US20110108227A1 - Process For Applying Composition Containing A Cationic Trivalent Metal And Debonder And Fluff Pulp Sheet Made From Same - Google Patents

Process For Applying Composition Containing A Cationic Trivalent Metal And Debonder And Fluff Pulp Sheet Made From Same Download PDF

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Publication number
US20110108227A1
US20110108227A1 US12/851,194 US85119410A US2011108227A1 US 20110108227 A1 US20110108227 A1 US 20110108227A1 US 85119410 A US85119410 A US 85119410A US 2011108227 A1 US2011108227 A1 US 2011108227A1
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Prior art keywords
fluff pulp
sheet
combination
web
product
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Abandoned
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US12/851,194
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English (en)
Inventor
James E. Sealey
Michael Hevenor
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International Paper Co
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International Paper Co
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Priority to US12/851,194 priority Critical patent/US20110108227A1/en
Assigned to INTERNATIONAL PAPER COMPANY reassignment INTERNATIONAL PAPER COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SEALEY, JAMES E., HEVENOR, MICHAEL
Publication of US20110108227A1 publication Critical patent/US20110108227A1/en
Priority to US14/669,523 priority patent/US20150197894A1/en
Priority to US15/681,689 priority patent/US10260201B2/en
Abandoned legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22—Agents rendering paper porous, absorbent or bulky
    • D21H21/24—Surfactants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/001—Modification of pulp properties
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/001—Modification of pulp properties
    • D21C9/002—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/001—Modification of pulp properties
    • D21C9/002—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives
    • D21C9/004—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives inorganic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/001—Modification of pulp properties
    • D21C9/007—Modification of pulp properties by mechanical or physical means
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07—Nitrogen-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22—Agents rendering paper porous, absorbent or bulky
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002—Tissue paper; Absorbent paper

Definitions

  • the invention relates to fluff pulp sheets, processes for making, and their use.
  • FIG. 1 shows a schematic example of one embodiment of a suitable papermaking machine, wherein A is a head box; B is a composition (e.g., fluff pulp mixture) applied to a table C from head box B; D is a formation shower; E is a suction box; F is a first press; G is a second press or transition to dryer H; I is a formation shower; J is a reel for taking up the finished fluff pulp sheet K; and L is an arrow showing the machine direction of the product as it progresses from head box A to reel J.
  • A is a head box
  • B is a composition (e.g., fluff pulp mixture) applied to a table C from head box B
  • D is a formation shower
  • E is a suction box
  • F is a first press
  • G is a second press or transition to dryer H
  • I is a formation shower
  • J is a reel for taking up the finished fluff pulp sheet K
  • L is an arrow showing the machine direction of the
  • One embodiment of the subject matter claimed herein results in significantly reduced operational risk, e.g., sheet breaking, in the manufacture of fluff pulp sheets. Another embodiment of the subject matter claimed herein results in improved fluff shred quality of fluff pulp sheets. Another embodiment of the subject matter claimed herein results in improved fluff fiber singulation of fluff pulp sheets. Another embodiment of the subject matter claimed herein results in reduced fiberization energy of fluff pulp sheets. Another embodiment of the subject matter claimed herein results in good Mullen values of fluff pulp sheets. Another embodiment of the subject matter claimed herein results in a fluff pulp sheet with reduced fiberization energy but which maintains good Mullen value. Another embodiment of the subject matter claimed herein is a fluff pulp sheet having improved surfactant retention.
  • fluff pulp sheet or absorbent product obtained therefrom having improved absorbency and low absorption times.
  • the fluff pulp sheet can be processed at high speeds without sheet breaks or other processing issues.
  • the subject matter claimed herein avoids the disadvantages of conveying a mechanically weak sheet through a paper machine.
  • One embodiment of the present invention relates to a process for making a fluff pulp sheet, comprising:
  • forming the web comprises one or more of contacting the fluff pulp mixture with a table in a papermaking machine, removing at least a portion of water from the fluff pulp mixture with a suction box under a table in a papermaking machine, heating the fluff pulp mixture, or a combination thereof.
