US2740759A - Preparation for treating textile fibers and yarns - Google Patents

Preparation for treating textile fibers and yarns Download PDF

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Publication number
US2740759A
US2740759A US319798A US31979852A US2740759A US 2740759 A US2740759 A US 2740759A US 319798 A US319798 A US 319798A US 31979852 A US31979852 A US 31979852A US 2740759 A US2740759 A US 2740759A
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water
parts
acid
lubricating
cellulosic
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Maeder Arthur
Albrecht Otto
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BASF Schweiz AG
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Ciba AG
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/288—Partial esters containing free carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/044—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms having cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C10M2215/082—Amides [having hydrocarbon substituents containing less than thirty carbon atoms] containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/46—Textile oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Definitions

  • the present invention provides a preparation for treating silk or artificial fibers or yarns, whereby the dilfculties described above can be overcome. advantageously made up in a concentrated form and subsequently diluted with water for use on the knitting machine.
  • the treatment of the threads may be carried out, when they are drawn from spools, by passing them, before they reach the knitting mechanism, through a treatment bath contained, for example, ina trough'attached to the knitting machine.
  • the expression preparation is used herein to denote the concentrated preparation if the concentration is of importance.
  • artificial fibers or yarns of non-cellulosic character there may be mentioned those made from polyamide, polylactam or polyacrylonitrile fibers, such as those known in commerce under the names nylon, Perlon and Orion, or fibers of copolymers of acrylonitrile with other polymerizable substances such, for example, as vinyl chloride, or fibers of poly-vinylidene chloride or polyurethanes or those synthesized on the basis of terephthalic acid.
  • the threads should be rendered supple and slidable.
  • the effect should persist at least until the threads are worked up in the knitting machine.
  • knitted meshes should remain fixed.
  • the tex The preparation is tile threads should not be chemically changed, or at least not in an undesired manner, by the constituents of the treatment bath.
  • the bath should not attack the metal parts of knitting machines.
  • the lubricating and fixing substances applied to the threads should not interfere with subsequent dyeing and finishing processes and must therefore be capable of being easily washed out.
  • the bath should not have an unpleasant odor.
  • the preparation of the invention in its simplest form contains in addition to water, a lubricating agent and a compound for retarding evaporation of the water.
  • anion active compounds of the kind used in the textile industry there may be used anion active compounds of the kind used in the textile industry as softening agents.
  • anion active compounds of the kind used in the textile industry as softening agents.
  • mono-esters of dicarboxylic acids with aliphatic compounds of high molecular weight containing an alcoholic hydroxyl group there may be mentioned, for example, mono-esters of dicarboxylic acids with aliphatic compounds of high molecular weight containing an alcoholic hydroxyl group.
  • Suchv compounds may be derived from alcohols of high molecular Weight, such as cetyl alcohol, octadecylalcohol, octadecyl S-hydroxyethyl ether or octadecyl fl-hydroxyethyl thioether, and also N-hydroxyalkylamides or hydroxyalkyl esters of fatty acids of high molecular weight such as N-(B-hydroxyethyl)-palrnitic acid amide,N-(fl-hydroxyethyl)-oleic acid amide, N-(Z- hydroxypropyl)-stearic acid amide or stearic acid B-hydroxythyl ester.
  • alcohols of high molecular Weight such as cetyl alcohol, octadecylalcohol, octadecyl S-hydroxyethyl ether or octadecyl fl-hydroxyethyl thioether
  • the dicarboxylic acids with which the aforesaid hydroxyl compounds are esterified, may be of the aliphatic or aromatic series. There may be mentioned phthalic acid, succinic acid and maleic acid. The preparation of such mono-esters is known or they can be made by methods in themselves known. There are also suitable condensation products of fatty acid methylolamides and thioglycollic acid, such as are obtainable as described in French Patents Nos. 858,459 and 900,068. In general it is of advantage to use as lubricating agents compounds which contain an aliphatic unbranched carbon chain containing about l6-18 carbon atoms.
