US20110146340A1 - Method of recovering carbon dioxide from gas and apparatus therefor - Google Patents

Method of recovering carbon dioxide from gas and apparatus therefor Download PDF

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Publication number
US20110146340A1
US20110146340A1 US12/311,350 US31135006A US2011146340A1 US 20110146340 A1 US20110146340 A1 US 20110146340A1 US 31135006 A US31135006 A US 31135006A US 2011146340 A1 US2011146340 A1 US 2011146340A1
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United States
Prior art keywords
exhaust gas
gas
carbon dioxide
hydrate
ice
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Abandoned
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US12/311,350
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English (en)
Inventor
Yoshitaka Yamamoto
Taro Kawamura
Kazuo Uchida
Hajime Kanda
Susumu Tanaka
Osamu Takano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Engineering and Shipbuilding Co Ltd
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
Mitsui Engineering and Shipbuilding Co Ltd
National Institute of Advanced Industrial Science and Technology AIST
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Application filed by Mitsui Engineering and Shipbuilding Co Ltd, National Institute of Advanced Industrial Science and Technology AIST filed Critical Mitsui Engineering and Shipbuilding Co Ltd
Assigned to NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY, MITSUI ENGINEERING & SHIPBUILDING CO., LTD. reassignment NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KANDA, HAJIME, KAWAMURA, TARO, TAKANO, OSAMU, TANAKA, SUSUMU, UCHIDA, KAZUO, YAMAMOTO, YOSHITAKA
Publication of US20110146340A1 publication Critical patent/US20110146340A1/en
Abandoned legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B01D53/79—Injecting reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Definitions

  • the present invention relates to a carbon dioxide separating and recovering method that involves: contacting exhaust gas with particulate ice at a low temperature by use of cold energy of LNG (liquefied natural gas) to generate carbon dioxide hydrate; and then fixing carbon dioxide (CO 2 ) in the exhaust gas to the gas hydrate, thereby recovering the carbon dioxide from the exhaust gas, and also relates to an apparatus therefor.
  • LNG liquefied natural gas
  • CO 2 carbon dioxide
  • a chemical absorption method is a method in which carbon dioxide is separated and recovered by making use of properties of an amine absorbing solution which absorbs carbon dioxide at 40° C. to 50° C. and releases carbon dioxide at 100° C. to 120° C.
  • the physical adsorption method is a method in which carbon dioxide is separated and recovered by making use of properties of zeolite that absorbs carbon dioxide when a pressure is applied and desorbs carbon dioxide when the pressure is reduced.
  • the membrane separation method is a method in which carbon dioxide is subjected to membrane-separation by use of a porous hollow fiber membrane.
  • the chemical absorption method or the physical adsorption method needs the reproduction of an absorbent and an adsorbent, and consume a large amount of energy as well. As such, it is not necessarily suitable as a method of separating carbon dioxide for fixing carbon dioxide.
  • the membrane separation method is a separation method based on the molecular size.
  • the nitrogen molecule and the carbon dioxide molecule included in combustion exhaust gas have substantially the same size, the two kinds of molecules are difficult to separate by this method.
  • the purity of the recovered carbon dioxide is low.
  • the method of separating carbon dioxide with gas hydrate has difficulty in generating gas hydrate including high-concentration carbon dioxide from exhaust gas with a small content of carbon dioxide such as gas turbine exhaust gas.
  • the present invention has been made on the basis of the research and experimental results.
  • the present invention is directed to provide a method of recovering carbon dioxide and an apparatus therefor that consume a less amount of energy by improving gas hydrate formation reaction that generally shows an extremely low production rate at a low temperature and by effectively making use of unused cold energy wasted when LNG used as a fuel is gasified in gas-turbine combined cycle power facilities.
  • the invention according to claim 1 is a method of recovering carbon dioxide from exhaust gas by gas-hydrating the carbon dioxide.
