US20150239637A1 - Packaging for a product comprising at least one hygroscopic flowable solid - Google Patents

Packaging for a product comprising at least one hygroscopic flowable solid Download PDF

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Publication number
US20150239637A1
US20150239637A1 US14/416,013 US201314416013A US2015239637A1 US 20150239637 A1 US20150239637 A1 US 20150239637A1 US 201314416013 A US201314416013 A US 201314416013A US 2015239637 A1 US2015239637 A1 US 2015239637A1
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US
United States
Prior art keywords
product
desiccant
transport container
packaging
moisture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US14/416,013
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English (en)
Inventor
Ralf Kranz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merck Patent GmbH
Original Assignee
Merck Patent GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR1257772A external-priority patent/FR2993545B3/fr
Priority claimed from DE202012007804U external-priority patent/DE202012007804U1/de
Application filed by Merck Patent GmbH filed Critical Merck Patent GmbH
Priority to US14/416,013 priority Critical patent/US20150239637A1/en
Assigned to MERCK PATENT GMBH reassignment MERCK PATENT GMBH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KRANZ, RALF
Publication of US20150239637A1 publication Critical patent/US20150239637A1/en
Abandoned legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • B65D81/26—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
    • B65D81/266—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants
    • B65D81/268—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants the absorber being enclosed in a small pack, e.g. bag, included in the package
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D33/00—Details of, or accessories for, sacks or bags
    • B65D33/16—End- or aperture-closing arrangements or devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D77/00—Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
    • B65D77/04—Articles or materials enclosed in two or more containers disposed one within another

