CN106106462A - A kind of bactericidal composition containing Enestroburin Yu pyrazoles indanyl Carbox amide - Google Patents
A kind of bactericidal composition containing Enestroburin Yu pyrazoles indanyl Carbox amide Download PDFInfo
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- CN106106462A CN106106462A CN201610506331.1A CN201610506331A CN106106462A CN 106106462 A CN106106462 A CN 106106462A CN 201610506331 A CN201610506331 A CN 201610506331A CN 106106462 A CN106106462 A CN 106106462A
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- Prior art keywords
- enestroburin
- carbox amide
- pyrazoles indanyl
- bactericidal composition
- powdery mildew
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- 0 CNC1=C*(*)*=C1N Chemical compound CNC1=C*(*)*=C1N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
Abstract
The present invention relates to a kind of bactericidal composition containing Enestroburin Yu pyrazoles indanyl Carbox amide, its effective ingredient is that Enestroburin compounds with pyrazoles indanyl Carbox amide.Wherein Enestroburin is 1～80: 80～1 with the mass ratio of pyrazoles indanyl Carbox amide, in preparation, effective ingredient Enestroburin accounts for the 1%～80% of whole preparation gross mass with the gross mass of pyrazoles indanyl Carbox amide, remaining is for allowing the auxiliary element using and accepting in pesticide, the formulations of pesticide that bactericidal composition of the present invention can be made are cream, suspending agent, wettable powder, water dispersible granules, aqueous emulsion, microemulsion.It is mainly used in preventing and treating wheat powdery mildew, rice blast, false smut, cucurbits powdery mildew, Fructus Lycopersici esculenti powdery mildew, rust of apple (Gymnosporangium yamadai), watermelon anthrax, flowers powdery mildew, cucumber downy mildew, downy mildew of garpe, scab, anthrax, spot defoliation etc. are also had extraordinary preventive effect.
Description
Technical field
The present invention relates to technical field of pesticide combination, be specifically related to one containing Enestroburin and pyrazoles indanyl Methanamide
The bactericidal composition of compounds.
Background technology
Enestroburin is the methoxy acrylic bactericide of Shenyang Chemical Engineering Inst's exploitation, and Enestroburin belongs to methoxyl group
The antibacterial that esters of acrylic acid fungicidal spectrum is wide, activity is high, has prevention and therapeutical effect, to by mastigomycetes, combine bacterium, ascus
The plurality of plant diseases that bacterium, basidiomycetes and Fungi Imperfecti cause has good prevention effect, to Fructus Cucumidis sativi, downy mildew of garpe, white wheat
Powder disease etc. has good prevention effect, the most also scab, anthrax, spot defoliation etc. is had extraordinary preventive effect.Alkene
The chemical name of trifloxystrobin be α-[2-[[[[4-(4-chlorphenyl)-butyl-3-alkene-2-base] imido grpup] epoxide] methyl] phenyl]-
'beta '-methoxy acrylic acid methyl ester, its chemical structural formula is
Pyrazoles indanyl Carbox amide as a kind of novel active composition, can kill efficiently plant fungal,
Bacterial disease, and can be mixed with most insecticide, antibacterial, antiviral, herbicide and plant nutrient product etc.,
Improve the effect that single dose is used.Its chemical name: 3-difluoromethyl-N-(fluoro-1,1, the 3-trimethyl-4-indanyl of 7-)-1-first
Base-4-pyrazolecarboxamide, its molecular structural formula is following, and (Me represents methyl-CH3):
Use the maximally efficient means that chemical agent is controlling plant diseases.But use single long-term continuous high dose
Chemical bactericide, easily cause the problems such as the residual of medicament, environmental pollution and resistance to Drug resistance fungus development.Reasonably chemistry
Bactericide compounded or mixture has an expansion fungicidal spectrum, improve prevention effect, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning,
Reducing residual, delay the actively feature such as Antifungal resistance and drug-fast generation and development, bactericide compounded is to solve above-mentioned asking
One of maximally efficient method of topic.Develop new product antibacterial price constantly rises, and by contrast, develop and study efficiently,
Low toxicity, low-residual compounding with mixture has small investment, the lead time is short and is paid attention to both at home and abroad, increasing develops one after another
Dynamics.We are on the basis of lab screening and field test, filter out Enestroburin and pyrazoles indanyl formamides compounds
Thing compounds, and has obvious potentiation.At present, Enestroburin is more general as antibacterial application in crop protection
Time, the application patent of pyrazoles indanyl Carbox amide, document are the most few, and therefore the present inventor is exploring two kinds of changes
On the basis of compound using value, Enestroburin and pyrazoles indanyl Methanamide mixture are combined and carries out explorative research, and this is new
Type bactericidal composition and application are the most not yet disclosed.
