US20160113278A1 - Aminoindanes amides having a high fungicidal activity and their phytosanitary compositions - Google Patents
Aminoindanes amides having a high fungicidal activity and their phytosanitary compositions Download PDFInfo
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
- C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D277/56—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
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- Life Sciences & Earth Sciences (AREA)
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- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
Description
- The present invention relates to new amides of 4-aminoindanes having a high fungicidal activity, the relative phytosanitary compositions and their use for the control of phytopathogenic fungi.
- More specifically, it relates to new amides of 4-aminoindanes, further substituted by specific groups on the phenyl group of indane, having a high activity in the control of pathogenic fungi of important agricultural crops.
- Amides obtained from benzoic or hetero-cyclylcarboxylic acids condensed with 4-aminoindanes are described in patent applications JP1070479, JP 1117864, JP1313402, JP2157266, JP2249966, JP3077381, JP62096471, EP199822, EP256503, EP276177, EP280275, EP569912, U.S. Pat. No. 5,093,347, WO2001/53259, WO2004/018438, WO2004/039789, WO2004/072023, WO2004/103975, WO2005/075452.
- In particular, EP199822 describes 1,3,5-trimethyl-N-(1,1-dimethyl-5-fluoro-4-indanyl)-4-pyrazolecarboxamide [compound (4)] and 1,5-dimethyl-3-trifluoro-methyl-N-(1,1-dimethyl-7-fluoro-4-indanyl)-4-pyrazole-carboxamide (page 15, lines 19-20); U.S. Pat. No. 5,093,347 describes 3-difluoromethyl-1-methyl-N-(1,1,3-trimethyl-4-indanyl)-4-pyrazolecarboxamide.
- The amides of 4-aminoindanes described in the prior art, however, are not completely satisfactory from the point of view of the level of fungicidal activity against phytopathogenic fungi, the action range, and phytotoxicity with respect to the agricultural crops to be protected.
- The Applicant has now surprisingly found that new amides, obtained by the condensation of heterocyclic acids substituted by a CF2H group, with 4-aminoindanes containing alkyl groups in positions 1 and 3 of indane and one or more further substituents on the phenyl ring, show, with respect to the compounds described above, a much higher fungicidal activity, a wider action range, a reduced or zero phytotoxicity with respect to the most important agricultural crops. The object of the present invention therefore relates to aminoindanes amides having the structural formula (I):
- wherein:
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- R1, R2 and R4, equal to or different from each other, represent a C1-C2 alkyl group, a C1-C2 haloalkyl group, a C3-C6 cycloalkyl group, a C3-C6 halocycloalkyl group, the groups R1 and R2 can also possibly be joined to form a C3-C6 cycloalkyl group spiro-condensed with indanyl;
- R3 represents a hydrogen atom, a C1-C3 alkyl group, a C1-C3 haloalkyl group, a C3-C6 cycloalkyl group, a C3-C6 halocycloalkyl group;
- R5 represents a halogen atom, a C1-C4 alkyl group, a C1-C4 haloalkyl group, a C1-C4 alkoxy group, a C1-C4 haloalkoxy group, an SH group, a C1-C4 alkylthio group, a C1-C4 haloalkylthio group;
- n represents an integer ranging from 1 to 3;
- A represents one of the following heterocycles A1-A5:
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- R6 is a C1-C3 alkyl group, a C1-C3 haloalkyl group, a C3-C6 cycloalkyl group, a C3-C6 halocycloalkyl group, a C1-C4 alkoxy group, a C1-C4 haloalkoxy group, an SH group, a C1-C4 alkylthio group, a C1-C4 haloalkylthio group.
- Examples of compounds having formula (I) which are particularly interesting for their activity are:
- (1) 3-difluoromethyl-N-(7-fluoro-1,1,3-trimethyl-4-indanyl)-1-methyl-4-pyrazolecarboxamide;
- (2) 4-difluoromethyl-N-(7-fluoro-1,1,3-trimethyl-4-indanyl)-2-methyl-5-thiazolecarboxamide;
- (3) 3-difluoromethyl-1-methyl-N-(1,1,3,7-tetramethyl-4-indanyl)-pyrazolecarboxamide;
- (4) 4-difluoromethyl-2-methyl-N-(1,1,3,7-tetramethyl-4-indanyl)-5-thiazolecarboxamide;
- (5) 3-difluoromethyl-1-methyl-N-(7-methoxy-1,1,3-trimethyl-4-indanyl)-4-pyrazolecarboxamide;
- (6) 4-difluoromethyl-2-methyl-N-(7-methoxy-1,1,3-trimethyl-4-indanyl)-5-thiazolecarboxamide;
- (7) 3-difluoromethyl-1-methyl-N-(7-methylthio-1,1,3-trimethyl-4-indanyl)-4-pyrazolecarboxamide;
- (8) 4-difluoromethyl-2-methyl-N-(7-methylthio-1,1,3-trimethyl-4-indanyl)-5-thiazolecarboxamide;
- (9) 3-difluoromethyl-1-methyl-N-(7-trifluoromethoxy-1,1,3-trimethyl-4-indanyl)-4-pyrazolecarboxamide;
- (10) 4-difluoromethyl-2-methyl-N-(7-trifluoromethoxy-1,1,3-trimethyl-4-indanyl)-5-thiazolecarboxamide;
- (11) 3-difluoromethyl-N-(7-fluoro-1,1,3-trimethyl-4-indanyl)-4-furazancarboxamide
- (12) 4-difluoromethyl-N-(7-fluoro-1,1,3-trimethyl-4-indanyl)-2-methylthio-4-pyrimidinecarboxamide.
- (13) 3-difluoromethyl-N-(7-chloro-1,1,3-trimethyl-4-indanyl)-1-methyl-4-pyrazolecarboxamide;
- (14) 3-difluoromethyl-N-(7-chloro-1,1-diethyl-3-methyl-4-indanyl)-1-methyl-4-pyrazolecarboxamide;
- (15) 4-difluoromethyl-N-(7-fluoro-1,1,3-trimethyl-4-indanyl)-5-thiadiazolecarboxamide.
- Preferred compounds having general formula (I) are those wherein A represents A1, R1, R2, R4 and R6 are a methyl group, R3 is a hydrogen atom, R5 represents a halogen.
- Examples of halogen are: fluorine, chlorine, bromine, iodine.
- Examples of C1-C4 alkyl, linear or branched, are methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl.
- Examples of C1-C4 haloalkyl are fluoromethyl, difluoromethyl, trifluoromethyl, chloromethyl, dichloromethyl, 2,2,2-trifluoroethyl, 1,1,2,2-tetrafluoroethyl, pentafluoroethyl, heptafluoropropyl, 4,4,4-trichlorobutyl.
- Examples of C1-C4 alkoxy, linear or branched, are methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, isobutoxy, sec-butoxy, tert-butoxy.
- Examples of C1-C4 haloalkoxy are fluoromethoxy, difluoromethoxy, trifluoromethoxy, chloromethoxy, dichloromethoxy, 2,2,2-trifluoroethoxy, 1,1,2,2-tetra-fluoroethoxy, 1,1,2,3,3,3-hexafluoropropoxy, 4,4,4-trichlorobutoxy.
- Examples of C3-C6 cycloalkyl are cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl.
- Examples of C3-C6 halocycloalkyl are 2,2-dichloro-cyclopropyl, 2,2-difluorocyclopropyl, 2,2,3,3-tetrafluorocyclobutyl, 3,3-difluorocyclopentyl, 2-fluorocyclohexyl.
- Examples of C1-C4 alkylthio, linear or branched, are methylthio, ethylthio, n-propylthio, isopropylthio, n-butylthio, isobutylthio, sec-butylthio, tert-butylthio.
- Examples of C1-C4 haloalkylthio are fluoromethylthio, difluoromethylthio, trifluoromethylthio, chloromethylthio, dichloromethylthio, 2,2,2-trifluoroethyl-thio, 1,1,2,2-tetra-fluoroethylthio, 1,1,2,3,3,3-hexafluoropropyl-thio, 4,4,4-trichloro-butylthio.
- Due to the asymmetry of the carbon atom in position 3 of the indanyl ring and possibly the atoms in position 1 (when R1 is different from R2) and 2 (when R3 is different from hydrogen), the compounds having formula (I) may occur as mixtures of optical isomers and possibly diastereoisomers.
- The compounds having formula (I) are therefore included in the spirit of the present invention both as racemic and possibly diastereoisomeric mixtures, both as partially separated mixtures, either as single optical isomers and possibly as single diastereoisomers.
- The compounds having formula (I) are prepared by reacting a substituted acid or one of its derivatives having formula (II), with an aniline having formula (III), according to the reaction scheme indicated below:
- In these formulae:
- A, R1, R2, R3, R4, R5 and n have the meanings defined above;
- X represents a hydroxy OH; a halogen atom; a C1-C4 alkoxy group; a phenoxy group; an acyloxy group RCOO wherein R in turn represents a group A, a C1-C4 alkyl group or a phenyl optionally substituted by C1-C4 alkyl groups, C1-C4 haloalky groups, halogen atoms.
- The reaction conditions for effecting the process indicated above, in which an acid or one of its corresponding halides, esters or anhydrides (possibly mixed) is reacted with an amine, are widely described in chemical literature, for example in “Advanced Organic Chemistry”, Jerry March, 4th Edition, 1992, John Wiley & Sons Pub., pages 417-424 and references cited therein.
- Various alternative conditions can be selected, also depending on the nature of the compound having formula (II); for example, when X represents a halogen atom, preferably chlorine, the reaction is normally carried out in the presence of an inert solvent and in the presence of an organic or inorganic base, at a temperature ranging from −20° C. to the boiling point of the reaction mixture.
