US3488833A - Copper alloys for vacuum switches - Google Patents

Copper alloys for vacuum switches Download PDF

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Publication number
US3488833A
US3488833A US550901A US3488833DA US3488833A US 3488833 A US3488833 A US 3488833A US 550901 A US550901 A US 550901A US 3488833D A US3488833D A US 3488833DA US 3488833 A US3488833 A US 3488833A
Authority
US
United States
Prior art keywords
copper
iron
alloy
copper alloys
vacuum switches
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US550901A
Other languages
English (en)
Inventor
Arthur George Knapton
George Thomas Moors
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Associated Electrical Industries Ltd
Original Assignee
Associated Electrical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Associated Electrical Industries Ltd filed Critical Associated Electrical Industries Ltd
Application granted granted Critical
Publication of US3488833A publication Critical patent/US3488833A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/021Composite material
    • H01H1/025Composite material having copper as the basic material
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/10Handling in a vacuum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00Obtaining copper
    • C22B15/0026Pyrometallurgy
    • C22B15/006Pyrometallurgy working up of molten copper, e.g. refining
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/0203Contacts characterised by the material thereof specially adapted for vacuum switches
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4998Combined manufacture including applying or shaping of fluent material
    • Y10T29/49988Metal casting
    • Y10T29/49989Followed by cutting or removing material

Definitions

  • This invention relates to the production of alloys for use in the contacts of vacuum switches.
  • the alloy should have the following properties:
  • a billet of O.F.H.C. (oxygen free, high conductivity) copper together with the required amount of high purity iron is placed in a previously degassed graphite crucible. If the iron were allowed to come into contact with the graphite crucible, before alloying with the copper, it would react with the graphite, causing damage to the crucible inside Wall and resulting in undue carbon pick-up in the melt. To prevent such contact, the iron is placed in a hole drilled in the copper billet. Using this method, no significant reaction occurs. The crucible is placed in a high frequency cvacuable furnace. To deoxidise the metal to the required low level of the order of 0.1 ppm. it is heated to 1350 C.
  • O.F.H.C. oxygen free, high conductivity
  • the temperature is then reduced to 1200 C. whilst the furnace is evacuated to a pressure of about mm. Hg, to degas the molten metal.
  • the metal is then solidified progressively from the bottom upwards by slowly raising the induction heating coil. This method of solidification produces a pipe-free ingot and facilitates the removal of any gas which may remain in the molten metal.
  • the graphite crucible wall is made sufliciently thin to be penetrated by the RF. field so that electromagnetic stirring of the molten metal is obtained.
  • the fingers of a split contrate contact are stressed in bending, and the properties of alloys for this purpose were compared by loading small cantilever strips of the materials.
  • the alloy samples are annealed at 700 C. for 2 hours and slowly cooled. After this treatment, the
  • alloy of copper with 2% iron has an electrical conductivity of 55% IACS.
  • the load required to give 0.020 deflection of the 2% iron alloy was 28 /2 lbs. compared with 13 lbs. for the 99% copper-1% silver alloy.
  • the elastic springback from the 0.020 deflection was considerably higher for the copper alloy containing 2% iron, i.e., 0.011" compared with 0.005" for the copper alloy containing 1% silver.
  • a pair of split-contrate switch contacts were made in the usual manner from a copper-2% iron alloy casting, to give a finger length of 1 /2".
  • the machined contacts were annealed at 700 C. for two hours and allowed to cool slowly.
  • the contacts were placed in a mechanical test rig with their fingers in juxtaposition as in normal use. A load of 1000 lbs. was applied to the pair of contacts and the amount of spring-back of the fingers was noted as the load was released.
  • Spring-back commenced when the load has been reduced to 300 lbs. and proceeded almost linearly down to zero load.
  • the total amount of spring-back was between 0.016" and 0.020", i.e., 0.008" to 0.010" for each contact. Satisfactory contact was thus maintained between all opposing pairs of fingers.
  • a method of manufacturing a contact for an electric vacuum switch which comprises providing a charge consisting essentially of 95 to 99% by weight copper and 5 to 1% by weight high purity iron in a previously degassed graphite crucible; heating the said charge in a furnace at a temperature of about 1350 C. in an atmosphere of hydrogen for about one hour to form a homogeneous melt; degassing the molten metal by reducing the temperature of the melt to about 1200 C. while evacuating the furnace to a pressure of about 10 mm. Hg; solidifying the melt to form an alloy body; and forming a contact from the alloy body in the cast state by machining.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • High-Tension Arc-Extinguishing Switches Without Spraying Means (AREA)
  • Contacts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
US550901A 1965-05-26 1966-05-18 Copper alloys for vacuum switches Expired - Lifetime US3488833A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB22405/65A GB1129152A (en) 1965-05-26 1965-05-26 Copper alloys for vacuum switches