  • the cationic trivalent metal or salt thereof is boron, zinc, iron, cobalt, nickel, aluminum, manganese, chromium, salt thereof, or a combination thereof. In another embodiment, the cationic trivalent metal or salt thereof is boron, zinc, iron, aluminum, manganese, salt thereof, or a combination thereof. In another embodiment, the cationic trivalent metal or salt thereof is boron, zinc, aluminum, salt thereof, or a combination thereof. In another embodiment, the cationic trivalent metal or salt thereof is boron, aluminum, salt thereof, or a combination thereof. In another embodiment, the cationic trivalent metal or salt thereof is aluminum, salt thereof, or a combination thereof. In another embodiment, the cationic trivalent metal or salt thereof is aluminum, salt thereof, or a combination thereof.
  • the salt is not particularly limited, and any suitable anion known to form a salt with the cationic trivalent metal should suffice.
  • the anion may be organic, inorganic, fatty acid, acetate, lactate, EDTA, halide, chloride, bromide, nitrate, chlorate, perchlorate, sulfate, acetate, carboxylate, hydroxide, nitrite, or the like, or combinations thereof.
  • the salt may be a simple salt, wherein the metal forms a salt with one or more of the same anion, or a complex salt, wherein the metal forms a salt with two or more different anions.
  • the salt is aluminum chloride, aluminum carbonate, aluminum sulfate or alum.
  • the first pH is ⁇ 5.0. This range includes all values and subranges therebetween, including 1, 2, 2.5, 3, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, 3.7, 3.8, 3.9, 4, 4.1, 4.2, 4.3, 4.4, 4.5, 4.6, 4.7, 4.8, 4.9, and ⁇ 5 or any value therein.
  • the second pH is ⁇ 5.0.
  • This range include all values and subranges therebetween, including 5.0, 5.1, 5.2, 5.3, 5.4, 5.5, 5.6, 5.7, 5.8, 5.9, 6.0, 6.1, 6.2, 6.3, 6.4, 6.5, 6.6, 6.7, 6.8, 6.9, 7, 8, 9, 10, 11 or any value therein.
  • the debonder surfactant may be suitably applied to the web.
  • the debonder surfactant may be suitably sprayed onto the web, for example using a formation shower or spray boom over the table, coated onto the web using known coating methods in the papermaking arts, or the web may be immersed into the debonder surfactant. Combinations of application methods are possible.
  • the debonder surfactant is sprayed onto the web.
  • the spraying is carried out using one or more formation showers over a table in a papermaking machine.
  • the web may be suitably dried in a drying section. Any method for drying commonly known in the art of fluff pulp papermaking may be utilized.
  • the drying section may include and contain a drying can, flotation dryer, cylinder drying, Condebelt drying, IR, or other drying means and mechanisms known in the art.
  • the fluff pulp sheet may be dried so as to contain any selected amount of water.
  • the web is dried using a flotation dryer.
  • a debonder surfactant may further and optionally be applied to the fluff pulp sheet.
  • the thus-applied second debonder surfactant may be the same or different from the debonder surfactant applied at the wet end.
  • the second debonder surfactant is applied to the fluff pulp sheet after the last drying step.
  • the second debonder surfactant is applied to the fluff pulp sheet before the sheet is taken up on the reel.
  • the second debonder surfactant may be suitably applied by spraying, for example, from a second formation shower or spray boom located at the dry end.
  • the applying of the (first) debonder surfactant is carried out before, during, or after the raising of the pH to the second pH, or a combination thereof.
  • the pH may be suitably raised, for example, by applying one or more known pH adjusters to the web as it moves along the table.
  • the pH adjuster may be applied using a formation shower, spray boom, or the like, or a combination thereof.
  • the web may be suitably dried to a moisture content of between 0 and 70%. This range includes all values and subranges therebetween, including 0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 12, 14, 16, 18, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70% or any combination thereof or range therein.
  • the web is dried to a moisture content of ⁇ 70%.
  • the web is dried to a moisture content of ⁇ 50%.
  • the web is dried to a moisture content of ⁇ 25%.
  • the web is dried to a moisture content of ⁇ 10%.
  • the web is dried to a moisture content of ⁇ 7%.
  • the web is dried to a moisture content of about 6.3%.
  • the web may have a basis weight ranging from 100 to 1100 gsm. This range includes all values and subranges therein, for example 100, 125, 150, 175, 200, 225, 250, 275, 300, 400, 500, 600, 700, 800, 900, 1000, 1100, or any combination thereof or range therein.