- Examples of solvents which can be used for the above reaction include water, aliphatic or cycloaliphatic hydrocarbons (petroleum ether, hexane, cyclohexane etc.), chlorinated hydrocarbons (methylene chloride, chloroform, carbon tetrachloride, dichloroethane, etc.), aromatic hydrocarbons (benzene, toluene, xylene, chlorobenzene, etc.), ethers (diethyl ether, diisopropyl ether, dimethoxyethane, dioxane, tetrahydrofuran, etc.), esters (ethyl acetate etc.), ketones (acetone, methylethylketone, methylpropyl-ketone, methylisobutylketone, etc.), nitriles (acetonitrile, benzonitrile, etc.), aprotic dipolar solvents (dimethylformamide, dimethylacetamide, hexamethylphosphorotriamide, dimethylsulfoxide, sulfolane, N-methylpyrrolidone, etc.)
- Inorganic bases which can be used for the purpose are, for example, hydroxides, carbonates and bicarbonates of sodium or potassium.
- Organic bases which can be used for the purpose are, for example, triethylamine, pyridine, 4-N,N-dimethyl-aminopyridine, N,N-dimethylaniline, N-methyl-piperidine, lutidine, diazabicyclo-octane (DABCO), diazabicyclononene (DBN), diazabicycloundecene (DBU).
- The intermediates having general formulae (II) and (III), when they are not already described in literature, can in any case be prepared by adapting synthetic methods well known to experts in the field.
- For example, pyrazolecarboxylic acids [formula (II) wherein A=A1, X═OH] can be prepared according to what is described in U.S. Pat. No. 5,093,347; thiazolecarboxylic acids [formula (II) wherein A=A2, X═OH] can be prepared according to what is described in DE 10250110; pyrimidinecarboxylic acids [formula (II) wherein A=A4, X═OH] can be prepared according to what is described in EP 569912.
- The corresponding acid derivatives (esters, anhydrides, halides) can be easily prepared from these according to what is described, for example, in “Advanced Organic Chemistry”, Jerry March, 4th Edition, 1992, John Wiley & Sons Pub., pages 392-402, 437-438 and references cited therein.
- As already mentioned, the compounds having general formula (I) have a very high fungicidal activity which is exerted with respect to numerous phytopathogenic fungi which attack important agricultural crops.
- A further object of the present invention therefore relates to the use of the compounds having general formula (I) for the control of phytopathogenic fungi of agricultural crops.
- Examples of phytopathogenic fungi which can be effectively fought with the compounds of general formula (I) according to the present invention, are those belonging to the groups of Basidiomycetes, Ascomycetes, Deuteromycetes or fungi imperfecti, Oomycetes: Puccinia spp., Ustilago spp., Tilletia spp., Uromyces spp., Phakopsora spp., Rhizoctonia spp., Erysiphe spp., Sphaerotheca spp., Podosphaera spp., Uncinula spp., Helminthosporium spp., Rhynchosporium spp., Pyrenophora spp., Monilinia spp., Sclerotinia spp., Septoria spp. (Mycosphaerella spp.), Venturia spp., Botrytis spp., Alternaria spp., Fusarium spp., Cercospora spp., Cercosporella herpotrichoides, Colletotrichum spp., Pyricularia oryzae, Sclerotium spp., Phytophtora spp., Pythium spp., Plasmopara viticola, Peronospora spp., Pseudoperonospora cubensis, Bremia lactucae.
- The main crops which can be protected with the compounds of the present invention comprise cereals (wheat, barley, rye, oats, rice, corn, sorghum, etc.), fruit trees (apple, pear, plumb, peach, almond, cherry, banana, vines, strawberry, raspberry, blackberry, etc.), citrus trees (orange, lemon, mandarin, grapefruit, etc.), legumes (beans, peas, lentils, soybean, etc.), vegetables (spinach, lettuce, asparagus, cabbage, carrots, onions, tomatoes, potatoes, aubergines, peppers, etc.), cucurbitaceae (pumpkins, zucchini, cucumbers, melons, water-melons, etc.), oilseeds (sunflower, rape, peanut, castor-oil plant, coconut, etc.) tobacco, coffee, tea, cocoa, sugar beet, sugar cane, cotton.
- In particular, the compounds having general formula (I) have proved to be considerably effective in the control of Plasmopara viticola on vines, Phytophtora infestans and Botrytis Cinerea on tomatoes, Puccinia recondita, Erysiphe graminis, Helminthosporium teres, Septoria nodorum and Fusarium spp. on cereals; in the control of Phakopsora pachyrhizi on soya; in the control of Uromyces appendiculatus on beans; in the control of Venturia inaequalis on apples, in the control of Sphaeroteca fuliginea on cucumbers.
- Furthermore, the compounds having general formula (I) are also effective in the control of phytopathogenic bacteria and viruses, such as for example Xanthomonas spp., Pseudomonas spp., Erwinia amylovora, the mosaic virus of tobacco.
- The compounds having formula (I) are capable of exerting a fungicidal action of both in curative and preventive applications and have a very low or zero phytotoxicity on the crops treated.
- For practical uses in agriculture, it is often preferable to use fungicidal compositions containing compounds having formula (I) according to the present invention, suitably formulated.
- A further object of the present invention relates to fungicidal compositions comprising one or more compounds having formula (I), a solvent and/or solid or liquid diluent, possibly a surfactant.
- The above fungicidal compositions can be in the form of dry powders, wettable powders, emulsifiable concentrates, emulsions, micro-emulsions, pastes, granulates, water dispersible granules, solutions, suspensions, etc.: the choice of the type of composition will depend on the specific use.
- The fungicidal compositions are prepared in the known way, for example by diluting or dissolving the active substance with a solvent medium and/or a solid or liquid diluent, possibly in the presence of surfactants.
- Solid diluents or supports which can be used for example are: silica, kaolin, bentonite, talc, diatomaceous earth, dolomite, calcium carbonate, magnesia, gypsum, clays, synthetic silicates, attapulgite, sepiolite.
- Solvents or liquid diluents which can be used, are for example, in addition to water, aromatic organic solvents (xylols or blends of alkylbenzols, chlorobenzene, etc.), paraffins (petroleum fractions), alcohols (methanol, propanol, butanol, octanol, glycerine, etc.), esters (ethyl acetate, isobutyl acetate, alkyl carbonates, alkyl esters of adipic acid, alkyl esters of glutaric acid, alkyl esters of succinic acid, alkyl esters of lactic acid, etc.), vegetable oils (rape oil, sunflower oil, soybean oil, castor oil, corn oil, peanut oil, and their alkyl esters), ketones (cyclohexanone, acetone, acetophenone, isophorone, ethylamylketone, etc.), amides (N,N-dimethylformamide, N-methylpyrrolidone, etc.), sulfoxides and sulfones (dimethylsulfoxide, dimethylsulfone, etc.), and mixtures thereof.
- Sodium salts, calcium salts, potassium salts, salts of triethylamine or triethanolamine of alkyl-naphthalenesulfonates, polynaphthalenesulfonates, alkyl sulfonates, aryl sulfonates, alkylaryl sulfonates, polycarboxylates, sulfosuccinates, alkyl sulfo-succinates, lignin sulfonates, alkyl sulfates, can be used as surfactants; as also polyethoxylated fatty alcohols, polyethoxylated alkylphenols, polyethoxylated esters of sorbitol, polypropoxy polyethoxylates (block polymers).
- The fungicidal compositions can also contain special additives for particular purposes, such as for example, antifreeze agents such as propylene glycol, or adhesion agents, such as gum Arabic, polyvinyl alcohol, polyvinyl pyrrolidone, etc.
- If desired, other compatible active principles can be added to the fungicidal compositions containing the compounds of general formula (I), such as, for example, fungicides different from those having general formula (I), phytoregulators, antibiotics, herbicides, insecticides, fertilizers and/or mixtures thereof.
- Examples of fungicides different from those having general formula (I), which can be included in the fungicidal compositions object of the present invention are: acibenzolar, ametoctradin, amisulbrom, ampropylfos, anilazine, azaconazole, azoxystrobin, benalaxyl, benalaxyl-M, benomyl, benthiavalicarb, bitertanol, bixafen, blasticidin-S, boscalid, bromuconazole, bupirimate, buthiobate, captafol, captan, carbendazim, carboxin, carpropamid, chinomethionat, chloroneb, chlorothalonil, chlozolinate, cyazofamid, cyflufenamid, cymoxanil, cyproconazole, cyprodinil, debacarb, dichlofluanid, dichlone, diclobutrazol, diclomezine, dicloran, diclocymet, diethofencarb, difenoconazole, diflumetorim, dimethirimol, dimethomorph, dimoxystrobin, diniconazole, dinocap, dipyrithione, ditalimfos, dithianon, dodemorph, dodine, edifenphos, epoxiconazole, etaconazole, ethaboxam, ethirimol, ethoxyquin, etridiazole, famoxadone, fenamidone, fenaminosulf, fenapanil, fenarimol, fenbuconazole, fenfuram, fenhexamid, fenoxanil, fenpiclonil, fenpropidin, fenpropimorph, fentin, ferbam, ferimzone, fluazinam, fludioxonil, flumetover, flumorph, fluopicolide, fluopyram, fluoroimide, fluotrimazole, fluoxastrobin, fluquinconazole, flusilazole, flusulfamide, flutianil, flutolanil, flutriafol, folpet, fosetyl-aluminium, fuberidazole, furalaxyl, furametpyr, furconazole, furconazole-cis, guazatine, hexaconazole, hymexazol, idrossichinolina solfato, imazalil, imibenconazole, iminoctadine, ipconazole, iprobenfos, iprodione, isoprothiolane, iprovalicarb, isopyrazam, isotianil, kasugamycin, kresoxim-methyl, mancopper, mancozeb, mandipropamid, maneb, mebenil, mepanipyrim, mepronil, meptyldinocap, metalaxyl, metalaxyl-M, metconazole, methfuroxam, metiram, metominostrobin, metrafenone, metsulfovax, myclobutanil, natamycin, nicobifen, nitrothal-isopropyl, nuarimol, ofurace, orysastrobin, oxadixyl, oxpoconazole, oxycarboxin, pefurazoate, penconazole, pencycuron, penflufen, pentachlorofenol and its salts, penthiopyrad, phthalide, picoxystrobin, piperalin, Bordeaux mixture, polyoxins, probenazole, prochloraz, procymidone, propamocarb, propiconazole, propineb, proquinazid, prothiocarb, prothioconazole, pyracarbolid, pyraclostrobin, pyrametostrobin, pyraoxystrobin, pyrazophos, pyribencarb, pyrifenox, pyrimethanil, pyroquilon, pyroxyfur, quinacetol, quinazamid, quinconazole, quinoxyfen, quintozene, rabenzazole, copper hydroxide, copper oxychloride, copper (I) oxide, copper sulfate, sedaxane, silthiofam, simeconazole, spiroxamine, streptomycin, tebuconazole, tetraconazole, thiabendazole, thiadifluor, thicyofen, thifluzamide, thiophanate, thiophanate-methyl, thiram, tiadinil, tioxymid, tolclofos-methyl, tolylfluanid, triadimefon, triadimenol, triarimol, triazbutil, triazoxide, tricyclazole, tridemorf, trifloxystrobin, triflumizole, triforine, triticonazole, uniconazole, uniconazole-P, validamycin, valifenalate, vinclozolin, zineb, ziram, sulfur, zoxamide.
