Classifications

• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
  • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
  • D21C9/10—Bleaching ; Apparatus therefor
  • D21C9/1026—Other features in bleaching processes
  • D21C9/1036—Use of compounds accelerating or improving the efficiency of the processes
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
  • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
  • D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
  • D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives

Definitions

• This invention relates to a process for the bleaching of cellulosic materials, especially fibrous cellulosic materials, such as wood pulp and straw. It further relates to an improved process resulting in a high order of economy from hydrogen peroxide bleaching.
• the primary object of bleaching cellulosic materials is to remove color-causing noncellulosic impurities from cellulose, or to modify them to facilitate their removal in a subsequent step.
• pulp of the wood it is customary to treat a pulp of the wood with chlorine, whereby much of the noncellulosic material is oxidized.
• a subsequent treatment step" with alkali such as sodium hydroxide causes the dissolution of oxidized noncellulosic material and its removal as soluble, colored bodies in wash liquors. Subsequent steps of washing and bleaching then lighten the color of the cellulose. It is conventional to employ hypochlorite, chlorine dioxide and hydrogen peroxide in these subsequent steps to result in bleached cellulose.
• steps employed in a bleaching sequence depends to a large degree upon the type of pulp employed and upon its prior treatment.
• Chemical wood pulp is often submitted to a sequence of bleaching steps which include a treatment with chlorine, a treatment with alkali (such as sodium hydroxide), a treatment with alkali metal hypochlorite (e.g., sodium hypochlorite), and one or more additional steps employing hydrogen peroxide or other oxidizing agent to produce a final high degree of whiteness.
• alkali such as sodium hydroxide
• alkali metal hypochlorite e.g., sodium hypochlorite
• additional steps employing hydrogen peroxide or other oxidizing agent to produce a final high degree of whiteness.
• Textile materials such as cotton are bleached in a sequence of steps although ordinarily a suitable textile sequence involves fewer steps than is employed in the bleaching of pulp.
• a suitable textile sequence involves fewer steps than is employed in the bleaching of pulp.
• Processes for bleaching cellulosic materials therefore involve a sequence of bleaching steps which include and often terminate with a treatment by hydrogen peroxide.
• a large portion of the hydrogen peroxide does not produce any bleaching.
• Often as much as 30 or 40 percent, commonly 25 percent by weight. of the hydrogen peroxide is discarded in the spent liquor because the concentration of hydrogen peroxide has become so low that it will no longer bleach rapidly.
• cellulosic material such as wood pulp and other natural cellulosic materials
• cellulosic material may be bleached by a sequence of steps utilizing hydrogen peroxide in one or more of such steps with substantial utilization of the hydrogen peroxide. It has been found that the rate at which hydrogen peroxide solution will bleach cellulosic materials may be accelerated to an economically attractive level when the hydrogen peroxide content is at low levels such as 1.0 percent by weight of the pulp or below.
• the addition of lower carboxylic acid anhydride in accordance herewith promotes the rate of reaction to consume all residual hydrogen peroxide in approximately minutes.
• an aqueous slurry of cellulosic material containing hydrogen peroxide at very low levels such as 0.1 percent 3,l93,445 Patented July 6, 1965 by weight of pulp or even less may be treated as herein disclosed to consume all the hydrogen peroxide. Concentrations of hydrogen peroxide of less than 0.5 percent by weight of pulp are often economically utilized.
• cellulosic material notably wood pulp
• This invention thus, in a principal embodiment, involves a two-stage procedure wherein organic carboxylic acid anhydride is added to a mixture of bleached pulp (or other cellulosic material) and bleaching liquors partially but incompletely depleted of hydrogen peroxide.
• a pulp of fibrous cellulosic materials is contacted with an aqueous solution containing alkaline aqueous hydrogen peroxide under conditions of temperature and time such that bleaching occurs and a substantial change in the light reflectance is observed.
• organic carboxylic acid notably acetic anhydride, is added to the resulting pulp-hydrogen peroxide system and the bleaching continued.
• Pulp suitably treated in performance of this invention may be groundwood pulp. This is prepared by grinding wood of specified types with water in conventional pulp-making apparatus to obtain a slurry. The concentration of pulp (equivalent to weight percent) is expressed as percent consistency and has become the industrys standard as defined by the Technical Association of the Paper and Pulp Industries (TAPPI).
• TAPPI Technical Association of the Paper and Pulp Industries
• any available commercial wood pulp may be employed although a typical wood pulp is composed of coniferous wood with a-minor portion of aspen.
