US1796857A - Lubricant - Google Patents

Lubricant Download PDF

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Publication number
US1796857A
US1796857A US227364A US22736427A US1796857A US 1796857 A US1796857 A US 1796857A US 227364 A US227364 A US 227364A US 22736427 A US22736427 A US 22736427A US 1796857 A US1796857 A US 1796857A
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US
United States
Prior art keywords
lubricant
diluent
lubricating oil
oil
engine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US227364A
Inventor
Daniel P Barnard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Priority to US227364A priority Critical patent/US1796857A/en
Application granted granted Critical
Publication of US1796857A publication Critical patent/US1796857A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/022Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/06Perfluorinated compounds

Definitions

  • This invention relates to lubricants and particularly to lubricants for aeroplane motors.
  • the lubricant consists of a base of lubricating oil, together with a relatively small amount of a relativey high volatile and substantially uninflammable diluent.
  • the lubricating oil may be of viscosity and lubricating properties suitable for any particular type of engine unden operating conditions.
  • volatile and uninflammable or relatively uninflammable diluent itis preferred to employ carbon tetrachloride, but it 1 is within the scope of the. invention to use chloroform or other suitable halogen substituted hydrocarbons, or a mixture of these with relativelysmall quantities of volatile hydrocarbons.
  • the lubricant may suitably consist of about 90% to 95% of hydrocarbon lubricating oil and 10% to 5% of volatile, uninflammable diluent.
  • the viscosity of the mixture may suitably be between 60 and 80 seconds Saybolt at 210 F. and less than 100,000 seconds Saybolt at F.
  • the diluent should be of such a volatility that it is substantially completely eliminated after full-load operation of the engine for about one hour or for a considerably shorter time especially where the diluent is uninflammable to a high degree. In general, a product boiling below 250 F. will have the desired degree-of volatility.
  • composition is given:
  • Lubricating oil 7 seconds Saybolt viscosity at 100 F., pour at 10 F 93% Carbon tetrachloride 7%
  • the mixture has a viscosity of 85,000 seconds Saybolt at -2() F. and 400 seconds Saybolt at 100 F.
  • the diluent is substantially completely eliminated after half an hour full-load operation of the engine so that the oil increases in viscosity to 730 seconds Saybolt at 100 F. and 65 seconds Saybolt at 210 R, which insures satisfactory lubrica- Applicat ion filed October 19, 1927. Serial No. 227,364.
  • the improved lubricant is particularly suitable for use in starting aeroplanes in very cold weather, since it insures oil circulation and lubrication when starting the engine and since the diluent is eliminated in a relatively short time, eflicient lubrication is insured during prblonged operation. Moreover, danger of explosion in the crank-case is avoided by the selection of a non-inflammable diluent.
  • the use of a hydrocarbon sufliciently volatile to behave in a similar manner results in a very low flash test for the oil, making it rather unsafe to handle and store.
  • the oil may be prepared by mixing the ingredients before supplying the oil to the engine, or, if desired, the appropriate amount of diluent may be supplied to the oil in the crank-case.
  • the latter method is particularly suitable where the aeroplane has been operated for some time so that the diluent has been eliminatedand then the engine stopped and allowed to become cold.
  • a lubricant for internal combustion engines comprising a fluid lubricating oil and a relatively volatile and substantially uninflammable diluent.
  • a lubricant for internal combustion engines comprising a lubricating oil of characteristics suitable for the effective lubrication of the engine under operating conditions and a relatively small amountof avolatile substantially uninflammable diluent.
  • a lubricant for internal combustion engines comprising hydrocarbon lubricating oil and a halogen substituted hydrocarbon boiling mainly below 250 F.
  • a diluted lubricant comprising a mineral lubricating oil and a chloro derivative of a hydrocarbon boiling mainly below 250.
  • a diluted lubricant comprising a mineral lubricating oil and carbon tetrachloride.
  • a lubricant for internal combustion engines comprising to of lubricating oil, and 10% to 5% of a halogen substituted hydrocarbon.
  • a lubricant for internal combustion engines comprising 90% to 95% of lubricating oil, and 10% to 5% of carbon tetrachloride.
  • a lubricant for internal combustion engines comprising 90% to 95% of lubricating oil, and 10% to 5% of carbon tetrachloride, and having a viscosity between 60 and 80 seconds Saybolt at 210 F. and less than 100,000 seconds Saybolt at 20 F.
  • a lubricant for internal combustion engines comprising 93% of a lubricating oil having a viscosity of about 7 30 seconds sa bolt at F. and a pour of about 10 F., and about 7% of carbon tetrachloride.
  • a lubricant forinternal combustion engines constituted mainly by hydrocarbon mineral lubricating oil of viscosity and lubrieating properties suitable for the engine underoperating conditions and not more than 10% of a readily volatile ,and substantially uninflljammable diluent boiling mainly below 250 11.
  • a lubricant for internal combustion engines comprising a lubricating oil of characteristics suitable for the effective lubrication of the engine under operating conditions and a relatively small amount of a substantially non-inflammable diluent boiling mainly below 250 F.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

