CN102960351A - Antiseptic composition containing enestroburin and SYP-7017 - Google Patents
Antiseptic composition containing enestroburin and SYP-7017 Download PDFInfo
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- CN102960351A CN102960351A CN2012104897290A CN201210489729A CN102960351A CN 102960351 A CN102960351 A CN 102960351A CN 2012104897290 A CN2012104897290 A CN 2012104897290A CN 201210489729 A CN201210489729 A CN 201210489729A CN 102960351 A CN102960351 A CN 102960351A
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- enestroburin
- bacterium ester
- chlorine nalidixic
- nalidixic bacterium
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Abstract
The invention relates to an antiseptic composition containing enestroburin and SYP-7017. The antiseptic composition comprises an effective ingredient compounded by enestroburin and SYP-7017 and auxiliary ingredients which are allowably and acceptably used in pesticides, wherein the mass ratio of the enestroburin to the SYP-7017 is (1-80):(80-1), the total mass of the effective ingredients of the enestroburin and the SYP-7017 in the preparation accounts for 1%-80% of the total mass of the overall preparation. The antiseptic composition can be prepared into the following pesticide formulations: missible oil, suspending agent, wettable powder, water dispersible granules, water emulsions and micro emulsions. The antiseptic composition is mainly used for prevention and control of wheat powdery mildew, rice blast, rice false smut, melon powdery mildew, tomato powdery mildew, apple rust, watermelon anthracnose, and powdery mildew of flowers and plants, and also has very good control effect on cucumber downy mildew, grape downy mildew, scab, anthracnose, alternaria leaf spot and the like.
Description
Technical field
The present invention relates to the agriculture chemical compounding technical field, be specifically related to a kind of bactericidal composition that contains Enestroburin and chlorine nalidixic bacterium ester.
Background technology
Enestroburin is the methoxy acrylic bactericide of Shenyang Chemical Engineering Inst's exploitation, Enestroburin belongs to wide, the active high bactericide of methoxy acrylic fungicidal spectrum, have prevention and therapeutic action, to by mastigomycetes, the plurality of plant diseases that causes in conjunction with bacterium, sac fungi, basidiomycetes and imperfect fungus good control efficiency being arranged, cucumber, downy mildew of garpe, wheat powdery mildew etc. there are good control efficiency, also scab, anthracnose, spot defoliation etc. are had extraordinary preventive effect simultaneously.The chemical name of Enestroburin is α-[2-[[[[4-(4-chlorphenyl)-Ding-3-alkene-2-yl] imido grpup] the oxygen base] methyl] phenyl]-the 'beta '-methoxy acrylic acid methyl esters, its chemical structural formula is
Chlorine nalidixic bacterium ester is the methoxy acrylic bactericide with independent intellectual property right that Shenyang Chemical Engineering Inst develops, chemical name N-methoxyl group-N-[2-[[(3,5,6-trichloropyridine-2-yl) oxygen] methyl] phenyl] methyl carbamate.Chlorine nalidixic bacterium ester is a kind of high-efficiency broad spectrum low toxicity bactericide, have prevention and therapeutic action, the multiple diseases such as the wheat powdery mildew that caused by sac fungi, basidiomycetes and imperfect fungus, rice blast, false smut, cucurbits powdery mildew, tomato powdery mildew, apple rust, watermelon anthrax, flowers powdery mildew are shown excellent control efficiency, during using, the field has no adverse effects to supplying to study the thing growth, to non-target organism and Environmental security.
Using chemical agent is the most effectively means of controlling plant diseases.But long-term use single chemical bactericide continuously high dose, cause easily the problems such as residual, the environmental pollution of medicament and anti-pesticide resistance fungi development.Reasonably chemical bactericide is composite or be mixed and have the expansion fungicidal spectrum, improve control efficiency, prolong the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, delay Antifungal resistance and the positive characteristics such as drug-fast generation and development, bactericide compounded is the most one of the effective method that addresses the above problem.Exploitation new product bactericide price is constantly soaring, and by contrast, exploitation is efficient with research, low toxicity, low-residual composite be mixed have small investment, the lead time is short and be subject to domestic and international attention, the numerous and confused dynamics that develops that strengthens.We filter out Enestroburin and chlorine nalidixic bacterium ester and carry out compositely on the basis of lab screening and field trial, have obvious synergistic effect.And about the composite bactericidal composition of Enestroburin and chlorine nalidixic bacterium ester and use and there is no at present the people and reported.