- The concentration of compounds having general formula (I) in the above compositions can vary within a wide range; it generally ranges from 1% to 90%, preferably from 5% to 50%.
- The application of these compositions can be effected on each part of the plant, for example on the leaves, stems, branches and roots, or on the seeds themselves before sowing, or on the ground in which the plant grows.
- A further object of the present invention therefore relates to a method for the control of phytopathogenic fungi in agricultural crops, which consists in the application of effective dosages of the compounds having formula (I), used as such or formulated in fungicidal compositions as described above.
- The quantity of compound to be applied for obtaining the desired effect can vary in relation to different factors, such as, for example, the compound used, the crop to be preserved, the type of pathogen, the degree of infection, the climatic conditions, the application method, the formulation adopted.
- Doses of compound ranging from 10 g to 5 kg per hectare of agricultural crop generally provide a sufficient control.
- The following examples are provided for a better understanding of the invention for illustrative and non-limiting purposes of the same.
- 0.4 ml of triethylamine were dropped into a solution of 7-fluoro-1,1,3-trimethyl-4-aminoindane (0.45 g) and 3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carbonyl chloride (0.44 g) in 8 ml of dichloromethane.
- After being kept under stirring for 8 hours at room temperature, diluted hydrochloric acid was added to the reaction mixture, the phases were separated and the aqueous phase was extracted with dichloromethane.
- The organic phases were then joined, anhydrified with sodium sulfate and concentrated at reduced pressure.
- The raw product obtained was subsequently purified on a silica gel column (eluent hexane/ethyl acetate 8/2) to give 0.45 g of the desired product, a white solid with a melting point of 147° C.
- 1H NMR (200 Mhz, CDCl3) δ a: 1.43 (3H,d), 1.38 (3H,s), 1.44 (3H,s), 1.66 (1H,dd), 2.21 (1H,dd), 3.38 (1H m), 3.98(3H,s),6.81 (1H, bs), 6.95 (1H,t), 6.70.(1H, m), 7.81 (1H,bs), 8.03 (1H,bs).
- Analogously to the procedure of Example 1, the compounds of general formula (I) reported in Table 1 have been prepared.
-
TABLE 1 Compound No A R1 R2 R3 R4 R5 2 3-difluoromethyl-1-methyl-4- Et Et H Me 7-F pyrazolyl 3 3-difluoromethyl-1-methyl-4- Me Me H Me 7-OMe pyrazolyl 4 4-difluoromethyl-2-methyl-5- Me Me H Me 7-F thiazolyl 5 3-difluoromethyl-1-methyl-4- Me Me H Me 7-Me pyrazolyl 6 3-difluoromethyl-1-methyl-4- Me Me H Me 7-Cl pyrazolyl 7 3-difluoromethyl-1-methyl-4- Me Me H Me 7-OCF3 pyrazolyl 8 3-difluoromethyl-1-methyl-4- Me Me H Me 7-SMe pyrazolyl Melting points: No 2: 115° C.; No 3: 110° C.; No 4: 95° C.; No 6: 140° C.; No 7: 105° C.; No 8: 97° C. - Leaves of wheat plants of the Salgemma variety, grown in pots in a conditioned environment kept at 20° C. and 70% of relative humidity (R.H.), were treated by spraying on both sides of the leaves with the compounds under examination, dispersed in hydroacetonic solutions at 20% by volume of acetone.
- After remaining 5 days in a conditioned environment, the plants were infected under dry conditions by shaking over them, in order to distribute the inoculum, plants previously infected by Erysiphe graminis.
- The plants were then maintained in the same cell, in a humidity-saturated environment and at a temperature ranging from 18 to 24° C. for 12 days.
- At the end of this period, the external symptoms of the pathogen appeared and it was therefore possible to proceed with the evaluation of the intensity of the infection, on both the parts treated directly with the products (T), and also on the parts which had developed during the test (NT), by means of a visible percentage evaluation scale of the area of affected leafs; the scale comprises, as extremes, the value 100 (healthy plant) and the value 0 (completely infected plant).
- At the same time, the phytotoxicity was evaluated (percentage of leaf necrosis) induced on the wheat plants by the application of the products: in this case, the evaluation scale varies from 0 (completely healthy plant) to 100 (completely necrotized plant).
- Table 2 shows the results obtained by carrying out the test described with compound N. 1, compared with the following reference products described in prior art:
- RC1: 3-difluoromethyl-1-methyl-N-(1,1,3-trimethyl-4-indanyl)-4-pyrazolecarboxamide of U.S. Pat. No. 5,093,347;
- RC2: 1,5-dimethyl-3-trifluoro-methyl-N-(1,1-dimethyl-7-fluoro-4-indanyl)-4-pyrazolecarboxamide [EP199822, page 15, lines 19-20];
- RC3: 1,3,5-trimethyl-N-(1,1-dimethyl-5-fluoro-4-indanyl)-4-pyrazolecarboxamide [EP199822,compound (4)].
-
TABLE 2 Preventive fungicidal activity (5 days) against Erysiphe graminis on wheat. Dose Activity Compound (ppm) T/NT Phytotoxicity N. 1 125 95/90 0 CR-1 125 70/65 10 CR-2 125 25/15 0 CR-3 125 10/0 0
Claims (16)
1-15. (canceled)
16. Aminoindane amides having structural formula (I):
wherein:
R1, R2 and R4, equal to or different from each other, represent a C1-C3 alkyl group, a C1-C3 haloalkyl group, a C3-C6 cycloalkyl group, a C3-C6 halocycloalkyl group, the groups R1 and R2 can possibly also be joined to form a C3-C6 cycloalkyl group spiro-condensed with indanyl;
R3 represents a hydrogen atom, a C1-C3 alkyl group, a C1-C3 haloalkyl group, a C3-C6 cycloalkyl group, a C3-C6 halocycloalkyl group;
R5 represents a halogen atom, a C1-C4 alkyl group, a C1-C4 haloalkyl group, a C1-C4 alkoxy group, a C1-C4 haloalkoxy group, an SH group, a C1-C4 alkylthio group, a C1-C4 haloalkylthio group;
n represents an integer ranging from 1 to 3;
A represents one of the following heterocycles A2-A5:
17. The compounds according to claim 16 , selected from the following compounds having general formula (I):
4-difluoromethyl-N-(7-fluoro-1,1,3-trimethyl-4-indanyl)-2-methyl-5-thiazolecarboxamide.
18. The compounds according to claim 16 , characterized in that they are in the form of racemic mixtures, diastereoisomeric mixtures, partially separated mixtures, single optical isomers and/or single diastereoisomers.
19. Fungicidal compositions comprising one or more compounds having formula (I) according to claim 16 , a solvent and/or solid or liquid diluent, possibly a surfactant.
20. Fungicidal compositions according to claim 19 , also comprising active principles compatible with the compounds having general formula (I), selected from fungicides different from the compounds having general formula (I), phytoregulators, antibiotics, herbicides, insecticides, fertilizers and/or mixtures thereof, antifreeze agents, adhesion agents.
21. The compositions according to claim 19 , wherein the concentration of compounds having general formula (I) ranges from 1 to 90% by weight with respect to the total weight of the composition, preferably from 5 to 50% by weight with respect to the total weight of the composition.
22. A method of controlling phytopathogenic fungi of agricultural crops comprising applying an effective amount to said agricultural crops of aminoindane amides having structural formula (I):
wherein:
R1, R2 and R4, equal to or different from each other, represent a C1-C3 alkyl group, a C1-C3 haloalkyl group, a C3-C6 cycloalkyl group, a C3-C6 halocycloalkyl group, the groups R1 and R2 can possibly also be joined to form a C3-C6 cycloalkyl group spiro-condensed with indanyl;
R3 represents a hydrogen atom, a C1-C3 alkyl group, a C1-C3 haloalkyl group, a C3-C6 cycloalkyl group, a C3-C6 halocycloalkyl group;
R5 represents a halogen atom, a C1-C4 alkyl group, a C1-C4 haloalkyl group, a C1-C4 alkoxy group, a C1-C4 haloalkoxy group, an SH group, a C1-C4 alkylthio group, a C1-C4 haloalkylthio group;
n represents an integer ranging from 1 to 3;
A represents one of the following heterocycles A2-A5:
23. A method of controlling phytopathogenic fungi of agricultural crops comprising applying an effective amount to said agricultural crops of the compounds according to claim 17 .
