CN108684680A - A kind of bactericidal composition - Google Patents

A kind of bactericidal composition Download PDF

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Publication number
CN108684680A
CN108684680A CN201710231110.2A CN201710231110A CN108684680A CN 108684680 A CN108684680 A CN 108684680A CN 201710231110 A CN201710231110 A CN 201710231110A CN 108684680 A CN108684680 A CN 108684680A
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Prior art keywords
fluorine
bacterium amine
active constituent
bactericidal composition
suspending agent
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CN201710231110.2A
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杨会营
刘晓娇
马嵩岳
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Yanhua Yongle (leting) Biological Technology Co Ltd
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Yanhua Yongle (leting) Biological Technology Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A kind of bactericidal composition, contain active components A and active constituent B, wherein, active components A is fluorine indenes azoles bacterium amine, active constituent B is selected from fludioxonil, azoles mepanipyrim, cyprodinil, amisulbrom, fluorine thiazole pyrrole ethyl ketone, one or more of dimethomorph, and the weight ratio of active components A and active constituent B are 1:50~50:1, bactericidal composition of the present invention can be configured to the conventional formulations such as suspending agent, microemulsion, microcapsule suspending agent, suspension seed-coating agent, wettable powder, water dispersible granules, dispersible oil-suspending agent.The present invention is higher to most of diseases controls in various crop, and bactericidal effect is notable, wide sterilization spectrum, has apparent synergistic effect, to crop safety.

Description

A kind of bactericidal composition
Technical field
The invention belongs to technical field of pesticide, are related to a kind of bactericidal composition of fluorine-containing indenes azoles bacterium amine.
Background technology
Fluorine indenes azoles bacterium amine chemical name:3- difluoromethyls-N- (the fluoro- 2,3- dihydros -1,1,3- trimethyls -1H- indenes -4- of 7- Base) -1- methyl-1 H- pyrazole-4-carboxamides, belong to wide spectrum SDHI series bactericidal agents, fungicidal spectrum covers all thifluzamides and Lu Na Gloomy fungicidal spectrum, in addition to Rhizoctonia solani special efficacy, all to anthrax, rust, early blight, powdery mildew, leaf mold, false smut preventive effect Very well.It will be high than Lu Nasen, green prince wife's activity especially in terms of powdery mildew.Structural formula is as follows:
Fludioxonil category wide spectrum, non-interior suction pyrroles series bactericidal agent, draw many pathogens such as sac fungus, basidiomycetes, Fungi Imperfecti The kind risen passes and soil-borne disease has extraordinary preventive effect, inhibits mycelia to give birth to by inhibiting the related transhipment of glucose phosphorylated It is long, eventually lead to germ death.Its unique mechanism of action does not have cross resistance with other known fungicide.Suitable for crop Wheat, barley, corn, pea, rape, rice, ornamental crops, hard fruit and vegetable Lay, grape and lawn etc., as foliage fungicide Rotten Fusariumsp, wheat net bunt bacterium, rhizoctonia solani etc. are avenged for preventing, has special efficacy to gray mold;As seed treatment:It is main It is used to prevent kind of biography and soil-borne disease bacterium such as Alternaria, Ascochyta, aspergillus, a Fusariumsp in cereal and fragrant-flowered garlic cereals crop Bits, long compacted spore bits, Rhizoctonia and Penicillium bacterium etc..
Azoles mepanipyrim is a kind of highly selective triazolo pyrimidine series bactericidal agent, belongs to mitochondrial respiratory inhibitor, can be efficient Neatly prevent downy mildew and late blight.The product resistance of rainwater washing against, can redistribute in blade, cover crop health at It is long, give full play to growth potential.
Cyprodinil chemical name:There is 4- cyclopropyl -6- Methyl-N-phenyl pyrimidine -2- amine protection, treatment, blade to wear Saturating and root systemic activity is mainly used for preventing gray mold, powdery mildew, scab, net blotch, glume blight and wheat eyeprint disease Deng, to crop safety, no poisoning.