Summary of the invention
Based on above situation, the object of the invention is to provide a kind of new and effective pesticide sterilizing composite.Be mainly used in preventing and treating wheat powdery mildew, rice blast, false smut, cucurbits powdery mildew, tomato powdery mildew, apple rust, watermelon anthrax, flowers powdery mildew, cucumber downy mildew, downy mildew of garpe, scab, anthracnose, spot defoliation etc. are also had extraordinary preventive effect.
Technical scheme of the present invention realizes by following measures:
A kind of bactericidal composition that contains Enestroburin and chlorine nalidixic bacterium ester, two yuan of the active ingredient Enestroburin of this bactericidal composition and chlorine nalidixic bacterium esters are composite, and all the other are auxiliary element.The mass ratio of active ingredient Enestroburin and chlorine nalidixic bacterium ester is 1～80: 80～1 in the wherein said Pesticidal combination, described bactericidal composition of the present invention is through the toxicity test experimental verification, the mass ratio of Enestroburin and chlorine nalidixic bacterium ester is 1～40: 40～1 o'clock, and synergistic effect is better.
The formulations of pesticide that described bactericidal composition of the present invention can be prepared are missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.Wherein active ingredient Enestroburin and the chlorine nalidixic bacterium ester gross mass in preparation accounts for 1%～80% of the whole quality of the pharmaceutical preparations, when wherein accounting for 5%-50%, and toxicity and the residual preferably balance that reaches, cost is also lower.
The specific embodiments of the formulations of pesticide that bactericidal composition of the present invention is mixed with is as follows:
Described bactericidal composition is cream preparation, and the mass fraction of component is: Enestroburin 1～80; 1～40 part of chlorine nalidixic bacterium ester; 10～30 parts of conventional emulsifiers; 20～50 parts of conventional solvents; 1～5 part of conventional synergist.The concrete production stage of this cream preparation adds emulsifier, the synergist rear oily liquids that becomes transparent and homogeneous that stirs after dissolving fully in the solvent again for first active ingredient Enestroburin and chlorine nalidixic bacterium ester being added, can namely can be made into the cream preparation of the present composition.
Described bactericidal composition is suspending agent, and the mass fraction of component is: 1～80 part of Enestroburin azoles; 1～40 part of chlorine nalidixic bacterium ester; 5～20 parts of dispersants; 1～5 part of antifreezing agent; 0.1～2 part of thickener; 0.1～0.8 part of defoamer; 0～10 part of penetrating agent; 0.1～5 part of pH value conditioning agent; Water, surplus.The concrete production stage of this suspending agent is for mixing other auxiliary agents first, mix through high speed shear, add active ingredient Enestroburin and chlorine nalidixic bacterium ester, abrading-ball is 2～3 hours in ball crusher, make a diameter all below 5mm, namely can be made into the suspending agent preparation of the present composition.
Described bactericidal composition is wetting powder, and the mass fraction of component is: 1～80 part of Enestroburin; 1～40 part of chlorine nalidixic bacterium ester; 3～10 parts of dispersants; 1～5 part of wetting agent; Filler, surplus.The concrete production stage of this wetting powder is: by above-mentioned prescription the active ingredient Enestroburin is mixed with chlorine nalidixic bacterium ester and dispersant, wetting agent and filler, uniform stirring in stirred tank, behind airslide disintegrating mill, mixing, namely can be made into the wetting powder of the present composition.
Described bactericidal composition is water dispersible granules, and the mass fraction of component is: 1～80 part of Enestroburin; 1～40 part of chlorine nalidixic bacterium ester; 3～10 parts of dispersants; 1～10 part of wetting agent; 1～5 part of disintegrant; The filler surplus.The concrete production stage of this water dispersible granules is: by above-mentioned prescription active ingredient Enestroburin and chlorine nalidixic bacterium ester and dispersant, wetting agent, disintegrant and filler are mixed, pulverize with micro jet, through mediating, then add and carry out granulation, drying, screening in the fluidized bed prilling dryer by sample analysis, namely can be made into the water dispersible granules of the present composition.
