US3177147A - Detergent compositions and preparation thereof - Google Patents
Detergent compositions and preparation thereof Download PDFInfo
- Publication number
- US3177147A US3177147A US135244A US13524461A US3177147A US 3177147 A US3177147 A US 3177147A US 135244 A US135244 A US 135244A US 13524461 A US13524461 A US 13524461A US 3177147 A US3177147 A US 3177147A
- Authority
- US
- United States
- Prior art keywords
- paste
- weight
- hydrogen peroxide
- sodium
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 title claims description 66
- 239000000203 mixture Substances 0.000 title claims description 55
- 238000002360 preparation method Methods 0.000 title claims description 20
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 76
- 239000002245 particle Substances 0.000 claims description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 38
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 34
- 229910052760 oxygen Inorganic materials 0.000 claims description 34
- 239000001301 oxygen Substances 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 32
- 230000008569 process Effects 0.000 claims description 29
- 238000002156 mixing Methods 0.000 claims description 27
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 15
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 15
- 239000000470 constituent Substances 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 11
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 claims description 10
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 9
- 239000012467 final product Substances 0.000 claims description 8
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 8
- 238000004581 coalescence Methods 0.000 claims description 7
- 229940077388 benzenesulfonate Drugs 0.000 claims description 5
- 239000003752 hydrotrope Substances 0.000 claims description 5
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 4
- 150000002978 peroxides Chemical class 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 238000005187 foaming Methods 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- NOJNFULGOQGBKB-UHFFFAOYSA-M sodium;3-[3-tert-butylsulfanyl-1-[[4-(6-ethoxypyridin-3-yl)phenyl]methyl]-5-[(5-methylpyridin-2-yl)methoxy]indol-2-yl]-2,2-dimethylpropanoate Chemical compound [Na+].C1=NC(OCC)=CC=C1C(C=C1)=CC=C1CN1C2=CC=C(OCC=3N=CC(C)=CC=3)C=C2C(SC(C)(C)C)=C1CC(C)(C)C([O-])=O NOJNFULGOQGBKB-UHFFFAOYSA-M 0.000 claims 1
- 239000000047 product Substances 0.000 description 28
- 239000000463 material Substances 0.000 description 17
- 239000004615 ingredient Substances 0.000 description 14
- 239000007787 solid Substances 0.000 description 13
- 239000004115 Sodium Silicate Substances 0.000 description 11
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 11
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 11
- 229910052911 sodium silicate Inorganic materials 0.000 description 11
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 10
- 239000001768 carboxy methyl cellulose Substances 0.000 description 10
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 10
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- 229910052938 sodium sulfate Inorganic materials 0.000 description 9
- 235000011152 sodium sulphate Nutrition 0.000 description 9
- 159000000000 sodium salts Chemical class 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- 239000007844 bleaching agent Substances 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 230000001427 coherent effect Effects 0.000 description 5
- 239000002178 crystalline material Substances 0.000 description 5
- 230000008961 swelling Effects 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 239000007850 fluorescent dye Substances 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- 229920000388 Polyphosphate Polymers 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000036571 hydration Effects 0.000 description 3
- 238000006703 hydration reaction Methods 0.000 description 3
- -1 iso-octyl phenoxy Chemical group 0.000 description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 3
- 239000001205 polyphosphate Substances 0.000 description 3
- 235000011176 polyphosphates Nutrition 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- 238000007873 sieving Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 229960001922 sodium perborate Drugs 0.000 description 3
- DUXXGJTXFHUORE-UHFFFAOYSA-M sodium;4-tridecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 DUXXGJTXFHUORE-UHFFFAOYSA-M 0.000 description 3
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229940098691 coco monoethanolamide Drugs 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- KRTNITDCKAVIFI-UHFFFAOYSA-N tridecyl benzenesulfonate Chemical class CCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 KRTNITDCKAVIFI-UHFFFAOYSA-N 0.000 description 2
