US20140013815A1 - Method for manufacturing roll for reducing rolling, and roll for reducing rolling - Google Patents

Method for manufacturing roll for reducing rolling, and roll for reducing rolling Download PDF

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Publication number
US20140013815A1
US20140013815A1 US14/008,587 US201214008587A US2014013815A1 US 20140013815 A1 US20140013815 A1 US 20140013815A1 US 201214008587 A US201214008587 A US 201214008587A US 2014013815 A1 US2014013815 A1 US 2014013815A1
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United States
Prior art keywords
roll
reducing
ridge part
rolling
curvature
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Abandoned
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US14/008,587
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English (en)
Inventor
Ryutaro Ogata
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
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Nippon Steel and Sumitomo Metal Corp
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Assigned to NIPPON STEEL & SUMITOMO METAL CORPORATION reassignment NIPPON STEEL & SUMITOMO METAL CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: OGATA, Ryutaro
Publication of US20140013815A1 publication Critical patent/US20140013815A1/en
Abandoned legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B27/00Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
    • B21B27/02Shape or construction of rolls
    • B21B27/024Rolls for bars, rods, rounds, tubes, wire or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B17/00Tube-rolling by rollers of which the axes are arranged essentially perpendicular to the axis of the work, e.g. "axial" tube-rolling
    • B21B17/14Tube-rolling by rollers of which the axes are arranged essentially perpendicular to the axis of the work, e.g. "axial" tube-rolling without mandrel, e.g. stretch-reducing mills
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49544Roller making