  • aliphatic alcohols which may be used, but which are not so advantageous as terpene alcohols from the point of view of their odor, there may be mentioned, inter alia, Z-ethylhexanol, isooctanol and trimethylhexanol.
  • the two main constituents namely the lubricating agent and the compound retarding evaporation
  • anion active or ion-free washing agents for example, sulfonated benzimidazoles substituted at the Z-carbon atom by an alkyl radical of high molecular weight, monocarboxylic acid esters of 4-sulfophthalic acid with higher fatty alcohols,
  • fatty alcohol sulfonates alkyl-aryl sulfonates or condensation products of higher fatty acids with aliphatic hydroxyor amino-sulfonic acids, and also salts of fatty acids, such as coconut fatty acids, palmitic acid or stearic acid, and finally polyglycol ethers derived from ethylene oxide and higher fatty alcohols or fatty amines.
  • Advantageously dispersing agents resistant to lime are used.
  • a solution promoter may afford the advantage of rendering the dispersions more stable and making it easier to dilute the concentrated preparations.
  • a solution promoter may afford the advantage of rendering the dispersions more stable and making it easier to dilute the concentrated preparations.
  • compounds which are soluble in water and organic liquids and are volatile There may be mentioned, for example, monoethers of ethylene glycol, such as ethylene glycol monomcthyl ether or ethylene glycol monoethyl ether.
  • the relative proportions of the ingredients of the preparations may vary within fairly wide limits. It has been found advantageous to use for every 10 parts of the lubricating agent, about 7.5-15 parts of the substance retarding evaporation, 4-20 parts of the dispersing agent, 2.5-5 parts of the solution promoter, 1.5-3.5 parts of the corrosion inhibitor and 1-3 parts of alkaline and buffer substances. It will be understood that the invention is not confined to these proportions, and that one or more of the components may be omitted, as explained above.
  • the quantity of water depends on the desired consistency of the preparation.
  • a preparation having the consistency of a paste is desired less water is used, and if on the other hand a liquid preparation is desired correspondingly more water is required.
  • concentration of the preparation is so adjusted that about 5-20 grams are required per liter bath liquor for preparing the treatment bath.
  • the preparation is advantageously diluted in such manner as to give a concentration of about 0.8 to 2 grams of lubricating agent and about 1-1.5 grams of I the substance retarding evaporation, per liter of bath liquid.
  • the preparation can be prepared in a simple manner by mixing the components advantageously at a raised temperature, for example, at 60-130 C. All the constitnents may be added at the same time. Alternatively, a mixture of two or three of the components may be made first, and the remaining ingredients added subsequently. In accordance with the latter procedure, for example, a mixture of the lubricating agent, the substance retarding evaporation and the solution promoter may be prepared first, and then an aqueous solution of the remaining components may be added to the resulting mixture.
  • Example I 21 parts of the sodium salt of phthalic acid monooctadecyl ester
  • Example 2 The mixture constitutes a thickly liquid clear solution.
  • Example 3 The procedure is the same as described in Example 1, except that the mixture has the following composition:
  • the resulting paste is given a pH value of 9 by the addition of caustic soda solution.
  • Example 4 The following ingredients are mixed together by heating at 120 C. for 2 hoursin a vessel fitted with stirring means and heated with steam:
  • the mixture is then cooled to room temperature while stirring.
  • the resulting paste has a pH of 9.
  • Example 5 The following ingredients are thoroughly mixed together by heating at C. and stirring for V2 hour in a vessel fitted with stirring mechanism and heated with steam:
  • Example 6 The procedure is the same as described in Example 5, except that the mixture has the following composition 5.2 parts of the condensation product from stearic acid methylolamide and thioglycollic acid, obtainable as described in Example 6 of French Patent No. 900,068,
  • a syrup is obtained which is turbid due to the solid constituents still in suspension.