Amisulbrom chemical name:3- (the fluoro- 2 methyl indole -1- bases sulfonyls of the bromo- 6- of 3-)-N, N- dimethyl -1H- 1,2,4- triazole -1- sulfonamide, is the triazolylsulfonamide series bactericidal agent of Japanese Nissan exploitation, and amisulbrom is sterilized for contact killing type Agent has certain osmotically active and good resistance of rainwater washing against ability, has very high activity to epidemic disease and downy mildew, especially It is very high to germ spore activity of dissociating, can inhibit fungi breathing and spore germination, be a medicament aimed at prevention.Indazole Flusulfamide is mainly used for preventing potato blight, downy mildew of garpe, cucurbit downy mildew and brassica vegetable clubroot etc..
Fluorine thiazole pyrrole ethyl ketone chemical name 1- (4- { 4-[(5RS) -5- (2,6- difluorophenyls) -4,5- dihydro -1,2- Evil Azoles -3- Jis ]- 1,3- thiazol-2-yls } -1- piperidyls) -2-[5- methyl -3- (trifluoromethyl) -1H- Bi Zuo-1-Jis ]Ethyl ketone is The newly developed first piperidyl thiazole isoxazoline series bactericidal agent of E.I.Du Pont Company.Fluorine thiazole pyrrole ethyl ketone has very favorable toxicity Learn and environmental characteristics, dosage is also few, higher to the safety of user, agricultural producer and environment, to cause potato and kind The phytophthora infestans of eggplant blight are efficient.Fluorine thiazole pyrrole ethyl ketone activity is high, effective to phytophthora infestans each stage of development, can be in host Long range transporting in plant can effectively prevent late blight under conditions of extremely severe.
Dimethomorph is a kind of therapeutic special less toxic fungicide of novel interior suction, and mechanism of action is to destroy germ cell wall The formation of film, causes the decomposition of spore cyst wall, and keeps germ dead.In addition to zoospore formation and spore swarm stage, to oomycetes There is effect in each stage of the history of life, especially more sensitive to the formation stages of sporangiophore and egg spore, if in sporangium and Egg spore forms preceding medication, then can completely inhibit the generation of spore.The medicine absorbability is strong, and root application can be entered by root Each position of plant;Blade sprays, and can enter blade interior.
Since various regions pesticide abuse causes resistance increasing, the lasting raising of pesticide dosage.However larger dose is indiscriminate With pesticide, cause to make havoc of environment, does not also play due effect well.Pass through our a large amount of field efficacies Experiment finds that using with for different pesticide species can be very good the generation of delaying drug resistance, drug effect be improved, to reduce pesticide Usage amount.
Have patent document by access, there is no this report at present, two kinds of different pesticides is compounded, not only to environment Close friend, can also complementary drawback greatly improve drug effect, lasting period and prevention spectrum, therefore also significantly reduce cost.
Invention content
The object of the present invention is to provide a kind of efficient, wide spectrum, safety and environmental protection extends the lasting period, reduces killing for labour cost Bacteria composition.
Above-mentioned bactericidal composition, active components A are fluorine indenes azoles bacterium amine, and active constituent B is selected from fludioxonil, azoles mepanipyrim, phonetic One or several kinds in collarium amine, amisulbrom, fluorine thiazole pyrrole ethyl ketone, dimethomorph, active components A and active constituent B Weight ratio be 1:50~50:1, preferred weight ratio 1:30~30:1, more preferable weight ratio is 1:20~20:1.
Using bactericidal composition of the present invention, it is equipped with auxiliary agent known to a person skilled in the art, in the art Dosage form according to the present invention is made in method well known to technical staff:Suspending agent, microemulsion, microcapsule suspending agent, suspended seed coating Agent, wettable powder, water dispersible granules, dispersible oil-suspending agent.
Above-mentioned bactericidal composition is suitable for crop disease control, can be used for preventing powdery mildew, downy mildew, scab, leaf Pinta, rice blast, banded sclerotial blight, late blight, damping-off, rot disease, spot defoliation, gray mold, head blight etc..