Definitions

  • the present invention relates to a method for manufacturing a roll for reducing rolling, and a roll for reducing rolling. More particularly, it relates to a method for manufacturing a roll for reducing rolling, and the roll for reducing rolling, which roll is used on a three-roll type reducing-rolling mill for reducing-rolling steel pipes.
  • a reducing-rolling mill which is represented by a sizer or a stretch reducer, reducing-rolls a steel pipe to a predetermined outside diameter dimension.
  • a three-roll type reducing-rolling mill has been known mainly.
  • the three-roll type reducing-rolling mills are described, for example, in WO 2005/070574 and WO 2005/092531.
  • the reducing-rolling mill is usually provided with a plurality of stands arranged along the pass line.
  • Each of the stands includes a plurality of rolls for reducing rolling each having a groove for forming a pass (caliber).
  • three rolls are arranged at equal intervals around the pass line, and also are arranged so as to be shifted by 60 degrees around the pass line with respect to the three rolls included in the previous-stage stand.
  • the roll included in each stand of the reducing-rolling mill has a groove of an elliptical arc shape in the transverse cross section (the cross section in the direction perpendicular to the pass line, that is, the cross section including the roll axis).
  • the draft per one stand can be increased to some extent.
  • An objective of the present invention is to provide a method for manufacturing a roll for reducing rolling capable of suppressing the occurrence of fin flaws or edge flaws.
  • the method for manufacturing a roll for reducing rolling in accordance with an embodiment of the present invention is a method for manufacturing a roll for reducing rolling, which roll is used on a three-roll type reducing-rolling mill for reducing-rolling steel pipes, and includes a caliber part having a groove of an arched shape in transverse cross section and flange parts adjacent to the caliber part.
  • the method for manufacturing a roll for reducing rolling includes a step of preparing a roll for reducing rolling, and a step of rounding a ridge part formed in the adjacent portion between the caliber part and the flange part by cutting the ridge part while rotating the roll for reducing rolling around the roll axis.
  • the average of radiuses of curvature measured at a 0.5 mm pitch is made in the range of 2.5 to 3.0 mm, and the difference between the maximum value and the minimum value of the radiuses of curvature is made at most 1.0 mm.
  • a roll for reducing rolling capable of suppressing the occurrence of fin flaws or edge flaws can be manufactured.
  • the roll for reducing rolling in accordance with this embodiment is used on a three-roll type reducing-rolling mill for reducing-rolling steel pipes.
  • the roll for reducing rolling includes a caliber part having a groove of an arched shape in transverse cross section, and flange parts adjacent to the caliber part.
  • the average of radiuses of curvature measured at a 0.5 mm pitch is in the range of 2.5 to 3.0 mm, and the difference between the maximum value and the minimum value of the radiuses of curvature is at most 1.0 mm.
  • the roll for reducing rolling in accordance with this embodiment can suppress the occurrence of fin flaws or edge flaws.
  • FIG. 1 is a side view of a three-roll type reducing-rolling mill.
  • FIG. 2 is a front view of a stand in FIG. 1 .
  • FIG. 3 is a front view of a stand at the previous stage of the stand shown in FIG. 2 .
  • FIG. 4 is a schematic view of a reducing rolling operation of a steel pipe performed by using the three-roll type reducing-rolling mill shown in FIG. 1 .
  • FIG. 5 is a front view of a roll for reducing rolling in FIG. 1 .
  • FIG. 6 is an enlarged view of the vicinity of a ridge part of the roll for reducing rolling shown in FIG. 5 .
  • FIG. 7 is a schematic view of a turning machine used for manufacturing the roll for reducing rolling shown in FIG. 5 .
  • FIG. 8 is an enlarged view of the vicinity of a ridge part of the roll for reducing rolling cut by the turning machine shown in FIG. 7 .
  • FIG. 9 is a schematic view for explaining a method for measuring the radius of curvature of the ridge part shown in FIG. 8 .
  • FIG. 10 is a view showing one example of a method for measuring the radius of curvature of the ridge part shown in FIG. 8 .
  • FIG. 11 is a sectional view of a cold-setting resin in FIG. 10 .
  • FIG. 12 a chart showing measurement results of the shapes and the radiuses of curvature of the rolls used in Examples.
  • FIG. 1 is a side view of a reducing-rolling mill 1 in accordance with the embodiment of the present invention.
  • This reducing-rolling mill 1 is of a three-roll type.
  • the reducing-rolling mill 1 is provided with a plurality of stands ST 1 to STm (m is a natural number) arranged along a pass line RA.
  • the reducing-rolling mill 1 is, for example, a stretch reducer, and the number m of stands is about 20 to 30.