24. A method of controlling phytopathogenic fungi of agricultural crops comprising applying an effective amount to said agricultural crops of compositions according to claim 19 .
25. A method of controlling phytopathogenic fungi of agricultural crops comprising applying an effective amount to said agricultural crops of compositions according to 19 for the control of phytopathogen fungi belonging to the group of Basidiomycetes, Ascomycetes, Deuteromycetes or fungi imperfecti, Oomycetes: Puccinia spp., Ustilago spp., Tilletia spp., Uromyces spp., Phakopsora spp., Rhizoctonia spp., Erysiphe spp., Sphaerotheca spp., Podosphaera spp., Uncinula spp., Helminthosporium spp., Rhynchosporium spp., Pyrenophora spp., Monilinia spp., Sclerotinia spp., Septoria spp. (Mycosphaerella spp.), Venturia spp., Botrytis spp., Alternaria spp., Fusarium spp., Cercospora spp., Cercosporella herpotrichoides, Colletotrichum spp., Pyricularia oryzae, Sclerotium spp., Phytophtora spp., Pythium spp., Plasmopara viticola, Peronospora spp., Pseudoperonospora cubensis, Bremia lactucae.
26. A method of controlling phytopathogenic fungi of agricultural crops comprising applying an effective amount to said agricultural crops of a composition according to claim 19 , wherein the agricultural crops are cereals, fruit trees, citrus fruits, legumes, horticultural crops, cucurbits, oleaginous plants, tobacco, coffee, tea, cocoa, sugar beet, sugar cane, cotton.
27. A method of controlling phytopathogenic fungi of agricultural crops comprising applying an effective amount to said agricultural crops of a composition according to claim 19 for the control of Plasmopara viticola on vines, Phytophtora infestans and Botrytis Cinerea on tomatoes, Puccinia recondita, Erisiphae graminis, Helminthosporium teres, Septoria nodorum and Fusarium spp. on cereals; Phakopsora pachyrhizi on soya; Uromyces appendiculatus on beans; Venturia inaequalis on apples, Sphaeroteca fuliginea on cucumbers.
28. A method of controlling phytopathogenic fungi of agricultural crops comprising applying an effective amount to said agricultural crops of a compound according to formula (I) of claim 16 for the control of phytopathogenic bacteria or viruses.
29. A method for controlling phytopathogenic fungi in agricultural crops, which consists in applying effective doses of a compound according to formula (I) of claim 16 in amounts ranging from 10 g to 5 kg per hectare of agricultural crop.
30. A method of controlling phytopathogenic fungi of agricultural crops comprising applying an effective amount of a composition according to claim 19 to said agricultural crops for the control of phytopathogenic bacteria or viruses.
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Families Citing this family (254)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1403275B1 (en) * | 2010-12-20 | 2013-10-17 | Isagro Ricerca Srl | HIGH-ACTIVITY INDANYLANILIDES FUNGICIDE AND THEIR PHYTOSANITARY COMPOSITIONS |
BR112014027643B1 (en) | 2012-05-09 | 2019-04-24 | Bayer Cropscience Ag | PIRAZOLE-INDANIL-CARBOXAMIDES. |
WO2013167544A1 (en) | 2012-05-09 | 2013-11-14 | Bayer Cropscience Ag | 5-halogenopyrazole indanyl carboxamides |
WO2013167549A1 (en) | 2012-05-09 | 2013-11-14 | Bayer Cropscience Ag | Pyrazole indanyl carboxamides |
ITMI20121045A1 (en) * | 2012-06-15 | 2013-12-16 | Isagro Ricerca Srl | SYNERGIC COMPOSITIONS FOR THE PROTECTION OF AGRICULTURAL CROPS AND ITS USE |
CA2895268A1 (en) | 2012-12-19 | 2014-06-26 | Bayer Cropscience Aktiengesellschaft | Difluoromethyl-nicotinic-indanyl carboxamides |
WO2014130409A2 (en) | 2013-02-21 | 2014-08-28 | E. I. Du Pont De Nemours And Company | Fungicidal pyrazole mixtures |
UA120913C2 (en) | 2013-10-03 | 2020-03-10 | Сінгента Партісіпейшнс Аг | Fungicidal compositions |
ITMI20132201A1 (en) * | 2013-12-23 | 2015-06-24 | Isagro Spa | PROCESS FOR PIRAZOLI REGIOSELECTIVE SYNTHESIS |
WO2015121802A1 (en) | 2014-02-12 | 2015-08-20 | Isagro S.P.A. | Benzoylphenyl-formamidines having a fungicidal activity, their agronomic compositions and relative use |
WO2015155713A1 (en) | 2014-04-09 | 2015-10-15 | Isagro S.P.A. | Process for the regioselective synthesis of 1,3, 4 -substituted pyrazoles |
WO2015157005A1 (en) | 2014-04-10 | 2015-10-15 | E I Du Pont De Nemours And Company | Substituted tolyl fungicide mixtures |
AR101820A1 (en) | 2014-06-25 | 2017-01-18 | Bayer Cropscience Ag | DIFLUOROMETIL-INDANIL-CARBOXAMIDAS NICOTÍNICAS |
JP6833836B2 (en) | 2015-10-14 | 2021-02-24 | シンジェンタ パーティシペーションズ アーゲー | Sterilizing and mold-killing composition |
US20190135798A1 (en) | 2015-11-02 | 2019-05-09 | Basf Se | Substituted Oxadiazoles for Combating Phytopathogenic Fungi |
EP3370525A1 (en) | 2015-11-04 | 2018-09-12 | Basf Se | Substituted oxadiazoles for combating phytopathogenic fungi |
BR112018009579A2 (en) | 2015-11-13 | 2018-11-06 | Basf Se | compound of formula i, mixture, agrochemical composition, compound use and fungal control method |
BR112018009566A2 (en) | 2015-11-13 | 2018-11-06 | Basf Se | compounds, mixture, agrochemical composition, use of compounds and method to combat phytopathogenic harmful fungi |
EA201891146A1 (en) | 2015-11-19 | 2018-12-28 | Басф Се | SUBSTITUTED OXADIAZOLES FOR FIGHT AGAINST PHYTOPATHOGEN MUSHROOMS |
EA201891153A1 (en) | 2015-11-19 | 2018-11-30 | Басф Се | SUBSTITUTED OXADIAZOLES FOR FIGHT AGAINST PHYTOPATHOGEN MUSHROOMS |
WO2017135137A1 (en) * | 2016-02-01 | 2017-08-10 | 住友化学株式会社 | Pest control composition and pest control method |
TW201738200A (en) | 2016-02-03 | 2017-11-01 | 拜耳作物科學股份有限公司 | Method for preparing substituted 4-aminoindane derivatives |
WO2017153200A1 (en) | 2016-03-10 | 2017-09-14 | Basf Se | Fungicidal mixtures iii comprising strobilurin-type fungicides |
JP2017165716A (en) | 2016-03-11 | 2017-09-21 | 住友化学株式会社 | Plant disease control composition and plant disease control method |
JP6988106B2 (en) * | 2016-03-11 | 2022-01-05 | 住友化学株式会社 | Plant disease control composition and plant disease control method |
JP2017165715A (en) * | 2016-03-11 | 2017-09-21 | 住友化学株式会社 | Plant disease control composition and plant disease control method |
CA3017751A1 (en) * | 2016-03-17 | 2017-09-21 | Fmc Corporation | Process for converting s-enantiomer to its racemic form |
AU2017250397A1 (en) | 2016-04-11 | 2018-10-11 | Basf Se | Substituted oxadiazoles for combating phytopathogenic fungi |
WO2017178549A1 (en) | 2016-04-12 | 2017-10-19 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
JP6780011B2 (en) | 2016-04-15 | 2020-11-04 | スティヒティング アイ−エフ プロダクト コラボレイション | Method for preparing 4-aminoindane derivative and related aminoindane amide |
US11192867B2 (en) | 2016-06-03 | 2021-12-07 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
AR108745A1 (en) | 2016-06-21 | 2018-09-19 | Syngenta Participations Ag | MICROBIOCIDES OXADIAZOL DERIVATIVES |
CN106106462A (en) * | 2016-06-30 | 2016-11-16 | 京博农化科技股份有限公司 | A kind of bactericidal composition containing Enestroburin Yu pyrazoles indanyl Carbox amide |
CN106070231A (en) * | 2016-06-30 | 2016-11-09 | 京博农化科技股份有限公司 | A kind of containing 2-cyano-3-amino-3-phenylancryic acetate with the bactericidal composition of pyrazoles indanyl Methanamide |
US20200138028A1 (en) | 2016-07-22 | 2020-05-07 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
US20190284148A1 (en) | 2016-07-22 | 2019-09-19 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
CN109476614A (en) | 2016-07-22 | 2019-03-15 | 先正达参股股份有限公司 | Kill the oxadiazole derivatives of microorganism |
WO2018029242A1 (en) | 2016-08-11 | 2018-02-15 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
HUE054977T2 (en) | 2016-09-07 | 2021-10-28 | Sumitomo Chemical Co | Imide compound and use thereof |
EP3512337A1 (en) | 2016-09-13 | 2019-07-24 | Basf Se | Fungicidal mixtures i comprising quinoline fungicides |
