US1547141A - Lubricant - Google Patents

Lubricant Download PDF

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Publication number
US1547141A
US1547141A US2686A US268625A US1547141A US 1547141 A US1547141 A US 1547141A US 2686 A US2686 A US 2686A US 268625 A US268625 A US 268625A US 1547141 A US1547141 A US 1547141A
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United States
Prior art keywords
oil
lubricant
viscosity
cold
fresh
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US2686A
Inventor
Robert E Wilson
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Standard Oil Co
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Standard Oil Co
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Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Priority to US2686A priority Critical patent/US1547141A/en
Application granted granted Critical
Publication of US1547141A publication Critical patent/US1547141A/en
Priority to US89764A priority patent/US1639347A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/042Mixtures of base-materials and additives the additives being compounds of unknown or incompletely defined constitution only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/02Petroleum fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/02Natural products
    • C10M159/04Petroleum fractions, e.g. tars, solvents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • C10M2203/1025Aliphatic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
    • C10M2203/1045Aromatic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106Naphthenic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106Naphthenic fractions
    • C10M2203/1065Naphthenic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks
    • C10M2203/1085Residual fractions, e.g. bright stocks used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • C10N2040/251Alcohol-fuelled engines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • C10N2040/255Gasoline engines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • C10N2040/255Gasoline engines
    • C10N2040/28Rotary engines

Definitions

  • This invention consists in a new lubricantfor automotive engines, a lubricant particularly adapted for use in cold weather in engines of the usual type wherein more or less .fuel enters the lubricant in the crank case.
  • the preferred oil of those within my invention is,,when cold and fresh, slightly less viscous than the general run of the light oils when fresh and it is therefore very easy weather. Nevertheless the new lubricant practically loses no viscosity by dilution, in an. average car in good condition and with proper carbureter adjustment in ordinary winter operation.
  • the advantage of easy starting with fresh lubricant can be obtained even though the oil be of a type giving a viscosity, after long use, generally similar to that of the medium oil now generally used.
  • the new lubricant is characterized by apractically horizontal curve of viscosity plotted against mileage, and hence has, for any given initial viscosity, a very high final viscosity. It is further distinguishable by being a clean marketable oil, free from suspended solids and colloidal carbon or asphalt and from noticeable disagreeable odor, and having a fiash'point above 150 F.
  • the preferred oil has a Saybolt viscosity at 100 F. of about 180, and on distillation gives an intial boiling point (thermometer in vapor) of about 350 F. and about 11% off at 460 F.
  • the fractionation of the oil may, of course, vary considerably, but in general it should contain from about 6% .to about 15% of fractions boiling between 300 F. and 460 F., and should have a Saybolt viscosity at 100 F. above 140.
  • the remaining 85 to 94% may suitably be a viscous lubricant oil, having a viscosity of 425 to 475 sec. Saybolt at 100 F.
  • a viscous lubricant oil having a viscosity of 425 to 475 sec.
  • Saybolt at 100 F.
  • colloidal carbon and marked disagreeable odor and characterized further in having an initial boiling point of 350 vF., a Sayboltviscosity of 180 at 100 F., a slight loss in viscosity during use, and about 11% of fractions boiling below 460.F.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)