Definitions

  • the invention relates to packaging for a product comprising at least one hygroscopic flowable solid, where the packaging has a sealable product bag made from a moisture-permeable material for the accommodation of the product, a transport container surrounding the product bag, and a desiccant which is arranged outside the product bag and inside the transport container.
  • hygroscopic flowable solids such as, for example, pulverulent substances
  • Numerous different types of packaging for this purpose are known from practice.
  • the product or the chemical substance is introduced into a sealable product bag for protection against contamination and subsequently introduced into a transport container.
  • the transport container can be, for example, a drum or a crate.
  • a desiccant in the transport container, which absorbs and stores moisture present in the transport container.
  • the desiccant is usually arranged in a bag or in a plurality of bags. These desiccant-filled desiccant bags are placed in the transport container either before or after the product-filled product bag.
  • WO 2003/004380 A2 describes packaging in which a plurality of bags filled with a desiccant are arranged in an interspace between the product bag and the transport container.
  • the desiccant bags are fixed in the region of a sealable opening of the product-filled product bag, for example by means of bands or loops.
  • the effort necessary for this purpose is considerable.
  • the desiccant bags can be arranged and fixed in the region of the opening of the product-filled product bag, they cannot be arranged and fixed at any desired place in the product bag or within the transport container without major effort.
  • a drying wrapping which can be detached from the transport container and is made from a moisture-impermeable material which surrounds the product bag containing the product is arranged in the transport container, and in that the desiccant is arranged on an inside of the drying wrapping facing the product bag containing the product. Due to the use of a drying wrapping, the arrangement of the desiccant inside the transport container or in the vicinity of the product bag containing the product can be pre-specified independently of the product bag used for the accommodation of the product and independently of the transport container. Expensive and complex modifications of the transport container are not necessary. It is equally unnecessary to attach the desiccant to the product bag or in the closure region of the product bag after the product bag has been filled with the product and the product bag has subsequently been sealed.
  • drying wrapping which can subsequently be placed in a transport container which is already present enables the transport containers which are already present to be retrofitted and used for the transport of hygroscopic products. Since the drying wrapping can be used with various transport containers, existing distribution systems with the corresponding transport containers can be retained unchanged. The additional cost for the acquisition and use of the drying wrapping is extremely low.
  • the drying wrapping can be designed to be re-usable and can remain in the transport container after the product bag containing the product is removed, so that the drying wrapping continues to be available for re-use of the transport container. It is likewise possible to produce and intend the drying wrapping for a single use and to design it as a disposable product.
  • a product bag which consists of a moisture-permeable material enhances the action of the desiccant. Should residues of moisture be present in the product bag or in the product located therein or accumulate after opening and re-sealing of the product bag, this moisture is transported through the moisture-permeable product bag into the interspace between the product bag and the surrounding drying wrapping, where it can be absorbed and bound by the desiccant.
  • the desiccant is arranged in at least one desiccant bag which is fixed to an inside of the drying wrapping.
  • Desiccant bags of this type are commercially and inexpensively available in numerous variants and shapes for different desiccants.
  • the desiccant bag can be fixed to the drying wrapping simply and reliably, for example by welding, adhesive bonding or sewing.
  • a plurality of desiccant bags are advantageously fixed to the drying wrapping at a separation from one another in order to favour the absorption of moisture by the desiccant located in the desiccant bags and in order to prevent the desiccant from concentrating in a small region within the transport container and the moisture not being absorbed or only being absorbed to a small extent in other regions.
  • the at least one desiccant bag is covered and fixed by a moisture-permeable covering on the inside of the drying wrapping.
  • the moisture-permeable covering may be perforated and made from the same moisture-impermeable material as the drying wrapping. If the drying wrapping consists, for example, of a film, the desiccant bags can be arranged in pockets produced by multiple turning-over and subsequent fixing, or adhesive bonding or welding of the pockets of the drying wrapping formed in this way.
  • the drying wrapping is matched to the shape of the transport container.
  • the drying wrapping can be placed in the interior of the transport container and can form an inner lining of the transport container. Due to the matching of the drying wrapping to the shape of the transport container, the arrangement of the drying wrapping in the transport container or relative to the transport container can be pre-specified and the position of the desiccant bags fixed to the drying wrapping in the interior or on the walls of the transport container can thus be pre-determined. Due to the drying wrapping lying against the transport container, the filling of the transport container with the product bag which is itself filled with the product does not become more difficult.
  • drying wrapping it is likewise conceivable and advantageous for individual applications for the drying wrapping to be matched to the shape of the product bag.
  • the product-filled product bag can then be introduced into the drying wrapping, with the arrangement of the desiccant or the individual desiccant bags relative to the filled product bag being pre-specified. In this way, a highly uniform distribution of the desiccant on the product bag and thus in the immediate vicinity of the product can also be ensured for the case where the filled product bag only occupies a part-region of the transport container and its position and shape within the transport container frequently change during transport.
  • the desiccant only to be arranged in a region of the drying wrapping facing an opening of the transport container.
  • an unused volume usually remains in the region of the opening of the transport container.
  • air which generally has a moisture content, is located in this volume.
  • the arrangement of the desiccant in this region facilitates effective dehumidification of the air present in the transport container.