• Hardwood pulps such as those available in the south may also be employed although it is preferred to employ preliminary treatment for the prior removal of ligneous impurities.
• Other pulps useful in this invention may be prepared from bagasse and straw.
• Pulp at a suitable consistency is treated herein with an aqueous solution containing hydrogen peroxide to obtain a preliminary bleach.
• Alkali may be added either separately or with the hydrogen peroxide to provide a distinct alkaline reaction.
• Bleaching of the pulp begins on admixture with hydrogen peroxide.
• the rate of bleaching is slow at temperatures near 25 C. and impractical periods of time would be required to produce an appreciable brightening of the pulp.
• a temperature of 40 to (3., notably 60 C. is employed.
• bleaching with hydrogen peroxide alone requires approximately 0.5 hour.
• Hydrogen peroxide for use herein may be provided as v a dilute aqueous hydrogen peroxide or as 50 percent by weight hydrogen peroxide as commercially available. If prepared in advance of utilization it has been found desirable to add sodium silicate solution and magnesium sulfate to the hydrogen peroxide to serve as bleach stabilizers. Alternately the hydrogen peroxide may be added directly to the pulp for bleaching. Various stabilizers such as sodium silicate or magnesium sulfate may likewise be added to the pulp at the commencement of the bleaching operation.
• the concentration of the chemicals employed in the practice hereof may be varied to suit conditions such as the degree of bleaching desired, the type of pulp employed, and the number of other steps employed in the bleaching sequence.
• the pulp concentration may be adjusted to 3 percent consistency. When bleached at such a consistency it is preferred to adjust the sodium silicate to percent by weight of the pulp solids. It is likewise preferred to adjust the magnesium sulfate concentration to 0.05 percent by weight of the pulp solids.
• Initial hydrogen peroxide concentration may be adjusted from 1 to percent by weight of the pulp solids, preferably 10 to 2 percent by weight.
• the pulp is then bleached by heating to a temperature selected within the bleaching range of to 100 C., by way of illustration 60 C.
• a sample of the pulp slurry is tested by conventional titration procedure and the residual hydrogen peroxide content is determined. Often one-half the original peroxide remains. From this, the required molar equivalent of carboxylic acid anhydride is calculated, for example, acetic anhydride, and is added thereto. In approximately 5 minutes the bleaching is complete and the pulp is washed and processed -in known manner.
• Organic carboxylic acid anhydrides which are useful in this invention include anhydrides a monobasic or dibasic saturated carboxylic acid containing 2 to 8 carbon atoms. It is desired that the more reactive acid anhydrides are employed, for example the anhydrides of formic acid, acetic acid, propionic acid, n-butyric acid, isobutyric acid, malonic acid, succinic acid, and their mixed anhydrides. Preferred for economic reasons is acetic anhydride.
• Bleaching is most advantageously carried out stepwise to obtain the benefits of bleaching with hydrogen peroxide alone in order to avoid too rapid bleaching and possible loss of hydrogen peroxide, followed by the addition of the acid anhydride at that point or stage at which the consumption of hydrogen peroxide and the desired bleaching action has slowed.
• inorganic peroxides which yield hydrogen peroxide on contact with water may also be employed, for example: alkali metal peroxides, viz., sodium peroxide, potassium peroxide, and lithium peroxide and alkaline earth metal peroxides, viz., barium peroxide.
• hydrogen peroxide yielding compounds such as percarbonates may be employed.
• the bleaching operation be carried out under conditions of alkaline reaction. This is necessary prior to the addition of acid anhydride. However, after the addition of acid anhydride bleaching may be obtained under conditions of slightly acid reaction, such as a pH of 6. At very high pH values, viz., 11 to 12, extreme degradation of the cellulosic material may result. Below about pH 5 bleaching action is impaired. Thus, it is preferred to bleach at pH values of 6.5 to 9. Often best reults may be obtained at pH 8.
• the time of bleaching is normally dependent upon the temperature. At 60 C. for pre-bleaching about minutes is required when the hydrogen peroxide concentration is l to 2 percent by weight of the pulp. An additional 5 minutes at this temperature and concentration will usually suflice after the addition of acid anhydride. Temperatures as high as 80 C. may be employed although as the temperature approaches 100 C. the hydrogen peroxide in the presence of the added acid anhydride is usually destroyed without producing a corresponding degree of bleaching. Lower temperatures, viz., 25 C. fail to produce significant bleaching during the pre-bleaching stage. Thus, preferred temperatures for pro-bleaching are usually from 45 to 80 C. for 10 to 45 minutes and after the addition of acid anhydride prefered temperatures are somewhat lower, viz., 30 to 70 C.
• the pulp consistency is most conveniently adjusted to 3 percent but may be adjusted to as high as 30 percent or as low as 1 percent. High consistencies result in cellulosic degradation due to high chemical concentration, while at one percent chemical inefficiency is often experienced. Therefore, it is preferred to operate at from 2 to 5 percent consistency and notably at 3 percent.