  • Example 7 A paste, which is stable and can be stored for a long time, is obtained by first thoroughly mixing together and stirring at 60 C., s
  • a-terpineol may be replaced by iso-octanol or fenchyl alcohol or pine oil.
  • Example 8 In the manner described in Example 5, there is first prepared a mixture by stirring together at 90 C.,
  • Example 9 30 denier yarn of polyhexamethylene-adipic acid amide is passed through a bath, attached to a stocking knitting machine, which contains, per liter, 10 grams of the preparation described in any one of Examples 1, 2, 3, and 6, or 12 grams of the preparation described in Example 4 or 5, or 5 grams of the preparation of Example 7, or 20 grams of the preparation of Example 8.
  • the yarn is then stripped and immediately knitted in the moist condition.
  • the threads so treated slide satisfactorily through all the eyelet holes and other parts of the knitting machine, the meshes formed during knitting are uniform and there is no appearance of curling.
  • the non-volatile constituents ofthe preparation dry on the fabric, and impart to it the desired stiflening and fixation, which is necessary for further treatment in the manufacture of stockings.
  • the constituents of the preparation on the fabric can easily be removed when the knitted goods are finished, by washing with warm water, and no residue remains which impairs subsequent dyeing and finishing processes.
  • a composition of matter suitable for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting which comprises Water, as a lubricating agent an anion active textile softening agent selected from the group consisting of a water-soluble salt of a monoester of a dicarbox ylic acid with an aliphatic compound of high molecular weight containing an alcoholic hydroxyl group, and a water soluble salt of a condensation product of a fatty acid methylolamide of high molecular weight and thioglycollic acid, and for retarding evaporation of the water an alcohol boiling within the range of 160 C.240 C. which is volatile with Water vapor and at least partially soluble in water, the composition containing for every 10 parts of said lubricating agent, 7.515 parts of said substance retarding evaporation of the water.
  • a composition of matter suitable for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting which comprises water, as a lubricating agent an anion active textile softening agent selected from the group consisting of a water-soluble salt of a monoester of a dicarboxylic acid with an aliphatic compound of high molecular weight containing an alcoholic hydroxyl group, and a Water solublesalt of a condensation product of a fatty acid methylolamide of high molecular weight and thioglycollic acid,
  • a dispersing agent selected from the group consisting softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting, which comprises Water, as a lubricating agent an anion active textile softening agent selected from the group consisting of a water-soluble salt of a monoester of a dicarboxylic acid with an aliphatic compound of high molecular weight containing an alcoholic hydroxyl group, and a water soluble salt of a condensation product of a fatty acid methylolamide'of high molecular weight and thioglycollic acid, for retarding evaporation of the water an alcohol boiling within the range of 160 C.240 C.
  • a dispersing agent selected from the group consisting of anion active and ion-free washing agents, and a solution promoter, the composition containing for every 10 parts of said lubricating agent, 7.515 partsof said substance retarding evaporation of the water, 4-20 parts 7 of said dispersing agent, and 2.5-5 parts of said solution promoter.
  • a composition of matter suitable for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting which comprises water, as a lubricating agent an anion active textile softening agent selected from the group consisting of a water-soluble salt of a monoester of a dicarboxylic acid with an aliphatic compound of high molecular weight containing an alcoholic hydroxyl group, and a water soluble salt of a condensation product of a fatty acid methylolamide of high molecular weight and thioglycollic acid, for retarding evaporation of the water an alcohol boiling within the range of 160 C.-240 C.
  • a dispersing agent selected from the group consisting of anion active and ion-free washing agents, a solution promoter, and a water soluble salt of nitrous acid as a corrosion inhibitor, the composition containing for every 10 parts of said lubricating agent, 7.5-15 parts of said sub- 1 stance retarding evaporation of the water, 4-20 parts of said dispersing agent, 2.5-5 parts of said solution promotor and 1.5-3.5 parts of said corrosion inhibitor.