  • fresh and moist air flows into the transport container each time the transport container is opened, for example for successive and gradual removal of the product. This air accumulates in the region close to the opening, where it can be effectively dehumidified.
  • the desiccant may be advantageous to arrange the desiccant distributed over the entire inside of the drying wrapping.
  • a relatively large number of desiccant bags can be fixed to the drying wrapping distributed at regular or alternatively irregular separations over the inside of the drying wrapping. Irrespective of the shape of the product-filled product bag and independently of the amount of product remaining in the transport container after partial removal, it can thus be ensured that a plurality of desiccant bags are arranged at a separation from one another in the vicinity of the product bag.
  • the product bag is a textile nonwoven made from thermally welded high density polyethylene (HDPE) fibres.
  • HDPE thermally welded high density polyethylene
  • a nonwoven material of this type is already extensively employed in practice. Besides high permeability to moisture and air, the advantageous properties of a nonwoven material of this type also include high tear strength and straightforward use together with numerous hygroscopic products from the chemical industry or pharmaceutical industry.
  • a particularly inexpensive and at the same time effective and moisture-impermeable drying wrapping consists of a thin polyethylene wrapping or film, or comprises a thin polyethylene wrapping of this type as coating or individual layer of the drying wrapping.
  • the individual desiccant bags are covered and fixed by a covering on the inside of the drying wrapping, where this covering may likewise consist of a thin polyethylene film, which is moisture-permeable owing to a perforation.
  • FIG. 1 shows a sectional view of packaging with a transport container, with a drying wrapping arranged in the transport container, and with a product-filled product bag,
  • FIG. 2 shows a sectional view of another packaging in which the drying wrapping surrounds and lies closely against the product-filled product bag
  • FIG. 3 shows a sectional view of yet another embodiment of packaging, in which the drying wrapping lying against the transport container has a plurality of desiccant bags which are fixed laterally to the drying wrapping by a perforated covering.
  • Packaging 1 depicted by way of example in FIG. 1 , has a sealable product bag 2 , which is filled with a flowable hygroscopic product 3 .
  • the product bag 2 consists of a moisture-permeable nonwoven material made from high density polyethylene (HDPE) fibres.
  • the hygroscopic product 3 can be, for example, a chemical substance which is required for the production of end products in the chemical or pharmaceutical industry.
  • the sealable product bag 2 is arranged in a transport container 4 surrounding the product bag 2 .
  • the transport container 4 has a drum-like basic body 5 , which can be sealed by means of a lid.
  • the transport container 4 consists of a moisture-impermeable material, for example polyethylene.
  • the lid 6 can be arranged and fixed on the basic body 5 in a moisture-tight manner by additional sealing elements 7 in order to seal the transport container 4 in a moisture-tight manner. If it appears necessary, the sealed transport container 4 can additionally be provided with a tamper-proof seal, for example in the form of a lead seal 8 .
  • a drying wrapping 10 matched to the shape of the transport container 4 is arranged in an interior 9 of the transport container 4 .
  • the drying wrapping 10 consists of a thin polyethylene film and is likewise designed to be moisture-impermeable.
  • a plurality of desiccant bags 13 are adhesively bonded to the inside 11 of the drying wrapping 10 in a region 12 of the drying wrapping 10 facing the lid 6 of the transport container 4 on an inside 11 of the drying wrapping 10 facing the product bag 2 with the product 3 located therein.
  • the desiccant bags 13 contain a suitable desiccant 14 , for example silica gel or zeolites, anhydrous sodium sulfate or magnesium sulfate.
  • Moisture present in the free interior 9 of the transport container 4 is absorbed and bound by the desiccant 14 in the desiccant bags 13 , which are arranged in this region 12 of the drying wrapping 10 . If residues of moisture are present in the product 3 , these are transported through the product bag 2 into the interior 9 of the transport container 4 , which is then dry, where they are likewise absorbed and bound by the desiccant 14 .
  • the shape of the drying wrapping 10 is matched to the shape of the product bag 2 , so that the drying wrapping 10 surrounds and lies closely against the filled product bag 2 .
  • a plurality of desiccant bags 13 are attached to the inside 11 of the drying wrapping 10 at regular separations.
  • the product bag 2 and the product 3 located therein are accordingly evenly dehumidified from all sides.
  • the shape of the surrounding transport container 4 is unimportant in this variant of the packaging 1 .
  • the shape of the drying wrapping 10 is matched to the shape of the transport container 4 , so that the drying wrapping 10 forms a lining of the side walls and base of the transport container.
  • the drying wrapping 10 can be placed in the transport container 4 before the introduction of the product bag 2 and does not hinder the subsequent introduction of the product bag 2 , even in a state already filled with the product.
  • the drying wrapping 10 has desiccant bags 13 , each containing a portion of the desiccant 14 , distributed over its side surfaces 15 .
  • Each individual desiccant bag 13 is covered by a covering 16 comprising a section of a polyethylene film matched thereto, and is fixed to the side surface 15 of the drying wrapping 10 .
  • the individual coverings 16 are each provided with a perforation 17 , so that the coverings are moisture-permeable in spite of the moisture-impermeable material polyethylene.
  • FIG. 1 , FIG. 2 and FIG. 3 For better understanding and in order to illustrate the invention, examples which fall within the scope of protection of the present invention are given in the drawings FIG. 1 , FIG. 2 and FIG. 3 .
  • the embodiments depicted may exist in modified variants. Owing to the general validity of the inventive principle described, the examples shown in the drawings are therefore not suitable for reducing the scope of protection of the present invention to these alone.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Food Science & Technology (AREA)
  • Packages (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
US14/416,013 2012-07-17 2013-07-05 Packaging for a product comprising at least one hygroscopic flowable solid Abandoned US20150239637A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US14/416,013 US20150239637A1 (en) 2012-07-17 2013-07-05 Packaging for a product comprising at least one hygroscopic flowable solid

