US3471379A - Tin plating baths - Google Patents
Tin plating baths Download PDFInfo
- Publication number
- US3471379A US3471379A US521803A US3471379DA US3471379A US 3471379 A US3471379 A US 3471379A US 521803 A US521803 A US 521803A US 3471379D A US3471379D A US 3471379DA US 3471379 A US3471379 A US 3471379A
- Authority
- US
- United States
- Prior art keywords
- bath
- tin
- baths
- electroplating
- brightening agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title description 15
- 238000007747 plating Methods 0.000 title description 2
- 150000001728 carbonyl compounds Chemical class 0.000 description 15
- 238000009713 electroplating Methods 0.000 description 14
- 238000005282 brightening Methods 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 10
- -1 aromatic carbonyl compound Chemical class 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 150000001450 anions Chemical class 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 125000000623 heterocyclic group Chemical group 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910001432 tin ion Inorganic materials 0.000 description 3
- VCDPHYIZVFJQCD-ZRDIBKRKSA-N (2e)-2-benzylidenecyclohexan-1-one Chemical compound O=C1CCCC\C1=C/C1=CC=CC=C1 VCDPHYIZVFJQCD-ZRDIBKRKSA-N 0.000 description 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 2
- BTQAJGSMXCDDAJ-UHFFFAOYSA-N 2,4,6-trihydroxybenzaldehyde Chemical compound OC1=CC(O)=C(C=O)C(O)=C1 BTQAJGSMXCDDAJ-UHFFFAOYSA-N 0.000 description 2
- LWRSYTXEQUUTKW-UHFFFAOYSA-N 2,4-dimethoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C(OC)=C1 LWRSYTXEQUUTKW-UHFFFAOYSA-N 0.000 description 2
- BMKTYUNXUYXQDZ-UHFFFAOYSA-N 2,6-dimethyl-3,6-dihydro-2h-pyran Chemical compound CC1CC=CC(C)O1 BMKTYUNXUYXQDZ-UHFFFAOYSA-N 0.000 description 2
- IBGBGRVKPALMCQ-UHFFFAOYSA-N 3,4-dihydroxybenzaldehyde Chemical compound OC1=CC=C(C=O)C=C1O IBGBGRVKPALMCQ-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- 241001070947 Fagus Species 0.000 description 2
- 235000010099 Fagus sylvatica Nutrition 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 229930016911 cinnamic acid Natural products 0.000 description 2
- 235000013985 cinnamic acid Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 2
- SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical compound OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- VCDPHYIZVFJQCD-BENRWUELSA-N (2z)-2-benzylidenecyclohexan-1-one Chemical group O=C1CCCC\C1=C\C1=CC=CC=C1 VCDPHYIZVFJQCD-BENRWUELSA-N 0.000 description 1
- BATOPAZDIZEVQF-MQQKCMAXSA-N (E,E)-2,4-hexadienal Chemical compound C\C=C\C=C\C=O BATOPAZDIZEVQF-MQQKCMAXSA-N 0.000 description 1
- UUKRKWJGNHNTRG-NSCUHMNNSA-N (e)-4-(4-chlorophenyl)but-3-en-2-one Chemical compound CC(=O)\C=C\C1=CC=C(Cl)C=C1 UUKRKWJGNHNTRG-NSCUHMNNSA-N 0.000 description 1
- LLVCDRTZBYXKII-CMDGGOBGSA-N (e)-5-methyl-1-phenylhex-1-en-3-one Chemical compound CC(C)CC(=O)\C=C\C1=CC=CC=C1 LLVCDRTZBYXKII-CMDGGOBGSA-N 0.000 description 1
- ZHSYTKRINSGEEO-UHFFFAOYSA-N 1,5-bis[4-(2-methylphenyl)phenyl]penta-1,4-dien-3-one Chemical compound C1(=C(C=CC=C1)C1=CC=C(C=CC(=O)C=CC2=CC=C(C=C2)C2=C(C=CC=C2)C)C=C1)C ZHSYTKRINSGEEO-UHFFFAOYSA-N 0.000 description 1
- KUIZKZHDMPERHR-UHFFFAOYSA-N 1-phenylprop-2-en-1-one Chemical compound C=CC(=O)C1=CC=CC=C1 KUIZKZHDMPERHR-UHFFFAOYSA-N 0.000 description 1
- HWELBVQVOKFQTR-UHFFFAOYSA-N 2,6-dimethyl-3,6-dihydro-2h-pyran-5-carbaldehyde Chemical compound CC1CC=C(C=O)C(C)O1 HWELBVQVOKFQTR-UHFFFAOYSA-N 0.000 description 1
- RILZRCJGXSFXNE-UHFFFAOYSA-N 2-[4-(trifluoromethoxy)phenyl]ethanol Chemical compound OCCC1=CC=C(OC(F)(F)F)C=C1 RILZRCJGXSFXNE-UHFFFAOYSA-N 0.000 description 1
- PCYGLFXKCBFGPC-UHFFFAOYSA-N 3,4-Dihydroxy hydroxymethyl benzene Natural products OCC1=CC=C(O)C(O)=C1 PCYGLFXKCBFGPC-UHFFFAOYSA-N 0.000 description 1
- AVPYQKSLYISFPO-UHFFFAOYSA-N 4-chlorobenzaldehyde Chemical compound ClC1=CC=C(C=O)C=C1 AVPYQKSLYISFPO-UHFFFAOYSA-N 0.000 description 1