  • a composition of matter suitable for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting which comprises water, as a lubricating agent an anion active textile softening agent selected from the group consisting of a water-soluble salt of a monoester of a dicarboxylic acid with an aliphatic compound of high molecular weight containing an alcoholic hydroxyl group, and a water soluble salt of a condensation product of a fatty acid methylolamide of hi h molecular weight and thioglycollic acid, for retarding evaporation of the water an alcohol boiling within the range of 160 -240 C.
  • an anion active textile softening agent selected from the group consisting of a water-soluble salt of a monoester of a dicarboxylic acid with an aliphatic compound of high molecular weight containing an alcoholic hydroxyl group, and a water soluble salt of a condensation product of
  • a dispersing agent selected from the group consisting of anion active and ion-free washing agents, a solution promoter, and a water soluble salt of nitrous acid as a corrosion inhibitor, the composition containing for every 10 parts of said lubricating agent, 7.5-15 parts of said substance retarding evaporation of the water, 4-20 parts of said dispersing agent, 2.5- parts of said solution promoter, and 1.5-3.5 parts of said corrosion inhibitor, and a quantity of an inorganic water-soluble substance of alkaline reaction such that the pH value of the composition is about 8-10.
  • a composition of matter suitable for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting which comprises water.
  • a lubricating agent an anion active textile softening agent selected from the group consisting of a water-soluble salt of a monocster of a dicarboxylic acid with an aliphatic compound of high molecular weight containing an alcoholic hydroxyl group, and a water soluble salt of a condensation product of a fatty acid methylolamide of high molecular weight and thioglycollic acid, for retarding evaporation of the water an alcohol boiling within the range of 160 C.-240 C.
  • a dispersing agent selected from the group consisting of anion active and ion-free washing agents, a solution promoter, a water soluble salt of nitrous acid as a corrosion inhibitor, and a butter substance, the composition containing for every parts of said lubricating agent, 7.5- parts of said substance retarding evaporation of the water, 4-20 parts of said dispersing agent, 2.5-5 parts of said solution promoter, 1.5-3.5 parts of said corrosion inhibitor and 1-3 parts of said buffer substance and a quantity of an inorganic water-soluble substance of alkaline reaction such that the pH value of the composition is about 8-10.
  • an anion-active .sulfonated washing agent resistant to lime as a solution promoter a mono-ether of ethyleneglycol, the composition containing for every 10 parts of said lubricating agent, 7.5-15 parts of said substance retarding evaporation of the water, 4-20 parts of said dispersing agent, 2.5-5 parts of said solution promoter, and a quantity of an inorganic water-soluble substance of alkaline reaction such that the pH value of the composition is about 8-10.
  • a composition of matter suitable for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting which comprises water, as a lubricating agent the sodium salt of phthalic acid mono-octadecyl ester, as substance retarding evaporation of water a-terpineol, as dispersing agent the sodium salt of N-benzyl-2-heptadecylbenzimidazole disulfonic acid, as solution promoter ethylene glycol monoethyl ether, as corrosion inhibitor sodium nitrite, as buffer substance trisodium phosphate, the composition containing for every 10 parts of said lubricating agent, 7.5-15 parts of said substance retarding evaporation of the water, 4-20 parts of said dispersing agent, 2.5-5 parts of said solution promoter, 1.5-3.5 parts of said corrosion inhibitor, 1-3 parts of said butter substance, and a quantity of sodium carbonate such that the pH value of the composition is about 8-10
  • a composition of matter suitable for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting which contains 10.5 parts of the sodium salt of phthalic acid monoctadecyl ester, 7.5 parts of tx-terpineol, 4.5 parts of the sodium salt of N-benzyl-2-heptadecylbenzimidazole-disulfonic acid, 2.5 parts of ethylene glycol monoethyl ether, 1.75 parts of sodium nitrite, 2 parts of sodium carbonate, 1 part of trisodium phosphate and parts of water.