Described bactericidal composition is aqueous emulsion, and the mass fraction of component is: 1～80 part of Enestroburin; 1～40 part of chlorine nalidixic bacterium ester; 3～30 parts of emulsifier; 5～15 parts of solvents; 2～15 parts of stabilizing agents; 1～5 part of antifreezing agent; 0.1～8 part of defoamer; 0.2～2 part of thickener; Water surplus.The concrete production stage of this aqueous emulsion is: at first Enestroburin and chlorine nalidixic bacterium ester, solvent and emulsifier, cosolvent are added together, make and be dissolved into uniform oil phase; With part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When the reactor high speed stirs, oil phase is added water, slowly add water until reach the phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear approximately half an hour, form the aqueous emulsion of oil-in-water type, namely can be made into the aqueous emulsion of the present composition.
Described bactericidal composition is microemulsion, and the mass fraction of component is: 1～80 part of Enestroburin, 1～40 part of chlorine nalidixic bacterium ester, 10～30 parts of emulsifier, 1～8 part of antifreezing agent, 0.5～10 part of stabilizing agent, 20～50 parts of conventional solvent cosolvents.Enestroburin and chlorine nalidixic bacterium ester are dissolved fully with cosolvent, add again other compositions such as emulsifier, antifreezing agent stabilizing agent, evenly mix, add at last entry, can be made into microemulsion after fully stirring.
Wherein above-described emulsifier is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, the alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, any or more than one any mixtures than forming in the polyoxyethylene aliphatic alcohol ether.
Described solvent is dimethylbenzene or biodiesel, toluene, and diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), one or more in the water equal solvent are arbitrarily than the mixture that forms.
Described dispersant is selected from polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene methyl ether condensate sulfate, the alkylsulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, one or more in the fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, and Nekal BX, moistening bleeding agent F, alkylbenzenesulfonate polyoxyethylene triphen is phosphenylic acid salt dimly, spaonin powder, silkworm excrement, one or more in the soapberry powder.
Described disintegrant is selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, one or more in the sodium bicarbonate.
Described thickener is selected from xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, in the polyvinyl alcohol one or more.
Described stabilizing agent is selected from sodium citrate, a kind of in the resorcinol.
Described antifreezing agent is selected from ethylene glycol, propane diols, one or more in the glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20The saturated fat acid compounds, C
8-10One or more of fatty alcohol.
Described filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, one or more in the precipitated calcium carbonate.
The composite bactericide of the present invention take Enestroburin and chlorine nalidixic bacterium ester as active ingredient has obvious synergistic effect, delay the drug-fast generation in key, and reduced one-tenth and produced cost and use cost, can be used for the improvement of resistance disease, be mainly used in preventing and treating wheat powdery mildew, rice blast, false smut, cucurbits powdery mildew, tomato powdery mildew, apple rust, watermelon anthrax, flowers powdery mildew, cucumber downy mildew, downy mildew of garpe, scab, anthracnose, spot defoliation etc. are also had extraordinary preventive effect.
Embodiment
For making technical scheme of the present invention, purpose and advantage are clearer, and the present invention describes with following specific embodiment, but the present invention is not limited to these examples.The mode that effect experiment of the present invention adopts indoor biometrics and field trial to combine, if no special instructions, the ratio of below mentioning all is ratio of quality and the number of copies.
Embodiment: the different proportioning co-toxicity experiments from chlorine nalidixic bacterium ester of Enestroburin.
1.1 reagent agent
The former medicine of 90 % Enestroburins, the former medicine of 95% chlorine nalidixic bacterium ester, above-mentioned former medicine provides by research and development department of extra large rel medicine company limited company.
1.2 test target
Never executed Enestroburin and chlorine nalidixic bacterium ester and cucumber of the same type from Shouguang, Shandong and gather potted plantly and separate, for the examination cucumber variety: Chang Chun Mi Ci.