Description

No Drawing.
to start in cold Patented July 21, 1925.
UNITED STATES 1 1,547,141 PATENT OFFICE.
ROBERT E. WILSON, OF CHICAGO, ILLINOIS, ASSIG-NOB TO STANDARD OIL COMPANY,
OF WHITING, INDIANA, A CORPORATION OF INDIANA.
LUBRICANT.
To all whom it may concern:
Be it known that I, ROBERT E. WILSON, a citizen of the United States, residing at Chicago, in the county of Cook and State of Illinois, have invented a new and useful Improvement in Lubricants, of which the following is a specification.
This invention consists in a new lubricantfor automotive engines, a lubricant particularly adapted for use in cold weather in engines of the usual type wherein more or less .fuel enters the lubricant in the crank case.
Heretofore there have been in use three broad types of lubricating oil which may be the heavier fractions of the fuel,which, par
ticularly when the motor is cold, leak past the piston rings and enter the oil body in the crank case.
There are serious objections to oils of each of the three types now in common use. Heavy oil is so viscous when freshly renewed in the motor as to make starting a cold motor altogether too difficult, and for this reason heavy oil is seldom used in winter. Medium oil is open to the same objection but to a lesser extent, and while it is very largely used as a winter lubricant, it is so viscous when cold and fresh as to throw a very heavy and undesirable load on the starting motor and battery and when highly diluted is too fluid to lubricate properly. Light oil, on the other hand, while far superior to the other grades from the standpoint of ease of starting when cold and fresh, loses viscosity by dilution so fast as to be a very poor lubricant frequently in less than a hundred miles of driving.
The preferred oil of those within my invention is,,when cold and fresh, slightly less viscous than the general run of the light oils when fresh and it is therefore very easy weather. Nevertheless the new lubricant practically loses no viscosity by dilution, in an. average car in good condition and with proper carbureter adjustment in ordinary winter operation. Thus,
Application filed January 15, 1925. Serial No. 2,686.
dium after five hundred miles of winter use.
While the properties of the preferred oil within myinvention have been set forth, it will be evident that it is not necessary to utilize the full benefit of the invention, for
the advantage of easy starting with fresh lubricant can be obtained even though the oil be of a type giving a viscosity, after long use, generally similar to that of the medium oil now generally used. In general the new lubricant. is characterized by apractically horizontal curve of viscosity plotted against mileage, and hence has, for any given initial viscosity, a very high final viscosity. It is further distinguishable by being a clean marketable oil, free from suspended solids and colloidal carbon or asphalt and from noticeable disagreeable odor, and having a fiash'point above 150 F.
The preferred oil has a Saybolt viscosity at 100 F. of about 180, and on distillation gives an intial boiling point (thermometer in vapor) of about 350 F. and about 11% off at 460 F. The fractionation of the oil may, of course, vary considerably, but in general it should contain from about 6% .to about 15% of fractions boiling between 300 F. and 460 F., and should have a Saybolt viscosity at 100 F. above 140.
As illustrative of one example in the practice of my invention in the case of ,paraflin type oil (including mid-continent oil), the remaining 85 to 94% may suitably be a viscous lubricant oil, having a viscosity of 425 to 475 sec. Saybolt at 100 F. Thus, with 89 parts by volume of' a lubricant oil of 450 sec. Saybolt, at 100 F. there is combined 11% of light distillate having a boiling point range of 350 to 460 F., there by providing a product having the advantages and characteristics above set forth.
.I claim:
1. The herein described marketable lubricating oil for cold weather use in automoloidal carbon and marked disagreeable odor,
- and characterized further by having a flash point above 150 F., a Saybolt viscosity of at least 140 at 100 F., a relatively low loss in viscosity during'use, and a content of between 7% and 15% of fractions boiling be- 10 tween about 300 F. and 460 F.
2. The herein described marketable lubrie cylinders, clear in I appearance, free from suspended solids, colappearance, free from suspended solids,
colloidal carbon and marked disagreeable odor, and characterized further in having an initial boiling point of 350 vF., a Sayboltviscosity of 180 at 100 F., a slight loss in viscosity during use, and about 11% of fractions boiling below 460.F.
' ROBERT WILSON.
US2686A 1925-01-15 1925-01-15 Lubricant Expired - Lifetime US1547141A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US2686A US1547141A (en) 1925-01-15 1925-01-15 Lubricant
US89764A US1639347A (en) 1925-01-15 1926-02-20 Lubricant for automotive engines

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2686A US1547141A (en) 1925-01-15 1925-01-15 Lubricant

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US1547141A true US1547141A (en) 1925-07-21

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2539531A (en) * 1947-06-09 1951-01-30 Clensos Steven Detergent for removing skin adherents and the like
US4853337A (en) * 1987-05-11 1989-08-01 Exxon Chemicals Patents Inc. Blending of hydrocarbon liquids

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2539531A (en) * 1947-06-09 1951-01-30 Clensos Steven Detergent for removing skin adherents and the like
US4853337A (en) * 1987-05-11 1989-08-01 Exxon Chemicals Patents Inc. Blending of hydrocarbon liquids

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