- BWHOZHOGCMHOBV-UHFFFAOYSA-N Benzalacetone Natural products CC(=O)C=CC1=CC=CC=C1 BWHOZHOGCMHOBV-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PIYTVILTPAHABD-UHFFFAOYSA-N acetaldehyde;2-methylaniline Chemical compound CC=O.CC1=CC=CC=C1N PIYTVILTPAHABD-UHFFFAOYSA-N 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- WRUAHXANJKHFIL-UHFFFAOYSA-N benzene-1,3-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC(S(O)(=O)=O)=C1 WRUAHXANJKHFIL-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- KBEBGUQPQBELIU-UHFFFAOYSA-N cinnamic acid ethyl ester Natural products CCOC(=O)C=CC1=CC=CC=C1 KBEBGUQPQBELIU-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- IQZPDFORWZTSKT-UHFFFAOYSA-N nitrosulphonic acid Chemical compound OS(=O)(=O)[N+]([O-])=O IQZPDFORWZTSKT-UHFFFAOYSA-N 0.000 description 1
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- BATOPAZDIZEVQF-UHFFFAOYSA-N sorbic aldehyde Natural products CC=CC=CC=O BATOPAZDIZEVQF-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 description 1
- BWHOZHOGCMHOBV-BQYQJAHWSA-N trans-benzylideneacetone Chemical compound CC(=O)\C=C\C1=CC=CC=C1 BWHOZHOGCMHOBV-BQYQJAHWSA-N 0.000 description 1
- DQFBYFPFKXHELB-VAWYXSNFSA-N trans-chalcone Chemical compound C=1C=CC=CC=1C(=O)\C=C\C1=CC=CC=C1 DQFBYFPFKXHELB-VAWYXSNFSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/30—Electroplating: Baths therefor from solutions of tin
- C25D3/32—Electroplating: Baths therefor from solutions of tin characterised by the organic bath constituents used
Definitions
- Electroplating bath for providing a bright tin deposit containing an anion, a non-ionic surfactant, tin ions and as a brightening agent, a carbonyl compound such as a heterocyclic or aromatic carbonyl compound with the carbonyl group directly attached to the ring.
- This invention relates to improvements in electroplating baths for obtaining bright tin deposits.
- Electroplating baths for the deposition of tin are well known. However, most of these baths suffer from the fact that the resultant tin deposits have a dull appearance which is unsuitable for many purposes. To brighten the tin deposits it was necessary to heat the deposit for a critical period of time and temperature.
- a principal object then of our invention is to provide an improved electroplating bath for the deposition of bright tin deposits. This and other objects of our invention will be apparent from the description that follows.
- an acid electroplating bath containing bivalent tin ions, at least one anion selected from the group consisting of sulfate, benzenesulfonate and fluoborate ions, a reducing agent, a non-ionic surfactant and as a brightening agent a carbonyl compound selected from the group consisting of aromatic andv heterocyclic ring containing aldehydes wherein the carbonyl group is directly attached to an aromatic or aromatic ring and a, ,8 olefinically unsaturated carbonyl compounds.
- the electroplating baths of our invention have the advantages of readily providing bright tin deposits even on work pieces having sharp edges or small apertures, allowing the electroplating to be carried out in a drum and permitting current densities of a factor of up to 1000.
- baths of our invention have'the decided-- advantage of being particularly stable.
- the bright tin deposits are immediately obtained.
- the tin-plated objects when removed from the bath, are coated with a thin brown-black layer which is readily removed by rinsing in a dilute alkali solution.
- the surfactant be a non-ionic surfactant as we have found that ionic surfactants do not 3,471,379 Patented Oct. 7, 1969 form a bright tin deposit over a wide range of current densities.
- both the carbonyl compound and the surfactant be employed as the surfactant alone does not provide bright tin deposits and the carbonyl compounds alone provide bright tin deposits only in a very restricted range of current densities (about 5 to 20 A./cm.
- the carbonyl compounds alone are not satisfactory for work pieces having sharp edges or plating carried out in a drum where the current density varies by a factor of or more.