Summary of the invention
Based on case above, present invention aim at providing a kind of new and effective pesticide sterilizing composite.It is mainly used in
Preventing and treating wheat powdery mildew, rice blast, false smut, cucurbits powdery mildew, Fructus Lycopersici esculenti powdery mildew, rust of apple (Gymnosporangium yamadai), watermelon anthrax, flowers are white
Powder is sick, and cucumber downy mildew, downy mildew of garpe, scab, anthrax, spot defoliation etc. are also had extraordinary preventive effect.
Technical scheme of the present invention is realized by following measures:
A kind of bactericidal composition containing Enestroburin Yu pyrazoles indanyl Carbox amide, this bactericidal composition
Effective ingredient is that Enestroburin and pyrazoles indanyl Carbox amide two yuan compound, wherein effective ingredient Enestroburin and pyrrole
The mass ratio of azoles indanyl Carbox amide is 1～80: 80～1；Enestroburin and pyrazoles indanyl formamides compounds
Thing accounts for the 1%～80% of the whole quality of the pharmaceutical preparations.
Preferably, the mass ratio of Enestroburin and pyrazoles indanyl Carbox amide is 1～40: 40～1.
Preferably, Enestroburin and pyrazoles indanyl Carbox amide account for the 5%～50% of the whole quality of the pharmaceutical preparations.
The formulations of pesticide that this bactericidal composition can be prepared as be cream, suspending agent, wettable powder, water dispersible granules,
Aqueous emulsion, microemulsion.
This bactericidal composition is at preventing and treating wheat powdery mildew, rice blast, false smut, cucurbits powdery mildew, Fructus Lycopersici esculenti powdery mildew, Fructus Mali pumilae
Rust, watermelon anthrax, flowers powdery mildew, to cucumber downy mildew, downy mildew of garpe, scab, anthrax, spot defoliation side
The application in face.
The present invention has with Enestroburin with the pyrazoles indanyl Carbox amide composite bactericide as effective ingredient
Significantly potentiation, delays the drug-fast generation in key, and reduces into product cost and use cost, can be used for resistance disease
Improvement, be mainly used in prevent and treat wheat powdery mildew, rice blast, false smut, cucurbits powdery mildew, Fructus Lycopersici esculenti powdery mildew, rust of apple (Gymnosporangium yamadai), west
Melon anthrax, flowers powdery mildew, also have cucumber downy mildew, downy mildew of garpe, scab, anthrax, spot defoliation etc.
Extraordinary preventive effect.
Detailed description of the invention
For making technical scheme, purpose and advantage are clearer, present invention specific examples below
Illustrate, but the present invention is not limited to these examples.The effect experimental of the present invention uses indoor biometrics and field test phase
In conjunction with mode, if no special instructions, ratio mentioned below is all mass fraction ratio.
Embodiment one
Described bactericidal composition is cream preparation, and the mass fraction of component is: Enestroburin 18%；Pyrazoles indanyl first
Amides compound 30%；Alkylphenol polyoxyethylene 3%, pulls open powder 1.5%, xanthan gum 0.3%, SAG622 organosilicon
0.05%, glycerol 5%, sodium benzoate 0.8%, remaining is supplied with deionized water, routinely the preparation of the suspending agent mode of production
48% Enestroburin pyrazoles indanyl Methanamide (18:30) suspending agent.
Embodiment two
Described bactericidal composition is suspending agent, and the mass fraction of component is: Enestroburin 24%；Pyrazoles indanyl formyl
Aminated compounds 24%；Alkylphenol polyoxyethylene 3%, pulls open powder 1.5%, xanthan gum 0.3%, SAG622 organosilicon
0.05%, glycerol 5%, sodium benzoate 0.8%, remaining is supplied with deionized water, routinely the preparation of the suspending agent mode of production
48% Enestroburin pyrazoles indanyl Methanamide (24:24) suspending agent.The concrete production stage of this suspending agent is first by other
Auxiliary agent mixes, and through high speed shear mix homogeneously, adds effective ingredient Enestroburin and pyrazoles indanyl Carbox amide,
Abrading-ball 2～3 hours in ball crusher, make a diameter all at below 5mm, i.e. can be made into the aqueous suspension formulations of the present composition.
Embodiment three
Described bactericidal composition is wettable powder, and the mass fraction of component is: Enestroburin 30%；Pyrazoles indanyl
Carbox amide 18%；Alkylphenol polyoxyethylene 3%, pulls open powder 1.5%, xanthan gum 0.3%, SAG622 organosilicon
0.05%, glycerol 5%, sodium benzoate 0.8%, remaining is supplied with deionized water, routinely the preparation of the suspending agent mode of production
48% Enestroburin pyrazoles indanyl Methanamide (30:18) suspending agent.
