US2789930A - Method of nitriding ferrous alloys - Google Patents
Method of nitriding ferrous alloys Download PDFInfo
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- US2789930A US2789930A US461377A US46137754A US2789930A US 2789930 A US2789930 A US 2789930A US 461377 A US461377 A US 461377A US 46137754 A US46137754 A US 46137754A US 2789930 A US2789930 A US 2789930A
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- 238000005121 nitriding Methods 0.000 title claims description 42
- 238000000034 method Methods 0.000 title claims description 16
- 229910000640 Fe alloy Inorganic materials 0.000 title description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 37
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 24
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 19
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 9
- 235000019270 ammonium chloride Nutrition 0.000 claims description 9
- 230000004888 barrier function Effects 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 7
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 6
- 239000003517 fume Substances 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 11
- 229910021529 ammonia Inorganic materials 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 210000002268 wool Anatomy 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/24—Nitriding
- C23C8/26—Nitriding of ferrous surfaces
Definitions
- This invention is directed broadly to the art of nitriding articles of ferrous alloys having a high chrome content.
- nitriding is highly desirable as it provides a hard surface (nitriding is at this writing customarily to a depth of .0005" to .03") having excellent wear-resistance characteristics and especially desirable for precision articles such as gear teeth and other parts which are thus provided with a hardened surface and with a tough underlying core of the chrome alloy.
- Such ferrous alloys of high chrome content have been found to be resistant to, and heretofore required special treatment to prepare the same for, the nitriding operation.
- Fig. l is a vertical sectional View showing anapparatus adapted for carrying out the method ot' Vthis invention.
- Fig. 2 is a schematic, enlarged sectional View of an article of high chrome alloy 10, having a nitriding inhibit-- ing film or surface42.
- the drawing illustrates the application of the invention to articles 10, 11 to be nitrided.
- Such articles may be of any miscellaneous form; those shown in the drawing are illustrative only.
- the articles are of a ferrous alloy having a high chrome. content, such as stainless steel articles. They are placed on a supporting surface 12 or the like which, with the side walls 13 and top wall 14, define the chamber 1S within which said articles to be nitrided are positioned.
- the articles may be disposed on wire screen or other supports 16, 17, which in turn may be either positioned on the surface 12 or otherwise secured interiorly of chamber 15.
- the chamber 15 is disposed in au opening 18 of a furnace 19 which may have suitable heating elements 20; opening 1S is normally substantially closed by a cover member 21 of suitable configuration.
- Ammonia gas is circulated in the chamber 15 and around the articles 10, 11 therein by suitable means, as, for example, by providing a source 22 for the ammonia Ffice gas, connected to suitable ammonia cylinders, tanks or other reservoir.
- the ammonia gas is pumped or otherwise passed through pipe 23 and out of the discharge outlet 24 thereof preferably adjacent the bottom wall 12 of the chamber 15.
- the pipe 23, above chamber 15, is disposed within a housing 25 with which said pipe defines a conduit 26 through which the ammonia gas may escape after circulating through chamber 15 and into discharge pipe 2'7 leading to the atmosphere as indicated by the arrow A.
- the pipe 23 may be coupled to the source 22 by suitable coupling 28 and sealed to the housing 25 by a collar 29.
- connection between the top wall 14 and side wall 13 of chamber 15 may assume any convenient or desired form, that shown in the drawing, com'- prising a downturned tiange 30 on the top wall 14 received within an upturned iiange 31 of side wall 13 and preferably sealed therein by a suitable sealing medium 32.
- amass d0 of wool of two or three cubic inches may be placed in a chamber 15 of three cubic feet after first moistening the mass 40 with l0 to l5 grams of 50% v (mild) hydrochloric acid.
- the rnass 40 is preferably placed in chamber l5 adjacent the point 24 of first entry of the ammonia gases therein and preferably adjacent the wall 13 so as to be close to the source of heat.
- the furnace heating elements 20 are energized -to bring the furnace to its operating temperature (920 degrees to 1150 degrees F.) for l hour to 96 hours, to nitride the articles l@ and 11 in the furnace.
- the ammonium chloride fumes continue to condenseon the articles and attack the chromeY oxide film until the articles approach their nitriding temperature, at which time the higher or increased temperature of the articles will volatiiize the .ammonium chloride condensate film; the articlesurfaces will then be cleanly exposed (without the barrier surface 42) to the continuously swept ammonia gas circulated through the chamber l5; clean nitriding ol the surfaces of articles 10 and lli is thus automaticaliy attained as the furnace cornes up to heat.