  • the method includes the steps of: cooling the exhaust gas to a given temperature by use of cold energy of liquefied natural gas; spraying water in a minute-ice generator having been cooled to a given temperature by use of the cold energy of the liquefied natural gas to generate minute ice; and introducing the minute ice and the cooled exhaust gas into a gas hydrate generator so as to cause the minute ice and carbon dioxide in the exhaust gas to react with each other in the gas hydrate generator, thereby generating carbon dioxide hydrate.
  • this method of recovering carbon dioxide it becomes possible to gas-hydrate minute ice including the core of the minute ice in a relatively short time by forming the minute ice (e.g., 0.1 ⁇ m to 10 ⁇ m) from ice that has been said to be difficult to be gas-hydrated at a low temperature of, for example, ⁇ 70° C. to ⁇ 100° C.
  • carbon dioxide can be recovered efficiently from exhaust gas, particularly, even from gas turbine exhaust gas having a low content of carbon dioxide (e.g., 3% to 4%).
  • the invention according to claim 2 is the method of separating and recovering carbon dioxide from exhaust gas, characterized in that, in claim 1 , exhaust gas cooled to approximately ⁇ 70° C. to ⁇ 100° C. by use of the cold energy of the liquefied natural gas is caused to contact with minute ice having a particle diameter of approximately 0.1 ⁇ m to 10 ⁇ m to thereby generate carbon dioxide hydrate.
  • the invention according to claim 3 is an apparatus of recovering carbon dioxide from exhaust gas by gas-hydrating the carbon dioxide.
  • the apparatus includes: a spray nozzle; a minute-ice generator which freezes particulate droplets of water sprayed from the spray nozzle by use of cold energy of liquefied natural gas to generate minute ice; and a gas hydrate generator into which the minute ice and exhaust gas cooled by use of the cold energy of the liquefied natural gas are introduced to generate carbon dioxide hydrate.
  • the invention according to claim 4 is the apparatus of recovering carbon dioxide from exhaust gas, characterized in that, in claim 3 , the exhaust gas in the gas hydrate generator is circulated between the gas hydrate generator and a circulating-gas cooler outside the gas hydrate generator, and that the exhaust gas is cooled by the circulating-gas cooler which makes use of the cold energy of the liquefied natural gas.
  • the invention according to claim 5 is the apparatus of recovering carbon dioxide in exhaust gas, characterized in that, in claim 3 , reaction heat generated in the gas hydrate generator is removed by using the exhaust gas cooled by use of the cold energy of the liquefied natural gas.
  • the invention according to claim 6 is an apparatus of recovering carbon dioxide from exhaust gas.
  • the apparatus includes: an exhaust gas precooler which precools exhaust gas by using low temperature-low pressure exhaust gas that has been depressurized to near an atmospheric pressure after carbon dioxide separation and recovery; an exhaust gas compressor which pressurizes the low temperature exhaust gas precooled by the exhaust gas precooler to a pressure necessary for gas hydrate generation; an exhaust gas recooler which recools the exhaust gas compressed by the exhaust gas compressor by use of low temperature-high pressure exhaust gas after the carbon dioxide separation and recovery; an exhaust gas expander which expands the high pressure exhaust gas up to an atmospheric pressure, the exhaust gas having been subjected to a rise in temperature by the exhaust gas recooler; and a gas hydrate generating device.
  • the gas hydrate generating device includes: a generation water pump which pressurizes generation water up to a pressure necessary for reaction; an assist gas compressor which pressurizes part of the exhaust gas up to an assist gas pressure necessary for spraying of the generation water; a spray nozzle which atomizes the generation water introduced therein together with assist gas; a minute-ice generator which generates minute ice by freezing the droplets of water atomized by the spray nozzle by use of cold energy of liquefied natural gas; a gas hydrate generator made up of multiple reaction vessels which are connected to each other meanderingly, and in which the minute ice and exhaust gas cooled by use of the cold energy of the liquefied natural gas are introduced; an exhaust gas circulation loop which substantially circularly connects the reaction vessels to each other through communication tubes; and a circulating-gas cooler which cools the exhaust gas circulating in the multiple reaction vessels with the liquefied natural gas.
