F P See footnote at end of Table I.
E =ExcelentTrans1ucent bluish-white particle size less than 1 micron. No separation. F=Fair-Milky white, particle size up to 4 microns. Slight ring of oil separation on surface. P=PoorChalky white, particle size above 4 microns. Creaming on surface.
TABLE IIL-FINISH AND FIBER PROCESS DATA Finish components A K L M N 0 Finish identities:
Mineral oil (viscosity 50 SUS) 50.0 50. 0 Lubricant. Butyl stearate- 50. O 50. 0 Do. Hexadccyl stearate 50. 0 Do. Refined coconut glyceride- 59. 0 Do. Sorbitan mononlpate 25. 0 25.0 5.0 Do. Oleic sodium soap- 0 17. 0 8. 0 Antistat-emulslfier. Ethoxylated lauric acid (15E0) 1 8.0 15. 0 Emulsifier.
Ethoxylated oleyl ether (IOEO) e 7.0 7.0 Do.
Ethoxylated castor oil (25120) a 5. 5 Do. Decaglycerol tetraoleate- 7. 5 Do. Glycerol mono0leate 3- 0 Do. Ethoxylated sorbltan monooleate (ZOEO) 5. 0 Do Ethoxylated tallow glyceride (15E0) 10.0 Do. sodium petroleum sulfonate 60-62'7 active on mineral oil 10. 0 Antistat-emulsifiet. Sullated glycerol trioleate 18 0 15 0 Do. Ethoxylated tallow amine (20EO 0 D0.
Fiber process data:
Percent finish on drawn yarn by weight 76 1. 03 95 1. 08 85 Percent finish on yarn after steam jet texturing I 75 50 .58 .68 Texturing performance 1 E P P F Yarn to metal friction of text. yarn in grams 64 0 105 58 Tufting G P P F 1 Steam jet texturing at 3,000 f.p.m.E=Excellent; F=Fair; P=Poor.
3 Major part of butyl-stearate or mineral oil lost by volatization.
3 Tuiting=Tufting performance per 50 yards length of 180 ends carpet on the 30" slot type tufting machine (5/32 gauge)G= Good-Less than pull backs and less than 15 snags; F=FairLess than 5 pull backs and less than snags. P=Poor-More than pull backs and more than 30 snags.
I See footnote at end of Table I.
What is claimed is:
1. A spin finish for polyamide yarn to be processed at high temperature, said finish being an oil in water emulsion of about 10 to 20 percent by weight of said oil portion, said oil portion consisting essentially of about to percent by weight of coconut oil, about 3 to 8 percent by weight of polyoxyethylene castor oil, about 5 to 10 percent by weight of decaglycerol tetraoleate, about 2 to 5 percent by weight of glycol monooleate, about 2 to 7 perecnt by weight of polyoxyethylene sorbitan monooleate, about 9 to 11 percent by weight of polyoxyethylene tallow glyceride, and about 8 to 12 percent by weight of sodium alkyl aryl petroleum sulfonate having a formula (C H- )SO Na Where n is between about 20 and about 30.
2. A spin finish for polyarnide yarn to be processed at high temperature, said finish being an oil in water emulsion of about 10 to 20 percent by weight of said oil portion, said oil portion consisting essentially of about 55 to 65 percent by weight of refined coconut glyceride, about 3 to 8 percent by weight of polyoxyethylene castor oil containing about 25 moles of ethylene oxide per mole of castor oil, about 5 to 10 percent by weight of decaglycerol tetraoleate, about 2 to 5 percent by weight of glycerol monooleate, about 2 to 7 percent by weight of polyoxyethylene sorbitan monooleate containing about 20 moles of ethylene oxide per mole of sorbitan monooleate, about 9 to 11 percent by weight of polyoxyethylene tallow glyceride containing about 15 moles of ethylene oxide per mole of tallow glyceride, and about 8 to 12 percent by weight of sodium petroleum sulfonate present as about 60 to 62% by weight active ingredient in mineral oil.
3. The spin finish of claim 2 wherein the sodium petroleum sulfonate is based on an alkyl-aryl petroleum sulfonate having a formula (C H )SO Na where n is between about 20 and about 30.
4. The spin finish of claim 3 is wherein the average molecular weight of the (C H )SO Na is about 430, and 30% of the petroleum product remains unsulfonated mineral oil.