- the ammonia gas sweeps the volatilized ammonia chloride gas out of the discharge opening 27 of chamber 15.
- the mass 40 has been described above as saturated with hydrochloric acid prior to its insertion in the cham,-
- Hydrochloric acid has been found suitable for the purpose as (1) it is believed to readily combine with ammonia gas to form a new compound which will effectively attack the oxide coating,.and (2) the newly formed compound is believed -to readily condense on the articles to be nitrided prior to their being brought up to their nitriding temperature, and to effectively attack the oxide coating thereon, and (3) the newly formed compound is believed to readily volatiiize off said articles as they approach their nitriding temperature so as to enable the nitriding operation to be proceeded with.
- Compounds and compositions other than hydrochloric acid may be used 'for the purpose pursuant to this invention provided they meet the requirements spccied above.
- the compound to be combined with ammonia may be other than an acid, provided it meets the requirements above. specified, and it may be introduced into the chamber by means other than vhysaturation of a mass, if desired, although the saturated mass technique, above dcscribed, has been found to be highly satisfactory.
- the method of preparing, for uitriding, an article of a ferrous alloy including chrome and having a film of chrome oxide serving as a nitriding barrier comprising positioning said article in a chamber, circulating ammonia gas around said article in said chamber, moistening a mass with hydrochloric acid, positioning said mass in said chamber in spaced apart relation to said article, heating said chamber to progressively heat the article up to its nitriding temperature, whereby hydrochloric acid fumes of said mass wili combine with the ammonia gas to form ammonium chloride vapors which will condense on the surfaces of said article and attack the chrome oxide coating thereof, and progressively heating said chamber to progressively bring the article up to its nitriding ternperature, whereby the previously condensed ammonium chloride vapors volatilize from said article so that nitriding may bc proceeded with on circulating7 ammonia gas onto said article.
- the method of preparing for nitriding, an article of a ferrous alloy including chrome and having a film of chrome oxide serving as a nitriding barrier comprising positioning Said article in a chamber, circulating ammonia gas around Said article in said chamber, positioning a mass moistened with hydrochloric acid in said chamber in spaced apart relation to said article, said mass being of less density and of more rapid ⁇ heat absorbing properties than said article, heating said chamber to the nitriding temperature of VSaid article, and continuing to pump ammonia gas through said chamber, whereby said hydrochloric acid will first combine with the ammonia gas to form ammonium chloride vapors which will condense on the surfaces of said article and attack the chrome oxide coating thereof, and, as said article reaches its nitriding temperature, will volatilize therefrom so that nitriding may be proceeded with.
- Ffhe method of preparing for nitriding, an article of a ferrous alloy including chrome and having a film of chrome oxide serving as a nitriding barrier comprising positioning said article ina chamber, circulating ammonia gas around said article in Said chamber, introducing an acid into said Vchamber in spaced apart relation to said' article, said acid being one that will combine with arnmonia Ito provide a new compound which will attack the chrome oxide film and which will not volatilize below the nitriding temperature of said article, heating said chamber to the nitriding temperature of said article, and continuing to pump ammonia.
- the method 0f preparing for nitriding, an article of a ferrous alloy including chrome and having a lm of chrome oxide serving as a ⁇ nitriding barrier, comprising positioning said article in a chamber, circulating ammonia gas around said article in said chamber, introducing hydrochloric acid into said chamber in spaced apart relationto said article, said acid being one that will combine with ammonia to provide a new compound which will attack the chrome oxide lm and which will not volatilize below the nitriding temperature of said article, heating said chamber to the nitriding temperature of said article, and continuing to pump ammonia ygas through said chamber, whereby said.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
Description
April 23, 1957 w, F, ENGELHARD 2,789,930
METHOD 0F NITRIDING FERROUS ALLOYS Filed Oct. 11, 1954 l IN VEN TOR. www ragefwd BY ,4f/M910 MM AT TORNEY United States Patent` METHOD F NITRIDING FERROUS ALLOYS Y William F. Engelhard, North Arlington, N. J.