  • FIG. 1 is a system flow chart of a method of separating and recovering carbon dioxide according to the present invention.
  • FIG. 2 is a block diagram of an apparatus of separating and recovering carbon dioxide according to the present invention.
  • a gas-turbine combined cycle power plant is shown as an example of an exhaust gas source origin; however, the exhaust gas source origin is not limited to this example.
  • a facility that carries out a method of separating and recovering carbon dioxide according to the present invention primarily includes a gas-turbine combined cycle power plant 10 , an exhaust gas precooler 11 , an exhaust gas compressor 12 , an exhaust gas recooler 13 , a carbon dioxide hydrate generating device (also called, “carbon dioxide separation and recovery device”) 14 and an exhaust gas expander 15 .
  • the arrow of a single line shows the flow of exhaust gas before carbon dioxide separation and recovery
  • the arrow of double lines shows the flow of exhaust gas after carbon dioxide separation and recovery.
  • Exhaust gas 1 a (carbon dioxide content: 3% to 4%, temperature: approximately 100° C., and pressure: approximately 0.1 MPa) discharged from the gas-turbine combined cycle power plant 10 is precooled to a given temperature by the exhaust gas precooler 11 .
  • low temperature-low pressure exhaust gas 1 e after carbon dioxide separation and recovery is used.
  • the pressure of the exhaust gas 1 e has been reduced to near the atmospheric pressure (e.g., 0.1 MPa) by the exhaust gas expander 15 after discharged from the carbon dioxide hydrate generating device 14 .
  • Low temperature-low pressure exhaust gas 1 c after precooled by the exhaust gas precooler 11 is pressurized by the exhaust gas compressor 12 to a pressure (e.g., 2 MPa) necessary for gas hydrate generation.
  • Exhaust gas 1 d pressurized by the exhaust gas compressor 12 is introduced into the exhaust gas recooler 13 , and then recooled with high pressure-low temperature (e.g., 2 MPa and approximately ⁇ 70° C.) exhaust gas 1 b that is discharged from the carbon dioxide hydrate generating device 14 after carbon dioxide separation and recovery.
  • high pressure-low temperature e.g., 2 MPa and approximately ⁇ 70° C.
  • High pressure-low temperature (e.g., 2 MPa and ⁇ 70° C.) exhaust gas 1 f recooled by the exhaust gas recooler 13 reacts with minute ice generated by utilization of cold energy of LNG and becomes carbon dioxide hydrate c.
  • Reference symbol w indicates generation water for minute ice manufacturing.
  • This carbon dioxide separation and recovery device includes the gas-turbine combined cycle power plant 10 , the exhaust gas precooler 11 , the exhaust gas compressor 12 , the exhaust gas recooler 13 , the carbon dioxide hydrate generating device 14 and the exhaust gas expander 15 .
  • the carbon dioxide hydrate generating device 14 includes a generation water pump 20 , an assist gas compressor 21 , a two-fluid spray nozzle 22 , a minute-ice generator 23 , a gas hydrate generator 24 , an exhaust gas circulation loop 25 , and a circulating-gas cooler 26 that utilizes cold energy of LNG.
  • an exhaust gas supply pipe 28 is connected to the exhaust gas circulation loop 25 through the exhaust gas precooler 11 , the exhaust gas compressor 12 and the exhaust gas recooler 13 .
  • the exhaust gas supply pipe 28 supplies the carbon dioxide hydrate generating device 14 with the exhaust gas 1 a discharged from the gas-turbine combined cycle power'plant 10 .
  • a branch pipe 29 branched from the exhaust gas supply pipe 28 reaches the two-fluid spray nozzle 22 in the minute-ice generator 23 through the assist gas compressor 21 .
  • an exhaust gas discharge pipe 30 that is connected to the exhaust gas circulation loop 25 is connected to an unillustrated chimney through the exhaust gas recooler 13 , the exhaust gas expander 15 and the exhaust gas precooler 11 .