  • FIG. 2 is a front view of a stand STi (i is a natural number not larger than m) of the reducing-rolling mill 1 shown in FIG. 1
  • FIG. 3 is a front view of a stand STi ⁇ 1.
  • each stand STi includes three rolls for reducing rolling (hereinafter, referred simply to as rolls) 11 .
  • the three rolls 11 are arranged at equal angular intervals around the pass line RA. Therefore, the three rolls 11 are arranged at angular intervals of 120 degrees around the pass line RA.
  • Each of the rolls 11 has a groove 20 whose transverse cross section (cross section in the roll axis direction) takes an arched shape.
  • the groove 20 of each of the three rolls 11 forms a caliber PA.
  • the three rolls 11 included in the stand STi are arranged so as to be shifted by 60 degrees around the pass line RA with respect to the three rolls 11 included in the previous-stage stand STi ⁇ 1.
  • each stand STi The three rolls of each stand STi are connected to each other by a bevel gear, not shown. By the rotation of one of the three rolls 11 made by a motor, not shown, all of the rolls 11 are rotated.
  • the cross-sectional area of the caliber PA formed by the three rolls 11 of each stand STi decreases in the subsequent stand. Therefore, the caliber PA formed at the stand ST 1 has the largest cross-sectional area, and the caliber PA formed at the rearmost stand STm has the smallest cross-sectional area.
  • a steel pipe is reducing-rolled by passing through from the stand ST 1 to the stand STm along the pass line RA, and by the reducing rolling, a steel pipe having a predetermined outside diameter and wall thickness is produced.
  • the roll 11 included in the stand STi has the shape shown in FIG. 5 .
  • the roll 11 includes a caliber part 50 and a pair of flange parts 51 .
  • the caliber part 50 is of a columnar shape, and has a groove 20 having an arched transverse cross section on the surface thereof.
  • the flange part 51 is of a disc shape, and is arranged coaxially with the caliber part 50 .
  • the flange part 51 has a frusto-conical shape in which the width decreases toward the direction of separating from the caliber part 50 .
  • the caliber part 50 and the flange parts 51 are formed as a single unit.
  • the transverse shape of the groove 20 that is, the shape of the groove 20 in the cross section in the roll axis direction X of the roll 11 is an arched one.
  • the groove 20 is of a circular arc shape having a radius Ra 1 .
  • the line segment DB connecting a groove bottom (the center in the roll axis direction of the groove 20 ) GB of the groove 20 to the pass line RA is shorter than the radius Ra 1 . Therefore, the transverse shape of the groove 20 is of an elliptical arc shape in which the line segment DB is a semiminor axis. Since the transverse shape of the groove 20 is an elliptical arc, the draft per one stand can be increased to some extent.
  • FIG. 6 is an enlarged view of the vicinity of the ridge part 52 shown in FIG. 5 .
  • the ridge part 52 extends in the circumferential direction of the roll 11 . Also, the ridge part 52 is rounded.
  • the above-described reducing-rolling mill 1 produces a thin-wall steel pipe by means of reducing rolling.
  • the thin-wall steel pipe has a wall thickness of, for example, 2.0 to 3.0 mm, and an outside diameter of, for example, 30.0 to 100.0 mm.
  • a fin flaw or an edge flaw occurs easily.
  • the edge flaw described herein means a linear flaw formed along the longitudinal direction on the surface of a steel pipe by the hollowing of the near-surface portion of steel pipe caused by the ridge part of roll.
  • the reason why the fin flaw or the edge flaw occurs easily on the thin-wall steel pipe is presumed to be that since the wall thickness is small, a portion of the steel pipe being rolled which portion comes into contact with the edge vicinity portion of the groove 20 (hereinafter, referred to as a metal portion) flows easily to the roll axis direction X.
  • the roll 11 By manufacturing the roll 11 based on the manufacturing method described below, especially when a thin-wall steel pipe is produced, the occurrence of fin flaws or edge flaws is suppressed. In the following, the method for manufacturing the roll 11 is described in detail.
  • FIG. 7 is a schematic view of a turning machine 60 .
  • the turning machine 60 includes a bed 601 , a headstock 602 , a carriage 603 , a tailstock 604 , and a control unit 605 .
  • the headstock 602 and the tailstock 604 each include a chuck, not shown.
  • the roll 11 is rotatably set on the turning machine 60 .
  • the headstock 602 is further provided with a motor, not shown. By the motor, the roll 11 is rotated around the roll axis.
  • the carriage 603 is movably disposed on the bed 601 .
  • the carriage 603 can be moved in the roll axis direction by a motor, not shown.
  • the carriage 603 is provided with a cutting tool 606 .
  • the cutting tool 606 can be moved in the direction perpendicular to the roll axis (the radial direction of the roll 11 ) by a servomotor, not shown.
  • the control unit 605 controls the rotating speed of the roll 11 .