Applications Claiming Priority (18)

Application Number Priority Date Filing Date Title
US201261672405P 2012-07-17 2012-07-17
EP12005230.3 2012-07-17
EP12005230 2012-07-17
FR1257772A FR2993545B3 (fr) 2012-07-17 2012-08-10 Emballage pour un produit avec au moins  une matiere solide  coulante hygroscopique.
FR1257772 2012-08-10
DE202012007804U DE202012007804U1 (de) 2012-08-14 2012-08-14 Verpackung für ein Produkt mit mindestens einem hygroskopischen rieselfähigen Feststoff
DE202012007804.6 2012-08-14
US13/586,098 US9428317B2 (en) 2012-07-17 2012-08-15 Package for a product with at least one hygroscopic pourable solid
ESU201230889 2012-08-21
ES201230889U ES1077680Y (es) 2012-07-17 2012-08-21 Embalaje para un producto con por lo menos un solido higroscopico de flujo libre
PLW.121296 2012-08-27
PL121296U PL67976Y1 (pl) 2012-07-17 2012-08-27 Opakowanie produktu z co najmniej jednym higroskopijnym, sypkim ciałem stałym
ATGM347/2012U AT13869U1 (de) 2012-07-17 2012-08-30 Verpackung für ein Produkt mit mindestens einem hygroskopischen rieselfähigen Feststoff
ATGM347/2012 2012-08-30
JP2012006065U JP3180382U (ja) 2012-07-17 2012-10-04 少なくとも１つの吸湿性で流動可能な固形物質を含む製品のための包装
JPJP2012-006065 2012-10-04
PCT/EP2013/001994 WO2014012633A1 (de) 2012-07-17 2013-07-05 Verpackung für ein produkt mit mindestens einem hygroskopischen rieselfähigen feststoff
US14/416,013 US20150239637A1 (en) 2012-07-17 2013-07-05 Packaging for a product comprising at least one hygroscopic flowable solid

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US13/586,098 Continuation-In-Part US9428317B2 (en) 2012-07-17 2012-08-15 Package for a product with at least one hygroscopic pourable solid

Publications (1)

Publication Number Publication Date
US20150239637A1 true US20150239637A1 (en) 2015-08-27

Family

ID=49950102

Family Applications (1)

Application Number Title Priority Date Filing Date
US14/416,013 Abandoned US20150239637A1 (en) 2012-07-17 2013-07-05 Packaging for a product comprising at least one hygroscopic flowable solid

Country Status (14)

Country Link
US (1) US20150239637A1 (https=)
EP (1) EP2874910B1 (https=)
JP (1) JP2015521981A (https=)
CN (1) CN104540748B (https=)
AR (1) AR092859A1 (https=)
CA (1) CA2879203C (https=)
DK (1) DK2874910T3 (https=)
ES (1) ES2628330T3 (https=)
HR (1) HRP20170867T1 (https=)
LT (1) LT2874910T (https=)
PL (1) PL2874910T3 (https=)
PT (1) PT2874910T (https=)
TW (1) TWI599523B (https=)
WO (1) WO2014012633A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140326621A1 (en) * 2013-05-03 2014-11-06 Au Optronics Corporation Carton
WO2017190036A1 (en) * 2016-04-29 2017-11-02 Avantor Performance Materials, Llc Packaging system for storage and shipment of solids
US20220081201A1 (en) * 2018-05-14 2022-03-17 Crown Products & Services, Inc. Moisture Prevention Packaging System and Method

Citations (8)

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US2524162A (en) * 1945-02-27 1950-10-03 Chavannes Marc Alfred Desiccant packaging
US4813791A (en) * 1987-09-18 1989-03-21 Multiform Desiccants, Inc. Bag with integral material treating packets
US6102198A (en) * 1997-05-22 2000-08-15 Mallinckrodt Inc. Bulk packaging system and method for retarding caking of organic and inorganic chemical compounds
US6308826B1 (en) * 1996-05-29 2001-10-30 Mallinckrodt Inc. Bulk packaging system and method for retarding caking of organic and inorganic chemical compounds
US6533405B1 (en) * 2001-12-18 2003-03-18 Hewlett-Packard Company Preserving inkjet print cartridge reliability while packaged
US20070084866A1 (en) * 2005-10-18 2007-04-19 Saeugling Kevin P Disposable bag with absorbent liner
US20130193007A1 (en) * 2012-01-28 2013-08-01 Honeywell International Inc. Packaging and methods of packaging particulate solids
US8528469B2 (en) * 2006-09-07 2013-09-10 Tuttoespresso S.P.A. Method and device for preservation of packaged beverage preparing product