  • a water supply pipe 31 is connected to the two-fluid spray nozzle 22 in the minute-ice generator 23 .
  • a water recovery pipe 32 that recovers water generated in the exhaust gas precooler 11 is connected to the water supply pipe 31 .
  • the gas-turbine combined cycle power plant 10 comprises an electrical generator 35 , a suction compressor 36 , an exhaust gas expander 37 , a combustor 38 and a waste-heat boiler 39 .
  • the electrical generator 35 is driven by the exhaust gas expander 37 , and thereby electricity is generated by the electrical generator 17 .
  • Exhaust gas discharged from the exhaust gas expander 37 in the gas-turbine combined cycle power plant 10 becomes the low temperature-normal pressure (e.g., 373 K (100° C.) and 0.1 MPa) exhaust gas 1 a after thermal recovery by the waste-heat boiler 39 , and is supplied to the exhaust gas precooler 11 .
  • the low temperature-normal pressure e.g., 373 K (100° C.) and 0.1 MPa
  • the exhaust gas 1 a supplied to this exhaust gas precooler 11 is precooled by using the low temperature-low pressure exhaust gas 1 e that has been subjected to carbon dioxide separation and recovery.
  • This exhaust gas 1 e is a low temperature-low pressure gas discharged from the carbon dioxide hydrate generating device 14 , and depressurized down to near the atmospheric pressure (e.g., 0.1 MPa) by the exhaust gas expander 15 .
  • the low temperature exhaust gas 1 c precooled (for example, ⁇ 40° C. to ⁇ 50° C.) by the exhaust gas precooler 11 is pressurized using the exhaust gas compressor 12 to a pressure (e.g., 2 MPa) necessary for the generation of gas hydrate.
  • a pressure e.g. 2 MPa
  • the exhaust gas 1 d compressed by the exhaust gas compressor 12 is introduced into the exhaust gas recooler 13 , and then recooled with low temperature-high pressure (e.g., 203 K ( ⁇ 70° C.), 2 MPa) exhaust gas 1 b that is discharged from the carbon dioxide hydrate generating device 14 described below after carbon dioxide separation and recovery.
  • low temperature-high pressure e.g., 203 K ( ⁇ 70° C.), 2 MPa
  • the exhaust gas 1 b After the low temperature-high pressure exhaust gas 1 b recools the exhaust gas 1 d pressurized by the exhaust gas compressor 12 , the exhaust gas 1 b is emitted to the atmosphere from an unillustrated chimney via the exhaust gas expander 15 .
  • the pressure of the gas 1 g emitted at this point is approximately, for example, 0.1 MPa.
  • the exhaust gas compressor 12 and the electrical generator 17 are driven by the exhaust gas expander 15 , and electricity is generated by the electrical generator 17 .
  • the carbon dioxide hydrate generating device 14 includes the generation water pump 20 , the assist gas compressor 21 , the two-fluid spray nozzle 22 , the minute-ice generator 23 , the gas hydrate generator 24 , the exhaust gas circulation loop 25 and the circulating-gas cooler 26 .
  • the generation water w for carbon dioxide hydrate generation is pressurized by the generation water pump 20 up to a pressure necessary for reaction.
  • part of the exhaust gas 1 f recooled by the exhaust gas recooler 13 is pressurized by the assist gas compressor 21 up to an assist gas pressure (e.g., 2.3 MPa) necessary for spraying of the generation water w.
  • the minute-ice generator 23 includes the two-fluid spray nozzle 22 .
  • This two-fluid spray nozzle 22 sprays the generation water w in a particulate form from a nozzle hole (unillustrated) with the valve opened by the introduction of assist gas 1 h.
  • this minute-ice generator 23 has a cooling jacket 27 on its outside, and instantaneously freezes the particulate water sprayed from the spray nozzle 22 by use of cold energy of LNG (liquefied natural gas) to generate minute ice (e.g., 0.1 ⁇ m to 10 ⁇ m) i.