  • the control unit 605 further controls the movement in the roll axis direction of the carriage 603 and the movement in the roll radial direction of the cutting tool 606 .
  • the control unit 605 may be provided with a storage device for storing the shape data of the groove 20 and the ridge part 52 . In this case, the control unit 605 controls the movement of the carriage 603 and the cutting tool 606 based on the shape data.
  • the groove 20 is formed by turning.
  • the ridge part 52 is cut.
  • the cutting tool 606 is exchanged, that is, an R cutting tool 607 having a concave-shaped tool tip having a predetermined curvature is set onto the carriage 603 .
  • the R cutting tool 607 is brought into contact with the ridge part 52 while the roll 11 is rotated to R-chamfer the ridge part 52 .
  • the ridge part 52 is cut so that the radius of curvature of the ridge part 52 satisfies the conditions described below.
  • FIG. 8 is an enlarged view of the ridge part 52 .
  • the ridge part 52 has a convex shape in the roll radial direction Y and also has a rounded shape.
  • the highest point in the Y direction of the ridge part 52 is defined as a top T 52 .
  • a region RA 52 within the range of 3.0 mm in the X direction with the top T 52 being the center is identified. Hereinafter, this region is defined as the ridge part region RA 52 .
  • the ridge part region RA 52 includes a range of 1.5 mm on the left-hand side (the caliber part 50 side) in the figure from the top T 52 and a range of 1.5 mm on the right-hand side (the flange part 51 side) from the top T 52 .
  • the radius of curvature is determined at a 0.5 mm pitch in the roll axis direction X.
  • points P 1 to Pn (n is a natural number) on the surface of the ridge part region RA 52 are identified at a 0.5 mm pitch in the roll axis direction X.
  • a radius of curvature Rt at point Pt (t is a natural number smaller than n) is determined as described below. Two points (point Pt ⁇ 1 and point Pt+1) adjacent to point Pt are identified. Next, a circle CRt drawn through the identified three points (point Pt ⁇ 1, point Pt, and point Pt+1) is determined. The radius of the determined circle CRt is defined as the radius of curvature Rt.
  • the radiuses of curvature R 1 to Rn (mm) at points P 1 to Pn satisfy Formulas (1) and (2).
  • Rmax is the maximum value of measured radiuses of curvature
  • Rmin is the minimum value of measured radiuses of curvature
  • the average of radiuses of curvature measured at a 0.5 mm pitch in the roll axis direction X in the ridge part region RA 52 is in the range of 2.5 to 3.0 mm, and the difference between the maximum value and the minimum value of the measured radiuses of curvature is at most 1.0 mm.
  • the F1 value is smaller than 2.5 mm, the metal portion that is in contact with the vicinity of edge of the groove 20 is restrained excessively by the ridge part 52 . For this reason, the metal portion is hollowed by the ridge part 52 , and an edge flaw occurs easily.
  • the radiuses of curvature at the above-described points P 1 to Pn are measured, for example, as described below.
  • a cold-setting resin 70 is brought into contact with an optional location of the ridge part 52 , and is cured to make a model of the shape of the ridge part 52 .
  • the surface shape of the cured cold-setting resin 70 is measured. Specifically, referring to FIG. 11 , the cross-sectional shape of the cold-setting resin 70 at the time when the cold-setting resin 70 is cut by a plane that includes the roll axis and extends in the roll radial direction is measured.
  • a region RA 72 in which the model of the ridge part 52 has been made has the same shape as that of the ridge part 52 . Therefore, by measuring the shape of the region RA 72 , the shape of the ridge part 52 can be determined. Based on the determined shape of the ridge part 52 , the radius of curvature Rn can be determined at a 0.5 mm pitch in the roll axis direction X. The shape may be measured by a measuring method other than the method using three-dimensional shape measuring machine.
  • the radius of curvature Rn is determined by the above-described method. Based on the determined radius of curvature Rn, it is judged whether or not the ridge part 52 satisfies Formulas (1) and (2). If the ridge part 52 does not satisfy Formula (1) or (2), the R cutting tool is adjusted, and the ridge part 52 is cut again by using the adjusted R cutting tool.
  • the roll 11 manufactured by the above-described manufacturing method is set on the reducing-rolling mill 11 , and reducing rolling is performed. In this case, the occurrence of fin flaws or edge flaws especially on a thin-wall steel pipe is suppressed.
  • the roll 11 manufactured by the above-described manufacturing method is set on the stand STi at which the outside diameter working ratio is 5.7 to 6.3%.
  • the outside diameter working ratio described herein is defined by Formula (3).
  • the roll 11 for reducing rolling in accordance with this embodiment is especially suitable to the case where a thin-wall steel pipe having an outside diameter of 30.0 mm to 100.0 mm and a wall thickness of 2.0 to 3.0 mm is produced.
