US3488833A - Copper alloys for vacuum switches - Google Patents
Copper alloys for vacuum switches Download PDFInfo
- Publication number
- US3488833A US3488833A US550901A US3488833DA US3488833A US 3488833 A US3488833 A US 3488833A US 550901 A US550901 A US 550901A US 3488833D A US3488833D A US 3488833DA US 3488833 A US3488833 A US 3488833A
- Authority
- US
- United States
- Prior art keywords
- copper
- iron
- alloy
- copper alloys
- vacuum switches
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000881 Cu alloy Inorganic materials 0.000 title description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- 229910045601 alloy Inorganic materials 0.000 description 10
- 239000000956 alloy Substances 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 9
- 229910052802 copper Inorganic materials 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- 229910000640 Fe alloy Inorganic materials 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 229910001316 Ag alloy Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 101000635799 Homo sapiens Run domain Beclin-1-interacting and cysteine-rich domain-containing protein Proteins 0.000 description 1
- 102100030852 Run domain Beclin-1-interacting and cysteine-rich domain-containing protein Human genes 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- IYRDVAUFQZOLSB-UHFFFAOYSA-N copper iron Chemical compound [Fe].[Cu] IYRDVAUFQZOLSB-UHFFFAOYSA-N 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010943 off-gassing Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/021—Composite material
- H01H1/025—Composite material having copper as the basic material
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/10—Handling in a vacuum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/006—Pyrometallurgy working up of molten copper, e.g. refining
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/0203—Contacts characterised by the material thereof specially adapted for vacuum switches
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4998—Combined manufacture including applying or shaping of fluent material
- Y10T29/49988—Metal casting
- Y10T29/49989—Followed by cutting or removing material
Definitions
- This invention relates to the production of alloys for use in the contacts of vacuum switches.
- the alloy should have the following properties:
- a billet of O.F.H.C. (oxygen free, high conductivity) copper together with the required amount of high purity iron is placed in a previously degassed graphite crucible. If the iron were allowed to come into contact with the graphite crucible, before alloying with the copper, it would react with the graphite, causing damage to the crucible inside Wall and resulting in undue carbon pick-up in the melt. To prevent such contact, the iron is placed in a hole drilled in the copper billet. Using this method, no significant reaction occurs. The crucible is placed in a high frequency cvacuable furnace. To deoxidise the metal to the required low level of the order of 0.1 ppm. it is heated to 1350 C.
- O.F.H.C. oxygen free, high conductivity
- the temperature is then reduced to 1200 C. whilst the furnace is evacuated to a pressure of about mm. Hg, to degas the molten metal.
- the metal is then solidified progressively from the bottom upwards by slowly raising the induction heating coil. This method of solidification produces a pipe-free ingot and facilitates the removal of any gas which may remain in the molten metal.
- the graphite crucible wall is made sufliciently thin to be penetrated by the RF. field so that electromagnetic stirring of the molten metal is obtained.
- the fingers of a split contrate contact are stressed in bending, and the properties of alloys for this purpose were compared by loading small cantilever strips of the materials.
- the alloy samples are annealed at 700 C. for 2 hours and slowly cooled. After this treatment, the
- alloy of copper with 2% iron has an electrical conductivity of 55% IACS.
- the load required to give 0.020 deflection of the 2% iron alloy was 28 /2 lbs. compared with 13 lbs. for the 99% copper-1% silver alloy.
- the elastic springback from the 0.020 deflection was considerably higher for the copper alloy containing 2% iron, i.e., 0.011" compared with 0.005" for the copper alloy containing 1% silver.
- a pair of split-contrate switch contacts were made in the usual manner from a copper-2% iron alloy casting, to give a finger length of 1 /2".
- the machined contacts were annealed at 700 C. for two hours and allowed to cool slowly.
- the contacts were placed in a mechanical test rig with their fingers in juxtaposition as in normal use. A load of 1000 lbs. was applied to the pair of contacts and the amount of spring-back of the fingers was noted as the load was released.
- Spring-back commenced when the load has been reduced to 300 lbs. and proceeded almost linearly down to zero load.
- the total amount of spring-back was between 0.016" and 0.020", i.e., 0.008" to 0.010" for each contact. Satisfactory contact was thus maintained between all opposing pairs of fingers.