Application October 11,1954, Serial No. 461,377
9 Claims. (Cl. 148-16.6)
This invention is directed broadly to the art of nitriding articles of ferrous alloys having a high chrome content. Such nitriding is highly desirable as it provides a hard surface (nitriding is at this writing customarily to a depth of .0005" to .03") having excellent wear-resistance characteristics and especially desirable for precision articles such as gear teeth and other parts which are thus provided with a hardened surface and with a tough underlying core of the chrome alloy. Such ferrous alloys of high chrome content, however, have been found to be resistant to, and heretofore required special treatment to prepare the same for, the nitriding operation. One prevailing theory as to the reason for the resistance of stainless steel alloys to nitriding is that the chrome in the alloy forms a chrome oxide surface coating which serves as a barrier to nitriding. lt has thus been found, in the case of articles of stainless steel, that such articles must irst be treated outside the furnace to remove the coating or barrier and then immediately placed in the furnace, before there is a chance for the coating to re-forrn, followed by another special procedure in the furnace kof several hours duration, before commencement of the actual nitriding operation.
The foregoing objections are obviated by the novel method and apparatus of this invention, below more particularly pointed out, pursuant to which thearticles to be nitrided are placed within the furnace without any special prior treatment, and then the furnace is brought up lto nitriding temperature in accordance with the usual nitriding-cycle practices; the articles'are automatically prepared for and nitrided without requiring special pre-treatment or special further handling or treatment in the furnace.
.ln the drawings:
Fig. l is a vertical sectional View showing anapparatus adapted for carrying out the method ot' Vthis invention, and
Fig. 2 is a schematic, enlarged sectional View of an article of high chrome alloy 10, having a nitriding inhibit-- ing film or surface42. y
The drawing illustrates the application of the invention to articles 10, 11 to be nitrided. Such articles may be of any miscellaneous form; those shown in the drawing are illustrative only. The articles are of a ferrous alloy having a high chrome. content, such as stainless steel articles. They are placed on a supporting surface 12 or the like which, with the side walls 13 and top wall 14, define the chamber 1S within which said articles to be nitrided are positioned. The articles may be disposed on wire screen or other supports 16, 17, which in turn may be either positioned on the surface 12 or otherwise secured interiorly of chamber 15. The chamber 15 is disposed in au opening 18 of a furnace 19 which may have suitable heating elements 20; opening 1S is normally substantially closed by a cover member 21 of suitable configuration.
Ammonia gas is circulated in the chamber 15 and around the articles 10, 11 therein by suitable means, as, for example, by providing a source 22 for the ammonia Ffice gas, connected to suitable ammonia cylinders, tanks or other reservoir. The ammonia gas is pumped or otherwise passed through pipe 23 and out of the discharge outlet 24 thereof preferably adjacent the bottom wall 12 of the chamber 15. The pipe 23, above chamber 15, is disposed within a housing 25 with which said pipe defines a conduit 26 through which the ammonia gas may escape after circulating through chamber 15 and into discharge pipe 2'7 leading to the atmosphere as indicated by the arrow A. The pipe 23 may be coupled to the source 22 by suitable coupling 28 and sealed to the housing 25 by a collar 29. The connection between the top wall 14 and side wall 13 of chamber 15 may assume any convenient or desired form, that shown in the drawing, com'- prising a downturned tiange 30 on the top wall 14 received within an upturned iiange 31 of side wall 13 and preferably sealed therein by a suitable sealing medium 32.
lt will be apparent that by this arrangement, initially the cover 21, then pipe 23, housing 25 and top wall 1d (which may be welded to the housing 25) may be lifted clear of the furnace. The objects (1d, 11 etc.) to -be nitrided may then be inserted into chamber 15, which would then be closed as noted in Fig. l. Pursuant to the present invention there is placed in the furnace, along with the work, a mass d0 such as mineral wool or other light, inert material such as silicon carbide wool, pre- ,viously soaked with hydrochloric acid. By way of example only of one form found convenient for the carrying out of this invention, and without limiting the saine thereto, amass d0 of wool of two or three cubic inches may be placed in a chamber 15 of three cubic feet after first moistening the mass 40 with l0 to l5 grams of 50% v (mild) hydrochloric acid.