  • the solids content of the web and/or fluff pulp sheet at the point or points of applying the debonder surfactant may suitably range from 1 to 100%. This range includes all values and subranges therebetween, including 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 99, 100%, or any combination thereof or any range therein.
  • the solids content of the web and/or fluff pulp sheet at the point or points of applying one or more debonder surfactant is >1%.
  • the solids content of the web and/or fluff pulp sheet at the point or points of applying one or more debonder surfactant is >25%.
  • the solids content of the web and/or fluff pulp sheet at the point or points of applying one or more debonder surfactant is >50%.
  • the fluff pulp mixture further comprises one or more additive such as whitener, colorant, pigment, optical brightening agent, wetting agent, binder, bleaching agent, other additive, or a combination thereof. If present, the amount of additive is not particularly limited. In one embodiment, the additive may be present in amounts ranging from about 0.005 to about 50 weight percent based on the weight of the fluff pulp mixture.
  • This range includes all values and subranges therebetween, including about 0.005, 0.006, 0.007, 0.008, 0.009, 0.01, 0.02, 0.03, 0.04, 0.05, 0.06, 0.07, 0.08, 0.09, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 15, 20, 25, 30, 35, 40, 45, and 50 weight percent, or any combination thereof, based on the weight of the fluff pulp mixture.
  • the web comprises a solids content of >1% by weight. This range includes all values and subranges therein, including 100, 99, 98, 97, 96, 95, 94, 93, 92, 91, 90, 85, 80, 75, 70, 65, 60, 55, 50, 45, 40, 35, 30, 25, 20, 15, 10, 9, 8, 7, 6, 5, 4, 3, 2, >1%, or any combination thereof or range therein.
  • the debonder surfactant is applied neat or as purchased. In another embodiment, the debonder surfactant is used in combination with one or more second debonder surfactant. In another embodiment, the debonder surfactant is applied from a solution, dispersion, emulsion, or the like. If applied in solution, dispersion, emulsion, or the like, or combination thereof. In one embodiment, if applied in solution, dispersion, emulsion, or the like, the debonder surfactant concentration may suitably range from 1 to 50% by weight solids content of debonder surfactant to the weight of solution, dispersion, emulsion, or the like. This range includes all values and subranges therebetween, including 0.5, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 25, 30, 35, 40, 45, 50%, or any combination thereof or range therein.
  • the debonder surfactant is in the form of a composition further comprising water and optionally one or more pH adjusting agent, whitener, colorant, pigment, optical brightening agent, wetting agent, binder, bleaching agent, trivalent cationic metal, alum, other additive, or a combination thereof. If present, the amount of additive is not particularly limited. In one embodiment, the additive may be present in amounts ranging from about 0.005 to about 50 weight percent based on the weight of the debonder surfactant composition.
  • This range includes all values and subranges therebetween, including about 0.005, 0.006, 0.007, 0.008, 0.009, 0.01, 0.02, 0.03, 0.04, 0.05, 0.06, 0.07, 0.08, 0.09, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 15, 20, 25, 30, 35, 40, 45, and 50 weight percent, or any combination thereof, based on the weight of the debonder surfactant composition.
  • Debonder surfactants are known in the fluff pulp and fluff pulp fiber arts. Any debonder surfactant is suitable for use in the present application, and the selection thereof is within the skill of one knowledgeable in the fluff pulp and fluff pulp fiber arts. Some examples, which are not intended to be limiting, include linear or branched monoalkyl amine, linear or branched dialkyl amine, linear or branched tertiary alkyl amine, linear or branched quaternary alkyl amine, ethoxylated alcohol, linear or branched, saturated or unsaturated hydrocarbon surfactant, fatty acid amide, fatty acid amide quaternary ammonium salt, dialkyl dimethyl quaternary ammonium salt, dialkylimidazolinium quaternary ammonium salt, dialkyl ester quaternary ammonium salt, triethanolamine-ditallow fatty acid, fatty acid ester of ethoxylated primary amine, ethoxylated
  • the method of applying the debonder surfactant to the web may be increased or decreased or otherwise controlled by controlling the various points of addition.
  • the amount of debonder surfactant applied at the wet end may be increased or decreased by respectively decreasing or increasing that amount applied at the dry end.
  • one or more than one of the same or different type of debonder surfactant, or any combination thereof may be applied at any point in the process.
  • the finished fluff pulp sheet may be fiberized or shredded, in accordance with methods known in the art.