  • a process for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting comprising treating the fiber and yarn with a bath which has been prepared with a composition of matter which comprises water, as a lubricating agent an anion active textile softening agent selected from the group consisting of a water-soluble salt of a monoester of a dicarboxylic acid with an aliphatic compound of high molecular weight containing an alcohol hydroxyl group, and a water soluble salt of a condensation product of a fatty acid methylolamide of high molecular Weight and thioglycollic acid, and for retarding evaporation of the water an alcohol boiling within the range of C.-240 C. which is volatile with water vapor and at least partially soluble in water, the composition containing for every 10 parts of said lubricating agent, 7.5-15 parts of said substance retarding evaporation of the water.
  • a process for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting comprising treating the fiber and yarn with a bath which has been prepared with a composition of matter which comprises water, as a lubricating agent an anion active textile softening agent selected from the group consisting of a watersoluble salt of a monoester of a dicarboxylic acid with an aliphatic compound of high molecular weight containing an alcoholic hydroxyl group, and a water soluble salt'of a condensation product of a fatty acid methylolamide of high molecular weight and thioglycollic acid, and for retarding evaporation of the water an alcohol boilipg within the range of 160 0-240 C.
  • a dispersing agent selected from the group consisting of anion active and ion-free washing agents, the composition containing for every 10 parts of said lubricating agent, 7.5-15 parts of said substance retarding evaporation of the water, and 4-20 parts of said dispersing agent.
  • a process for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting comprising treating the fiber and yarn with a bath which has been prepared with a composition of matter which comprises water, as a lubricating agent an anion active textile softening agent selected from the group consisting of a water-soluble salt of a monoester of a dicarboxylic acid with an aliphatic compound of high molecular weight containing an alcoholic hydroxyl group, and a water soluble salt of a condensation product of a fatty acid methylolamide of high molecular weight and thioglycollic acid, for retarding evaporation of the water an alcohol boiling within the range of 160 C.-240 C.
  • a dispersing agent selected from the group consisting of anion active and ion-free washing agents and a solution promoter, the composition containing for every 10 parts of said lubricating agent, 7.5-l5 parts of said substance retarding evaporation of the water, 4-20 parts of said dispersing agent, and 2.5-5 parts of said solution promoter.
  • a process for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting comprising treating the fiber and yarn with a bath which has been prepared with a composition of matter which comprises water, as a lubricating agent an anion active textile softening agent selected from the group consisting of a Water-.
  • a dispersing agent selected from the group consisting of anion active and ion-free washing agents, a solution promoter and a water soluble salt of nitrous acid as a corrosion inhibitor, the composition containing for every parts of said lubricating agent, 7.5-l5 parts of said substance retarding evaporation of the water, 4-20 parts of said dispersing agent, 2.5-5 parts of said solution promoter, and 1.5-3.5 parts of said corrosion inhibitor.
  • a process for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting comprising treating the fiber and yarn with a bath which has been prepared with a composition of matter which comprises water, as a lubricating agent an anion active textile softening agent selected from the group consisting of a watersoluble salt of a monoester of a dicarboxylic acid with an aliphatic compound of high molecular weight containing an alcoholic hydroxyl group, and a water soluble salt of a condensation product of a fatty acid methylolamide of high molecular weight and thioglycollie acid, for retarding evaporation of the water an alcohol boiling within the range of 160 C.-240 C.
  • a dispersing agent selected from the group consisting of anion active and ion-free washing agents, a solution promoter, a water soluble salt of nitrous acid as a corrosion inhibitor, the composition containing for every 10 parts of said lubricating agent, 7.5- parts of said substance retarding evaporation of the water, 4-20 parts of said dispersing agent, 2.5-5 parts of said solution promoter, and 1.5-3.5 parts of said corrosion inhibitor, and a quantity of an inorganic water-soluble substance '10 of alkaline reaction such that the pH'value of the com position is about 8-10.