- a method of manufacturing a contact for an electric vacuum switch which comprises providing a charge consisting essentially of 95 to 99% by weight copper and 5 to 1% by weight high purity iron in a previously degassed graphite crucible; heating the said charge in a furnace at a temperature of about 1350 C. in an atmosphere of hydrogen for about one hour to form a homogeneous melt; degassing the molten metal by reducing the temperature of the melt to about 1200 C. while evacuating the furnace to a pressure of about 10 mm. Hg; solidifying the melt to form an alloy body; and forming a contact from the alloy body in the cast state by machining.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- High-Tension Arc-Extinguishing Switches Without Spraying Means (AREA)
- Contacts (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB22405/65A GB1129152A (en) | 1965-05-26 | 1965-05-26 | Copper alloys for vacuum switches |
Publications (1)
Publication Number | Publication Date |
---|---|
US3488833A true US3488833A (en) | 1970-01-13 |
Family
ID=10178843
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US550901A Expired - Lifetime US3488833A (en) | 1965-05-26 | 1966-05-18 | Copper alloys for vacuum switches |
Country Status (6)
Country | Link |
---|---|
US (1) | US3488833A (enrdf_load_stackoverflow) |
BE (1) | BE681664A (enrdf_load_stackoverflow) |
CH (1) | CH495620A (enrdf_load_stackoverflow) |
DE (1) | DE1533157A1 (enrdf_load_stackoverflow) |
GB (1) | GB1129152A (enrdf_load_stackoverflow) |
NL (1) | NL6607198A (enrdf_load_stackoverflow) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2203167B (en) * | 1987-03-25 | 1990-11-28 | Matsushita Electric Works Ltd | Composite conductive material and method for manufacturing same |
Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US184884A (en) * | 1876-11-28 | Improvement in composition alloys | ||
US298983A (en) * | 1884-05-20 | Process of purifying molten iron and steel | ||
US415656A (en) * | 1889-11-19 | Henri schneider | ||
US557182A (en) * | 1896-03-31 | Educational chart | ||
US1144034A (en) * | 1913-04-08 | 1915-06-22 | Anonima Italiana Gio Ansaldo & C Soc | Process for the treatment of steel. |
FR635673A (fr) * | 1926-05-26 | 1928-03-22 | Copper Deoxydation Corp | Procédé pyrométallurgique d'affinage et de coulée du cuivre |
US1921060A (en) * | 1931-03-23 | 1933-08-08 | Clyde E Williams | Method of purifying metals |
US2048824A (en) * | 1932-05-13 | 1936-07-28 | Simpson Kenneth Miller | Alloys and method of manufacture |
US2066512A (en) * | 1934-10-17 | 1937-01-05 | Smith Corp A O | Alloy |
US2140607A (en) * | 1935-10-19 | 1938-12-20 | American Metal Co Ltd | Method of and apparatus for casting deoxidized copper |
US2169187A (en) * | 1938-10-21 | 1939-08-08 | Westinghouse Electric & Mfg Co | Copper base alloy |
US2169189A (en) * | 1938-10-21 | 1939-08-08 | Westinghouse Electric & Mfg Co | Copper base alloy |
US2576267A (en) * | 1948-10-27 | 1951-11-27 | Bell Telephone Labor Inc | Preparation of germanium rectifier material |
US3019102A (en) * | 1960-08-19 | 1962-01-30 | American Metal Climax Inc | Copper-zirconium-hafnium alloys |
FR1480989A (fr) * | 1965-05-26 | 1967-05-12 | Ass Elect Ind | Procédé de préparation des alliages de cuivre pour les interrupteurs sous vide |
-
1965
- 1965-05-26 GB GB22405/65A patent/GB1129152A/en not_active Expired
-
1966
- 1966-05-18 US US550901A patent/US3488833A/en not_active Expired - Lifetime
- 1966-05-23 DE DE19661533157 patent/DE1533157A1/de active Pending
- 1966-05-24 CH CH746066A patent/CH495620A/de not_active IP Right Cessation
- 1966-05-25 NL NL6607198A patent/NL6607198A/xx unknown
- 1966-05-26 BE BE681664D patent/BE681664A/xx unknown
Patent Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US184884A (en) * | 1876-11-28 | Improvement in composition alloys | ||
US298983A (en) * | 1884-05-20 | Process of purifying molten iron and steel | ||
US415656A (en) * | 1889-11-19 | Henri schneider | ||
US557182A (en) * | 1896-03-31 | Educational chart | ||
US1144034A (en) * | 1913-04-08 | 1915-06-22 | Anonima Italiana Gio Ansaldo & C Soc | Process for the treatment of steel. |
FR635673A (fr) * | 1926-05-26 | 1928-03-22 | Copper Deoxydation Corp | Procédé pyrométallurgique d'affinage et de coulée du cuivre |
US1921060A (en) * | 1931-03-23 | 1933-08-08 | Clyde E Williams | Method of purifying metals |
US2048824A (en) * | 1932-05-13 | 1936-07-28 | Simpson Kenneth Miller | Alloys and method of manufacture |
US2066512A (en) * | 1934-10-17 | 1937-01-05 | Smith Corp A O | Alloy |
US2140607A (en) * | 1935-10-19 | 1938-12-20 | American Metal Co Ltd | Method of and apparatus for casting deoxidized copper |
US2169187A (en) * | 1938-10-21 | 1939-08-08 | Westinghouse Electric & Mfg Co | Copper base alloy |
US2169189A (en) * | 1938-10-21 | 1939-08-08 | Westinghouse Electric & Mfg Co | Copper base alloy |
US2576267A (en) * | 1948-10-27 | 1951-11-27 | Bell Telephone Labor Inc | Preparation of germanium rectifier material |
US3019102A (en) * | 1960-08-19 | 1962-01-30 | American Metal Climax Inc | Copper-zirconium-hafnium alloys |
FR1480989A (fr) * | 1965-05-26 | 1967-05-12 | Ass Elect Ind | Procédé de préparation des alliages de cuivre pour les interrupteurs sous vide |
Also Published As
Publication number | Publication date |
---|---|
NL6607198A (enrdf_load_stackoverflow) | 1966-11-28 |
CH495620A (de) | 1970-08-31 |
DE1533157A1 (de) | 1970-01-02 |
BE681664A (enrdf_load_stackoverflow) | 1966-10-31 |
GB1129152A (en) | 1968-10-02 |
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