  • the fiberizing or shredding may be carried out in a hammermill.
  • the fluff pulp sheet and/or fiberized or shredded fluff pulp sheet, or a combination thereof may be suitably incorporated into one or more of an adsorbent product, paper product, personal care product, medical product, insulating product, construction product, structural material, cement, food product, veterinary product, packaging product, diaper, tampon, sanitary napkin, gauze, bandage, fire retardant, or a combination thereof.
  • an adsorbent product paper product, personal care product, medical product, insulating product, construction product, structural material, cement, food product, veterinary product, packaging product, diaper, tampon, sanitary napkin, gauze, bandage, fire retardant, or a combination thereof.
  • Another embodiment relates to a fluff pulp sheet, made by the process described herein.
  • Another embodiment relates to a fluff pulp sheet, comprising:
  • At least one cationic trivalent metal, salt thereof, or combination thereof at least one cationic trivalent metal, salt thereof, or combination thereof;
  • the fiberization energy, sometimes called the shred energy, of the fluff pulp sheet is suitably less than 145 kJ/kg. This range includes all values and subranges therebetween, including 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 100, 105, 110, 115, 120, 125, 130, 135, 140, 145 kJ/kg, or any combination thereof or any range therein. In one embodiment, the fiberization energy of the fluff pulp sheet is less than 135 kJ/kg. In another embodiment, the fiberization energy of the fluff pulp sheet is from 120 to less than 145 kJ/kg.
  • the fiberization energy of the fluff pulp sheet is less than 120 kJ/kg. In another embodiment, the fiberization energy of the fluff pulp sheet is from 100 to 120 kJ/kg. In another embodiment, the fiberization energy of the fluff pulp sheet is less than 100 kJ/kg. In another embodiment, the fiberization energy of the fluff pulp sheet is less than 95 kJ/kg.
  • the fluff pulp sheet has a SCAN-C 33:80 adsorption time of ⁇ 4.0 s.
  • This range includes all values and subranges therebetween, including 1, 1.1, 1.2, 1.3, 1.4, 1.5, 1.6, 1.7, 1.8, 1.9, 2, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.8, 2.9, 3, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, 3.7, 3.8, 3.9, ⁇ 4.0 s, or any range therein.
  • the fluff pulp sheet on screen fractionation has a % Good of ⁇ 50%.
  • This range includes all values and subranges therebetween, including 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 100%, or any range therein.
  • the fluff pulp sheet on screen fractionation has a % Fines of ⁇ 40%. This range includes all values and subranges therebetween, including 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 15, 20, 25, 30, 35, 40%, or any combination thereof or any range therein.
  • the fluff pulp sheet on screen fractionation has a % Pieces of ⁇ 30%. This range includes all values and subranges therebetween, including 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 15, 20, 25, 30%, or any combination thereof or any range therein.
  • the fluff pulp sheet has a Mullen of ⁇ 90 psi. This range includes all values and subranges therebetween, including 90, 95, 100, 105, 110, 115, 120, 125, 130, 135, 140, 145, 150, 155, 160, 165, 170, 175, 180, 185, 190, 195, 200, 205, 210, 215, 220, 225, 230, 235, 240, 245, 250 psi, and higher, or any range therein.
  • the fluff pulp sheet contains the debonder surfactant in an amount of ⁇ 1 lb solids debonder surfactant per ton of the fluff pulp fibers.
  • This range includes all values and subranges therebetween, including 1, 1.1, 1.2, 1.3, 1.4, 1.5, 1.6, 1.7, 1.8, 1.9, 2, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.8, 2.9, 3, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, 3.7, 3.8, 3.9, 4, 4.0, 5, 5.0, 6, 7, 8, 9, 10, 15, 20 lb solids debonder surfactant per ton of the fluff pulp fibers, and higher, or any combination thereof or any range therein.
  • this range is the total amount over all the debonder surfactants present in the fluff pulp sheet.
  • the cationic trivalent metal, salt thereof, or combination thereof is present in the fluff pulp sheet in an amount of ⁇ 1 lb per ton of fluff pulp fibers.
  • This range includes all values and subranges therebetween, including 1, 1.1, 1.2, 1.3, 1.4, 1.5, 1.6, 1.7, 1.8, 1.9, 2, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.8, 2.9, 3, 3.0, 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, 3.7, 3.8, 3.9, 4, 4.0, 5, 5.0, 6, 7, 8, 9, 10, 15, 20, 25, 30, 35 lb cationic trivalent metal, salt thereof, or combination thereof per ton of the fluff pulp fibers, or any combination thereof or any range therein.