• the ratio of acid anhydride to hydrogen peroxide may be varied within Wide limits without observable ill effects.
• acetic anhydride employed, the optimum results appear to result at a molar ratio of 1:1.
• the residual peroxide is determined by titration before adding acid anhydride.
• a sample of partially bleached wood pulp in contact with residual bleaching liquors, on titration may be found to contain 0.68 percent by weight hydrogen peroxide. This requires adding sutlicient acetic anhydride to give a solution initially having:
• EXAMPLE I A sample of coniferous groundwood pulp was adjusted to 3 percent consistency and treated with 1.5 percent calcium chloride by weight of pulp for 15 minutes at 25 C. to insure pulp freshness.
• Reagents containing hydrogen peroxide were prepared with 41 Baum aqueous sodium silicate and magnesium sulfate. These reagents were refrigerated until needed to minimize decomposition.
• Example I was repeated employing 2.0 percent by weight sodium hydroxide and resulted in a preliminary bleached pulp having 67.0 brightness (G.E. units) with residual liquor containing 0.52 percent by weight hydrogen per-
• Example I was repeated employing 0.5 percent hydrogen peroxide, 0.75 percent sodium hydroxide by weight of pulp solids to give a preliminary bleached pulp having a brightness of 65.5 G.E. units and residual liquor containing 0.34 percent by weight hydrogen peroxide.
• the bleaching produced is as follows:
• Example IV Example I was repeated employing 0.5 percent hydrogen peroxide, 2.0 percent sodium hydroxide by weight of the pulp solids at a bleaching temperature of 66 C. This resulted in a preliminary bleached pulp having a GE. brightness of 65.0 units and residual liquor containing 0.225 percent hydrogen peroxide by weight of pulp. Addition of acetic anhydride resulted in the following:
• Example I was repeated employing 12 percent consistency pulp having a brightness of 61.1 GB. units. After 1 hour from 1.5 percent only 0.23 percent hydrogen peroxide by weight of pulp remained. One-half of the calculated molecular equivalent of acetic anhydride was added and bleaching was continued for 0.084 hour at 70 C. The final brightness was 75.0 GB. units.
• the invention described herein is useful as a bleaching process for groundwood pulp bleaching. It is admirably suited to use as the second stage of a two-step procedure wherein the pulp is bleached with alkaline peroxide to result in partial bleaching and residual peroxide liquor containing from 0.2 to 1.0 percent hydrogen peroxide by weight of pulp which would usually be wasted.
• Low concentration levels of hydrogen peroxide, viz., below 0.2 percent by Weight of pulp may be utilized but generally result in imperceptibly small bleaching improvement, hence residual concentrations above 0.2 percent by weight of pulp are preferred. Concentrations of residual hydrogen peroxide greater than about 1.5 percent by weight of pulp are still capable of producing moderately rapid bleaching without adding carboxylic acid anhydride.
• Woody fibers such as straw, bagasse, hemp, sisal, bast, ramie, abaca, jute, flax, and linden may also be treated by the process herein.
• Textile fibers of cellulosic nature viz., cotton, linen, etc.
• Textile fibers of cellulosic nature viz., cotton, linen, etc.
• Mixtures of Woody fibers and cotton-like fibers such as those employed in rag paper manufacture are not precluded.
• a method of bleaching cellulosic material which comprises contacting said material with aqueous hydrogen peroxide solution to provide bleached material in contact with residual hydrogen peroxide and thereafter treating such bleached material still in contact with residual hydrogen peroxide with anhydride of 2 to 8 carbon carboxylic acid.
• a method of bleaching cellulosic material which comprises contacting said material with aqueous hydrogen peroxide solution containing from 1 to 10 percent by weight hydrogen peroxide, consuming a portion but not all of the hydrogen peroxide whereby to bleach said material, thereafter adding carboxylic acid anhydride to the solution of reduced hydrogen peroxide content in contact with said material and effecting further bleaching of the material.
• the improvement which comprises accelerating the rate at which hydrogen peroxide solution containing less than 1.0 percent by weight hydrogen peroxide bleaches cellulosic material by adding to said solution carboxylic acid anhydride of 2 to 8 carbon atoms.

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• Engineering & Computer Science (AREA)
• Life Sciences & Earth Sciences (AREA)
• Wood Science & Technology (AREA)
• Textile Engineering (AREA)
• Paper (AREA)

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Cited By (26)

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Citations (8)

• 0
  • BE BE633420D patent/BE633420A/xx unknown
  • NO NO109292D patent/NO109292C/no unknown
  • NL NL293489D patent/NL293489A/xx unknown
• 1962
  • 1962-07-16 US US210193A patent/US3193445A/en not_active Expired - Lifetime
• 1963
  • 1963-06-07 FR FR937347A patent/FR1379645A/fr not_active Expired
  • 1963-07-04 DE DE19631546276 patent/DE1546276A1/de active Pending
  • 1963-07-12 GB GB27643/63A patent/GB974073A/en not_active Expired

Patent Citations (8)

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