  • the roll 11 can suppress the occurrence of fin flaws and edge flaws to some extent even in the case where a steel pipe having an outside diameter and a wall thickness other than those described above.
  • the roll 11 is applied to at least one stand STi of the plurality of stands ST 1 to STm, the above-described effect can be achieved to some extent. If the roll 11 is applied to the stand STi at which the outside diameter working ratio defined by Formula (3) is in the above-described range, a remarkable effect can be achieved.
  • the transverse shape of the groove 20 is a circular arc having the radius Ra 1 .
  • the shape of the groove 20 is not limited to this one.
  • the transverse shape of the groove 20 may be such that the groove bottom portion thereof is of a circular arc shape having the radius Ra 1 , and the groove edge portion thereof is of an arched shape having a radius Ra 2 (Ra 2 >Ra 1 ).
  • the groove edge portion may be of a straight line shape.
  • An arched transverse shape of the groove 20 suffices.
  • the ridge part 52 is cut by using the turning machine 60 and the R cutting tool 607 .
  • the ridge part 52 may be cut by any other well-known method.
  • the groove 20 and the ridge part 52 may be cut continuously by using the control unit 605 of the turning machine 60 .
  • the ridge part 52 may be cut following the adjustment of the setting position of the R cutting tool 607 made by the worker without the use of the control unit 605 .
  • a plurality of rolls having differently shaped ridge parts were prepared.
  • the occurrence ratio of fin flaws and edge flaws at the time when reducing rolling was performed by using each roll was examined.
  • a stretch reducer (three-roll type) provided with twenty-six stands was used. Also, rolls of Set A to Set C shown in FIG. 12 were prepared.
  • each roll of each set (Set A to Set C)
  • the shape of ridge part was measured.
  • Each set included three rolls 11 .
  • a model of the shape of one optional location of the ridge part 52 of the roll 11 was made by using a cold-setting resin (Technovit).
  • the radius of curvature of the ridge part region RA 52 was determined at a 0.5 mm pitch by using the above-described method.
  • FIG. 12 shows the shape and the radius of curvature of the ridge part 52 of each set, which were obtained by the model made as described above.
  • the shapes of the ridge parts of Set A to Set C are shown by graphs.
  • the ordinate (Y-coordinate) of each graph represents the distance in the roll radial direction.
  • the abscissa (X-coordinate) of the graph represents the distance in the roll axis direction X.
  • the dotted line in the graph represents the shape of ridge part in the case where the radius of curvature is 2.5 mm.
  • the solid line in the graph represents the actual shape of the roll 11 of each set.
  • the radiuses of curvature of the ridge part shapes shown in the “R shape” column which were determined at a 0.5 mm pitch in the roll axis direction X, are shown by graphs.
  • the ordinate of each graph represents the radius of curvature (mm).
  • the abscissa (X-coordinate) represents the coordinate in the roll axis direction X.
  • “T 52 ” on the abscissa represents the position of the top T 52 of the ridge part 52 .
  • T 52 ⁇ 1.5 mm represents a position 1.5 mm distant from the top T 52 to the left-hand side (the caliber part side) in the figure
  • T 52 +1.5 mm represents a position 1.5 mm distant from the top T 52 to the right-hand side (the flange part side) in the figure.
  • the range between “T 52 ⁇ 1.5 mm” and “T 52 +1.5 mm” represents the ridge part region RA 52 .
  • Set B satisfied Formulas (1) and (2).
  • the F1 value of Set A exceeded 3.0 mm, and the F2 value thereof exceeded 1.0 mm. That is, Set A did not satisfy Formulas (1) and (2).
  • the F1 value exceeded 3.0 mm, and the F2 value exceeded 1.0 mm. Therefore, Set C also did not satisfy Formulas (1) and (2).
  • the rolls of Set A were set onto No. 3 stand.
  • twenty steel pipes having a material quality corresponding to XSTC of JIS Standard were reducing-rolled at a hot processing to produce thin-wall steel pipes each having an outside diameter of 31.8 mm and a wall thickness of 2.5 mm.
  • the outside diameter working ratio in reducing rolling as a whole was 71%.
  • Flaw occurrence ratio (%) (number of steel pipes on which fin flaw or edge flaw was found/total number of reducing-rolled steel pipes) ⁇ 100 (5)
  • Table 1 gives the examination results. Referring to Table 1, the F1 value of the roll of Set B satisfied Formula (1), and the F2 value thereof satisfied Formula (2). Therefore, in the reducing rolling operation using the rolls of Set B, the flaw occurrence ratio was 0%.
  • the roll of Set C did not satisfy Formulas (1) and (2). Therefore, the flaw occurrence ratio was high, being 30.0%. Also, the roll of Set A did not satisfy Formulas (1) and (2). Therefore, the flaw occurrence ratio was 20.0%.

