US3073379A - Gas operated heaters - Google Patents

Gas operated heaters Download PDF

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US3073379A
US3073379A US28470A US2847060A US3073379A US 3073379 A US3073379 A US 3073379A US 28470 A US28470 A US 28470A US 2847060 A US2847060 A US 2847060A US 3073379 A US3073379 A US 3073379A
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gas
plate member
casing
end wall
heater
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US28470A
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Martin Bernard Thomas David
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Maywick Appliances Ltd
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Maywick Appliances Ltd
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23D—BURNERS
    • F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/12—Radiant burners
    • F23D14/18—Radiant burners using catalysis for flameless combustion
    • F23D14/181—Radiant burners using catalysis for flameless combustion with carbon containing radiating surface

Definitions

  • the invention relates to gas operated heaters and particularly to heaters in which the gas which may be town gas, propane,-butane or the like is oxidised by a catalyst so that the heated air from the heater is without flame, smoke or smell and is free from carbon monoxide or unburncd gas.- e e Y
  • Such catalytic, combustion heaters are of particular application for example in dwelling houses, oiices, workshops, drying ovens or filling stations where there are inilammable gases or liquids, since the combustion of the heaters being without llame or incandescence, the safety factor is therefore very much higher than with ordinary heaters. .y 4
  • a gas operated heater having diffusing means through which the gas is passed to and through a catalytic oxidising layer before passing to atmosphere.
  • the gas inlet of the heater is formed integral with the casing of the heater ⁇ as by welding, brazing or soldering to the casing and threaded to be connected as by an armoured hose or by tubing to the source of gas supply.
  • the gas inletv is drilled to provide a xed orifice of pre-determined dimensions so that.
  • Ad acitive a coarse grained cartridge of Carborunduin may be provided inthe gas inlet to prevent overheating or blow-back.
  • the heater may be formed withl a casing of frustoconical, frusto-pyramidal, cylindrical or any other convenienteshape and the diffusing means may comprise a ceramic, Carborundum or metallic plate member alone or in combination with other vmembers as, for example, an asbestos backing or sealing plate and/ or a fibrous mass as, for example, fibre glass sol disposed as to ensure that all the gas supplied to the heater is passed through the dilusing means before being passed to and through the catalytic layer before passing to atmosphere.
  • the ditiuser plate member may comprise a metal plate, as for example an aluminium or sheet steel plate, the face of the plate nearer to the gas inlet, the rear face, being formed with a recessed portion, advantageously in the form of a scroll, to provide a path or guide to lead the gas outwardly from the central portion of the plate towards the peripheral area, spaced apertures being provided in the path to permit and direct the flow of gas towards the catalytic layer.
  • a star ⁇ formation may be provided as raised portions on the rear face of the plate to provide a plurality of panels ot' sector form in which the gas is led to the peripheral area.
  • a sealingmember may be provided, as, for example, an asbestos backing plate or sheet, held in close contact with the diffuser plate as, for example, by bolts or the like.
  • the diffuser plate member may be secured to an inner peripheral wall of the 'easing as, for example, by welding.
  • the dilusing means may also comprise in front of the diffuser plate member, a perforated metal sheet member in which the perforations are formed as by stabbing or punching, to present a plurality of projections on which a librous mass of low thermal conductivity is impaled and held in position.
  • means may be provided, advantageously in front of the perforated metal sheet member, for pre-heating the gas, the brous mass and the catalytic oxidising layer, such means advantageously comprising a shrouded electrical element and thermostatic control means may be provided whereby the pre-heater circuit is broken when a determined temperature is reached.
  • any other convenient means of pre-heating the catalytic mass may be used; thus for example as an alternative to electrical pre-heating a by-pass from the gas supply may be provided to provide a direct undiiiused supply oi gas to be burnt prior to turning on the full gas supply and adapted to be automatically cut ot as soon as the full gas supply is in operation.
  • the' pre-heating to, ⁇ the required temperature maybe effected by external heating means.