The rnass 40 is preferably placed in chamber l5 adjacent the point 24 of first entry of the ammonia gases therein and preferably adjacent the wall 13 so as to be close to the source of heat. The furnace heating elements 20 are energized -to bring the furnace to its operating temperature (920 degrees to 1150 degrees F.) for l hour to 96 hours, to nitride the articles l@ and 11 in the furnace.
lt is believed that this invention operates pursuant to this phenomenon: The hydrochloric acid fumes emanating from mass 40 combine with the ammonia gas sweeping through chamber 15, forming ammonium chloride fumes or vapor which sweeps over articles 1?, 11. As the furnace heating cycle is initiated, the parts 10 and t being dense, will come up to heat slowly, with the result that the surfaces of articles V10 and 1li will probably initially be about 35 or 40 degrees F. behind the temperature of mass 40. The ammonium chloride vapors condense on the entire 'surface of articles 1t), 11 in la uniform fashion and attack the chrome oxide'iilm barrier thereon. As the furnace continues to come up to heat, the ammonium chloride fumes continue to condenseon the articles and attack the chromeY oxide film until the articles approach their nitriding temperature, at which time the higher or increased temperature of the articles will volatiiize the .ammonium chloride condensate film; the articlesurfaces will then be cleanly exposed (without the barrier surface 42) to the continuously swept ammonia gas circulated through the chamber l5; clean nitriding ol the surfaces of articles 10 and lli is thus automaticaliy attained as the furnace cornes up to heat. The ammonia gas sweeps the volatilized ammonia chloride gas out of the discharge opening 27 of chamber 15.
It will be noted that the operation is completely automatic and dispenses with any need for special or previous handlingA of the articles.
The mass 40 has been described above as saturated with hydrochloric acid prior to its insertion in the cham,-
ber, for the purpose mentioned. Hydrochloric acid has been found suitable for the purpose as (1) it is believed to readily combine with ammonia gas to form a new compound which will effectively attack the oxide coating,.and (2) the newly formed compound is believed -to readily condense on the articles to be nitrided prior to their being brought up to their nitriding temperature, and to effectively attack the oxide coating thereon, and (3) the newly formed compound is believed to readily volatiiize off said articles as they approach their nitriding temperature so as to enable the nitriding operation to be proceeded with. Compounds and compositions other than hydrochloric acid may be used 'for the purpose pursuant to this invention provided they meet the requirements spccied above.
The compound to be combined with ammonia may be other than an acid, provided it meets the requirements above. specified, and it may be introduced into the chamber by means other than vhysaturation of a mass, if desired, although the saturated mass technique, above dcscribed, has been found to be highly satisfactory.
i claim:
l. The method of preparing, for uitriding, an article of a ferrous alloy including chrome and having a film of chrome oxide serving as a nitriding barrier, comprising positioning said article in a chamber, circulating ammonia gas around said article in said chamber, moistening a mass with hydrochloric acid, positioning said mass in said chamber in spaced apart relation to said article, heating said chamber to progressively heat the article up to its nitriding temperature, whereby hydrochloric acid fumes of said mass wili combine with the ammonia gas to form ammonium chloride vapors which will condense on the surfaces of said article and attack the chrome oxide coating thereof, and progressively heating said chamber to progressively bring the article up to its nitriding ternperature, whereby the previously condensed ammonium chloride vapors volatilize from said article so that nitriding may bc proceeded with on circulating7 ammonia gas onto said article.
2. Vin the method set forth in claim l, the further step of so circulating said ammonia around said article by introducing said gas into said chamber from a point below the article and providing an `exhaust for said gas above the article, to thereby circulate said gas around said articie and out ofthe chamber.
3. in the method set forth in claim 2, the further step of disposing the mass intermediate the points of entry and discharge of the ammonia gas so that the hydrochloric vapors may combine with the ammonia gas and be swept therewith around the article in the movement of said ammonia gas through 'the chamber.
4. in the method set forth in claim 3, the further step of disposing the mass adjacent the wall of the chamber through which the furnace heat is passed said mass being of a material which will rnorc rapidly absorb heat then said article.
5. ln the method set for in claim 2, the steps of disposing said article inwardly of said wall and above the bottom wall of the chamber and disposing the mass at the junction of the botto-m and side walls of the chamber.
silicon carbide wool.
7. The method of preparing for nitriding, an article of a ferrous alloy including chrome and having a film of chrome oxide serving as a nitriding barrier, comprising positioning Said article in a chamber, circulating ammonia gas around Said article in said chamber, positioning a mass moistened with hydrochloric acid in said chamber in spaced apart relation to said article, said mass being of less density and of more rapid `heat absorbing properties than said article, heating said chamber to the nitriding temperature of VSaid article, and continuing to pump ammonia gas through said chamber, whereby said hydrochloric acid will first combine with the ammonia gas to form ammonium chloride vapors which will condense on the surfaces of said article and attack the chrome oxide coating thereof, and, as said article reaches its nitriding temperature, will volatilize therefrom so that nitriding may be proceeded with.