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JPH0173113U (https=) * 1987-11-02 1989-05-17
JPH0474673U (https=) * 1990-11-14 1992-06-30
JP3409543B2 (ja) * 1994-12-26 2003-05-26 味の素株式会社 固結防止包装容器
JP4388683B2 (ja) * 2000-10-18 2009-12-24 協和発酵バイオ株式会社 包装容器および包装方法
DE10132251A1 (de) * 2001-07-04 2003-01-23 Honeywell Speciality Chemicals Verpackung für einen Feststoff
JP2003187967A (ja) * 2001-12-20 2003-07-04 Ulvac Japan Ltd 有機ｅｌ表示装置
JP2010006472A (ja) * 2008-05-26 2010-01-14 Kyocera Corp 太陽電池の梱包方法および該梱包方法により得られる梱包体

Patent Citations (8)

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Publication number Priority date Publication date Assignee Title
US2524162A (en) * 1945-02-27 1950-10-03 Chavannes Marc Alfred Desiccant packaging
US4813791A (en) * 1987-09-18 1989-03-21 Multiform Desiccants, Inc. Bag with integral material treating packets
US6308826B1 (en) * 1996-05-29 2001-10-30 Mallinckrodt Inc. Bulk packaging system and method for retarding caking of organic and inorganic chemical compounds
US6102198A (en) * 1997-05-22 2000-08-15 Mallinckrodt Inc. Bulk packaging system and method for retarding caking of organic and inorganic chemical compounds
US6533405B1 (en) * 2001-12-18 2003-03-18 Hewlett-Packard Company Preserving inkjet print cartridge reliability while packaged
US20070084866A1 (en) * 2005-10-18 2007-04-19 Saeugling Kevin P Disposable bag with absorbent liner
US8528469B2 (en) * 2006-09-07 2013-09-10 Tuttoespresso S.P.A. Method and device for preservation of packaged beverage preparing product
US20130193007A1 (en) * 2012-01-28 2013-08-01 Honeywell International Inc. Packaging and methods of packaging particulate solids

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140326621A1 (en) * 2013-05-03 2014-11-06 Au Optronics Corporation Carton
US9409693B2 (en) * 2013-05-03 2016-08-09 Au Optronics Corporation Carton
WO2017190036A1 (en) * 2016-04-29 2017-11-02 Avantor Performance Materials, Llc Packaging system for storage and shipment of solids
US20190135519A1 (en) * 2016-04-29 2019-05-09 Avantor Performance Materials, Llc Packaging system for storage and shipment of solids
CN109843743A (zh) * 2016-04-29 2019-06-04 安万托特性材料有限责任公司 用于储存和运送固体的包装系统
US11661258B2 (en) * 2016-04-29 2023-05-30 Avantor Performance Materials, Llc Packaging system for storage and shipment of solids
US20220081201A1 (en) * 2018-05-14 2022-03-17 Crown Products & Services, Inc. Moisture Prevention Packaging System and Method
US11745939B2 (en) * 2018-05-14 2023-09-05 Crown Products & Services, Inc. Moisture prevention packaging method

Also Published As

Publication number Publication date
EP2874910A1 (de) 2015-05-27
DK2874910T3 (en) 2017-07-03
CN104540748B (zh) 2017-02-22
CN104540748A (zh) 2015-04-22
WO2014012633A1 (de) 2014-01-23
PT2874910T (pt) 2017-06-26
CA2879203A1 (en) 2014-01-23
HRP20170867T1 (hr) 2017-09-08
PL2874910T3 (pl) 2017-07-31
LT2874910T (lt) 2017-05-10
JP2015521981A (ja) 2015-08-03
ES2628330T3 (es) 2017-08-02
TWI599523B (zh) 2017-09-21
EP2874910B1 (de) 2017-03-15
AR092859A1 (es) 2015-05-06
TW201420458A (zh) 2014-06-01
CA2879203C (en) 2020-06-30

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