1.3 test method
1.3.1 medicament preparation
Use first the former medicine of acetone solution, result according to preliminary experiment is made into 5 different proportionings with two an amount of former medicines, it is stand-by with acetone each processing to be diluted to respectively 5 concentration gradients again, and the ratio of 5 different proportioning active ingredients from chlorine nalidixic bacterium ester of Enestroburin is respectively 18:30; 24:24; 30:18; 36:12; 42:6.
In pot for growing seedlings, place the greenhouse to cultivate susceptible cucumber variety Chang Chun Mi Ci cultivation, plant grows to three to four leaf after dates, gathers the blade of identical leaf age, is used for cultivation and the mensuration of powdery mildew of cucumber bacterium.
1.3.2 the cultivation of powdery mildew of cucumber bacterium and the preparation of spore suspension
The powdery mildew of cucumber bacterium adopts the plants method to cultivate under 20 ℃, the condition of 12h alternation of light and darkness, and per 30 d turn culture 1 time.With the conidium on the sterile water wash-out incidence of leaf, being mixed with spore concentration is l * 10 during inoculation
6The suspension of individual/mL.
1.3.3 strains tested sensitivity testing
Adopt leaf dish moisturizing method to carry out toxicity test.First the blade that gathers is prepared into the leaf dish that diameter is 1.5cm, mixing at random, place respectively the series concentration liquid that configures to soak lh, 50 leaf dishes of each concentration, test is with the blank that is treated to of adding medicine not, after soaking end, leaf faces up and puts on the wetting blotting paper of identical liquor strength, liquid on the leaf dish is blotted, the spore suspension l0L for preparing is inoculated in leaf dish central authorities, after room temperature is placed 5 min, places under 20 ℃, the condition of 1 2h alternation of light and darkness and cultivate, measure the onset area on the leaf dish behind the 10d, calculate EC
50
On the basis of preliminary experiment, respectively single dose Enestroburin and chlorine nalidixic bacterium ester are carried out toxicity test in order to upper method, the two EC
50Value is respectively 20.85 ㎎/l and 12.68 ㎎/l
The percentage that accounts for the leaf disc area according to lesion area is divided sick level
0 grade: anosis;
1 grade: the sorus area accounts for below 5% of whole leaf area;
3 grades: the sorus area accounts for below the 6%-10% of whole leaf area;
5 grades: the sorus area accounts for below the 11%-20% of whole leaf area;
7 grades: the sorus area accounts for below the 21%-50% of whole leaf area;
9 grades: the sorus area accounts for more than 50% of whole leaf area.
1.3.4 mixture toxicity test and interpretation of result
Carry out the toxicity test of mixture according to mixed ratio with single dose toxicity test method.
If contrast lethality＜5% is not proofreaied and correct, the contrast lethality by formula 2 is proofreaied and correct between 5%-20%, the contrast lethality〉20%, test need be reformed.
Take the logarithm value of drug concentration (mg/L) as independent variable x, take the probability value of corrected mortality as dependent variable y, set up respectively the virulence regression equation formula, adopt DPS software to calculate the LC of single dose and each proportioning mixture
50Calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun.Co-toxicity coefficient CTC, computing formula is as follows: (take Enestroburin as the standard medicament, its toxicity index is 100):
The LC of the toxicity index of chlorine nalidixic bacterium ester (TI)=Enestroburin
50The LC of/chlorine nalidixic bacterium ester
50* 100
The LC of the true toxicity index (ATI) of M=Enestroburin
50The LC of/M
50* 100
The TI of the TI of the theoretical toxicity index (TTI) of M=Enestroburin * P Enestroburin+chlorine nalidixic bacterium ester * P chlorine nalidixic bacterium ester
The TTI of the ATI/M of the co-toxicity coefficient of M (CTC)=M * 100
In the formula:
M is Enestroburin and the mixture of the different proportionings of chlorine nalidixic bacterium ester
The P Enestroburin is Enestroburin shared ratio in mixture
The P chlorine nalidixic bacterium ester is chlorine nalidixic bacterium ester shared ratio in mixture.