  • Pre-heating is effective to ensure an initial ⁇ combustion temperature sufficient to start the action oi the oxidising layer, the'normal temperature of operation being effective to i,maintain the action lonce started'.
  • Thejv'catalytic oxidising layer may comprise, Vfor example, asbestos wool or an yasbestos sheet, cloth, or the like, impregnated with a suitablelcatalyst, the sheet iorm- ,1 ing thejtront face'of the heater and being held in posi-
  • FIGURE 2 is a plan view of the rear face of the dif- I y fuser plate member.
  • the heater comprises a cylindrical casing 1 with gas inlet nozzle 2 screw threaded in a boss formed integral with and externally is the rear wall of the casing.
  • a diffuser plate 3 formed as an aluminium plate bolted by bolts 5 to an asbestos backing. and sealing sheet d is provided to be held in contact with the inner surface of the rear Wall of the casing, the bolts 5 passing through screw threaded holes 6 in the plate and corresponding holesin the asbestos sealing sheet.
  • the rear face of the diffuser plate 3 is recessed in the form of Ia scroll 7 and holes 8, of determined dimensions, are bored within the recessed scroll portion 7 to permit and direct the flow of gas forwardly through 4the plate 3i.
  • a perforated metal sheet,A 9 is positioned adjacent to the front face of the diiiusei' plate 3, the periorations being formed as by punching, Ior stabbing, to present projections on Ithe front face of the ⁇ sheet on which a fibrous mass 11 is impaled held in position.
  • the brous mass lll. may comprise ibre marketed under the registered'trademark Rocsil and m-ay be in loose t form or may be compacted or formated to a prescribed density.
  • pre-heating means indicated generally by 10 formed as ,an electrical element mounted within .a shroud, and connected to plug nd socket means 12.
  • a wire mesh 13 is provided, and in front of the wire 13 a catalytic oxidising layer 14 of asbestos cloth or sheeting impregnated with a catalyst, the sheeting being advantageously of the composition described in British patent application No. 40,811/59.
  • the asbestos cloth or sheet forms the front face of the heater and is held in position by a wire mesh 15, formed with a nim 16, to engage around the casing 1 4and to be held in position as by screw means (not shown in the drawings).
  • the heater is 11" in diameter with a dir'user plate also l1 in diameter on which the scrolled path is Ma" deep and 3/23 Wide.
  • the apertures through the diffuser plate are made with a number 70 drill.
  • a 250 watt electric pre-heater is provided between the diffuser plate and the catalytic oxidising layer.
  • the electric pre-heater is used to raise the temperature of the catalytic layer to 160 F. Butane (Calor gas) at a pressure of 14 Water gauge is supplied to the heater; 1 cubic foot per hour was consumed and 3200 B.t.u. per hour were produced.
  • Butane Calor gas
  • a gas operated heater comprising: a casing having an end wall with an inlet for supplying gas into the adjacent end of said easing; diffusing means substantially filling said casing, said diffusing means including a dituser plate member adjacent to said end wall of said casing, a brous mass of low thermal conductivity extending from adjacent to said plate member to the other end of said casing, and a catalytic oxidizing layer substantially de-V iining the other end of said casing, said catalytic oxidizing layer being impregnated with a catalyst, said -plate member having a recess adjacent said end wall and defining with said end wall an elongated path communicating with said inlet; and means defining a plumunicating with said path, said gas passing through said apertures in said plate member and said fibrous mass without substantial oxidization and being oxidized as it passes through said catalytic oxidizing layer whereby the oxidation products are free to exit from said casing.
  • a gas operated heater according to claim 1 including an asbestos sealing member between said apertured diffuser plate member and said end wall of said casing, said sealing member having a central opening communicating with said inlet.
  • a gas operated heater according to claim 2 in which a perforated metal sheet is provided between the apertured plate member and the brous mass, the perforations in the metal sheet having a plurality of projections thereon on which the fibrous mass is impaled and held in position.
  • a gas operated heater according to claim 3 includ ing pre-heating means comprising a shrouded electrical element disposed between the perforated metal sheet and the brous mass.
  • a gas operated heater according to claim 2 in which the recessed portion of the apertured plate member is formed as a scroll.
  • a gas operated heater according to claim 1 including a shrouded electrical heating element disposed between said apertured plate member and said fibrous mass for preheating the gas before it reaches the catalytic oxidizing layer.