References Cited UNITED STATES PATENTS 2,565,403 '8/1951 Sproule et al. 2528.7 3,198,732 8/1965 Olney 2528.9 3,306,850 2/1967 Olsen 2528.7 3,672,977 6/1972 Dardoufas 2528.9 X 3,687,721 8/ 1972 Dardoufas 2528.9 X
HERBERT B. GUYNN, Primary Examiner US. Cl. X.R.
2872.12, WT; 1l7--138.8 N, 139.5 C.Q.; 2528.9
UNITED STATES PATENT OFFICE I CERTIFICATE- OF CORRECTION Patent No. 3,78 Dated December 25, 1973 m-( Robert Moore Marshall at al.
It is certified that error appears in the aboveidentified patent and that said Letters Patent are hereby correctedes shown below:
Colfimn 2, line 19, "atcive" should be --active-- Column 2, in Table I, add footnote (a) after "weight", moles of ethylene oxide permole of base material- Table III, Footnote 3 11nder.item "F'f after "Less-than", :the numeral "5" should bei50-- ColuI nn claim 4, line 1, "is" shouldbe deleted. after "claim 3" Signed and Sealed this 18th day June 1974,
(SEAL) Attest: I
EDWARD M.FLETCHE R,-JR. C. MARSHALL A DANN Attesting Officer Commissioner of Patents I FORM PO-1050 (10-69) UscOMM-DC scan-Pas I w [1.5. GOVERNMENT PRINTING OFFICE "I! 0-l66.-38l,
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22182872A | 1972-01-28 | 1972-01-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3781202A true US3781202A (en) | 1973-12-25 |
Family
ID=22829571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00221828A Expired - Lifetime US3781202A (en) | 1972-01-28 | 1972-01-28 | Spin finish for polyamide yarn processed at high temperature |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3781202A (en) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3954631A (en) * | 1974-08-09 | 1976-05-04 | Allied Chemical Corporation | Spin finish for textured carpet yarn |
| US3993571A (en) * | 1975-04-11 | 1976-11-23 | Allied Chemical Corporation | Spin finish for yarn used in food packaging |
| US4126564A (en) * | 1977-12-12 | 1978-11-21 | Allied Chemical Corporation | Spin finish for polyamide carpet yarn |
| US4134839A (en) * | 1978-02-02 | 1979-01-16 | Allied Chemical Corporation | Soil resistant spin finish for polyamide textile yarn |
| US4191656A (en) * | 1978-10-05 | 1980-03-04 | Allied Chemical Corporation | Non-yellowing biocide for control of bacteria in spin finish emulsions used on nylon yarn |
| US4192754A (en) * | 1978-12-28 | 1980-03-11 | Allied Chemical Corporation | Soil resistant yarn finish composition for synthetic organic polymer yarn |
| US4210700A (en) * | 1978-09-15 | 1980-07-01 | Allied Chemical Corporation | Production of polyester yarn |
| US4283292A (en) * | 1978-12-28 | 1981-08-11 | Allied Chemical Corporation | Soil resistant yarn finish for synthetic organic polymer yarn |
| US4371658A (en) * | 1980-05-05 | 1983-02-01 | Allied Corporation | Polyamide yarn spin finish containing a glyceride and oxidized polyethylene |
| US4389456A (en) * | 1981-10-30 | 1983-06-21 | Allied Corporation | Stabilized finish composition |
| US4390591A (en) * | 1981-10-30 | 1983-06-28 | Allied Corporation | Stabilized finish composition |
| EP0119948A2 (en) * | 1983-03-17 | 1984-09-26 | The Goodyear Tire & Rubber Company | Treated yarn, method of preparation and rubber/cord composite |
| US4957648A (en) * | 1987-08-06 | 1990-09-18 | The Lubrizol Corporation | Spin fiber lubricant compositions |
| US5011616A (en) * | 1990-02-23 | 1991-04-30 | Allied-Signal Inc. | Finish composition for fine denier polyamide yarn |
| WO2001009427A1 (en) * | 1999-07-30 | 2001-02-08 | Alliedsignal Inc. | Spin finish |
| US6365065B1 (en) | 1999-04-07 | 2002-04-02 | Alliedsignal Inc. | Spin finish |
| US20040007687A1 (en) * | 2002-07-11 | 2004-01-15 | Hubert Dobbelstein | Formulation of a highly viscous mineral oil for the production of filters for tobacco products |
