US2059567A - Prevention of sludge formation in lubricating oils - Google Patents

Prevention of sludge formation in lubricating oils Download PDF

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Publication number
US2059567A
US2059567A US754283A US75428334A US2059567A US 2059567 A US2059567 A US 2059567A US 754283 A US754283 A US 754283A US 75428334 A US75428334 A US 75428334A US 2059567 A US2059567 A US 2059567A
Authority
US
United States
Prior art keywords
oil
chromium
tin
oleate
lubricating oils
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US754283A
Other languages
English (en)
Inventor
Evans Elliott Alfred
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CC Wakefield and Co Ltd
Original Assignee
CC Wakefield and Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CC Wakefield and Co Ltd filed Critical CC Wakefield and Co Ltd
Application granted granted Critical
Publication of US2059567A publication Critical patent/US2059567A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/05Metals; Alloys
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/08Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds
    • C10M2227/082Pb compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds

Definitions

  • a lubricant for use in internal-combustion engines having ferrous metal cylinders which lubricant comprises a lubricating oil having dispersed therein one or more substances of a class which counteracts the catalytic action of the ferrous metal upon the oil.
  • This class of materials includes organic compounds of chromium and organic compounds of tin. Other suitable organo-metallic compounds may readily be determined by carrying out oxidation tests on the oil in the presence of iron.
  • a feature of this invention therefore consists in dispersing in the lubricating oil, in addition to an anticatalyst, a small proportion of a substance for counteracting the aforesaid direct oxidation.
  • Various substances are already known to possess this property, such as tin compounds; thus, according to this invention there may be dispersed in the oil'bpth a small proportion of an organic compound of chromium and a small proportion of an organic compound of tin. It is indicated above that tin is included in the class of material which counteracts the catalytic action of the ferrous metal upon the oil. It, however,
  • Another cause of deterioration of the lubricating oil is due to spontaneous ignition or cracking'of the oil under high temperature and pressure conditions.
  • the lubricating oil has dispersed therein both a small proportion of a substance for counteracting the aforesaid action of metallic surfaces on the oil, for example a small proportion of chromium or its compounds, and a small proportion of a sludge-preventing substance, such as tin or its compounds, and a small proportion of a substance for raising the temperature at which spontaneous ignition or cracking of the 011 takes place, for example tetra-ethyl lead or other suitable lead compounds.
  • a substance for counteracting the aforesaid action of metallic surfaces on the oil for example a small proportion of chromium or its compounds
  • a sludge-preventing substance such as tin or its compounds
  • a substance for raising the temperature at which spontaneous ignition or cracking of the 011 takes place for example tetra-ethyl lead or other suitable lead compounds.
  • the invention includes within its scope a lubricant comprising a lubricating oil having dispersed therein in addition to a small proportion of an organic compound of chromium either a small proportion of an organic compound of tin, or of an organic compound of lead, or both said latter substances.
  • oil-soluble compounds of the above metals are selected, such as chromium oleate, tin oleate and tetra-ethyl lead, which substances may be added to the oil in proportions of up to 1% by weight of each compound, according to the nature of the lubricating oil treated.
  • chromium oleate such as chromium oleate, tin oleate and tetra-ethyl lead
  • chromium oleate such as chromium oleate, tin oleate and tetra-ethyl lead
  • a lubricant comprising a lubricating oil 5 ing oil having dispersed therein material having dispersed therein in material amounts 5 amounts up to .4% chromium oleate, up to up to .4% chromium oleate and up to .1% tin .1% tin oleate and up to .1% tetra-ethyl lead. oleate.
  • a lubricant comprising a. parafilnic ELLIOTT ALFRED EVANS.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Lubrication Of Internal Combustion Engines (AREA)
US754283A 1933-12-30 1934-11-22 Prevention of sludge formation in lubricating oils Expired - Lifetime US2059567A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB36695/33A GB431066A (en) 1933-12-30 1933-12-30 Improvements in relation to the treatment of lubricating oils

Publications (1)

Publication Number Publication Date
US2059567A true US2059567A (en) 1936-11-03

Family

ID=10390417

Family Applications (1)

Application Number Title Priority Date Filing Date
US754283A Expired - Lifetime US2059567A (en) 1933-12-30 1934-11-22 Prevention of sludge formation in lubricating oils

Country Status (6)

Country Link
US (1) US2059567A (fr)
BE (1) BE405989A (fr)
DE (1) DE701121C (fr)
FR (1) FR780448A (fr)
GB (1) GB431066A (fr)
NL (1) NL38179C (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2763613A (en) * 1953-10-29 1956-09-18 Shell Dev Lubricating oil containing dicyclopentadienyl iron and an oil soluble organic divalent metal salt
US2763617A (en) * 1953-10-29 1956-09-18 Shell Dev Lubricating oil containing dicyclopentadienyl iron and a wear inhibiting agent
US3303132A (en) * 1964-03-19 1967-02-07 Mobil Oil Corp High temperature lubricating compositions
US4863892A (en) * 1983-08-16 1989-09-05 Phillips Petroleum Company Antifoulants comprising tin, antimony and aluminum for thermal cracking processes

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB658243A (en) * 1947-02-27 1951-10-03 Wakefield & Co Ltd C C Improvements in or relating to lubricating compositions and additives therefor

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2763613A (en) * 1953-10-29 1956-09-18 Shell Dev Lubricating oil containing dicyclopentadienyl iron and an oil soluble organic divalent metal salt
US2763617A (en) * 1953-10-29 1956-09-18 Shell Dev Lubricating oil containing dicyclopentadienyl iron and a wear inhibiting agent
US3303132A (en) * 1964-03-19 1967-02-07 Mobil Oil Corp High temperature lubricating compositions
US4863892A (en) * 1983-08-16 1989-09-05 Phillips Petroleum Company Antifoulants comprising tin, antimony and aluminum for thermal cracking processes

Also Published As

Publication number Publication date
BE405989A (fr)
FR780448A (fr) 1935-04-26
NL38179C (fr)
DE701121C (de) 1941-01-09
GB431066A (en) 1935-07-01

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