Publications (1)

Publication Number Publication Date
US3488833A true US3488833A (en) 1970-01-13

Family

ID=10178843

Family Applications (1)

Application Number Title Priority Date Filing Date
US550901A Expired - Lifetime US3488833A (en) 1965-05-26 1966-05-18 Copper alloys for vacuum switches

Country Status (6)

Country Link
US (1) US3488833A (enrdf_load_stackoverflow)
BE (1) BE681664A (enrdf_load_stackoverflow)
CH (1) CH495620A (enrdf_load_stackoverflow)
DE (1) DE1533157A1 (enrdf_load_stackoverflow)
GB (1) GB1129152A (enrdf_load_stackoverflow)
NL (1) NL6607198A (enrdf_load_stackoverflow)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2203167B (en) * 1987-03-25 1990-11-28 Matsushita Electric Works Ltd Composite conductive material and method for manufacturing same

Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US184884A (en) * 1876-11-28 Improvement in composition alloys
US298983A (en) * 1884-05-20 Process of purifying molten iron and steel
US415656A (en) * 1889-11-19 Henri schneider
US557182A (en) * 1896-03-31 Educational chart
US1144034A (en) * 1913-04-08 1915-06-22 Anonima Italiana Gio Ansaldo & C Soc Process for the treatment of steel.
FR635673A (fr) * 1926-05-26 1928-03-22 Copper Deoxydation Corp Procédé pyrométallurgique d'affinage et de coulée du cuivre
US1921060A (en) * 1931-03-23 1933-08-08 Clyde E Williams Method of purifying metals
US2048824A (en) * 1932-05-13 1936-07-28 Simpson Kenneth Miller Alloys and method of manufacture
US2066512A (en) * 1934-10-17 1937-01-05 Smith Corp A O Alloy
US2140607A (en) * 1935-10-19 1938-12-20 American Metal Co Ltd Method of and apparatus for casting deoxidized copper
US2169187A (en) * 1938-10-21 1939-08-08 Westinghouse Electric & Mfg Co Copper base alloy
US2169189A (en) * 1938-10-21 1939-08-08 Westinghouse Electric & Mfg Co Copper base alloy
US2576267A (en) * 1948-10-27 1951-11-27 Bell Telephone Labor Inc Preparation of germanium rectifier material
US3019102A (en) * 1960-08-19 1962-01-30 American Metal Climax Inc Copper-zirconium-hafnium alloys
FR1480989A (fr) * 1965-05-26 1967-05-12 Ass Elect Ind Procédé de préparation des alliages de cuivre pour les interrupteurs sous vide

Patent Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US184884A (en) * 1876-11-28 Improvement in composition alloys
US298983A (en) * 1884-05-20 Process of purifying molten iron and steel
US415656A (en) * 1889-11-19 Henri schneider
US557182A (en) * 1896-03-31 Educational chart
US1144034A (en) * 1913-04-08 1915-06-22 Anonima Italiana Gio Ansaldo & C Soc Process for the treatment of steel.
FR635673A (fr) * 1926-05-26 1928-03-22 Copper Deoxydation Corp Procédé pyrométallurgique d'affinage et de coulée du cuivre
US1921060A (en) * 1931-03-23 1933-08-08 Clyde E Williams Method of purifying metals
US2048824A (en) * 1932-05-13 1936-07-28 Simpson Kenneth Miller Alloys and method of manufacture
US2066512A (en) * 1934-10-17 1937-01-05 Smith Corp A O Alloy
US2140607A (en) * 1935-10-19 1938-12-20 American Metal Co Ltd Method of and apparatus for casting deoxidized copper
US2169187A (en) * 1938-10-21 1939-08-08 Westinghouse Electric & Mfg Co Copper base alloy
US2169189A (en) * 1938-10-21 1939-08-08 Westinghouse Electric & Mfg Co Copper base alloy
US2576267A (en) * 1948-10-27 1951-11-27 Bell Telephone Labor Inc Preparation of germanium rectifier material
US3019102A (en) * 1960-08-19 1962-01-30 American Metal Climax Inc Copper-zirconium-hafnium alloys
FR1480989A (fr) * 1965-05-26 1967-05-12 Ass Elect Ind Procédé de préparation des alliages de cuivre pour les interrupteurs sous vide

Also Published As

Publication number Publication date
NL6607198A (enrdf_load_stackoverflow) 1966-11-28
CH495620A (de) 1970-08-31
DE1533157A1 (de) 1970-01-02
BE681664A (enrdf_load_stackoverflow) 1966-10-31
GB1129152A (en) 1968-10-02

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