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  • Physics & Mathematics (AREA)
  • Geometry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
  • Rolls And Other Rotary Bodies (AREA)
US14/008,587 2011-03-31 2012-03-28 Method for manufacturing roll for reducing rolling, and roll for reducing rolling Abandoned US20140013815A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2011079759A JP5003833B1 (ja) 2011-03-31 2011-03-31 絞り圧延用ロールの製造方法、及び、絞り圧延用ロール
JP2011-079759 2011-03-31
PCT/JP2012/058058 WO2012133484A1 (fr) 2011-03-31 2012-03-28 Procédé de fabrication d'un cylindre de réduction et cylindre de réduction

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US20140013815A1 true US20140013815A1 (en) 2014-01-16

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US (1) US20140013815A1 (fr)
EP (1) EP2692453B1 (fr)
JP (1) JP5003833B1 (fr)
CN (1) CN103459056B (fr)
BR (1) BR112013023809B1 (fr)
MX (1) MX338263B (fr)
WO (1) WO2012133484A1 (fr)

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CN116078810A (zh) * 2023-02-17 2023-05-09 科城精铜(广州)有限公司 一种提高铜杆抗拉强度的轧制装置及方法

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CN103341514B (zh) * 2013-07-05 2015-08-19 中北大学 一种曲线回转外形筒体零件的辊挤去飞边成型装置
CN112007951B (zh) * 2019-05-31 2022-08-16 宝山钢铁股份有限公司 高频直缝焊管的精成型圆管孔型的成型方法
CN114273571B (zh) * 2021-12-01 2024-03-22 中北大学 一种带内网格筋筒形件辊挤成形模具

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US8166789B2 (en) * 2004-01-21 2012-05-01 Sumitomo Metal Industries, Ltd. Pipe or tube reducing mill and roll for reducing mill
US9027377B2 (en) * 2007-01-11 2015-05-12 Nippon Steel & Sumitomo Metal Corporation Rolling stand

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JP4441912B2 (ja) * 2005-03-28 2010-03-31 住友金属工業株式会社 マンドレルミル圧延方法
BRPI0810055B1 (pt) * 2007-02-08 2016-10-18 Nippon Steel & Sumitomo Metal Corp rolo raiado para um redutor e redutor

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US3952570A (en) * 1973-07-04 1976-04-27 Firma Friedrich Kocks Stretch reducing mills
US8166789B2 (en) * 2004-01-21 2012-05-01 Sumitomo Metal Industries, Ltd. Pipe or tube reducing mill and roll for reducing mill
US9027377B2 (en) * 2007-01-11 2015-05-12 Nippon Steel & Sumitomo Metal Corporation Rolling stand

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116078810A (zh) * 2023-02-17 2023-05-09 科城精铜(广州)有限公司 一种提高铜杆抗拉强度的轧制装置及方法

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CN103459056B (zh) 2015-03-04
JP5003833B1 (ja) 2012-08-15
WO2012133484A1 (fr) 2012-10-04
CN103459056A (zh) 2013-12-18
BR112013023809B1 (pt) 2019-04-02
EP2692453B1 (fr) 2015-12-30
MX338263B (es) 2016-04-11
EP2692453A4 (fr) 2014-11-19
MX2013011178A (es) 2013-12-06
EP2692453A1 (fr) 2014-02-05
BR112013023809A2 (pt) 2016-12-13
JP2012213786A (ja) 2012-11-08

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