WO2018055135A1 (en) | 2016-09-23 | 2018-03-29 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
WO2018055133A1 (en) | 2016-09-23 | 2018-03-29 | Syngenta Participations Ag | Microbiocidal tetrazolone derivatives |
WO2018054721A1 (en) | 2016-09-26 | 2018-03-29 | Basf Se | Pyridine compounds for controlling phytopathogenic harmful fungi |
WO2018054711A1 (en) | 2016-09-26 | 2018-03-29 | Basf Se | Pyridine compounds for controlling phytopathogenic harmful fungi |
WO2018054723A1 (en) | 2016-09-26 | 2018-03-29 | Basf Se | Pyridine compounds for controlling phytopathogenic harmful fungi |
WO2018065182A1 (en) | 2016-10-04 | 2018-04-12 | Basf Se | Reduced quinoline compounds as antifuni agents |
DK3522715T3 (en) | 2016-10-06 | 2021-04-12 | Syngenta Participations Ag | MICROBIOCIDE OXADIAZOLE DERIVATIVES |
WO2018073110A1 (en) | 2016-10-20 | 2018-04-26 | Basf Se | Quinoline compounds as fungicides |
CN107996581A (en) * | 2016-10-27 | 2018-05-08 | 燕化永乐(乐亭)生物科技有限公司 | A kind of composite bactericide |
EP3555056A1 (en) | 2016-12-19 | 2019-10-23 | Basf Se | Substituted oxadiazoles for combating phytopathogenic fungi |
CN108200910A (en) * | 2016-12-20 | 2018-06-26 | 燕化永乐(乐亭)生物科技有限公司 | A kind of composite bactericide |
EP3339297A1 (en) | 2016-12-20 | 2018-06-27 | Basf Se | Substituted oxadiazoles for combating phytopathogenic fungi |
EP3338552A1 (en) | 2016-12-21 | 2018-06-27 | Basf Se | Use of a tetrazolinone fungicide on transgenic plants |
CN110191881A (en) | 2017-01-23 | 2019-08-30 | 巴斯夫欧洲公司 | Antifungal pyridine compounds |
US11051513B2 (en) | 2017-01-26 | 2021-07-06 | Mitsui Chemicals Agro, Inc. | Pyridone compounds and agricultural and horticultural fungicides containing the same as active ingredients |
WO2018149754A1 (en) | 2017-02-16 | 2018-08-23 | Basf Se | Pyridine compounds |
EP3585773B1 (en) | 2017-02-21 | 2021-04-07 | Basf Se | Substituted oxadiazoles for combating phytopathogenic fungi |
CN108450470A (en) * | 2017-02-22 | 2018-08-28 | 燕化永乐(乐亭)生物科技有限公司 | A kind of bactericidal composition |
UY37623A (en) | 2017-03-03 | 2018-09-28 | Syngenta Participations Ag | DERIVATIVES OF OXADIAZOL THIOPHEN FUNGICIDES |
CN110392683A (en) | 2017-03-10 | 2019-10-29 | 先正达参股股份有限公司 | Kill the oxadiazole derivatives of microorganism |
CN110461159B (en) | 2017-03-31 | 2022-03-11 | 先正达参股股份有限公司 | Fungicidal compositions |
JP7161823B2 (en) | 2017-03-31 | 2022-10-27 | ビーエーエスエフ ソシエタス・ヨーロピア | Pyrimidinium compounds and mixtures thereof for combating animal pests |
BR112019020134B1 (en) | 2017-03-31 | 2023-05-09 | Syngenta Participations Ag | FUNGICIDAL COMPOSITIONS |
US20210101874A1 (en) | 2017-04-03 | 2021-04-08 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
BR112019020739B1 (en) | 2017-04-05 | 2023-12-19 | Syngenta Participations Ag | COMPOUNDS DERIVED FROM OXADIAZOLE MICROBIOCIDES AND THEIR USE, AGROCHEMICAL COMPOSITION, METHOD TO CONTROL OR PREVENT INFESTATION OF USEFUL PLANTS BY PHYTOPATHOGENIC MICROORGANISMS |
BR112019021019B1 (en) | 2017-04-05 | 2023-12-05 | Syngenta Participations Ag | Microbiocidal oxadiazole-derived compounds, agricultural composition, method for controlling or preventing infestation of useful plants by phytopathogenic microorganisms and use of an oxadiazole-derived compound |
WO2018184988A1 (en) | 2017-04-05 | 2018-10-11 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
WO2018184982A1 (en) | 2017-04-05 | 2018-10-11 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
BR112019020756B1 (en) | 2017-04-05 | 2023-11-28 | Syngenta Participations Ag | COMPOUNDS DERIVED FROM OXADIAZOLE MICROBICIDES, AGROCHEMICAL COMPOSITION COMPRISING THE SAME, METHOD FOR CONTROLLING OR PREVENTING INFESTATION OF USEFUL PLANTS BY PHYTOPATHOGENIC MICROORGANISMS AND USE OF THESE COMPOUNDS |
BR112019020734B1 (en) | 2017-04-05 | 2023-12-05 | Syngenta Participations Ag | Compounds derived from oxadiazole, agrochemical composition, method for controlling or preventing infestation of useful plants by phytopathogenic microorganisms and use of said compounds |
WO2018185211A1 (en) | 2017-04-06 | 2018-10-11 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
EP3606914A1 (en) | 2017-04-06 | 2020-02-12 | Basf Se | Pyridine compounds |
US20200045974A1 (en) | 2017-04-07 | 2020-02-13 | Basf Se | Substituted Oxadiazoles for Combating Phytopathogenic Fungi |
JP7168556B2 (en) | 2017-04-10 | 2022-11-09 | 三井化学アグロ株式会社 | Pyridone compound and agricultural and horticultural fungicide containing it as an active ingredient |
EP3611166B1 (en) | 2017-04-10 | 2022-09-21 | Mitsui Chemicals Agro, Inc. | Pyridone compound, and agricultural and horticultural fungicide having this as active component |
CN108684680A (en) * | 2017-04-10 | 2018-10-23 | 燕化永乐(乐亭)生物科技有限公司 | A kind of bactericidal composition |
WO2018188962A1 (en) | 2017-04-11 | 2018-10-18 | Basf Se | Substituted oxadiazoles for combating phytopathogenic fungi |
CN110234627B (en) | 2017-04-11 | 2023-09-01 | 三井化学植保株式会社 | Pyridone compound and agricultural/horticultural bactericide containing pyridone compound as active ingredient |
CA3059301A1 (en) | 2017-04-20 | 2018-10-25 | Pi Industries Ltd. | Novel phenylamine compounds |
EP3618629A1 (en) | 2017-05-02 | 2020-03-11 | Basf Se | Fungicidal mixture comprising substituted 3-phenyl-5-(trifluoromethyl)-1,2,4-oxadiazoles |
WO2018202491A1 (en) | 2017-05-04 | 2018-11-08 | Basf Se | Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi |
WO2018202487A1 (en) | 2017-05-04 | 2018-11-08 | Basf Se | Substituted 5-(haloalkyl)-5-hydroxy-isoxazoles for combating phytopathogenic fungi |
EP3618628A1 (en) | 2017-05-05 | 2020-03-11 | Basf Se | Fungicidal mixtures comprising triazole compounds |
CN108849911A (en) * | 2017-05-10 | 2018-11-23 | 燕化永乐(乐亭)生物科技有限公司 | A kind of bactericidal composition |
WO2018210659A1 (en) | 2017-05-15 | 2018-11-22 | Basf Se | Heteroaryl compounds as agrochemical fungicides |
WO2018210661A1 (en) | 2017-05-15 | 2018-11-22 | Basf Se | Heteroaryl compounds as agrochemical fungicides |
WO2018210660A1 (en) | 2017-05-15 | 2018-11-22 | Basf Se | Heteroaryl compounds as agrochemical fungicides |
WO2018210658A1 (en) | 2017-05-15 | 2018-11-22 | Basf Se | Heteroaryl compounds as agrochemical fungicides |
CN108925570A (en) * | 2017-05-27 | 2018-12-04 | 燕化永乐(乐亭)生物科技有限公司 | A kind of composite bactericide |
IL270873B2 (en) | 2017-05-30 | 2023-04-01 | Basf Se | “derivatives of pyridine and pyrazine compounds, composition comprising them and their use as fungicides” |
EP3630753A1 (en) | 2017-06-02 | 2020-04-08 | Syngenta Participations AG | Microbiocidal oxadiazole derivatives |
BR112019024993A2 (en) | 2017-06-02 | 2020-06-16 | Syngenta Participations Ag | FUNGICIDED COMPOSITIONS |
WO2018219797A1 (en) | 2017-06-02 | 2018-12-06 | Basf Se | Substituted oxadiazoles for combating phytopathogenic fungi |
US11117863B2 (en) | 2017-06-08 | 2021-09-14 | Mitsui Chemicals Agro, Inc. | Pyridone compounds and agricultural and horticultural fungicides containing the same as active ingredients |
BR112019026331A2 (en) | 2017-06-14 | 2020-07-21 | Syngenta Participations Ag | fungicidal compositions |
WO2018234139A1 (en) | 2017-06-19 | 2018-12-27 | Basf Se | 2-[[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]aryloxy](thio)acetamides for combating phytopathogenic fungi |
KR102611830B1 (en) | 2017-06-27 | 2023-12-11 | 바이엘 악티엔게젤샤프트 | Method for preparing substituted 4-aminoindan derivatives |
BR112019027900A2 (en) | 2017-06-28 | 2020-07-21 | Syngenta Participations Ag | fungicidal compositions |
WO2019002158A1 (en) | 2017-06-30 | 2019-01-03 | Basf Se | Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi |
EP3648604A1 (en) | 2017-07-05 | 2020-05-13 | BASF Agro B.V. | Fungicidal mixtures of mefentrifluconazole |
WO2019007717A1 (en) | 2017-07-06 | 2019-01-10 | Basf Se | Pesticidal mixtures |
WO2019007719A1 (en) | 2017-07-07 | 2019-01-10 | Basf Se | Pesticidal mixtures |