Above-mentioned bactericidal composition has the characteristics that:1. fluorine indenes azoles bacterium amine belongs to novel environment friendly fungicide, bactericidal effect is strong, Two kinds of fungicide modes of action have complementarity;2. the occupation mode diversification of preparation, expands prevention and treatment range, has and increase well Effect acts on;3. two kinds of ingredients are without apparent cross resistance, active ingredient is novel, and the mode of action is unique;4. reduce labor intensity and Drug cost reduces the pollution to environment.
Specific implementation mode
It is active using indoor biological for verification active components A and the synergistic effect after active constituent B compoundings in the present invention With two methods of field control effectiveness test, the two kinds of test methods used are described individually below.Wherein, active constituent A is fluorine indenes azoles bacterium amine, and active constituent B is fludioxonil, azoles mepanipyrim, cyprodinil, amisulbrom, fluorine thiazole pyrrole ethyl ketone, alkene Morpholide.
Experiment one:The indoor biometrics experiment of fluorine indenes azoles bacterium amine and fludioxonil compounding.The subjects of indoor biometrics are rice Bakanae disease germ.Reference"Farm-chemical indoor determination test rule fungicide"It carries out, calculates each medicament to pathogen EC50, compare the virulence and bacteriostasis of different agents.
The co-toxicity of mixture preparation is indicated using the co-toxicity coefficient method of Sun Yunpei:
Mixture preparation survey toxicity index
The mixture preparation theoretical toxicity index TTI=∑s (pharmaceutically active ingredient of the toxicity index ATI of certain medicine × in mixture Percentage).
The co-toxicity coefficient of mixture preparation
Co-toxicity coefficient CTC is synergistic effect when being more than 120, is antagonism when being less than 80, is when between 80~120 Addition.
1 fluorine indenes azoles bacterium amine of table is with fludioxonil different ratio to the measurement result of bakanae disease of rice germ co-toxicity coefficient
As can be seen from Table 1, when fluorine indenes azoles bacterium amine and fludioxonil compound in varing proportions, the co-toxicity coefficient of complex preparation (CTC) 120 are all higher than, there is the synergistic effect of different proportion to the prevention of bakanae disease of rice, when fluorine indenes azoles bacterium amine and fludioxonil 1:20~20:When 1, co-toxicity coefficient (CTC) is all higher than 134, and synergistic effect is more notable.
Experiment two:The indoor biometrics experiment of fluorine indenes azoles bacterium amine and azoles mepanipyrim compounding, subjects are cucumber downy mildew disease Bacterium.Reference"Farm-chemical indoor determination test rule fungicide"It carries out, calculates EC of each medicament to pathogen50, than less With the virulence and bacteriostasis of medicament.
2 fluorine indenes azoles bacterium amine of table is with azoles mepanipyrim different ratio to the measurement result of cucumber downy mildew germ co-toxicity coefficient
As can be seen from Table 2, when fluorine indenes azoles bacterium amine and azoles mepanipyrim compound in varing proportions, the total poison system of complex preparation Number (CTC) is all higher than 120, has the synergistic effect of different proportion to the prevention of cucumber downy mildew, when fluorine indenes azoles bacterium amine and azoles are phonetic Bacterium amine is 1:20~20:When 1, co-toxicity coefficient (CTC) is all higher than 132, and synergistic effect is more notable.
Experiment three:The indoor biometrics experiment of fluorine indenes azoles bacterium amine and cyprodinil compounding, subjects are grape grey mould disease Bacterium, reference"Farm-chemical indoor determination test rule fungicide"It carries out, calculates EC of each medicament to pathogen50, than less With the virulence and bacteriostasis of medicament.
3 fluorine indenes azoles bacterium amine of table is with cyprodinil different ratio to the measurement result of grape grey mould germ co-toxicity coefficient
As can be seen from Table 3, when fluorine indenes azoles bacterium amine and cyprodinil compound in varing proportions, the total poison system of complex preparation Number (CTC) is all higher than 120, has the synergistic effect of different proportion to the prevention of grape grey mould, when fluorine indenes azoles bacterium amine and phonetic bacterium Cyclammonium is 1:20~20:When 1, co-toxicity coefficient (CTC) is all higher than 134, and synergistic effect is more notable.