2.1 toxicity test result
Table 1 Enestroburin and chlorine nalidixic bacterium ester are to the toxicity test of powdery mildew of cucumber
| Process title | Proportioning | Virulence regression equation (Y=a+bX) | The correlation coefficient r value | LC 50（mg/L） | Co-toxicity coefficient (CTC) |
| Enestroburin | _____ | Y=2.5694X+1.6107 | 0.9894 | 20.85 | _______ |
| Chlorine nalidixic bacterium ester | _____ | Y=2.6964X+2.0255 | 0.9882 | 12.68 | _______ |
| Enestroburin: chlorine nalidixic bacterium ester | 18：30 | Y=2.7374X+2.2854 | 0.9892 | 9.81 | 151.49 |
| Enestroburin: chlorine nalidixic bacterium ester | 24：24 | Y=2.4694X+2.5879 | 0.9914 | 9.48 | 166.32 |
| Enestroburin: chlorine nalidixic bacterium ester | 30：18 | Y=2.7432X+2.3718 | 0.9891 | 9.08 | 184.91 |
| Enestroburin: chlorine nalidixic bacterium ester | 36：12 | Y=2.7963X+2.1410 | 0.9884 | 10.53 | 170.55 |
| Enestroburin: chlorine nalidixic bacterium ester | 42：6 | Y=2.9423X+1.7994 | 0.9901 | 12.24 | 157.68 |
As can be seen from the table, the result of the test of different proportion proportioning shows, is 18:30 in the active ingredient ratio; 24:24; 30:18; 36:12; When 42:6 dilutes respectively, all show stronger synergistic effect, wherein take Enestroburin and chlorine nalidixic bacterium ester as 30:18 the time synergistic effect best, its co-toxicity coefficient is 184.91.Suggestion is carried out further field control effectiveness test to suitable proportion 30:18 left and right sides mixture preparation, to estimate its field practical application effect.
3 field trials are prevented and treated powdery mildew of cucumber, the experimental result of downy mildew
3.1 field trial is prevented and treated powdery mildew of cucumber
3.1.1 test method
Test is on Shandong Pingdu City cucumber ground, and 4 points of every residential quarter investigation are investigated 2 strains at every, put down in writing occurring degree with staging, and grade scale is as follows:
0 grade: anosis;
1 grade: the sorus area accounts for below 5% of whole leaf area;
3 grades: the sorus area accounts for below the 6%-10% of whole leaf area;
5 grades: the sorus area accounts for below the 11%-20% of whole leaf area;
7 grades: the sorus area accounts for below the 21%-50% of whole leaf area;
9 grades: the sorus area accounts for more than 50% of whole leaf area.
3.1.2 control time and number of times
Test is investigated 4 times altogether, and radix investigation before the medicine was investigated behind 7 days, 7 days for the second time and the medicine behind the medicine for the first time in 15 days.
3.1.3 drug effect computational methods
Sick leaf rate (the %)=sick number of sheets/investigate total number of sheets * 100
Disease index=∑ (the sick numbers of sheets at different levels * relative level numerical value)/(investigating total number of sheets * 9) * 100
Control efficiency (%)=(disease index behind disease index before the 1-(blank district medicine * treatment region medicine)/(disease index before disease index behind the blank district medicine * treatment region medicine)) * 100.
3.1.4 poisoning investigation method
Whether continuous 15d range estimation medicament has poisoning to crop after the dispenser.
3.1.5 result of the test and analysis
Each processes the effect of preventing and treating powdery mildew of cucumber.(table 2)
Each processes the effect of preventing and treating powdery mildew of cucumber table 2
48% Enestroburin and chlorine nalidixic bacterium ester are higher than Enestroburin and chlorine nalidixic bacterium ester single dose with 30:18 ratio composite bactericide for the successful of controlling of powdery mildew of cucumber as shown in Table 2,15 days bactericidal effect still reaches more than 90% behind second time medicine, and bactericidal effect increases progressively with the increase of dosage.According to the field range estimation, in the test dose scope, plant growth is normal, and the poisoning phenomenon to cucumber does not all appear in each treatment agent, illustrates that it is safe to cucumber.Advise that the bactericide different from the mechanism of action mixes use to delay the drug-fast generation of germ.