Embodiment four
Described bactericidal composition is water dispersible granules, and the mass fraction of component is: Enestroburin 36%；Pyrazoles indanyl
Carbox amide 12%；Alkylphenol polyoxyethylene 3%, pulls open powder 1.5%, xanthan gum 0.3%, SAG622 organosilicon
0.05%, glycerol 5%, sodium benzoate 0.8%, remaining is supplied with deionized water, routinely the preparation of the suspending agent mode of production
48% Enestroburin pyrazoles indanyl Methanamide (36:12) suspending agent.
Embodiment five
Described bactericidal composition is aqueous emulsion, and the mass fraction of component is: Enestroburin 42%；Pyrazoles indanyl formyl
Aminated compounds 6%；Alkylphenol polyoxyethylene 3%, pulls open powder 1.5%, xanthan gum 0.3%, SAG622 organosilicon 0.05%,
Glycerol 5%, sodium benzoate 0.8%, remaining is supplied with deionized water, and the suspending agent mode of production prepares 48% alkene oxime bacterium routinely
Ester pyrazoles indanyl Methanamide (42:6) suspending agent.
Experimental example
Enestroburin is tested with pyrazoles indanyl Carbox amide different ratio co-toxicity.
1.1 reagent agent
The 90% former medicine of Enestroburin, the 95% pyrazoles former medicine of indanyl Carbox amide, above-mentioned former medicine is by Jing Bonong
Change research and development department of Science and Technology Co., Ltd. to provide.
1.2 test targets never executed from Shouguang, Shandong Enestroburin and pyrazoles indanyl Carbox amide and with
The Fructus Cucumidis sativi of type gathers separation potted plantly, for examination cucumber variety: Chang Chun Mi Ci.
1.3 test method
1.3.1 medicament preparation
First with the former medicine of acetone solution, according to the result of preliminary experiment, two appropriate former medicines are made into 5 different ratio, then use
It is stand-by that each process is diluted to 5 Concentraton gradient by acetone respectively, and 5 Enestroburins are with pyrazoles indanyl Carbox amide not
It is respectively 18:30 with the ratio of proportioning effective ingredient；24:24；30:18；36:12；42:6.(the respectively number of embodiment one～five
According to)
Being cultivated in pot for growing seedlings by susceptible cucumber variety Chang Chun Mi Ci, be placed in greenhouse cultivation, plant grows to three to four leaves
After date, gathers the blade of identical leaf age, for cultivation and the mensuration of cucumber powdery mildew's pathogen.
2.1 toxicity test results
Table 1 Enestroburin and the pyrazoles indanyl Carbox amide toxicity test to powdery mildew of cucumber
As can be seen from the table, the result of the test of different proportion proportioning shows, is 18:30 in effective ingredient ratio；24:
24；30:18；36:12；When 42:6 dilutes respectively, all show stronger potentiation, wherein with Enestroburin and pyrazoles indane
The when that base Carbox amide being 30:18, synergistic effect is optimal, and its co-toxicity coefficient is 184.91.Suggestion is to suitable proportion
About 30:18 mixture preparation carries out further field control effectiveness test, to evaluate its field practical application effect.
3 field tests prevent and treat powdery mildew of cucumber, the experimental result of downy mildew
3.1 field tests prevent and treat powdery mildew of cucumber
3.1.1 test method
Test on Shandong Pingdu City Fructus Cucumidis sativi ground, 4 points of every community investigation, every some investigation 2 strains.
3.1.2 result of the test and analyze each process and prevent and treat the effect (table 2) of powdery mildew of cucumber.
Table 2 respectively processes the effect preventing and treating powdery mildew of cucumber
48% Enestroburin and pyrazoles indanyl Carbox amide are with 30:18 ratio composite bactericide as shown in Table 2
Effect controlled apparently higher than Enestroburin and pyrazoles indanyl Carbox amide single dose for powdery mildew of cucumber, in second time
After medicine, the bactericidal effect of 15 days still reaches more than 90%, and bactericidal effect is incremented by with the increase of dosage.Estimate according to field,
In the range of test dose, plant growth is normal, and the poisoning phenomenon to Fructus Cucumidis sativi does not all occur in each treatment agent, illustrates that Fructus Cucumidis sativi is by it
Safety.Advise that the antibacterial different from the mechanism of action is used in mixed way to delay the drug-fast generation of pathogenic bacteria.
4.1 field test preventing and treating cucumber downy mildews
4.1.1 test method
Test on Shandong Pingdu City Fructus Cucumidis sativi ground, 4 points of every community investigation, every some investigation 2 strains.
4.1.2 result of the test and analyze each process preventing and treating cucumber downy mildew effect (table 3)
Table 3 respectively processes the effect of preventing and treating cucumber downy mildew.
The Mixed Pharmacy of different proportion as can be seen from Table 3, is tested by different consumptions, and after medicine, it is to Cucumis satiuus L.