Experiment four:The indoor biometrics experiment of fluorine indenes azoles bacterium amine and amisulbrom compounding, subjects are potato late blight Germ.Reference"Farm-chemical indoor determination test rule fungicide"It carries out, calculates EC of each medicament to pathogen50, than Compared with the virulence and bacteriostasis of different agents.
4 fluorine indenes azoles bacterium amine of table is with amisulbrom different ratio to the measurement result of late blight of potato germ co-toxicity coefficient
As can be seen from Table 4, when fluorine indenes azoles bacterium amine and amisulbrom compound in varing proportions, the total poison of complex preparation Coefficient (CTC) is all higher than 120, there is the synergistic effect of different proportion to the prevention of the late blight of potato, when fluorine indenes azoles bacterium amine and Amisulbrom is 1:20~20:When 1, co-toxicity coefficient (CTC) is all higher than 133, and synergistic effect is more notable.
Experiment five:The indoor biometrics experiment of fluorine indenes azoles bacterium amine and fluorine thiazole pyrrole ethyl ketone compounding, subjects are potato evening Epidemic disease germ.Reference"Farm-chemical indoor determination test rule fungicide"It carries out, calculates EC of each medicament to pathogen50, Compare the virulence and bacteriostasis of different agents.
5 fluorine indenes azoles bacterium amine of table is with fluorine thiazole pyrrole ethyl ketone different ratio to the measurement knot of late blight of potato germ co-toxicity coefficient Fruit
As can be seen from Table 5, when fluorine indenes azoles bacterium amine and fluorine thiazole pyrrole ethyl ketone compound in varing proportions, complex preparation is total to Malicious coefficient (CTC) is all higher than 120, there is the synergistic effect of different proportion to the prevention of the late blight of potato, when fluorine indenes azoles bacterium amine With fluorine thiazole pyrrole ethyl ketone 1:20~20:When 1, co-toxicity coefficient (CTC) is all higher than 134, and synergistic effect is more notable.
Experiment six:The indoor biometrics experiment of fluorine indenes azoles bacterium amine and dimethomorph compounding, subjects are cucumber downy mildew disease Bacterium.Reference"Farm-chemical indoor determination test rule fungicide"It carries out, calculates EC of each medicament to pathogen50, than less With the virulence and bacteriostasis of medicament.
6 fluorine indenes azoles bacterium amine of table is with dimethomorph different ratio to the measurement result of cucumber downy mildew germ co-toxicity coefficient
As can be seen from Table 6, when fluorine indenes azoles bacterium amine and dimethomorph compound in varing proportions, the total poison system of complex preparation Number (CTC) is all higher than 120, has the synergistic effect of different proportion to the prevention of cucumber downy mildew, wherein fluorine indenes azoles bacterium amine and alkene The proportioning of morpholide is 1:20~20:When 1, co-toxicity coefficient (CTC) is all higher than 133, and synergistic effect is more notable.
It can be seen that after active components A and active constituent B compoundings by the above raw test, drug effect increases, There is good synergistic effect after the two compounding.
It being further illustrated the present invention below by specific embodiment, the following examples are not limitations of the present invention, Only further supplement.Percentage is weight percentage in formula, and used active compound and auxiliary agent are that other producers carry For.