- the carbonyl compounds employed must be free of ionizable substituents and substituents reducible in the bath.
- undesirable substituents are nitro, sulfonic acid, carboxylic acid, amino groups and substituted amino groups.
- the at, 3 olefinically unsaturated carbonyl compound is a compound of the formula:
- R2 R3 R4 wherein each of the symbols R R and R is a hydrogen atom, an aromatic, heterocyclic or aliphatic group or such a group wholly or partly hydrogenated, having, as the case may be, non-ionizable substituents or substituents not reducible in this medium, R is hydrogen, an alkyl group or an esterified carboxylic group or wherein the combination v I ll R13 is,.for example not in tautomeric relationship to form it. t,
- the carbonyl compounds themselves or derivatives of the carbonyl compounds which are converted by hydrolysis in the bath into the carbonyl compounds may be employed.
- brightening compounds Only small quantities of the carbonyl compounds (hereinafter called brightening compounds) are required. Thus quantities as small as about 25 mgs. per litre of bath liquid or even less are frequently sufficient. The upper limit is determined only by economic reasons and the solubility of the brightening agent.
- concentration of the non-ionic surfactant may vary considerably usually from about 0.1 g. to 10 g. per litre of bath liquid.
- non-ionic surfactants examples include Detergents and Emulsifiers 1963 Annual. John W. McCutcheon, -Inc., Morristown, New
- Example 1 An aqueous tin-plating bath of the following composition was prepared:
- An acid electroplating bath for depositing bright deposits of tin, said bath comprising an aqueous solution containing tin ions, at least one anion selected from the group consisting of sulfate, benzenesulfonate and fluoroborate ions, a reducing agent, a non-ionic surfactant and as the sole brightening agent at least about 25 mg. per liter of a carbonyl compound selected from the group consisting of A -dihydro-o-tolylaldehyde, A -dihydrobenzaldehyde, 3-formyl, 5,6-dihydro-2,6-dimethylpyrane and 2-benzalcyclohexanone.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL6501841A NL128321C (enrdf_load_stackoverflow) | 1965-02-13 | 1965-02-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3471379A true US3471379A (en) | 1969-10-07 |
Family
ID=19792365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US521803A Expired - Lifetime US3471379A (en) | 1965-02-13 | 1966-01-20 | Tin plating baths |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3471379A (enrdf_load_stackoverflow) |
| AT (1) | AT259965B (enrdf_load_stackoverflow) |
| BE (1) | BE676396A (enrdf_load_stackoverflow) |
| DE (1) | DE1496940B2 (enrdf_load_stackoverflow) |
| ES (1) | ES322902A1 (enrdf_load_stackoverflow) |
| FR (1) | FR1468083A (enrdf_load_stackoverflow) |
| GB (1) | GB1141283A (enrdf_load_stackoverflow) |
| NL (1) | NL128321C (enrdf_load_stackoverflow) |
| SE (1) | SE309141B (enrdf_load_stackoverflow) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3634212A (en) * | 1970-05-06 | 1972-01-11 | M & T Chemicals Inc | Electrodeposition of bright acid tin and electrolytes therefor |
| US3755096A (en) * | 1971-07-01 | 1973-08-28 | M & T Chemicals Inc | Bright acid tin plating |
| US3769182A (en) * | 1970-10-22 | 1973-10-30 | Conversion Chem Corp | Bath and method for electrodepositing tin and/or lead |
| US3875029A (en) * | 1974-02-19 | 1975-04-01 | R O Hull & Company Inc | Plating bath for electrodeposition of bright tin and tin-lead alloy |
| US4207148A (en) * | 1975-11-28 | 1980-06-10 | Minnesota Mining And Manufacturing Company | Electroplating bath for the electrodeposition of tin and tin/cadmium deposits |
| US4242182A (en) * | 1978-07-21 | 1980-12-30 | Francine Popescu | Bright tin electroplating bath |
| US5814202A (en) * | 1997-10-14 | 1998-09-29 | Usx Corporation | Electrolytic tin plating process with reduced sludge production |
| US20050211561A1 (en) * | 1999-08-06 | 2005-09-29 | Ibiden Co., Ltd. | Electroplating solution, method for manufacturing multilayer printed circuit board using the same solution, and multilayer printed circuit board |