  • LNG liquefied natural gas
  • the cooling jacket 27 uses, as a coolant, a coolant a cooled to a given temperature by utilization of the cold energy of LNG.
  • the gas hydrate generator 24 is made up of multiple reaction vessels 41 a to 41 d that are arranged meanderingly. These reaction vessels 41 a to 41 d seem to be arranged in parallel at a glance, but they are connected substantially in series.
  • the left end part (upstream end) of the reaction vessel 41 a on the top row is connected to the outlet of the minute-ice generator 23 through a communication tube 42 a .
  • the right end part (downstream end) of the reaction vessel 41 a on the top row communicates with the right end part (upstream end) of the reaction vessel 41 b on the second row through a communication tube 42 .
  • the left end part (downstream end) of the reaction vessel 41 b on the second row communicates with the left end part (upstream end) of the reaction vessel 41 c on the third row through a communication tube 42 .
  • the right end part (downstream end) of the reaction vessel 41 c on the third row communicates with the right end part (upstream end) of the reaction vessel 41 d on the fourth row (lowest row) through a communication tube 42 .
  • the reaction vessel 41 d on the lowest row includes a discharge pipe 43 on its left end part (downstream end).
  • the exhaust gas circulation loop 25 makes the exhaust gas 1 f circulate along the multiple reaction vessels 41 a to 41 d described above.
  • One end of a piping 45 for circulation loop formation is connected to the left end part of the reaction vessel 41 a on the top row, and the other end is connected to the right end part of the reaction vessel 41 d on the lowest row.
  • the reaction vessel 41 a on the top row and the reaction vessel 41 b on the second row communicate with each other on their left end parts through a communication tube 46 a .
  • the reaction vessel 41 b on the second row and the reaction vessel 41 c on the third row communicate with each other on their right end parts through a communication tube 46 b .
  • the reaction vessel 41 c on the third row and the reaction vessel 41 d on the lowest row communicate with each other on their left end parts through a communication tube 46 c.
  • the reaction vessels 41 a to 41 d each include a stirrer 47 to stir the minute ice i in the reaction vessels 41 a to 41 d to promote the reaction of the minute ice i with the exhaust gas 1 f.
  • the exhaust gas 1 a (carbon dioxide content: 3% to 4%, temperature: 100° C., and pressure: 0.1 MPa) discharged from the gas-turbine combined cycle power plant 10 is introduced into the exhaust gas precooler 11 , and then precooled in the exhaust gas precooler 11 by use of the low temperature-low pressure (e.g., 0.1 MPa) exhaust gas 1 e.
  • the low temperature-low pressure e.g., 0.1 MPa
  • the low temperature-low pressure exhaust gas 1 c (for example, ⁇ 40° C. to ⁇ 50° C., 0.1 MPa) after precooled by the exhaust gas precooler 11 is pressurized using the exhaust gas compressor 12 to a pressure (e.g., 2 MPa) necessary for the generation of gas hydrate.
  • the exhaust gas 1 d pressurized by the exhaust gas compressor 12 is supplied to the exhaust gas recooler 13 , and recooled in the exhaust gas recooler 13 with the low temperature-high pressure (e.g., ⁇ 70° C., 2 MPa) exhaust gas 1 b that is discharged from the exhaust gas hydrate generating device 14 after carbon dioxide separation and recovery.
  • exhaust gas 1 f recooled in the exhaust gas recooler 13 is pressurized to a given pressure (e.g., 2.3 MPa) by the assist gas compressor 21 .
  • this assist gas 1 f is supplied to the two-fluid spray nozzle 22 , the valve or vent incorporated in the two-fluid spray nozzle 22 is opened as already described. Then, the generation water w pressurized by the generation water pump 20 is sprayed in a particulate form within the minute-ice generator 23 .
  • This minute particulate water is instantaneously frozen to become the minute ice i because the inside of the minute-ice generator 23 is cooled to a given temperature (e.g., ⁇ 30° C. to ⁇ 50° C.) by the cooling jacket 27 .