  • this range is the total amount over all the cationic trivalent metal, salt thereof, or combination thereof present in the fluff pulp fibers.
  • the cationic trivalent metal is present in the fluff pulp sheet in an amount ⁇ 150 ppm.
  • This range includes all values and subranges therebetween, including 150, 155, 160, 165, 170, 175, 180, 185, 190, 195, 200, 205, 210, 215, 220, 225, 230, 235, 240, 245, 250, 300, 330, 400, 450, 500, 550, 750, and 1000 ppm, and higher, or any combination thereof or any range therein.
  • the fluff pulp sheet has a moisture content of 25% or less. This range includes all values and subranges therebetween, including 0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 12, 14, 16, 18, 20, 25%, or any combination thereof or range therein.
  • the fluff pulp sheet has a moisture content of 20% or less.
  • the fluff pulp sheet has a moisture content of 10% or less.
  • the fluff pulp sheet has a moisture content of 7% or less.
  • the fluff pulp sheet has a moisture content of about 6.3%.
  • the fluff pulp sheet has a density of 0.5 to 0.75 g/cc. This range includes all values and subranges therebetween, including 0.5, 0.55, 0.6, 0.65, 0.7, and 0.75 g/cc, or any range therein.
  • the fluff pulp sheet has a caliper of 40 to 70 mm. This range includes all values and subranges therebetween, including 40, 45, 50, 55, 60, 65, 70 mm, and any range therein.
  • the fluff pulp sheet may have a basis weight ranging from 100 to 1100 gsm. This range includes all values and subranges therein, for example 100, 125, 150, 175, 200, 225, 250, 275, 300, 400, 500, 600, 700, 800, 900, 1000, 1100, or any combination thereof or range therein.
  • Another embodiment relates to an adsorbent product, paper product, personal care product, medical product, insulating product, construction product, structural material, cement, food product, veterinary product, packaging product, diaper, tampon, sanitary napkin, gauze, bandage, fire retardant, or a combination thereof, comprising the fluff pulp sheet and/or fiberized or shredded fluff pulp sheet, or a combination thereof.
  • Another embodiment relates to the use of an adsorbent product, paper product, personal care product, medical product, insulating product, construction product, structural material, cement, food product, veterinary product, packaging product, diaper, tampon, sanitary napkin, gauze, bandage, fire retardant, or a combination thereof, comprising the fluff pulp sheet and/or fiberized or shredded fluff pulp sheet, or a combination thereof.
  • Fluff pulp and fluff pulp fibers are known in the papermaking art. Any fluff pulp or fluff pulp fiber is suitable for use in the present application, and the selection thereof is within the skill of one knowledgeable in the fluff pulp and fluff pulp fiber arts. One or more than one, or any combination thereof, of fluff pulp and/or fluff pulp fibers may be used.
  • the fluff pulp and fluff pulp fibers may be treated or untreated, and they may optionally contain one or more than one additives, or combination thereof, which are known in the art. Given the teachings herein, the level of treatment, if desired, and the amount of additives may be readily determined by one of ordinary skill in the fluff pulp and fluff pulp fiber arts.
  • Fluff pulp typically includes cellulosic fiber.
  • the type of cellulosic fiber is not critical, and any such fiber known or suitable for use in fluff pulp paper can be used.
  • the fluff pulp can made from pulp fibers derived from hardwood trees, softwood trees, or a combination of hardwood and softwood trees.
  • the fluff pulp fibers may be prepared by one or more known or suitable digestion, refining, and/or bleaching operations such as, for example, known mechanical, thermomechanical, chemical and/or semichemical pulping and/or other well known pulping processes.
  • hardwood pulps as may be used herein include fibrous pulp derived from the woody substance of deciduous trees (angiosperms) such as birch, oak, beech, maple, and eucalyptus.
  • softwood pulps as may be used herein include fibrous pulps derived from the woody substance of coniferous trees (gymnosperms) such as varieties of fir, spruce, and pine, as for example loblolly pine, slash pine, Colorado spruce, balsam fir and Douglas fir.