8. Ffhe method of preparing for nitriding, an article of a ferrous alloy including chrome and having a film of chrome oxide serving as a nitriding barrier, comprising positioning said article ina chamber, circulating ammonia gas around said article in Said chamber, introducing an acid into said Vchamber in spaced apart relation to said' article, said acid being one that will combine with arnmonia Ito provide a new compound which will attack the chrome oxide film and which will not volatilize below the nitriding temperature of said article, heating said chamber to the nitriding temperature of said article, and continuing to pump ammonia. gas through said chamber, whereby said acid will first combine with the ammonia gas to form ammonium vapors which will condense on the surfaces of said article and attack the chrome oxide coating thereof, and, as said article reaches its nitriding temperature, will volatilize therefrom so that nitriding may be proceeded with.
9. The method 0f preparing for nitriding, an article of a ferrous alloy including chrome and having a lm of chrome oxide serving as a `nitriding barrier, comprising positioning said article in a chamber, circulating ammonia gas around said article in said chamber, introducing hydrochloric acid into said chamber in spaced apart relationto said article, said acid being one that will combine with ammonia to provide a new compound which will attack the chrome oxide lm and which will not volatilize below the nitriding temperature of said article, heating said chamber to the nitriding temperature of said article, and continuing to pump ammonia ygas through said chamber, whereby said. acid will first combine with the arnmonia gas to form ammonium vapors which Will condense on the surfaces of said article vand attack the chrome om'de coating thereof, and, as said article reaches its nitriding temperature, will volatilize therefrom so that nitriding may be proceeded with.
References Cited in the le of this patent UNITED STATES PATENTS 1,923,814 Egan Aug. 22, i933 1,930,388 Hatfield Oct. l0, 1933 1,958,575 Hengstenberg May 15, 1934 OTHER REFERENCES Metal Progress, December 1946, page 1212.
Claims (1)
1. THE METHOD OF PREPARING, FOR NITRIDING, AN ARTICLE OF A FERROUS ALLOY INCLUDING CHROME AND HAVING A FILM OF CHROME OXIDE SERVING AS A NITRIDING BARRIER, COMPRISING POSITIONING SAID ARTICLE IN A CHAMBER, CIRCULATING AMMONIA GAS AROUND SAID ARTICLE IN SAID CHAMBER, MOISTENING A MASS WITH HYDROCHLORIC ACID, POSITIONING SAID MASS IN SAID CHAMBER IN SPACED APART RELATION TO SAID ARTICLE, HEATING SAID CHAMBER TO PROGRESSIVELY HEAT THE ARTICLE UP TO ITS NITRIDING TEMPERATURE, WHEREBY HYDROCHOLORIC ACID FUMES OF SAID MASS WILL COMBINE WITH THE AMMOMIA GAS TO FORM AMMONIUM CHLORIDE VAPORS WHICH WILL CONDENSE ON THE SURFACES OF SAID ARTICLE AND ATTACK THE CHROME OXIDE COATING THEREOF, AND PROGRESSIVELY HEATING AND CHAMBER TO PROGRESSIVELY BRING THE ARTICLE UP TO ITS NITRIDING TEMPERATURE, WHEREBY THE PREVIOUSLY CONDENSED AMMONIUM CHLORIDE VAPORS VOLATILIZE FROM SAID ARTICLE SO THAT NITRIDING MAY BE PROCESSED WITH ON CIRCULATING AMMONIA GAS ONTO SAID ARTICLE.