| CN103898570A (zh) * | 2012-12-27 | 2014-07-02 | 罗门哈斯电子材料有限公司 | 锡或锡合金电镀液 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL151449B (nl) * | 1966-09-14 | 1976-11-15 | Philips Nv | Werkwijze voor de bereiding van een zuur bad voor het elektrolytisch neerslaan van tin. |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE299792C (enrdf_load_stackoverflow) * | 1917-03-15 | |||
| US2870070A (en) * | 1957-07-17 | 1959-01-20 | United States Steel Corp | Electrodeposition of tin and electrolyte therefor |
| GB842898A (en) * | 1956-01-16 | 1960-07-27 | Ingeborg Geldbach | Method of electrolytically depositing smooth layers of tin |
| US3361652A (en) * | 1963-08-28 | 1968-01-02 | Max Schlotter Dr Ing | Electrodeposition of bright tin |
-
1965
- 1965-02-13 NL NL6501841A patent/NL128321C/xx active
-
1966
- 1966-01-20 US US521803A patent/US3471379A/en not_active Expired - Lifetime
- 1966-02-10 DE DE19661496940 patent/DE1496940B2/de active Pending
- 1966-02-10 GB GB5877/66A patent/GB1141283A/en not_active Expired
- 1966-02-10 AT AT120266A patent/AT259965B/de active
- 1966-02-10 SE SE1713/66A patent/SE309141B/xx unknown
- 1966-02-11 FR FR49314A patent/FR1468083A/fr not_active Expired
- 1966-02-11 ES ES0322902A patent/ES322902A1/es not_active Expired
- 1966-02-11 BE BE676396D patent/BE676396A/xx unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE299792C (enrdf_load_stackoverflow) * | 1917-03-15 | |||
| GB842898A (en) * | 1956-01-16 | 1960-07-27 | Ingeborg Geldbach | Method of electrolytically depositing smooth layers of tin |
| US2870070A (en) * | 1957-07-17 | 1959-01-20 | United States Steel Corp | Electrodeposition of tin and electrolyte therefor |
| US3361652A (en) * | 1963-08-28 | 1968-01-02 | Max Schlotter Dr Ing | Electrodeposition of bright tin |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3634212A (en) * | 1970-05-06 | 1972-01-11 | M & T Chemicals Inc | Electrodeposition of bright acid tin and electrolytes therefor |
| US3769182A (en) * | 1970-10-22 | 1973-10-30 | Conversion Chem Corp | Bath and method for electrodepositing tin and/or lead |
| US3755096A (en) * | 1971-07-01 | 1973-08-28 | M & T Chemicals Inc | Bright acid tin plating |
| US3875029A (en) * | 1974-02-19 | 1975-04-01 | R O Hull & Company Inc | Plating bath for electrodeposition of bright tin and tin-lead alloy |
| US4207148A (en) * | 1975-11-28 | 1980-06-10 | Minnesota Mining And Manufacturing Company | Electroplating bath for the electrodeposition of tin and tin/cadmium deposits |
| US4242182A (en) * | 1978-07-21 | 1980-12-30 | Francine Popescu | Bright tin electroplating bath |
| US5814202A (en) * | 1997-10-14 | 1998-09-29 | Usx Corporation | Electrolytic tin plating process with reduced sludge production |
| US20050211561A1 (en) * | 1999-08-06 | 2005-09-29 | Ibiden Co., Ltd. | Electroplating solution, method for manufacturing multilayer printed circuit board using the same solution, and multilayer printed circuit board |
| US20080230263A1 (en) * | 1999-08-06 | 2008-09-25 | Ibiden Co., Ltd. | Electroplating solution, method for manufacturing multilayer printed circuit board using the same solution, and multilayer printed circuit board |
| US7812262B2 (en) | 1999-08-06 | 2010-10-12 | Ibiden Co., Ltd. | Multilayer printed circuit board |
| US7993510B2 (en) * | 1999-08-06 | 2011-08-09 | Ibiden Co., Ltd. | Electroplating solution, method for manufacturing multilayer printed circuit board using the same solution, and multilayer printed circuit board |
| CN103898570A (zh) * | 2012-12-27 | 2014-07-02 | 罗门哈斯电子材料有限公司 | 锡或锡合金电镀液 |
| US20140183050A1 (en) * | 2012-12-27 | 2014-07-03 | Rohm And Haas Electronic Materials Llc | Tin or tin alloy plating liquid |
| US9926637B2 (en) | 2012-12-27 | 2018-03-27 | Rohm And Haas Electronic Materials Llc | Tin or tin alloy plating liquid |
Also Published As
| Publication number | Publication date |
|---|---|
| AT259965B (de) | 1968-02-12 |
| SE309141B (enrdf_load_stackoverflow) | 1969-03-10 |
| NL6501841A (enrdf_load_stackoverflow) | 1966-08-15 |
| FR1468083A (fr) | 1967-02-03 |
| ES322902A1 (es) | 1966-11-16 |
| BE676396A (enrdf_load_stackoverflow) | 1966-08-11 |
| DE1496940B2 (de) | 1971-04-15 |
| NL128321C (enrdf_load_stackoverflow) | |
| GB1141283A (en) | 1969-01-29 |
| DE1496940A1 (de) | 1970-10-01 |
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