  • a process for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting comprising treating the fiber and yarn with a bath which has been prepared with a composition of matter which comprises water, as a lubricating agent an anion active textile softening agent selected from the group consisting of a water-soluble salt of a monoester of a dicarboxylic acid with an aliphatic compound of high molecular weight containing an aicoholic hydroxyl group, and a water soluble salt of a condensation product of a fatty acid methylolamide of high molecular weight and thioglycollic acid, for retarding evaporation of the water an alcohol boiling with the range of C.-240 C.
  • a dispersing agent selected from the group consisting of anion active and ion-free washing agents, a solution promoter, a water soluble salt of nitrous acid as a corrosion inhibitor, and a buffer substance, the composition containing for every 10 parts of said lubricating agent, 7.5-15 parts of said substance retarding evaporation of the water, 4-20 parts of said dispersing agent, 2.5-5 parts of said solution promoter, l.5-3.5 parts of said corrosion inhibitor and 1-3 parts of said buffer substance and a quantity of an inorganic water-soluble substance of alkaline reaction such that the pH value of the composition is about 8-10.
  • a process for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting comprising treating the fiber and yarn with a bath which has been prepared with a composition of matter which comprises water, as a lubricating agent a water soluble salt of a monoester of a dicarboxylic acid with an aliphatic compound of high molecular weight containing an alcoholic hydroxyl group, as a substance retarding evaporation of water an alcohol boiling within the range of 160-240 C.
  • an anion active sulfonated washing agent resistant to lime as a solution promoter a monoether of ethyleneglycol, the composition containing for every 10 parts of said lubricating agent, 7.5-15 parts of said substance retarding evaporation of the water, 4-20 parts of said dispersing agent, 2.5-5 parts of said solution promoter, and a quantity of an inorganic watersoluble substance of alkaline reaction such that the pH value of the composition is about 8-10.
  • a process for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting comprising treating the fiber and yarn with a bath which has been prepared with a composition of matter which comprises water, as a lubricating agent the sodium salt of phthalic acid mono-octadecyl ester, as substance retarding evaporation of water a-terpineol, as dispersing agent the sodium salt of N-benzyl-2-heptadecyl-benzimidazole disulfonic acid, as solution promoter ethylene glycol monoethyl ether, as corrosion inhibitor sodium nitrite, as buffer substance trisodium phosphate, the composition containing for every 10 parts of said lubricating agent, 7.5-15 parts of said substance retarding evaporation of the water, 4-20 parts of said dispersing agent, 2.5-5 parts of said solution promoter, and 1.5-3.5 parts of said corrosion inhibitor, 1-3 parts of said buffer substance and
  • a process for lubricating and softening silk and artificial fibers and yarns of cellulosic and non-cellulosic character preparatory to knitting comprising treating the fiber and yarn with a bath which has been prepared with a composition of matter which contains 10.5 parts of the sodium salt of phthalic acid monooetadecyl ester, 7.5 parts of a-terpineol, 4.5 parts of the sodium salt of N-benzyl-2-heptadecyl-benzimidazole-disulfonic acid,

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2944920A (en) * 1955-11-07 1960-07-12 Emery Industries Inc Process for lubricating and promoting the cohesion of textile fibers
US2960463A (en) * 1957-03-26 1960-11-15 Hooker Chemical Corp Process of stabilizing aqueous emulsions of tertiary aromatic phosphites