EP3427587A1 (en) | 2017-07-10 | 2019-01-16 | Basf Se | Pesticidal mixtures |
CN109221146B (en) * | 2017-07-10 | 2021-04-06 | 江苏龙灯化学有限公司 | Use of triflumizole amine for reducing or preventing corn infection by helminthosporium macrostoma |
BR112020000456A2 (en) | 2017-07-11 | 2020-07-21 | Syngenta Participations Ag | microbiocidal oxadiazole derivatives |
WO2019011923A1 (en) | 2017-07-11 | 2019-01-17 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
WO2019011926A1 (en) | 2017-07-11 | 2019-01-17 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
WO2019011928A1 (en) | 2017-07-11 | 2019-01-17 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
WO2019012001A1 (en) | 2017-07-12 | 2019-01-17 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
BR112020000371A2 (en) | 2017-07-12 | 2020-07-14 | Syngenta Participations Ag | microbiocidal oxadiazole derivatives |
WO2019012003A1 (en) | 2017-07-13 | 2019-01-17 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
WO2019025250A1 (en) | 2017-08-04 | 2019-02-07 | Basf Se | Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi |
WO2019038042A1 (en) | 2017-08-21 | 2019-02-28 | Basf Se | Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi |
EP3675638A1 (en) | 2017-08-29 | 2020-07-08 | Basf Se | Pesticidal mixtures |
WO2019042932A1 (en) | 2017-08-31 | 2019-03-07 | Basf Se | Method of controlling rice pests in rice |
EP3453706A1 (en) | 2017-09-08 | 2019-03-13 | Basf Se | Pesticidal imidazole compounds |
US11266146B2 (en) | 2017-09-13 | 2022-03-08 | Syngenta Participations Ag | Microbiocidal quinoline (thio)carboxamide derivatives |
EP3681868B1 (en) | 2017-09-13 | 2021-08-04 | Syngenta Participations AG | Microbiocidal quinoline (thio)carboxamide derivatives |
CN111164076A (en) | 2017-09-13 | 2020-05-15 | 先正达参股股份有限公司 | Microbicidal quinoline (thio) carboxamide derivatives |
US11241011B2 (en) | 2017-09-13 | 2022-02-08 | Syngenta Participations Ag | Microbiocidal quinoline (thio)carboxamide derivatives |
CN111148736A (en) | 2017-09-13 | 2020-05-12 | 先正达参股股份有限公司 | Microbicidal quinoline (thio) carboxamide derivatives |
EP3681867B1 (en) | 2017-09-13 | 2021-08-11 | Syngenta Participations AG | Microbiocidal quinoline (thio)carboxamide derivatives |
WO2019053016A1 (en) | 2017-09-13 | 2019-03-21 | Syngenta Participations Ag | Microbiocidal quinoline (thio)carboxamide derivatives |
WO2019052932A1 (en) | 2017-09-18 | 2019-03-21 | Basf Se | Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi |
WO2019057660A1 (en) | 2017-09-25 | 2019-03-28 | Basf Se | Indole and azaindole compounds with substituted 6-membered aryl and heteroaryl rings as agrochemical fungicides |
UY37912A (en) | 2017-10-05 | 2019-05-31 | Syngenta Participations Ag | PICOLINAMIDE DERIVATIVES FUNGICIDES THAT CONTAIN HETEROARILO OR HETEROARILOXI TERMINAL GROUPS |
UY37913A (en) | 2017-10-05 | 2019-05-31 | Syngenta Participations Ag | PICOLINAMIDE DERIVATIVES FUNGICIDES THAT CARRY A QUATERNARY TERMINAL GROUP |
CN111201227B (en) | 2017-10-13 | 2024-03-15 | 巴斯夫欧洲公司 | Imidazolium compounds for combating animal pests |
EP3710429B1 (en) | 2017-11-15 | 2023-04-05 | Syngenta Participations AG | Microbiocidal picolinamide derivatives |
CN111356679A (en) | 2017-11-20 | 2020-06-30 | 先正达参股股份有限公司 | Microbicidal oxadiazole derivatives |
WO2019101511A1 (en) | 2017-11-23 | 2019-05-31 | Basf Se | Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi |
MX2020005425A (en) | 2017-11-29 | 2020-08-27 | Syngenta Participations Ag | Microbiocidal thiazole derivatives. |
WO2019115511A1 (en) | 2017-12-14 | 2019-06-20 | Basf Se | Fungicidal mixture comprising substituted 3-phenyl-5-(trifluoromethyl)-1,2,4-oxadiazoles |
WO2019115343A1 (en) | 2017-12-15 | 2019-06-20 | Basf Se | Fungicidal mixture comprising substituted pyridines |
MX2020006259A (en) * | 2017-12-15 | 2020-12-03 | Stichting I F Product Collaboration | Compositions for the protection of agrarian crops and use thereof. |
BR112020011990A2 (en) | 2017-12-19 | 2020-11-17 | Syngenta Participations Ag | microbiocidal picolinamide derivatives |
WO2019121143A1 (en) | 2017-12-20 | 2019-06-27 | Basf Se | Substituted cyclopropyl derivatives |
WO2019123196A1 (en) | 2017-12-20 | 2019-06-27 | Pi Industries Ltd. | Fluoralkenyl compounds, process for preparation and use thereof |
CA3087313A1 (en) | 2018-01-09 | 2019-08-01 | Basf Se | Silylethynyl hetaryl compounds as nitrification inhibitors |
WO2019137995A1 (en) | 2018-01-11 | 2019-07-18 | Basf Se | Novel pyridazine compounds for controlling invertebrate pests |
WO2019150311A1 (en) | 2018-02-02 | 2019-08-08 | Pi Industries Ltd. | 1-3 dithiol compounds and their use for the protection of crops from phytopathogenic microorganisms |
WO2019154665A1 (en) | 2018-02-07 | 2019-08-15 | Basf Se | New pyridine carboxamides |
WO2019154663A1 (en) | 2018-02-07 | 2019-08-15 | Basf Se | New pyridine carboxamides |
EP3530118A1 (en) | 2018-02-26 | 2019-08-28 | Basf Se | Fungicidal mixtures |
EP3530116A1 (en) | 2018-02-27 | 2019-08-28 | Basf Se | Fungicidal mixtures comprising xemium |
KR20200128405A (en) | 2018-02-28 | 2020-11-12 | 바스프 에스이 | Use of N-functionalized alkoxy pyrazole compounds as nitrification inhibitors |
CA3089381A1 (en) | 2018-02-28 | 2019-09-06 | Basf Se | Use of pyrazole propargyl ethers as nitrification inhibitors |
JP7440418B2 (en) | 2018-02-28 | 2024-02-28 | ビーエーエスエフ ソシエタス・ヨーロピア | Use of alkoxypyrazoles as nitrification inhibitors |
BR112020015467A2 (en) | 2018-02-28 | 2020-12-08 | Basf Se | FUNGICIDAL MIXTURES, FUNGICIDAL COMPOSITION, METHODS TO CONTROL PHYTOPATOGENIC FUNGI, TO IMPROVE PLANT HEALTH AND TO PROTECT PLANT PROPAGATION MATERIAL AGAINST PHYTOPHOGENIC FUNGI AND PLANT PROPAGATION MATERIAL |
CN111801014B (en) | 2018-03-01 | 2022-05-27 | 巴斯夫农业公司 | Fungicidal compositions of cloroxen |
EP3533331A1 (en) | 2018-03-02 | 2019-09-04 | Basf Se | Fungicidal mixtures comprising pydiflumetofen |
EP3533333A1 (en) | 2018-03-02 | 2019-09-04 | Basf Se | Fungicidal mixtures comprising pydiflumetofen |
EP3536150A1 (en) | 2018-03-06 | 2019-09-11 | Basf Se | Fungicidal mixtures comprising fluxapyroxad |
WO2019175713A1 (en) | 2018-03-14 | 2019-09-19 | Basf Corporation | New catechol molecules and their use as inhibitors to p450 related metabolic pathways |
WO2019175712A1 (en) | 2018-03-14 | 2019-09-19 | Basf Corporation | New uses for catechol molecules as inhibitors to glutathione s-transferase metabolic pathways |
BR112020017808A2 (en) | 2018-03-26 | 2020-12-22 | Bayer Aktiengesellschaft | ENATIOSELECTIVE HYDROGENATION OF 1,2-DI-HYDROQUINOLINS REPLACED IN 4 IN THE PRESENCE OF A QUIRAL IRIDY CATALYST |
AR114466A1 (en) | 2018-04-04 | 2020-09-09 | Fmc Corp | FORMULATIONS OF SDHI FUNGICIDE EMULSIBLE CONCENTRATES |
WO2019207062A1 (en) | 2018-04-26 | 2019-10-31 | Syngenta Participations Ag | Microbiocidal oxadiazole derivatives |
CN112423590B (en) | 2018-05-15 | 2022-07-08 | 巴斯夫欧洲公司 | Mixtures and use comprising benzpyrimoxan and oxazosulfyl and methods for their application |
WO2019219464A1 (en) | 2018-05-15 | 2019-11-21 | Basf Se | Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi |
WO2019224092A1 (en) | 2018-05-22 | 2019-11-28 | Basf Se | Pesticidally active c15-derivatives of ginkgolides |
JP2021524854A (en) | 2018-05-23 | 2021-09-16 | バイエル・アクチエンゲゼルシヤフト | Substitution 4-Aminoindane Production Method |
WO2019224175A1 (en) | 2018-05-23 | 2019-11-28 | Bayer Aktiengesellschaft | Process for producing difluoromethyl-nicotinic-indanyl carboxamides |
WO2019224179A1 (en) | 2018-05-23 | 2019-11-28 | Bayer Aktiengesellschaft | Process for producing substituted 4-aminoindane derivatives from 2-(hydroxyalkyl)-anilines |
WO2019224174A1 (en) | 2018-05-23 | 2019-11-28 | Bayer Aktiengesellschaft | Process for producing 2-(fluoroalkyl)nicotinic acids |
WO2020002472A1 (en) | 2018-06-28 | 2020-01-02 | Basf Se | Use of alkynylthiophenes as nitrification inhibitors |