Embodiment 1 (30% fluorine indenes azoles bacterium amine fludioxonil suspension seed-coating agent)
Embodiment 2 (25% fluorine indenes azoles bacterium amine fludioxonil suspension seed-coating agent)
Embodiment 3 (11% fluorine indenes azoles bacterium amine fludioxonil suspension seed-coating agent)
Embodiment 4 (18% fluorine indenes azoles bacterium amine fludioxonil suspension seed-coating agent)
Embodiment 5 (21% fluorine indenes azoles bacterium amine azoles mepanipyrim suspending agent)
Embodiment 6 (22% fluorine indenes azoles bacterium amine azoles mepanipyrim suspending agent)
Embodiment 7 (30% fluorine indenes azoles bacterium amine azoles mepanipyrim suspending agent)
Embodiment 8 (21% fluorine indenes azoles bacterium amine azoles mepanipyrim suspending agent)
Embodiment 9 (31% fluorine indenes azoles bacterium amine cyprodinil suspending agent)
Embodiment 10 (25.5% fluorine indenes azoles bacterium amine cyprodinil suspending agent)
Embodiment 11 (32% fluorine indenes azoles bacterium amine cyprodinil water dispersible granule)
Embodiment 12 (32% fluorine indenes azoles bacterium amine cyprodinil water dispersible granule)
Embodiment 13 (20% fluorine indenes azoles bacterium amine amisulbrom suspending agent)
Embodiment 14 (24% fluorine indenes azoles bacterium amine amisulbrom water dispersible granules)
Embodiment 15 (25.5% fluorine indenes azoles bacterium amine amisulbrom suspending agent)
Embodiment 16 (the 15% dispersible oil-suspending agent of fluorine indenes azoles bacterium amine fluorine thiazole pyrrole ethyl ketone)
Embodiment 17 (the 10% dispersible oil-suspending agent of fluorine indenes azoles bacterium amine fluorine thiazole pyrrole ethyl ketone)
Embodiment 18 (the 15.5% dispersible oil-suspending agent of fluorine indenes azoles bacterium amine fluorine thiazole pyrrole ethyl ketone)
Embodiment 19 (33% fluorine indenes azoles bacterium amine dimethomorph water dispersion granula)
Embodiment 20 (30% fluorine indenes azoles bacterium amine dimethomorph suspending agent)
Select above example to carry out field trial, verification complex preparation to the control effect of crop, while by with work Property ingredient A and active constituent B single doses carry out Contrast on effect, the synergistic effect of preparation after verification compounding.Comparison medicament includes:5% Fluorine indenes azoles bacterium amine suspension seed-coating agent (dosage form English name:FS), 5% fluorine indenes azoles bacterium amine suspending agent (dosage form English name:SC), 25g/L fludioxonils suspension seed-coating agent (dosage form English name:FS), 25% azoles mepanipyrim suspending agent (dosage form English name:SC), 50% cyprodinil water dispersible granule (dosage form English name:WDG), 18% amisulbrom suspending agent (dosage form English name: SC), 10% fluorine thiazole pyrrole ethyl ketone dispersible oil-suspending agent (dosage form English name:OD), 50% dimethomorph wettable powder (agent Type English name:WP).
Experiment seven:Fluorine indenes azoles bacterium amine and active constituent B complex preparations and the field medicine of different agents prevention bakanae disease of rice Effect experiment, reference"Field control effectiveness test criterion"Carry out field control effectiveness test and evaluating drug effect.
Computational methods:According to sick seedling number survey data, the diseased plant rate and control effect of each processing are calculated.
7 fluorine indenes azoles bacterium amine of table and active constituent B complex preparations and the test result of different agents prevention bakanae disease of rice
It is seen from the above data that complex preparation before transplanting to the preventive effect of bakanae disease of rice more than 87%, taking out To the preventive effect of bakanae disease of rice more than 90% before fringe, single dose is compared, there is good synergistic effect after compounding, extend holding effect It is phase, more longlasting to the control effect of bakanae disease of rice.
Experiment eight:Fluorine indenes azoles bacterium amine prevents cucumber downy mildew field efficacy with active constituent B complex preparations and different agents Experiment, reference"Field control effectiveness test criterion"Carry out field control effectiveness test and evaluating drug effect.
Computational methods:According to Disease investigation data, the disease index and control effect of each processing are calculated.
The test result of 8 fluorine indenes azoles bacterium amine of table and active constituent B complex preparations and different agents prevention cucumber downy mildew
It is seen from the above data that 7 days preventive effects to cucumber downy mildew are more than 86% after medicine for complex preparation, in medicine 14 days preventive effects to cucumber downy mildew compare single dose, have good synergistic effect after compounding, extend and hold more than 89% afterwards It is the effect phase, more longlasting to the control effect of powdery mildew of cucumber.
Experiment nine:Fluorine indenes azoles bacterium amine prevents grape grey mould field efficacy with active constituent B complex preparations and different agents Experiment, reference"Field control effectiveness test criterion"Carry out field control effectiveness test and evaluating drug effect.