Description

Jan. 15, 1963 B T D. MARUN 3,073,379
GAS OPERATED HEATERS Filed May 11, 1960 INVENTOR.
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United States Patent Oilice ddllid'lg Patented dan. l5, 1953 3,073,379 GAS OPERATED HEATERS Bernard Thomas David Martin, Quinton, Wick Crescent,
Wickford, Essex, England, assigner to Maywick Appliances Limited, Wickford, Essex, England, a British company Filed May 11, 1960, Ser. No. 28,470 Claims priority, application Great Britain May 11, 1959 7 Ciaims. (Cl. 158-114) The invention relates to gas operated heaters and particularly to heaters in which the gas which may be town gas, propane,-butane or the like is oxidised by a catalyst so that the heated air from the heater is without flame, smoke or smell and is free from carbon monoxide or unburncd gas.- e e Y Such catalytic, combustion heaters are of particular application for example in dwelling houses, oiices, workshops, drying ovens or filling stations where there are inilammable gases or liquids, since the combustion of the heaters being without llame or incandescence, the safety factor is therefore very much higher than with ordinary heaters. .y 4
According to the invention a gas operated heater is provided having diffusing means through which the gas is passed to and through a catalytic oxidising layer before passing to atmosphere.
Advantageously the gas inlet of the heater is formed integral with the casing of the heater` as by welding, brazing or soldering to the casing and threaded to be connected as by an armoured hose or by tubing to the source of gas supply. I The gas inletv is drilled to provide a xed orifice of pre-determined dimensions so that.
no inadvertent alteration of the supply can be made; incomplete orA wasteful supply of gas is thereby avoided. Advautageously a coarse grained cartridge of Carborunduin may be provided inthe gas inlet to prevent overheating or blow-back.
The heater may be formed withl a casing of frustoconical, frusto-pyramidal, cylindrical or any other convenienteshape and the diffusing means may comprise a ceramic, Carborundum or metallic plate member alone or in combination with other vmembers as, for example, an asbestos backing or sealing plate and/ or a fibrous mass as, for example, fibre glass sol disposed as to ensure that all the gas supplied to the heater is passed through the dilusing means before being passed to and through the catalytic layer before passing to atmosphere.
According to the invention furthermore the ditiuser plate member may comprise a metal plate, as for example an aluminium or sheet steel plate, the face of the plate nearer to the gas inlet, the rear face, being formed with a recessed portion, advantageously in the form of a scroll, to provide a path or guide to lead the gas outwardly from the central portion of the plate towards the peripheral area, spaced apertures being provided in the path to permit and direct the flow of gas towards the catalytic layer. Alternatively a star` formation may be provided as raised portions on the rear face of the plate to provide a plurality of panels ot' sector form in which the gas is led to the peripheral area. Y
To prevent leakage of the gas rearwardly or around the periphery of the diiuser plate member, a sealingmember may be provided, as, for example, an asbestos backing plate or sheet, held in close contact with the diffuser plate as, for example, by bolts or the like. Alternatively the diffuser plate member may be secured to an inner peripheral wall of the 'easing as, for example, by welding.
According to the invention furthermore the dilusing means may also comprise in front of the diffuser plate member, a perforated metal sheet member in which the perforations are formed as by stabbing or punching, to present a plurality of projections on which a librous mass of low thermal conductivity is impaled and held in position.
Because of the low conductivity of the brous mass loss of heat rearwardly is prevented and all the heat from the combusted gas is available at the front of the heater. Any disadvantage which may result from the reduced rate of flow of heat forwardly from the pre- Leater element because oi the low conductivity of the adjacent iibrous mass is more than oliset by the restrictive action of the mass on the passage of heat in the reverse direction.
According to the invention furthermore, means may be provided, advantageously in front of the perforated metal sheet member, for pre-heating the gas, the brous mass and the catalytic oxidising layer, such means advantageously comprising a shrouded electrical element and thermostatic control means may be provided whereby the pre-heater circuit is broken when a determined temperature is reached. v
Any other convenient means of pre-heating the catalytic mass may be used; thus for example as an alternative to electrical pre-heating a by-pass from the gas supply may be provided to provide a direct undiiiused supply oi gas to be burnt prior to turning on the full gas supply and adapted to be automatically cut ot as soon as the full gas supply is in operation. Alternatively the' pre-heating to,` the required temperature maybe effected by external heating means.
Pre-heating is effective to ensure an initial `combustion temperature sufficient to start the action oi the oxidising layer, the'normal temperature of operation being effective to i,maintain the action lonce started'.