h Patented 17, 1931 UNITED STATES PATENT orrlca DANIELE. BARNABD, F W'HITING, INDIANA, ASSIGNOR TO STANDARD OIL COMPANY,
- OF WHITIN G, INDIILAIN'A, A CORPORATION OF INDIANA LUBRICANT No Drawing.
- r This invention relates to lubricants and particularly to lubricants for aeroplane motors. s
According to the invention the lubricant consists of a base of lubricating oil, together with a relatively small amount of a relativey high volatile and substantially uninflammable diluent. 1
The lubricating oil may be of viscosity and lubricating properties suitable for any particular type of engine unden operating conditions. As thevolatile and uninflammable or relatively uninflammable diluent, itis preferred to employ carbon tetrachloride, but it 1 is within the scope of the. invention to use chloroform or other suitable halogen substituted hydrocarbons, or a mixture of these with relativelysmall quantities of volatile hydrocarbons.
The lubricant may suitably consist of about 90% to 95% of hydrocarbon lubricating oil and 10% to 5% of volatile, uninflammable diluent. For use as an aeroplane oil in cold weather, the viscosity of the mixture may suitably be between 60 and 80 seconds Saybolt at 210 F. and less than 100,000 seconds Saybolt at F.
The diluent should be of such a volatility that it is substantially completely eliminated after full-load operation of the engine for about one hour or for a considerably shorter time especially where the diluent is uninflammable to a high degree. In general, a product boiling below 250 F. will have the desired degree-of volatility.
By way of example, the following composition is given:
Lubricating oil 7 seconds Saybolt viscosity at 100 F., pour at 10 F 93% Carbon tetrachloride 7% The mixture has a viscosity of 85,000 seconds Saybolt at -2() F. and 400 seconds Saybolt at 100 F. The diluent is substantially completely eliminated after half an hour full-load operation of the engine so that the oil increases in viscosity to 730 seconds Saybolt at 100 F. and 65 seconds Saybolt at 210 R, which insures satisfactory lubrica- Applicat ion filed October 19, 1927. Serial No. 227,364.
tion for the engine undefi operating conditions.
- The improved lubricant is particularly suitable for use in starting aeroplanes in very cold weather, since it insures oil circulation and lubrication when starting the engine and since the diluent is eliminated in a relatively short time, eflicient lubrication is insured during prblonged operation. Moreover, danger of explosion in the crank-case is avoided by the selection of a non-inflammable diluent. The use of a hydrocarbon sufliciently volatile to behave in a similar manner results in a very low flash test for the oil, making it rather unsafe to handle and store.
The oil may be prepared by mixing the ingredients before supplying the oil to the engine, or, if desired, the appropriate amount of diluent may be supplied to the oil in the crank-case. The latter method is particularly suitable where the aeroplane has been operated for some time so that the diluent has been eliminatedand then the engine stopped and allowed to become cold.
Although the invention has been described in connection with the details of a specific example thereof, it must be understood that it is not'intended to be limited thereto, except insofar as included in the accompanying claims.
I claim:
1. A lubricant for internal combustion engines comprising a fluid lubricating oil and a relatively volatile and substantially uninflammable diluent.
2. A lubricant for internal combustion engines comprising a lubricating oil of characteristics suitable for the effective lubrication of the engine under operating conditions and a relatively small amountof avolatile substantially uninflammable diluent.
3. A lubricant for internal combustion engines comprising hydrocarbon lubricating oil and a halogen substituted hydrocarbon boiling mainly below 250 F.
4. A diluted lubricant comprising a mineral lubricating oil and a chloro derivative of a hydrocarbon boiling mainly below 250.
5. A diluted lubricant comprising a mineral lubricating oil and carbon tetrachloride.
'6. A lubricant for internal combustion engines comprising to of lubricating oil, and 10% to 5% of a halogen substituted hydrocarbon.
7 A lubricant for internal combustion engines comprising 90% to 95% of lubricating oil, and 10% to 5% of carbon tetrachloride.
8. A lubricant for internal combustion engines comprising 90% to 95% of lubricating oil, and 10% to 5% of carbon tetrachloride, and having a viscosity between 60 and 80 seconds Saybolt at 210 F. and less than 100,000 seconds Saybolt at 20 F.
9. A lubricant for internal combustion engines comprising 93% of a lubricating oil having a viscosity of about 7 30 seconds sa bolt at F. and a pour of about 10 F., and about 7% of carbon tetrachloride.
10. A lubricant forinternal combustion engines constituted mainly by hydrocarbon mineral lubricating oil of viscosity and lubrieating properties suitable for the engine underoperating conditions and not more than 10% of a readily volatile ,and substantially uninflljammable diluent boiling mainly below 250 11. A lubricant for internal combustion engines comprising a lubricating oil of characteristics suitable for the effective lubrication of the engine under operating conditions and a relatively small amount of a substantially non-inflammable diluent boiling mainly below 250 F.
In witness whereof, I have hereunto set my hand this 13th day of October, 1927.
' DANIEL P. BARNARD.
US227364A 1927-10-19 1927-10-19 Lubricant Expired - Lifetime US1796857A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2616815A (en) * 1950-04-12 1952-11-04 Robert R Parmentier Transparentizing compositions and process
US2755224A (en) * 1952-12-18 1956-07-17 Exxon Research Engineering Co Process for improving lubricating oils
US2853450A (en) * 1955-08-15 1958-09-23 Francis Earle Lab Inc Extinguishing agents for magnesium fires

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2616815A (en) * 1950-04-12 1952-11-04 Robert R Parmentier Transparentizing compositions and process
US2755224A (en) * 1952-12-18 1956-07-17 Exxon Research Engineering Co Process for improving lubricating oils
US2853450A (en) * 1955-08-15 1958-09-23 Francis Earle Lab Inc Extinguishing agents for magnesium fires

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