BR112020026877A2 (en) | 2018-06-29 | 2021-04-06 | Syngenta Crop Protection Ag | MICROBIOCIDAL OXADIAZOL DERIVATIVES |
EP3818058A1 (en) | 2018-07-02 | 2021-05-12 | Syngenta Crop Protection AG | 3-(2-thienyl)-5-(trifluoromethyl)-1,2,4-oxadiazole derivatives as agrochemical fungicides |
WO2020007646A1 (en) | 2018-07-02 | 2020-01-09 | Basf Se | Pesticidal mixtures |
WO2020016180A1 (en) | 2018-07-16 | 2020-01-23 | Syngenta Crop Protection Ag | Microbiocidal oxadiazole derivatives |
EP3826983A1 (en) | 2018-07-23 | 2021-06-02 | Basf Se | Use of substituted 2-thiazolines as nitrification inhibitors |
WO2020020765A1 (en) | 2018-07-23 | 2020-01-30 | Basf Se | Use of a substituted thiazolidine compound as nitrification inhibitor |
TWI828725B (en) | 2018-07-25 | 2024-01-11 | 日商三井化學植保股份有限公司 | Pyridone compounds and agricultural and horticultural fungicides containing the same as active ingredients |
AR115984A1 (en) | 2018-08-17 | 2021-03-17 | Pi Industries Ltd | 1,2-DITIOLONE COMPOUNDS AND THEIR USES |
EP3613736A1 (en) | 2018-08-22 | 2020-02-26 | Basf Se | Substituted glutarimide derivatives |
JP2022501353A (en) | 2018-09-19 | 2022-01-06 | シンジェンタ クロップ プロテクション アクチェンゲゼルシャフト | Microbial quinoline carboxamide derivative |
JP2022502390A (en) | 2018-09-26 | 2022-01-11 | シンジェンタ クロップ プロテクション アクチェンゲゼルシャフト | Sterilizing and mold-killing composition |
EP3628157A1 (en) | 2018-09-28 | 2020-04-01 | Basf Se | Method of controlling insecticide resistant insects and virus transmission to plants |
EP3628156A1 (en) | 2018-09-28 | 2020-04-01 | Basf Se | Method for controlling pests of sugarcane, citrus, rapeseed, and potato plants |
BR112021004526A2 (en) | 2018-09-28 | 2021-06-08 | Basf Se | use of compost, methods of plant protection, control or combating invertebrate pests, and seed and seed treatment |
EP3628158A1 (en) | 2018-09-28 | 2020-04-01 | Basf Se | Pesticidal mixture comprising a mesoionic compound and a biopesticide |
WO2020070132A1 (en) | 2018-10-06 | 2020-04-09 | Syngenta Participations Ag | Microbiocidal quinoline dihydro-(thiazine)oxazine derivatives |
WO2020070131A1 (en) | 2018-10-06 | 2020-04-09 | Syngenta Participations Ag | Microbiocidal quinoline dihydro-(thiazine)oxazine derivatives |
TW202035404A (en) | 2018-10-24 | 2020-10-01 | 瑞士商先正達農作物保護公司 | Pesticidally active heterocyclic derivatives with sulfoximine containing substituents |
EP3643705A1 (en) | 2018-10-24 | 2020-04-29 | Basf Se | Pesticidal compounds |
WO2020095161A1 (en) | 2018-11-05 | 2020-05-14 | Pi Industries Ltd. | Nitrone compounds and use thereof |
EP3670501A1 (en) | 2018-12-17 | 2020-06-24 | Basf Se | Substituted [1,2,4]triazole compounds as fungicides |
WO2020141135A1 (en) | 2018-12-31 | 2020-07-09 | Syngenta Crop Protection Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
WO2020141136A1 (en) | 2018-12-31 | 2020-07-09 | Syngenta Crop Protection Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
EP3696177A1 (en) | 2019-02-12 | 2020-08-19 | Basf Se | Heterocyclic compounds for the control of invertebrate pests |
EP3730489A1 (en) | 2019-04-25 | 2020-10-28 | Basf Se | Heteroaryl compounds as agrochemical fungicides |
EP3769623A1 (en) | 2019-07-22 | 2021-01-27 | Basf Se | Mesoionic imidazolium compounds and derivatives for combating animal pests |
WO2020239517A1 (en) | 2019-05-29 | 2020-12-03 | Basf Se | Mesoionic imidazolium compounds and derivatives for combating animal pests |
WO2020244969A1 (en) | 2019-06-06 | 2020-12-10 | Basf Se | Pyridine derivatives and their use as fungicides |
WO2020244970A1 (en) | 2019-06-06 | 2020-12-10 | Basf Se | New carbocyclic pyridine carboxamides |
KR20220017940A (en) | 2019-06-06 | 2022-02-14 | 바스프 에스이 | fungicidal N-(pyrid-3-yl)carboxamide |
IT201900011127A1 (en) | 2019-07-08 | 2021-01-08 | Isagro Spa | Compounds with fungicidal activity, relative agronomic compositions and use for the control of phytopathogenic fungi |
EP3766879A1 (en) | 2019-07-19 | 2021-01-20 | Basf Se | Pesticidal pyrazole derivatives |
BR112022005528A2 (en) | 2019-09-25 | 2022-06-21 | Bayer Ag | Novel iridium catalysts for the enantioselective hydrogenation of 4-substituted 1,2-dihydroquinolines |
US20220306583A1 (en) | 2019-09-25 | 2022-09-29 | Bayer Aktiengesellschaft | Improved enantioselective hydrogenation of 4-substituted 1,2-dihydroquinolines in presence of a chiral iridium catalyst and an additive |
IT201900017330A1 (en) | 2019-09-26 | 2021-03-26 | Isagro Spa | PROCESS FOR THE PREPARATION OF (R) -4-AMINOINDANE AND CORRESPONDING AMIDES. |
WO2021063735A1 (en) | 2019-10-02 | 2021-04-08 | Basf Se | New bicyclic pyridine derivatives |
WO2021063736A1 (en) | 2019-10-02 | 2021-04-08 | Basf Se | Bicyclic pyridine derivatives |
IT201900021960A1 (en) | 2019-11-22 | 2021-05-22 | Isagro Spa | Compounds with fungicidal activity, their agronomic compositions and related preparation method |
BR112022012469A2 (en) | 2019-12-23 | 2022-09-06 | Basf Se | METHOD AND COMPOSITION FOR THE PROTECTION OF PLANT OR VEGETABLE PROPAGATION MATERIAL, USE OF AT LEAST ONE ACTIVE COMPOUND AND AT LEAST ONE ENZYME, SEEDS AND KIT OF PARTS |
WO2021170463A1 (en) | 2020-02-28 | 2021-09-02 | BASF Agro B.V. | Methods and uses of a mixture comprising alpha-cypermethrin and dinotefuran for controlling invertebrate pests in turf |
BR112022017563A2 (en) | 2020-03-04 | 2022-10-18 | Basf Se | USE OF COMPOUNDS, AGROCHEMICAL COMPOSITION AND METHOD TO FIGHT HARMFUL PHYTOPATOGENIC FUNGI |
WO2021209360A1 (en) | 2020-04-14 | 2021-10-21 | Basf Se | Fungicidal mixtures comprising substituted 3-phenyl-5-(trifluoromethyl)-1,2,4-oxadiazoles |
EP3903584A1 (en) | 2020-04-28 | 2021-11-03 | Basf Se | Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors iv |
EP3903581A1 (en) | 2020-04-28 | 2021-11-03 | Basf Se | Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors i |
EP4143167A1 (en) | 2020-04-28 | 2023-03-08 | Basf Se | Pesticidal compounds |
EP3903582A1 (en) | 2020-04-28 | 2021-11-03 | Basf Se | Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors ii |
EP3903583A1 (en) | 2020-04-28 | 2021-11-03 | Basf Se | Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors iii |
EP3909950A1 (en) | 2020-05-13 | 2021-11-17 | Basf Se | Heterocyclic compounds for the control of invertebrate pests |
EP3945089A1 (en) | 2020-07-31 | 2022-02-02 | Basf Se | Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors v |
WO2021249800A1 (en) | 2020-06-10 | 2021-12-16 | Basf Se | Substituted [1,2,4]triazole compounds as fungicides |
EP3939961A1 (en) | 2020-07-16 | 2022-01-19 | Basf Se | Strobilurin type compounds and their use for combating phytopathogenic fungi |
WO2022017836A1 (en) | 2020-07-20 | 2022-01-27 | BASF Agro B.V. | Fungicidal compositions comprising (r)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1- (1,2,4-triazol-1-yl)propan-2-ol |
EP3970494A1 (en) | 2020-09-21 | 2022-03-23 | Basf Se | Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors viii |
TW202229241A (en) | 2020-09-26 | 2022-08-01 | 印度商皮埃企業有限公司 | Nematocidal compounds and use thereof |
WO2022078945A1 (en) | 2020-10-13 | 2022-04-21 | Bayer Aktiengesellschaft | Asymmetric transfer hydrogenation of 2-aryl substituted bicyclic pyridine ketones in presence of a chiral ruthenium catalyst |
EP4236691A1 (en) | 2020-10-27 | 2023-09-06 | BASF Agro B.V. | Compositions comprising mefentrifluconazole |
WO2022090071A1 (en) | 2020-11-02 | 2022-05-05 | Basf Se | Use of mefenpyr-diethyl for controlling phytopathogenic fungi |
WO2022090069A1 (en) | 2020-11-02 | 2022-05-05 | Basf Se | Compositions comprising mefenpyr-diethyl |
WO2022106304A1 (en) | 2020-11-23 | 2022-05-27 | BASF Agro B.V. | Compositions comprising mefentrifluconazole |
EP4018830A1 (en) | 2020-12-23 | 2022-06-29 | Basf Se | Pesticidal mixtures |
WO2022167488A1 (en) | 2021-02-02 | 2022-08-11 | Basf Se | Synergistic action of dcd and alkoxypyrazoles as nitrification inhibitors |