Thejv'catalytic oxidising layer may comprise, Vfor example, asbestos wool or an yasbestos sheet, cloth, or the like, impregnated with a suitablelcatalyst, the sheet iorm- ,1 ing thejtront face'of the heater and being held in posi- FIGURE 2 is a plan view of the rear face of the dif- I y fuser plate member.
In the construction illustrated in the drawings the heater comprises a cylindrical casing 1 with gas inlet nozzle 2 screw threaded in a boss formed integral with and externally is the rear wall of the casing.
A diffuser plate 3, formed as an aluminium plate bolted by bolts 5 to an asbestos backing. and sealing sheet d is provided to be held in contact with the inner surface of the rear Wall of the casing, the bolts 5 passing through screw threaded holes 6 in the plate and corresponding holesin the asbestos sealing sheet.
The rear face of the diffuser plate 3 is recessed in the form of Ia scroll 7 and holes 8, of determined dimensions, are bored within the recessed scroll portion 7 to permit and direct the flow of gas forwardly through 4the plate 3i.
A perforated metal sheet,A 9 is positioned adjacent to the front face of the diiiusei' plate 3, the periorations being formed as by punching, Ior stabbing, to present projections on Ithe front face of the `sheet on which a fibrous mass 11 is impaled held in position. l
The brous mass lll. may comprise ibre marketed under the registered'trademark Rocsil and m-ay be in loose t form or may be compacted or formated to a prescribed density.
Secured to the perforated metal sheet 9 are pre-heating means indicated generally by 10 formed as ,an electrical element mounted within .a shroud, and connected to plug nd socket means 12.
Immediately in front of the fibrous mass 11, a wire mesh 13 is provided, and in front ofthe wire 13 a catalytic oxidising layer 14 of asbestos cloth or sheeting impregnated with a catalyst, the sheeting being advantageously of the composition described in British patent application No. 40,811/59.
The asbestos cloth or sheet forms the front face of the heater and is held in position by a wire mesh 15, formed with a nim 16, to engage around the casing 1 4and to be held in position as by screw means (not shown in the drawings).
The operation of a heater according lto the invention is illustrated in the following example.
In one construction the heater is 11" in diameter with a dir'user plate also l1 in diameter on which the scrolled path is Ma" deep and 3/23 Wide. The apertures through the diffuser plate are made with a number 70 drill. A 250 watt electric pre-heater is provided between the diffuser plate and the catalytic oxidising layer.
The electric pre-heater is used to raise the temperature of the catalytic layer to 160 F. Butane (Calor gas) at a pressure of 14 Water gauge is supplied to the heater; 1 cubic foot per hour was consumed and 3200 B.t.u. per hour were produced.
What I claim is:
1. A gas operated heater comprising: a casing having an end wall with an inlet for supplying gas into the adjacent end of said easing; diffusing means substantially filling said casing, said diffusing means including a dituser plate member adjacent to said end wall of said casing, a brous mass of low thermal conductivity extending from adjacent to said plate member to the other end of said casing, and a catalytic oxidizing layer substantially de-V iining the other end of said casing, said catalytic oxidizing layer being impregnated with a catalyst, said -plate member having a recess adjacent said end wall and defining with said end wall an elongated path communicating with said inlet; and means defining a plumunicating with said path, said gas passing through said apertures in said plate member and said fibrous mass without substantial oxidization and being oxidized as it passes through said catalytic oxidizing layer whereby the oxidation products are free to exit from said casing.
2. A gas operated heater according to claim 1 including an asbestos sealing member between said apertured diffuser plate member and said end wall of said casing, said sealing member having a central opening communicating with said inlet.
3. A gas operated heater according to claim 2 in which a perforated metal sheet is provided between the apertured plate member and the brous mass, the perforations in the metal sheet having a plurality of projections thereon on which the fibrous mass is impaled and held in position.
4. A gas operated heater according to claim 3 includ ing pre-heating means comprising a shrouded electrical element disposed between the perforated metal sheet and the brous mass.
5. A gas operated heater according to claim 2 in which the recessed portion of the apertured plate member is formed as a scroll. t
6. A gas operated heater according to claim 1 in which the catalytic oxidising layer comprises a sheet of asbestos impregnated with a catalyst.
7. A gas operated heater according to claim 1 including a shrouded electrical heating element disposed between said apertured plate member and said fibrous mass for preheating the gas before it reaches the catalytic oxidizing layer.
References Cited in the file of this patent UNITED STATES PATENTS 1,223,248 Bone et al. Apr. 17, 1917 1,374,619 White Apr. 12, 1921 2,194,208 Moran Mar. 19, 1940 3,029,802 Webster Apr. 17, 1962 FOREIGN PATENTS 477,958 France Aug. 21, 1915 1,078,372 France May 12, 1954 211,141 Australia Mar. 22, 1956 l 1,137,775 France Jan. 2l, 1957 565,879 Belgium Apr. 15, 1958 815,100 Great Britain June 17, 1959