  • At least a portion of the pulp fibers may be provided from non-woody herbaceous plants including, but not limited to, kenaf, hemp, jute, flax, sisal, or abaca, although legal restrictions and other considerations may make the utilization of hemp and other fiber sources impractical or impossible.
  • Either bleached or unbleached fluff pulp fiber may be utilized. Recycled fluff pulp fibers are also suitable for use.
  • the fluff pulp sheet may suitably contain from 1 to 99 wt % of fluff pulp fibers based upon the total weight of the fluff pulp sheet. In one embodiment, the fluff pulp sheet may contain from 5 to 95 wt % of fluff pulp fibers based upon the total weight of the fluff pulp sheet.
  • ranges include any and all values and subranges therebetween, for example, 1, 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95 and 99 wt %.
  • the fluff pulp sheet may optionally contain from 1 to 100 wt % fluff pulp fibers originating from softwood species based upon the total amount of fluff pulp fibers in the fluff pulp sheet.
  • the fluff pulp sheet may contain 10 to 60 wt % fluff pulp fibers originating from softwood species based upon the total amount of fluff pulp fibers in the fluff pulp sheet. These ranges include 1, 2, 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, and 100 wt % and any and all ranges and subranges therein, based upon the total amount of fluff pulp fibers in the fluff pulp sheet.
  • the softwood fibers may optionally originate from softwood species having a Canadian Standard Freeness (CSF) of from 300 to 750.
  • the fluff pulp sheet contains fluff pulp fibers from a softwood species having a CSF from 400 to 550.
  • ranges include any and all values and subranges therebetween, for example, 300, 310, 320, 330, 340, 350, 360, 370, 380, 390, 400, 410, 420, 430, 440, 450, 460, 470, 480, 490, 500, 510, 520, 530, 540, 550, 560, 570, 580, 590, 600, 610, 620, 630, 640, 650, 660, 670, 680, 690, 700, 710, 720, 730, 740, and 750 CSF.
  • Canadian Standard Freeness is as measured by TAPPI T-227 standard test.
  • the fluff pulp sheet may optionally contain from 1 to 100 wt % fluff pulp fibers originating from hardwood species based upon the total amount of fluff pulp fibers in the fluff pulp sheet.
  • the fluff pulp sheet may contain from 30 to 90 wt % fluff pulp fibers originating from hardwood species, based upon the total amount of fluff pulp fibers in the fluff pulp sheet. These ranges include 1, 2, 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, and 100 wt %, and any and all values and subranges therein, based upon the total amount of fluff pulp fibers in the fluff pulp sheet.
  • All or part of the hardwood fibers may optionally originate from hardwood species having a Canadian Standard Freeness of from 300 to 750.
  • the fluff pulp sheet may contain fibers from hardwood species having CSF values of from 400 to 550. These ranges include 300, 310, 320, 330, 340, 350, 360, 370, 380, 390, 400, 410, 420, 430, 440, 450, 460, 470, 480, 490, 500, 510, 520, 530, 540, 550, 560, 570, 580, 590, 600, 610, 620, 630, 640, 650, 660, 670, 680, 690, 700, 710, 720, 730, 740, and 750 CSF, and any and all ranges and subranges therein.
  • the fluff pulp sheet may optionally contain less refined fluff pulp fibers, for example, less refined softwood fibers, less refined hardwood, or both. Combinations of less refined and more refined fibers are possible.
  • the fluff pulp sheet contains fibers that are at least 2% less refined than that of fluff pulp fibers used in conventional fluff pulp sheets. This range includes all values and subranges therebetween, including at least 2, 5, 10, 15, and 20%. For example, if a conventional fluff pulp sheet contains fibers, softwood and/or hardwood, having a Canadian Standard Freeness of 350, then, in one embodiment, the fluff pulp sheet may contain fibers having a CSF of 385 (i.e. refined 10% less than conventional).
  • the hardwood/softwood fluff pulp fiber weight ratio may optionally range from 0.001 to 1000.
  • the hardwood/softwood ratio may range from 90/10 to 30/60. These ranges include all values and subranges therebetween, including 0.001, 0.002, 0.005, 0.01, 0.02, 0.05, 0.1, 0.2, 0.5, 1, 2, 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 100, 200, 300, 400, 500, 600, 700, 800, 900, and 1000.
  • the softwood fibers, hardwood fibers, or both may be optionally modified by physical and/or chemical processes to obtain the fluff pulp.