| CN101949093A (en) * | 2010-09-17 | 2011-01-19 | 嘉兴高科新纤维有限公司 | Finish for nylon FDY and preparation method |
-
1972
- 1972-01-28 US US00221828A patent/US3781202A/en not_active Expired - Lifetime
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3954631A (en) * | 1974-08-09 | 1976-05-04 | Allied Chemical Corporation | Spin finish for textured carpet yarn |
| US3993571A (en) * | 1975-04-11 | 1976-11-23 | Allied Chemical Corporation | Spin finish for yarn used in food packaging |
| US4126564A (en) * | 1977-12-12 | 1978-11-21 | Allied Chemical Corporation | Spin finish for polyamide carpet yarn |
| US4134839A (en) * | 1978-02-02 | 1979-01-16 | Allied Chemical Corporation | Soil resistant spin finish for polyamide textile yarn |
| US4210700A (en) * | 1978-09-15 | 1980-07-01 | Allied Chemical Corporation | Production of polyester yarn |
| US4191656A (en) * | 1978-10-05 | 1980-03-04 | Allied Chemical Corporation | Non-yellowing biocide for control of bacteria in spin finish emulsions used on nylon yarn |
| US4192754A (en) * | 1978-12-28 | 1980-03-11 | Allied Chemical Corporation | Soil resistant yarn finish composition for synthetic organic polymer yarn |
| US4283292A (en) * | 1978-12-28 | 1981-08-11 | Allied Chemical Corporation | Soil resistant yarn finish for synthetic organic polymer yarn |
| US4371658A (en) * | 1980-05-05 | 1983-02-01 | Allied Corporation | Polyamide yarn spin finish containing a glyceride and oxidized polyethylene |
| US4389456A (en) * | 1981-10-30 | 1983-06-21 | Allied Corporation | Stabilized finish composition |
| US4390591A (en) * | 1981-10-30 | 1983-06-28 | Allied Corporation | Stabilized finish composition |
| EP0119948A2 (en) * | 1983-03-17 | 1984-09-26 | The Goodyear Tire & Rubber Company | Treated yarn, method of preparation and rubber/cord composite |
| EP0119948A3 (en) * | 1983-03-17 | 1987-12-09 | The Goodyear Tire & Rubber Company | Treated yarn, method of preparation and rubber/cord composite |
| US4957648A (en) * | 1987-08-06 | 1990-09-18 | The Lubrizol Corporation | Spin fiber lubricant compositions |
| US5011616A (en) * | 1990-02-23 | 1991-04-30 | Allied-Signal Inc. | Finish composition for fine denier polyamide yarn |
| US20020171061A1 (en) * | 1999-04-07 | 2002-11-21 | Ralf Klein | Spin finish |
| US6365065B1 (en) | 1999-04-07 | 2002-04-02 | Alliedsignal Inc. | Spin finish |
| US6770231B2 (en) | 1999-04-07 | 2004-08-03 | Alliedsignal, Inc | Spin finish |
| US20040144951A1 (en) * | 1999-07-30 | 2004-07-29 | Alliedsignal Inc. | Spin finish |
| US6712988B2 (en) | 1999-07-30 | 2004-03-30 | Honeywell International Inc. | Spin finish |
| WO2001009427A1 (en) * | 1999-07-30 | 2001-02-08 | Alliedsignal Inc. | Spin finish |
| US6426142B1 (en) | 1999-07-30 | 2002-07-30 | Alliedsignal Inc. | Spin finish |
| US6908579B2 (en) | 1999-07-30 | 2005-06-21 | Performance Fibers, Inc. | Process for making a yarn having a spin finish |
| US20050142360A1 (en) * | 1999-07-30 | 2005-06-30 | Ralf Klein | Spin finish |
| US7021349B2 (en) | 1999-07-30 | 2006-04-04 | Performance Fibers, Inc. | Spin finish |
| US20040007687A1 (en) * | 2002-07-11 | 2004-01-15 | Hubert Dobbelstein | Formulation of a highly viscous mineral oil for the production of filters for tobacco products |
| US7153447B2 (en) * | 2002-07-11 | 2006-12-26 | Emini Shefqet | Formulation of a highly viscous mineral oil for the production of filters for tobacco products |
| CN101949093A (en) * | 2010-09-17 | 2011-01-19 | 嘉兴高科新纤维有限公司 | Finish for nylon FDY and preparation method |
| CN101949093B (en) * | 2010-09-17 | 2012-05-02 | 嘉兴高科新纤维有限公司 | Finish for nylon FDY and preparation method |
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