Claims (1)

1. A GAS OPERATED HEATER COMPRISING: A CAUSING HAVING AN END WALL WITH AN INLET FOR SUPPLYING GAS INTO THE ADAJACENT END OF SAID CUASING; DIFFUSING MEANS SUBSTANTIALLY FILLING SAID CAUSING, SAID DIFFUSING MEANS INCLUDING A DIFFUSER PLATE MEMBER ADJACENT TO SAID END WALL OF SAID CASING, A FIRBROUS MASS OF LOW THERMAL CONDCUTIVITY EXTENDING FROM ADJACENT TO SAID PLATE MEMBER TO THE OTHER END OF SAID CASING, AND A CATALYTIC OXIDIZING LAYER SUBSTANTIALLY DEFINING THE OTHER END OF SAID CASING, SAID CATALYTIC OXIDIZING LAYER BEING IMPREGNATED WITH A CATALYST, SAID PLATE MEMBER HAVING A RECESS ADJACENT SAID END WALL DEFINING WITH SAID END WALL AN ELONGATED PATH COMMUNICATING WITH SAID INLET; AND MEANS DEFINING A PLURALITY OF APERTURES THROUGH SAID PLATE MEMBER AND COMMUNICATING WITH SAID PATH, SAID, SAID GAS PASSING THROUGH SAID APERTURES IN SAID PLATE MEMBER AND SAID FIBROUS MASS WITHOUT SUBSTANTIAL OXIDIZATION AND BEING OXIDIZED AS IT PASSES THROUGH SAID CATALYTIC OXIDIZING LAYER WHEREBY THE OXIDATION PRODUCTS ARE FREE TO EXIT FROM SAID CASING.
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3199570A (en) * 1963-05-28 1965-08-10 Selas Corp Of America Industrial burner
US3216478A (en) * 1962-04-13 1965-11-09 Electro Refractories & Abrasiv Radiant gas burner tile
US3784353A (en) * 1972-01-28 1974-01-08 G Chapurin Flameless gas catalytic heater
US3857669A (en) * 1971-09-02 1974-12-31 Impala Ind Inc Catalytic heater head
US3930790A (en) * 1971-04-08 1976-01-06 Ethyl Corporation Method and apparatus for shrinking plastic film over grouped articles
US4538985A (en) * 1982-09-08 1985-09-03 Webasto-Werk W. Baier Gmbh & Co. Vaporization burner
US5235667A (en) * 1991-05-24 1993-08-10 Casso-Solar Corp. Heating method and assembly utilizing electric heating elements in conjunction with combustion
US5281130A (en) * 1986-07-11 1994-01-25 Lebaigue Research Limited Domestic gas fires
WO1998046940A1 (en) * 1997-04-14 1998-10-22 New England Catalytic Technologies, Inc. Gas catalytic heaters with improved temperature distribution
US5851498A (en) * 1996-12-02 1998-12-22 Catalytic Systems Technologies, Ltd. Boiler heated by catalytic combustion
US20030223920A1 (en) * 2002-06-04 2003-12-04 Critchley John N. Method for repairing catalytic heaters
EP1547685A1 (en) * 2003-12-24 2005-06-29 Nijmaprobe B.V. Process for preparing a catalyst for flameless generation of heat and a device for receiving the catalyst
EP1717517A3 (en) * 2005-04-29 2008-12-24 J. Eberspächer GmbH Co. KG Evaporator arrangement, particularly for a car heating appliance or for a reformer