- MCVUKOYZUCWLQQ-UHFFFAOYSA-N tridecylbenzene Chemical compound CCCCCCCCCCCCCC1=CC=CC=C1 MCVUKOYZUCWLQQ-UHFFFAOYSA-N 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- PVXSFEGIHWMAOD-UHFFFAOYSA-N 2-tridecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O PVXSFEGIHWMAOD-UHFFFAOYSA-N 0.000 description 1
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000001996 bearing alloy Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- VJKYNWPQVZHJAR-UHFFFAOYSA-H hexasodium trisulfate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O VJKYNWPQVZHJAR-UHFFFAOYSA-H 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- TWHXWYVOWJCXSI-UHFFFAOYSA-N phosphoric acid;hydrate Chemical class O.OP(O)(O)=O TWHXWYVOWJCXSI-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229940023144 sodium glycolate Drugs 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- JEJAMASKDTUEBZ-UHFFFAOYSA-N tris(1,1,3-tribromo-2,2-dimethylpropyl) phosphate Chemical compound BrCC(C)(C)C(Br)(Br)OP(=O)(OC(Br)(Br)C(C)(C)CBr)OC(Br)(Br)C(C)(C)CBr JEJAMASKDTUEBZ-UHFFFAOYSA-N 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
Definitions
- Oxygen yielding per-compounds other than hydrogen peroxide which may be employed in the instant process include the per-salts, such as, for example, sodium perborate, although in such a case it is usually necessary to use more vigorous conditions, e.g., a paste temperature of at least about 65 C., or the use of a decomposition catalyst, in order to achieve adequate liberation of oxygen while the paste is in a fluid or plastic condition conducive to expansion.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA603895 | 1960-09-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3177147A true US3177147A (en) | 1965-04-06 |
Family
ID=25560539
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US135244A Expired - Lifetime US3177147A (en) | 1960-09-23 | 1961-08-31 | Detergent compositions and preparation thereof |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US3177147A (en)) |
| AT (1) | AT279779B (en)) |
| BE (1) | BE608466A (en)) |
| BR (1) | BR6132869D0 (en)) |
| CH (1) | CH411197A (en)) |
| CY (1) | CY403A (en)) |
| DE (1) | DE1144866B (en)) |
| ES (1) | ES270653A1 (en)) |
| FI (2) | FI44656C (en)) |
| FR (1) | FR1301604A (en)) |
| GB (1) | GB993980A (en)) |
| MY (1) | MY6800011A (en)) |
| NL (2) | NL139004B (en)) |
| OA (1) | OA00996A (en)) |
| SE (1) | SE343883B (en)) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3367876A (en) * | 1964-07-24 | 1968-02-06 | Fmc Corp | Process for producing cleaning tablets |
| US3549541A (en) * | 1968-05-31 | 1970-12-22 | Colgate Palmolive Co | Enzyme carrying detergent particles |
| US3926827A (en) * | 1973-03-29 | 1975-12-16 | Colgate Palmolive Co | Method for making detergent compositions |
| US3931036A (en) * | 1974-05-13 | 1976-01-06 | Philadelphia Quartz Company | Compacted alkali metal silicate |
| US4118333A (en) * | 1975-10-20 | 1978-10-03 | Colgate-Palmolive Company | Manufacture of particulate detergents |
| US4269722A (en) * | 1976-09-29 | 1981-05-26 | Colgate-Palmolive Company | Bottled particulate detergent |
| US4310431A (en) * | 1976-02-26 | 1982-01-12 | Colgate Palmolive Company | Free flowing builder beads and detergents |
| US4351740A (en) * | 1976-09-29 | 1982-09-28 | Colgate Palmolive Company | Bottled particulate detergent |
| US4444673A (en) * | 1976-09-29 | 1984-04-24 | Colgate-Palmolive Company | Bottle particulate detergent |
| US4549977A (en) * | 1976-09-29 | 1985-10-29 | Colgate-Palmolive Company | Bottled particulate detergent |
| US5399297A (en) * | 1990-12-03 | 1995-03-21 | Henkel Kommanditgesellschaft Auf Aktien | Solid detergents |
| US6376453B1 (en) * | 1997-12-10 | 2002-04-23 | Kao Corporation | Detergent particles |
| GB2425128A (en) * | 2005-04-11 | 2006-10-18 | Unilever Plc | Granular detergent and process of making granular detergent |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8141797B2 (en) | 2001-01-25 | 2012-03-27 | Durr Systems Inc. | Rotary atomizer for particulate paints |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2623856A (en) * | 1952-12-30 | Tetraborate detergent compositionx | ||
| US2874123A (en) * | 1954-09-07 | 1959-02-17 | Colgate Palmolive Co | Process for the preparation of granular compositions |
| US2913417A (en) * | 1959-11-17 | Detergent composition | ||
| US2952638A (en) * | 1956-08-03 | 1960-09-13 | Procter & Gamble | Deaeration and purification of anionic detergent compositions |
| US2972584A (en) * | 1955-06-11 | 1961-02-21 | Henkel & Cie Gmbh | Production of granular water-soluble perborate-containing salt mixtures |
| US2979464A (en) * | 1956-11-09 | 1961-04-11 | Degussa | Perborate granulation |