Computational methods:According to Disease investigation data, the disease index and control effect of each processing are calculated.
The test result of 9 fluorine indenes azoles bacterium amine of table and active constituent B complex preparations and different agents prevention grape grey mould
It is seen from the above data that 7 days preventive effects to grape grey mould are more than 85% after medicine for complex preparation, in medicine 14 days preventive effects to grape grey mould compare single dose, have good synergistic effect after compounding, extend and hold more than 89% afterwards It is the effect phase, more longlasting to the control effect of grape grey mould.
Experiment ten:Fluorine indenes azoles bacterium amine and active constituent B complex preparations and different agents prevention late blight of potato field medicine Effect experiment, reference"Field control effectiveness test criterion"Carry out field control effectiveness test and evaluating drug effect.
Computational methods:According to Disease investigation data, the disease index and control effect of each processing are calculated.
10 fluorine indenes azoles bacterium amine of table prevents late blight of potato test result with active constituent B complex preparations and different agents
It is seen from the above data that complex preparation after medicine 7 days preventive effects to the late blight of potato more than 86%, 14 days preventive effects to the late blight of potato compare single dose, have good synergistic effect after compounding, extend more than 89% after medicine It is lasting period, to the control effect of the late blight of potato more longlasting.
In conclusion bactericidal composition of the present invention is applied in crops, can not only controlling disease, improve drug effect, prolong The long lasting period, and mitigate the amount of labour of peasant, reduce cost.The present invention can implement and unobvious violate the present invention premise Under, it can carry out arbitrary form combination between technical characteristic described in different technologies scheme and form other technologies scheme.More than Specific implementation mode and embodiment are that invention is explained in detail, but is not defined to the scope of the present invention, It modifies and replaces in the principle without departing from claim, be within the scope of protection of the invention interior.

Claims (5)

1. a kind of bactericidal composition, it is characterised in that:Containing active components A and active constituent B, the active components A is fluorine indenes Azoles bacterium amine, active constituent B are selected from fludioxonil, azoles mepanipyrim, cyprodinil, amisulbrom, fluorine thiazole pyrrole ethyl ketone, dimethomorph One or more of, the weight ratio of active components A and active constituent B are 1:50~50:1.
2. bactericidal composition according to claim 1, it is characterised in that:Active components A and the weight ratio of active constituent B are 1:30~30:1.
3. bactericidal composition according to claim 1, it is characterised in that:Active components A and the weight ratio of active constituent B are 1:20~20:1.
4. bactericidal composition according to claim 1, it is characterised in that:Suspending agent, micro- is made by active constituent and auxiliary material Emulsion, microcapsule suspending agent, suspension seed-coating agent, wettable powder, water dispersible granules, dispersible oil-suspending agent.
5. bactericidal composition according to claim 1, for preventing powdery mildew, downy mildew, scab, leaf spot, rice blast Disease, banded sclerotial blight, late blight, damping-off, rot disease, spot defoliation, gray mold, head blight etc..
CN201710231110.2A 2017-04-10 2017-04-10 A kind of bactericidal composition Pending CN108684680A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023180909A1 (en) * 2022-03-22 2023-09-28 Upl Limited An agrochemical composition

Citations (2)

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Publication number Priority date Publication date Assignee Title
CN103502220A (en) * 2010-12-20 2014-01-08 I-F产品协作基金会 Aminoindanes amides having a high fungicidal activity and phytosanitary compositions thereof
CN104602523A (en) * 2012-06-15 2015-05-06 I-F产品协作基金会 Synergistic compositions for the protection of agrarian crops and the use thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103502220A (en) * 2010-12-20 2014-01-08 I-F产品协作基金会 Aminoindanes amides having a high fungicidal activity and phytosanitary compositions thereof
CN104602523A (en) * 2012-06-15 2015-05-06 I-F产品协作基金会 Synergistic compositions for the protection of agrarian crops and the use thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023180909A1 (en) * 2022-03-22 2023-09-28 Upl Limited An agrochemical composition

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Application publication date: 20181023