EP4043444A1 (en) | 2021-02-11 | 2022-08-17 | Basf Se | Substituted isoxazoline derivatives |
EP4337012A1 (en) | 2021-05-11 | 2024-03-20 | Basf Se | Fungicidal mixtures comprising substituted 3-phenyl-5-(trifluoromethyl)-1,2,4-oxadiazoles |
BR112023023989A2 (en) | 2021-05-18 | 2024-01-30 | Basf Se | COMPOUNDS, COMPOSITION, METHOD TO COMBAT PHYTOPATHOGENIC AND SEED FUNGI |
EP4341258A1 (en) | 2021-05-18 | 2024-03-27 | Basf Se | New substituted pyridines as fungicides |
IL308534A (en) | 2021-05-18 | 2024-01-01 | Basf Se | New substituted pyridines as fungicides |
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EP4094579A1 (en) | 2021-05-28 | 2022-11-30 | Basf Se | Pesticidal mixtures comprising metyltetraprole |
WO2022268810A1 (en) | 2021-06-21 | 2022-12-29 | Basf Se | Metal-organic frameworks with pyrazole-based building blocks |
EP4119547A1 (en) | 2021-07-12 | 2023-01-18 | Basf Se | Triazole compounds for the control of invertebrate pests |
CN116138260B (en) * | 2021-07-22 | 2024-03-15 | 青岛海利尔生物科技有限公司 | Sterilization composition containing penoxsulam and benzyl picoxystrobin |
KR20240042636A (en) | 2021-08-02 | 2024-04-02 | 바스프 에스이 | (3-pyridyl)-quinazoline |
CN117794908A (en) | 2021-08-02 | 2024-03-29 | 巴斯夫欧洲公司 | (3-quinolinyl) -quinazolines |
EP4140986A1 (en) | 2021-08-23 | 2023-03-01 | Basf Se | Pyrazine compounds for the control of invertebrate pests |
EP4140995A1 (en) | 2021-08-27 | 2023-03-01 | Basf Se | Pyrazine compounds for the control of invertebrate pests |
EP4151631A1 (en) | 2021-09-20 | 2023-03-22 | Basf Se | Heterocyclic compounds for the control of invertebrate pests |
WO2023072671A1 (en) | 2021-10-28 | 2023-05-04 | Basf Se | Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors ix |
WO2023072670A1 (en) | 2021-10-28 | 2023-05-04 | Basf Se | Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors x |
EP4194453A1 (en) | 2021-12-08 | 2023-06-14 | Basf Se | Pyrazine compounds for the control of invertebrate pests |
EP4198033A1 (en) | 2021-12-14 | 2023-06-21 | Basf Se | Heterocyclic compounds for the control of invertebrate pests |
EP4198023A1 (en) | 2021-12-16 | 2023-06-21 | Basf Se | Pesticidally active thiosemicarbazone compounds |
CN114467956B (en) * | 2022-02-23 | 2023-06-16 | 青岛奥迪斯生物科技有限公司 | Pesticide composition containing penflufen and application thereof |
EP4238971A1 (en) | 2022-03-02 | 2023-09-06 | Basf Se | Substituted isoxazoline derivatives |
WO2023203066A1 (en) | 2022-04-21 | 2023-10-26 | Basf Se | Synergistic action as nitrification inhibitors of dcd oligomers with alkoxypyrazole and its oligomers |
CN114766493A (en) * | 2022-04-29 | 2022-07-22 | 青岛恒宁生物科技有限公司 | Bactericidal composition containing agricultural antibiotic and application thereof |
WO2024028243A1 (en) | 2022-08-02 | 2024-02-08 | Basf Se | Pyrazolo pesticidal compounds |
EP4342885A1 (en) | 2022-09-20 | 2024-03-27 | Basf Se | N-(3-(aminomethyl)-phenyl)-5-(4-phenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-amine derivatives and similar compounds as pesticides |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7470793B2 (en) * | 2002-10-28 | 2008-12-30 | Bayer Cropscience Ag | Thiazol-(bi)cycloalkyl-carboxanilides |
US9192160B2 (en) * | 2010-12-20 | 2015-11-24 | Stichting I-F Product Collaboration | Aminoindanes amides having a high fungicidal activity and their phytosanitary compositions |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59194071A (en) | 1983-04-18 | 1984-11-02 | Nifco Inc | Manufacture of filter of car fuel tank |
KR920003893B1 (en) * | 1984-10-29 | 1992-05-18 | 스미또모가가꾸고오교 가부시끼가이샤 | Pyrazolecarboxamide derivatives |
DK383086A (en) | 1985-08-21 | 1987-02-22 | Rohm & Haas | (2-CYANO-2-ARYLETHYL) PYRIDINES, THEIR PREPARATION AND THEIR USE AS FUNGICIDES |
JPS62249966A (en) | 1986-04-22 | 1987-10-30 | Sumitomo Chem Co Ltd | N-indanylamide derivative and fungicide containing same as active ingredient |
CA1293975C (en) * | 1986-08-12 | 1992-01-07 | Naoko Sasaki | Pyridinecarboxamide derivatives and their use as fungicide |
US4837242A (en) | 1987-01-20 | 1989-06-06 | Sumitomo Chemical Company, Limited | Thiazoles and pyrazoles as fungicides |
US4914097A (en) | 1987-02-25 | 1990-04-03 | Mitsubishi Kasei Corporation | N-indanyl carboxamide derivative and agricultural/horticultural fungicide containing the derivative as active ingredient |
JPH01117864A (en) | 1987-07-02 | 1989-05-10 | Sumitomo Chem Co Ltd | Substituted nicotinic acid derivative, its production and agricultural and horticultural fungicide containing said derivative as active component |
JPS6470479A (en) | 1987-09-10 | 1989-03-15 | Sumitomo Chemical Co | Heterocylic carboxylic acid derivative, production thereof and agricultural and horticultural germicide containing said derivative as active ingredient |
JP2582863B2 (en) | 1988-06-13 | 1997-02-19 | 三菱化学株式会社 | Gray mold control agent containing N-indanylcarboxylic acid amide derivative as active ingredient |
JP2717852B2 (en) | 1988-12-09 | 1998-02-25 | 株式会社紀文食品 | Method for measuring freshness of frozen surimi |
JPH02157266A (en) | 1988-12-12 | 1990-06-18 | Mitsubishi Kasei Corp | N-indanylcarboxylic acid amide derivative and germicide for agriculture and horticulture containing the same as active ingredient |
US5093347A (en) * | 1991-01-28 | 1992-03-03 | Monsanto Company | 3-difluoromethylpyrazolecarboxamide fungicides, compositions and use |
JPH06296471A (en) | 1992-04-20 | 1994-10-25 | Kagoshima Pref Gov Keizai Nogyo Kyodo Kumiai Rengokai | Production of noodle of 100% sweet potato powder |
JP3077381B2 (en) | 1992-05-14 | 2000-08-14 | 住友化学工業株式会社 | Wood preservatives |
HUT63941A (en) | 1992-05-15 | 1993-11-29 | Hoechst Ag | Process for producing 4-alkyl-substituted pyrimidine-5-carboxanilide derivatives, and fungicidal compositions comprising same |
US5498624A (en) | 1995-05-03 | 1996-03-12 | Monsanto Company | Selected pyrazolyl derivatives |
GB0001447D0 (en) | 2000-01-21 | 2000-03-08 | Novartis Ag | Organic compounds |
MXPA05001819A (en) | 2002-08-22 | 2005-04-19 | Syngenta Participations Ag | Microbiocidal (e.g. fungicidal) 1,2,3-triazole derivatives. |
AU2004212056A1 (en) | 2003-02-14 | 2004-08-26 | Bayer Cropscience Aktiengesellschaft | Oxathiin carboxamide |
AU2004240720A1 (en) | 2003-05-21 | 2004-12-02 | Bayer Cropscience Aktiengesellschaft | Iodopyrazolyl carboxanilides |
DE102004005785A1 (en) | 2004-02-06 | 2005-08-25 | Bayer Cropscience Ag | 2-Halogenfuryl / thienyl-3-carboxamide |
MX2008000584A (en) | 2005-07-18 | 2008-03-14 | Syngenta Participations Ag | Pyrazole-4- carboxamide derivatives as microbiocides. |
CL2008002242A1 (en) | 2007-07-31 | 2009-08-21 | Bayer Cropscience Ag | N-cycloalkyl-n-carboxamide, thiocarboxamide, bicyclic derivatives or n-substituted carboximidamide derivatives; fungicidal composition; and method to control phytopathogenic fungi in crops. |
AU2009211416A1 (en) | 2008-02-05 | 2009-08-13 | Basf Se | Plant health composition |
AU2009211411A1 (en) | 2008-02-05 | 2009-08-13 | Basf Se | Plant health composition |
PL2563135T3 (en) | 2010-04-28 | 2017-06-30 | Sumitomo Chemical Company, Limited | Plant disease control composition and its use |
HUE030648T2 (en) | 2010-10-25 | 2017-05-29 | Lanxess Deutschland Gmbh | Fungicidal penflufen mixtures |
ITMI20121045A1 (en) | 2012-06-15 | 2013-12-16 | Isagro Ricerca Srl | SYNERGIC COMPOSITIONS FOR THE PROTECTION OF AGRICULTURAL CROPS AND ITS USE |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7470793B2 (en) * | 2002-10-28 | 2008-12-30 | Bayer Cropscience Ag | Thiazol-(bi)cycloalkyl-carboxanilides |
US9192160B2 (en) * | 2010-12-20 | 2015-11-24 | Stichting I-F Product Collaboration | Aminoindanes amides having a high fungicidal activity and their phytosanitary compositions |
Non-Patent Citations (1)
Title |
---|
Jeschke Pest Manag. Sci. 2010, 66, 10-27, published on line 21 August 2009 * |
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