US2983625A (en) * 1957-02-20 1961-05-09 American Viscose Corp Treatment of silica coated fibers
US3161594A (en) * 1961-07-14 1964-12-15 Eastman Kodak Co Textile lubricant composition
US3348968A (en) * 1963-02-21 1967-10-24 Ici Ltd Synthetic textile treated with polyalkenoxy agents and corrosion inhibiting salts to prevent static electric charges
US4057503A (en) * 1975-10-20 1977-11-08 Pennwalt Corporation Concentrates for imparting temporary soil release resins in fabrics during laundering
US4153561A (en) * 1976-12-31 1979-05-08 Hoechst Aktiengesellschaft Conditioning agent
US4351738A (en) * 1979-08-21 1982-09-28 Teijin Limited Yarn treating composition for high-speed friction draw-false twist texturing and a filamentary yarn treated with the same
CN104195830A (zh) * 2014-08-27 2014-12-10 无锡市奇盛针织手套厂 一种毛织物抗起毛起球剂及其制备方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106637951A (zh) * 2016-12-15 2017-05-10 吴江市北厍盛源纺织品助剂厂 一种添加有柠檬酸钠的纺织品整理剂及其制备方法

Citations (5)

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US2025435A (en) * 1933-07-01 1935-12-24 American Enka Corp Treating natural and artificial fibers
US2086590A (en) * 1932-05-17 1937-07-13 Celanese Corp Textile material and method of making the same
US2158374A (en) * 1936-01-27 1939-05-16 Union Oil Co Soluble oils
US2361472A (en) * 1940-04-08 1944-10-31 Chem Ind Basel Imidazole derivatives and process of preparing the same
US2629701A (en) * 1949-05-27 1953-02-24 Upson Co Compositions containing esters of a glycol and polycarboxylic acids and the treatment of cellulose therewith

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AT143841B (de) * 1931-07-27 1935-12-10 Italiana Della Viscosa Soc Gen Verfahren zum Schlichten von Kunstseide.
DE728235C (de) * 1940-03-07 1942-11-23 Boehme Fettchemie G M B H Schmaelzmittel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2086590A (en) * 1932-05-17 1937-07-13 Celanese Corp Textile material and method of making the same
US2025435A (en) * 1933-07-01 1935-12-24 American Enka Corp Treating natural and artificial fibers
US2158374A (en) * 1936-01-27 1939-05-16 Union Oil Co Soluble oils
US2361472A (en) * 1940-04-08 1944-10-31 Chem Ind Basel Imidazole derivatives and process of preparing the same
US2629701A (en) * 1949-05-27 1953-02-24 Upson Co Compositions containing esters of a glycol and polycarboxylic acids and the treatment of cellulose therewith

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2944920A (en) * 1955-11-07 1960-07-12 Emery Industries Inc Process for lubricating and promoting the cohesion of textile fibers
US2983625A (en) * 1957-02-20 1961-05-09 American Viscose Corp Treatment of silica coated fibers
US2960463A (en) * 1957-03-26 1960-11-15 Hooker Chemical Corp Process of stabilizing aqueous emulsions of tertiary aromatic phosphites
US3161594A (en) * 1961-07-14 1964-12-15 Eastman Kodak Co Textile lubricant composition
US3348968A (en) * 1963-02-21 1967-10-24 Ici Ltd Synthetic textile treated with polyalkenoxy agents and corrosion inhibiting salts to prevent static electric charges
US4057503A (en) * 1975-10-20 1977-11-08 Pennwalt Corporation Concentrates for imparting temporary soil release resins in fabrics during laundering
US4153561A (en) * 1976-12-31 1979-05-08 Hoechst Aktiengesellschaft Conditioning agent
US4351738A (en) * 1979-08-21 1982-09-28 Teijin Limited Yarn treating composition for high-speed friction draw-false twist texturing and a filamentary yarn treated with the same
CN104195830A (zh) * 2014-08-27 2014-12-10 无锡市奇盛针织手套厂 一种毛织物抗起毛起球剂及其制备方法
CN104195830B (zh) * 2014-08-27 2016-04-13 无锡市奇盛针织手套厂 一种毛织物抗起毛起球剂及其制备方法

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BE515476A (en))
GB773574A (en) 1957-05-01
FR1071842A (fr) 1954-09-06
NL91992C (en))
NL94057C (en))
DE1009151B (de) 1957-05-29
NL173761B (nl)

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