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US461377A US2789930A (en) | 1954-10-11 | 1954-10-11 | Method of nitriding ferrous alloys |
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US461377A US2789930A (en) | 1954-10-11 | 1954-10-11 | Method of nitriding ferrous alloys |
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3140205A (en) * | 1962-07-26 | 1964-07-07 | Chapman Division Crane Co | Process for nitriding steels of the low, medium and high alloy types by first removing the passive oxide surface film |
US3219531A (en) * | 1960-08-04 | 1965-11-23 | Ind Chimique Sa | Flavone derivatives |
JPS5623268A (en) * | 1980-07-12 | 1981-03-05 | Chuo Spring Co Ltd | Soft nitriding method for steel |
US4264380A (en) * | 1979-11-16 | 1981-04-28 | General Electric Company | Nitride casehardening process and the nitrided product thereof |
US5039357A (en) * | 1990-06-15 | 1991-08-13 | Dynamic Metal Treating, Inc. | Method for nitriding and nitrocarburizing rifle barrels in a fluidized bed furnace |
FR2725015A1 (en) * | 1994-09-23 | 1996-03-29 | Innovatique Sa | Low pressure nitriding of metal workpiece |
US6093303A (en) * | 1998-08-12 | 2000-07-25 | Swagelok Company | Low temperature case hardening processes |
US6165597A (en) * | 1998-08-12 | 2000-12-26 | Swagelok Company | Selective case hardening processes at low temperature |
US6547888B1 (en) | 2000-01-28 | 2003-04-15 | Swagelok Company | Modified low temperature case hardening processes |
US20030155045A1 (en) * | 2002-02-05 | 2003-08-21 | Williams Peter C. | Lubricated low temperature carburized stainless steel parts |
US20210172046A1 (en) * | 2019-12-06 | 2021-06-10 | Swagelok Company | Chemical activation of self-passivating metals |
US11649538B2 (en) | 2018-06-11 | 2023-05-16 | Swagelok Company | Chemical activation of self-passivating metals |
US11885027B2 (en) | 2020-04-29 | 2024-01-30 | Swagelok Company | Activation of self-passivating metals using reagent coatings for low temperature nitrocarburization |
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US1923814A (en) * | 1931-08-11 | 1933-08-22 | Electro Metallurg Co | Nitriding |
US1930388A (en) * | 1931-02-25 | 1933-10-10 | Thos Firth & John Brown Ltd | Process for hardening alloy steels |
US1958575A (en) * | 1930-06-02 | 1934-05-15 | Nitralloy Corp | Process for hardening iron, steel, and cast iron alloys by nitriding |
-
1954
- 1954-10-11 US US461377A patent/US2789930A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US1958575A (en) * | 1930-06-02 | 1934-05-15 | Nitralloy Corp | Process for hardening iron, steel, and cast iron alloys by nitriding |
US1930388A (en) * | 1931-02-25 | 1933-10-10 | Thos Firth & John Brown Ltd | Process for hardening alloy steels |
US1923814A (en) * | 1931-08-11 | 1933-08-22 | Electro Metallurg Co | Nitriding |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3219531A (en) * | 1960-08-04 | 1965-11-23 | Ind Chimique Sa | Flavone derivatives |
US3140205A (en) * | 1962-07-26 | 1964-07-07 | Chapman Division Crane Co | Process for nitriding steels of the low, medium and high alloy types by first removing the passive oxide surface film |
US4264380A (en) * | 1979-11-16 | 1981-04-28 | General Electric Company | Nitride casehardening process and the nitrided product thereof |
JPS5623268A (en) * | 1980-07-12 | 1981-03-05 | Chuo Spring Co Ltd | Soft nitriding method for steel |
US5039357A (en) * | 1990-06-15 | 1991-08-13 | Dynamic Metal Treating, Inc. | Method for nitriding and nitrocarburizing rifle barrels in a fluidized bed furnace |
FR2725015A1 (en) * | 1994-09-23 | 1996-03-29 | Innovatique Sa | Low pressure nitriding of metal workpiece |
US6093303A (en) * | 1998-08-12 | 2000-07-25 | Swagelok Company | Low temperature case hardening processes |
US6165597A (en) * | 1998-08-12 | 2000-12-26 | Swagelok Company | Selective case hardening processes at low temperature |
US6461448B1 (en) | 1998-08-12 | 2002-10-08 | Swagelok Company | Low temperature case hardening processes |
US6547888B1 (en) | 2000-01-28 | 2003-04-15 | Swagelok Company | Modified low temperature case hardening processes |
US20030155045A1 (en) * | 2002-02-05 | 2003-08-21 | Williams Peter C. | Lubricated low temperature carburized stainless steel parts |
US11649538B2 (en) | 2018-06-11 | 2023-05-16 | Swagelok Company | Chemical activation of self-passivating metals |
US20210172046A1 (en) * | 2019-12-06 | 2021-06-10 | Swagelok Company | Chemical activation of self-passivating metals |
US11885027B2 (en) | 2020-04-29 | 2024-01-30 | Swagelok Company | Activation of self-passivating metals using reagent coatings for low temperature nitrocarburization |
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