  • This minute ice i is supplied to the upstream end of the reaction vessel 41 a on the top row of the exhaust gas hydrate generator 24 , and then transported to the downstream end while being stirred by the stirrer 47 .
  • the high pressure (e.g., 2 MPa) exhaust gas 1 f supplied to the piping 45 for loop formation from the exhaust gas supply pipe 28 is cooled to a given temperature (e.g., 203 K ( ⁇ 70° C.) to 173 K ( ⁇ 100° C.)) by the circulating-gas cooler 26 that makes use of the cold energy of LNG (b). Then, the exhaust gas 1 f is supplied to the downstream end of the reaction vessel 41 a on the top row.
  • the minute ice i is transported toward the reaction vessel 41 d on the lowest row from the reaction vessel 41 a on the top row one after another.
  • the minute ice i is to be discharged, in the end, from the discharge pipe 43 disposed in the reaction vessel 41 d on the lowest row to the outside of the system.
  • the ice reacts with carbon dioxide included in the exhaust gas 1 f to become carbon dioxide hydrate c.
  • the carbon dioxide in the exhaust gas is incorporated into this carbon dioxide hydrate c by 60% to 80% relative to the carbon dioxide hydrate c.
  • the concentration of the carbon dioxide in the exhaust gas discharged from the chimney 16 is lowered by the amount.
  • the reaction heat generated when the carbon dioxide in the exhaust gas reacts with the minute ice i is removed by the cold energy of the exhaust gas 1 f.
  • the invention can be applied not only to gas-turbine combined cycle power plants, but also widely to facilities that discharge carbon dioxide such as incinerators.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Carbon And Carbon Compounds (AREA)
US12/311,350 2006-09-29 2006-09-29 Method of recovering carbon dioxide from gas and apparatus therefor Abandoned US20110146340A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2006/319571 WO2008041299A1 (fr) 2006-09-29 2006-09-29 Procédé de récupération de dioxyde de carbone à partir de gaz d'échappement et appareil associé

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US (1) US20110146340A1 (zh)
EP (1) EP2067516B1 (zh)
CN (1) CN101511449B (zh)
CA (1) CA2664454C (zh)
DK (1) DK2067516T3 (zh)
NO (1) NO20091698L (zh)
WO (1) WO2008041299A1 (zh)

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CN103170235A (zh) * 2011-12-21 2013-06-26 苏州爱儿森环境科技有限公司 基于二氧化碳水合物的含二氧化碳废气回收方法及装置
JP6427455B2 (ja) * 2015-04-10 2018-11-21 Ｉｈｉプラント建設株式会社 オゾンハイドレート製造装置、および、オゾンハイドレート製造方法
CN106474904B (zh) * 2016-11-25 2019-03-08 中国科学院广州能源研究所 一种水合物法联合化学吸收法的co2气体分离装置及方法
CN107344063A (zh) * 2017-07-31 2017-11-14 中国科学院广州能源研究所 一种水合物法连续分离气体的装置与方法
CN108579361A (zh) * 2018-05-09 2018-09-28 常州大学 一种lng发电厂尾气中二氧化碳低能耗捕集装置
CN110947262B (zh) * 2019-12-20 2021-04-20 大连理工大学 基于水合物的颗粒物/废气协同脱除系统及方法
CN112473336A (zh) * 2020-11-25 2021-03-12 兰州理工大学 一种水合物法回收和储存烟气中co2的方法

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CN101511449A (zh) 2009-08-19
EP2067516A1 (en) 2009-06-10
EP2067516A4 (en) 2010-12-01
EP2067516B1 (en) 2012-07-04
CN101511449B (zh) 2012-10-10
CA2664454A1 (en) 2008-10-04
WO2008041299A1 (fr) 2008-04-10
NO20091698L (no) 2009-04-28
CA2664454C (en) 2012-05-08
DK2067516T3 (da) 2012-10-08

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