4.1 field trial control cucumber downy mildew
4.1.1 test method
Test is on Shandong Pingdu City cucumber ground, and 4 points of every residential quarter investigation are investigated 2 strains at every, put down in writing occurring degree with staging, and grade scale is as follows:
0 grade: anosis;
1 grade: the sorus area accounts for below 5% of whole leaf area;
3 grades: the sorus area accounts for below the 6%-10% of whole leaf area;
5 grades: the sorus area accounts for below the 11%-20% of whole leaf area;
7 grades: the sorus area accounts for below the 21%-50% of whole leaf area;
9 grades: the sorus area accounts for more than 50% of whole leaf area.
4.1.2 control time and number of times
Test is investigated 4 times altogether, radix investigation before the medicine, for the first time behind the medicine 7 days, investigated in 15 days behind 7 days and the medicine behind the medicine for the second time.
4.1.3 drug effect computational methods
Sick leaf rate (the %)=sick number of sheets/investigate total number of sheets * 100
Disease index=∑ (the sick numbers of sheets at different levels * relative level numerical value)/(investigating total number of sheets * 9) * 100
Control efficiency (%)=(disease index behind disease index before the 1-(blank district medicine * treatment region medicine)/(disease index before disease index behind the blank district medicine * treatment region medicine)) * 100.
4.1.4 poisoning investigation method
Whether continuous 7d range estimation medicament has poisoning to crop after the dispenser.
4.1.5 result of the test and analysis
Each processes the effect (table 3) of control cucumber downy mildew
Each processes the effect of control cucumber downy mildew table 3.
The Mixed Pharmacy of different proportion is tested by different consumptions as can be seen from Table 3, and its control to cucumber downy mildew all is better than contrasting medicament behind the medicine, and bactericidal effect increases progressively with the increase of dosage.According to the field range estimation, in the test dose scope, plant growth is normal, and the poisoning phenomenon to cucumber does not all appear in each treatment agent, illustrates that it is safe to cucumber.Advise that the bactericide different from the mechanism of action mixes use to delay the drug-fast generation of germ.
In sum, the present invention contains the bactericidal composition of Enestroburin and chlorine nalidixic bacterium ester, powdery mildew of cucumber and cucumber downy mildew are had good control efficiency, and it is to the target crop safety.Complex preparation has not only improved preventive effect, and has enlarged fungicidal spectrum, so this compounded combination tool in production practices is of great significance.
Claims (5)
1. bactericidal composition that contains Enestroburin and chlorine nalidixic bacterium ester, it is characterized in that: the active ingredient of this bactericidal composition is that Enestroburin and two yuan of chlorine nalidixic bacterium esters are composite, and wherein the mass ratio of active ingredient Enestroburin and chlorine nalidixic bacterium ester is 1～80: 80～1.
2. bactericidal composition according to claim 1, it is characterized in that: the quality optimization ratio of Enestroburin and chlorine nalidixic bacterium ester is 1～40: 40～1.
3. bactericidal composition according to claim 1, it is characterized in that: Enestroburin and chlorine nalidixic bacterium ester account for 1%～80% of the whole quality of the pharmaceutical preparations.
4. bactericidal composition according to claim 3, it is characterized in that: Enestroburin and chlorine nalidixic bacterium ester account for 5%～50% of the whole quality of the pharmaceutical preparations.
5. according to claim 1 and 2 or 3 or 4 described bactericidal compositions, it is characterized in that: the formulations of pesticide that this bactericidal composition can be prepared into are missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106106462A (en) * | 2016-06-30 | 2016-11-16 | 京博农化科技股份有限公司 | A kind of bactericidal composition containing Enestroburin Yu pyrazoles indanyl Carbox amide |
-
2012
- 2012-11-27 CN CN2012104897290A patent/CN102960351A/en active Pending
Non-Patent Citations (2)
| Title |
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| 张鹭等: "复合物Ⅲ抑制剂型杀菌剂――结构类型和作用机理", 《化学进展》 * |
| 杨共强等: "6种杀菌剂对小麦白粉病的防治效果", 《植物保护》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106106462A (en) * | 2016-06-30 | 2016-11-16 | 京博农化科技股份有限公司 | A kind of bactericidal composition containing Enestroburin Yu pyrazoles indanyl Carbox amide |
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Application publication date: 20130313 |