| US3037838A (en) * | 1958-07-03 | 1962-06-05 | Hagan Chemicals & Controls Inc | Method of preparing granulated condensed phosphate peroxyhydrate |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE573818C (de) * | 1931-07-19 | 1933-04-06 | Vohrer Herbert | Verfahren zur Herstellung von Seifenpulver |
| DE864596C (de) * | 1951-02-21 | 1953-01-26 | Willy Dr Weiss | Verfahren zur Herstellung von spezifisch leichten und lockeren Wasch- und Reinigungsmitteln |
| FR1099166A (fr) * | 1954-02-12 | 1955-08-31 | Derives Du Soufre Soc Ind Des | Perfectionnement à la fabrication des produits de nettoyage |
| DE1091263B (de) * | 1959-07-20 | 1960-10-20 | Colgate Palmolive Co | Verfahren zur Herstellung von Reinigungsmitteln von niederem Schuettgewicht |
-
0
- BE BE608466D patent/BE608466A/xx unknown
- NL NL269436D patent/NL269436A/xx unknown
-
1961
- 1961-08-31 US US135244A patent/US3177147A/en not_active Expired - Lifetime
- 1961-09-16 DE DEC25082A patent/DE1144866B/de active Pending
- 1961-09-19 GB GB33551/61A patent/GB993980A/en not_active Expired
- 1961-09-20 AT AT07122/61A patent/AT279779B/de active
- 1961-09-21 NL NL61269436A patent/NL139004B/xx not_active IP Right Cessation
- 1961-09-21 CH CH1097761A patent/CH411197A/de unknown
- 1961-09-21 ES ES0270653A patent/ES270653A1/es not_active Expired
- 1961-09-22 FR FR873908A patent/FR1301604A/fr not_active Expired
- 1961-09-22 BR BR132869/61A patent/BR6132869D0/pt unknown
- 1961-09-22 FI FI611663A patent/FI44656C/fi active
-
1964
- 1964-12-29 OA OA51099A patent/OA00996A/xx unknown
-
1966
- 1966-03-12 FI FI660632A patent/FI44657C/fi active
- 1966-12-12 SE SE17036/66A patent/SE343883B/xx unknown
-
1967
- 1967-09-01 CY CY40367A patent/CY403A/xx unknown
-
1968
- 1968-12-31 MY MY196811A patent/MY6800011A/xx unknown
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2623856A (en) * | 1952-12-30 | Tetraborate detergent compositionx | ||
| US2913417A (en) * | 1959-11-17 | Detergent composition | ||
| US2874123A (en) * | 1954-09-07 | 1959-02-17 | Colgate Palmolive Co | Process for the preparation of granular compositions |
| US2972584A (en) * | 1955-06-11 | 1961-02-21 | Henkel & Cie Gmbh | Production of granular water-soluble perborate-containing salt mixtures |
| US2952638A (en) * | 1956-08-03 | 1960-09-13 | Procter & Gamble | Deaeration and purification of anionic detergent compositions |
| US2979464A (en) * | 1956-11-09 | 1961-04-11 | Degussa | Perborate granulation |
| US3037838A (en) * | 1958-07-03 | 1962-06-05 | Hagan Chemicals & Controls Inc | Method of preparing granulated condensed phosphate peroxyhydrate |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3367876A (en) * | 1964-07-24 | 1968-02-06 | Fmc Corp | Process for producing cleaning tablets |
| US3549541A (en) * | 1968-05-31 | 1970-12-22 | Colgate Palmolive Co | Enzyme carrying detergent particles |
| US3926827A (en) * | 1973-03-29 | 1975-12-16 | Colgate Palmolive Co | Method for making detergent compositions |
| US3931036A (en) * | 1974-05-13 | 1976-01-06 | Philadelphia Quartz Company | Compacted alkali metal silicate |
| US4118333A (en) * | 1975-10-20 | 1978-10-03 | Colgate-Palmolive Company | Manufacture of particulate detergents |
| US4310431A (en) * | 1976-02-26 | 1982-01-12 | Colgate Palmolive Company | Free flowing builder beads and detergents |
| US4269722A (en) * | 1976-09-29 | 1981-05-26 | Colgate-Palmolive Company | Bottled particulate detergent |
| US4351740A (en) * | 1976-09-29 | 1982-09-28 | Colgate Palmolive Company | Bottled particulate detergent |
| US4444673A (en) * | 1976-09-29 | 1984-04-24 | Colgate-Palmolive Company | Bottle particulate detergent |
| US4549977A (en) * | 1976-09-29 | 1985-10-29 | Colgate-Palmolive Company | Bottled particulate detergent |
| US5399297A (en) * | 1990-12-03 | 1995-03-21 | Henkel Kommanditgesellschaft Auf Aktien | Solid detergents |
| US6376453B1 (en) * | 1997-12-10 | 2002-04-23 | Kao Corporation | Detergent particles |
| GB2425128A (en) * | 2005-04-11 | 2006-10-18 | Unilever Plc | Granular detergent and process of making granular detergent |
| GB2425128B (en) * | 2005-04-11 | 2010-01-13 | Unilever Plc | Drying surfactant paste |
Also Published As
| Publication number | Publication date |
|---|---|
| MY6800011A (en) | 1968-12-31 |
| OA00996A (fr) | 1968-08-07 |
| FI44656B (en)) | 1971-08-31 |
| NL269436A (en)) | |
| FR1301604A (fr) | 1962-08-17 |
| CY403A (en) | 1967-09-01 |
| NL139004B (nl) | 1973-06-15 |
| CH411197A (de) | 1966-04-15 |
| FI44657B (en)) | 1971-08-31 |
| DE1144866B (de) | 1963-03-07 |
| FI44657C (fi) | 1971-12-10 |
| FI44656C (fi) | 1971-12-10 |
| BR6132869D0 (pt) | 1973-08-14 |
| BE608466A (en)) | |
| SE343883B (en)) | 1972-03-20 |
| GB993980A (en) | 1965-06-02 |
| AT279779B (de) | 1970-03-25 |
| ES270653A1 (es) | 1962-03-01 |
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