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE565879A (en) *
FR477958A (en) * 1914-07-09 1915-11-18 Alfred Adam Process and devices for the flameless surface combustion of combustible gases
US1223248A (en) * 1917-03-17 1917-04-17 Radiant Heating Ltd Combustion of mixed gases.
US1374619A (en) * 1920-04-15 1921-04-12 Central Oil & Gas Stove Co Kindler-holder
US2194208A (en) * 1937-01-12 1940-03-19 Clarence E Moran Fluid fuel burner
FR1078372A (en) * 1952-03-10 1954-11-17 Gogas Goch & Co Method and device for the catalytic combustion of hydrocarbon products
FR1137775A (en) * 1955-07-19 1957-06-04 advanced heating element for gas-catalyzed heaters
GB815100A (en) * 1954-11-12 1959-06-17 Wagner Hans Improvements in or relating to apparatus for effecting glow combustion at high temperature
US3029802A (en) * 1958-10-15 1962-04-17 Otto Bernz Company Inc Automobile heater

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE565879A (en) *
FR477958A (en) * 1914-07-09 1915-11-18 Alfred Adam Process and devices for the flameless surface combustion of combustible gases
US1223248A (en) * 1917-03-17 1917-04-17 Radiant Heating Ltd Combustion of mixed gases.
US1374619A (en) * 1920-04-15 1921-04-12 Central Oil & Gas Stove Co Kindler-holder
US2194208A (en) * 1937-01-12 1940-03-19 Clarence E Moran Fluid fuel burner
FR1078372A (en) * 1952-03-10 1954-11-17 Gogas Goch & Co Method and device for the catalytic combustion of hydrocarbon products
GB815100A (en) * 1954-11-12 1959-06-17 Wagner Hans Improvements in or relating to apparatus for effecting glow combustion at high temperature
FR1137775A (en) * 1955-07-19 1957-06-04 advanced heating element for gas-catalyzed heaters
US3029802A (en) * 1958-10-15 1962-04-17 Otto Bernz Company Inc Automobile heater

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3216478A (en) * 1962-04-13 1965-11-09 Electro Refractories & Abrasiv Radiant gas burner tile
US3199570A (en) * 1963-05-28 1965-08-10 Selas Corp Of America Industrial burner
US3930790A (en) * 1971-04-08 1976-01-06 Ethyl Corporation Method and apparatus for shrinking plastic film over grouped articles
US3857669A (en) * 1971-09-02 1974-12-31 Impala Ind Inc Catalytic heater head
US3784353A (en) * 1972-01-28 1974-01-08 G Chapurin Flameless gas catalytic heater
US4538985A (en) * 1982-09-08 1985-09-03 Webasto-Werk W. Baier Gmbh & Co. Vaporization burner
US5281130A (en) * 1986-07-11 1994-01-25 Lebaigue Research Limited Domestic gas fires
US5235667A (en) * 1991-05-24 1993-08-10 Casso-Solar Corp. Heating method and assembly utilizing electric heating elements in conjunction with combustion
US5851498A (en) * 1996-12-02 1998-12-22 Catalytic Systems Technologies, Ltd. Boiler heated by catalytic combustion
WO1998046940A1 (en) * 1997-04-14 1998-10-22 New England Catalytic Technologies, Inc. Gas catalytic heaters with improved temperature distribution
GB2338659A (en) * 1997-04-14 1999-12-29 New England Catalytic Technolo Gas catalytic heaters with improved temperature distribution
US6045355A (en) * 1997-04-14 2000-04-04 New England Catalytic Technologies, Inc. Gas catalytic heaters with improved temperature distribution
GB2338659B (en) * 1997-04-14 2001-12-19 New England Catalytic Technolo Gas catalytic heaters with improved temperature distribution
US20030223920A1 (en) * 2002-06-04 2003-12-04 Critchley John N. Method for repairing catalytic heaters
EP1547685A1 (en) * 2003-12-24 2005-06-29 Nijmaprobe B.V. Process for preparing a catalyst for flameless generation of heat and a device for receiving the catalyst
EP1717517A3 (en) * 2005-04-29 2008-12-24 J. Eberspächer GmbH Co. KG Evaporator arrangement, particularly for a car heating appliance or for a reformer

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