The preventing and treating of mildew is superior to compare medicament, and bactericidal effect is incremented by with the increase of dosage.Estimate according to field, at test dose model
In enclosing, plant growth is normal, and the poisoning phenomenon to Fructus Cucumidis sativi does not all occur in each treatment agent, illustrates that it is safe to Fructus Cucumidis sativi.Build
Discuss the antibacterial different from the mechanism of action to be used in mixed way to delay the drug-fast generation of pathogenic bacteria.
In sum, the present invention contains the bactericidal composition of Enestroburin and pyrazoles indanyl Carbox amide, right
Powdery mildew of cucumber and cucumber downy mildew have good prevention effect, and it is to Target crops safety.Complex preparation not only improves
Preventive effect, and expand fungicidal spectrum, so this compounded combination has being of great significance in production practices.
Claims (5)
1. the bactericidal composition containing Enestroburin with pyrazoles indanyl Carbox amide, it is characterised in that: this kills
The effective ingredient of bacteria composition is that Enestroburin and pyrazoles indanyl Carbox amide two yuan compound, wherein effective ingredient alkene
Trifloxystrobin is 1～80: 80～1 with the mass ratio of pyrazoles indanyl Carbox amide；Enestroburin and pyrazoles indanyl first
Amides compound accounts for the 1%～80% of the whole quality of the pharmaceutical preparations.
Bactericidal composition containing Enestroburin Yu pyrazoles indanyl Carbox amide the most according to claim 1,
It is characterized in that: the mass ratio of Enestroburin and pyrazoles indanyl Carbox amide is 1～40: 40～1.
Bactericidal composition containing Enestroburin Yu pyrazoles indanyl Carbox amide the most according to claim 1,
It is characterized in that: Enestroburin and pyrazoles indanyl Carbox amide account for the 5%～50% of the whole quality of the pharmaceutical preparations.
Bactericidal composition containing Enestroburin Yu pyrazoles indanyl Carbox amide the most according to claim 1,
It is characterized in that: the formulations of pesticide that this bactericidal composition can be prepared as are cream, suspending agent, wettable powder, water-dispersible grain
Agent, aqueous emulsion, microemulsion.
Bactericidal composition containing Enestroburin Yu pyrazoles indanyl Carbox amide the most according to claim 1,
It is characterized in that: this bactericidal composition preventing and treating wheat powdery mildew, rice blast, false smut, cucurbits powdery mildew, Fructus Lycopersici esculenti powdery mildew,
Rust of apple (Gymnosporangium yamadai), watermelon anthrax, flowers powdery mildew, to cucumber downy mildew, downy mildew of garpe, scab, anthrax, speckle fallen leaves
Application in terms of Bing.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109984135A (en) * | 2018-11-14 | 2019-07-09 | 东莞东阳光科研发有限公司 | A kind of application of bactericidal composition and its preparation, bactericidal composition and its preparation |
| WO2020121346A1 (en) * | 2018-12-14 | 2020-06-18 | Isagro S.P.A. | Suspoemulsion containing fluindapyr and use thereof as fungicide in crop plants |
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| CN103502220A (en) * | 2010-12-20 | 2014-01-08 | I-F产品协作基金会 | Aminoindanes amides having a high fungicidal activity and phytosanitary compositions thereof |
| CN104602523A (en) * | 2012-06-15 | 2015-05-06 | I-F产品协作基金会 | Synergistic compositions for the protection of agrarian crops and the use thereof |
| GB2521255A (en) * | 2013-10-22 | 2015-06-17 | Syngenta Participations Ag | Method of combating corynespora |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102858163A (en) * | 2010-04-28 | 2013-01-02 | 住友化学株式会社 | Plant disease control composition and its use |
| CN103502220A (en) * | 2010-12-20 | 2014-01-08 | I-F产品协作基金会 | Aminoindanes amides having a high fungicidal activity and phytosanitary compositions thereof |
| CN104602523A (en) * | 2012-06-15 | 2015-05-06 | I-F产品协作基金会 | Synergistic compositions for the protection of agrarian crops and the use thereof |
| CN102960351A (en) * | 2012-11-27 | 2013-03-13 | 海利尔药业集团股份有限公司 | Antiseptic composition containing enestroburin and SYP-7017 |
| GB2521255A (en) * | 2013-10-22 | 2015-06-17 | Syngenta Participations Ag | Method of combating corynespora |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109984135A (en) * | 2018-11-14 | 2019-07-09 | 东莞东阳光科研发有限公司 | A kind of application of bactericidal composition and its preparation, bactericidal composition and its preparation |
| WO2020121346A1 (en) * | 2018-12-14 | 2020-06-18 | Isagro S.P.A. | Suspoemulsion containing fluindapyr and use thereof as fungicide in crop plants |
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