  • physical processes include, but are not limited to, electromagnetic and mechanical processes.
  • electrical modifications include, but are not limited to, processes involving contacting the fibers with an electromagnetic energy source such as light and/or electrical current.
  • mechanical modifications include, but are not limited to, processes involving contacting an inanimate object with the fibers. Examples of such inanimate objects include those with sharp and/or dull edges.
  • Such processes also involve, for example, cutting, kneading, pounding, impaling, and the like, and combinations thereof.
  • Nonlimiting examples of chemical modifications include conventional chemical fiber processes such as crosslinking and/or precipitation of complexes thereon.
  • suitable modifications of fibers include those found in U.S. Pat. Nos. 6,592,717, 6,592,712, 6,582,557, 6,579,415, 6,579,414, 6,506,282, 6,471,824, 6,361,651, 6,146,494, H1,704, 5,731,080, 5,698,688, 5,698,074, 5,667,637, 5,662,773, 5,531,728, 5,443,899, 5,360,420, 5,266,250, 5,209,953, 5,160,789, 5,049,235, 4,986,882, 4,496,427, 4,431,481, 4,174,417, 4,166,894, 4,075,136, and 4,022,965, the entire contents of each of which are hereby incorporated, independently, by reference.
  • fluff examples include those commercially available RW SupersoftTM, Supersoft LTM, RW Supersoft PlusTM, GT Supersoft PlusTM, RW Fluff LITETM, RW Fluff 110TM, RW Fluff 150TM, RW Fluff 160TM, GP 4881TM, GT PulpTM, RW SSPTM, GP 4825TM, alone, or in any combination.
  • additives such as pH adjusting agent, whitener, colorant, pigment, optical brightening agent, wetting agent, binder, bleaching agent, trivalent cationic metal, alum, other additive, or a combination thereof may be utilized.
  • Such compounds are known in the art and otherwise commercially available. Given the teachings herein, one of ordinary skill in the fluff pulp and fluff pulp papermaking arts would be able to select and use them as appropriate.
  • the amount of additive is not particularly limited. In one embodiment, the additive may be present in amounts ranging from about 0.005 to about 50 weight percent based on the weight of the fluff pulp sheet.
  • This range includes all values and subranges therebetween, including about 0.005, 0.006, 0.007, 0.008, 0.009, 0.01, 0.02, 0.03, 0.04, 0.05, 0.06, 0.07, 0.08, 0.09, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 15, 20, 25, 30, 35, 40, 45, and 50 weight percent, or any combination thereof, based on the weight of the finished fluff pulp sheet.
  • optical brightening agents may be optionally present.
  • the optical brightening agents are fluorescent dyes or pigments that absorb ultraviolet radiation and reemit it at a higher wavelengths in the visible spectrum (blue), thereby effecting a white, bright appearance to the paper sheet when added to the stock furnish, but any optical brightening agent may be used.
  • optical brighteners include, but are not limited to azoles, biphenyls, coumarins, furans, stilbenes, ionic brighteners, including anionic, cationic, and anionic (neutral) compounds, such as the EccobriteTM and EccowhiteTM compounds available from Eastern Color & Chemical Co.
  • naphthalimides such as the LeucophorTM range of optical brighteners available from the Clariant Corporation (Muttenz, Switzerland), and TinopalTM from Ciba Specialty Chemicals (Basel, Switzerland); salts of such compounds including but not limited to alkali metal salts, alkaline earth metal salts, transition metal salts, organic salts and ammonium salts of such brightening agents; and combinations of one or more of the foregoing agents.
  • optional fillers include, but are not limited to, clay, calcium carbonate, calcium sulfate hemihydrate, and calcium sulfate dehydrate, chalk, GCC, PCC, and the like.
  • optional binders include, but are not limited to, polyvinyl alcohol, Amres (a Kymene type), Bayer Parez, polychloride emulsion, modified starch such as hydroxyethyl starch, starch, polyacrylamide, modified polyacrylamide, polyol, polyol carbonyl adduct, ethanedial/polyol condensate, polyamide, epichlorohydrin, glyoxal, glyoxal urea, ethanedial, aliphatic polyisocyanate, isocyanate, 1,6 hexamethylene diisocyanate, diisocyanate, polyisocyanate, polyester, polyester resin, polyacrylate, polyacrylate resin, acrylate, and methacrylate.
  • Other optional substances include, but are not limited to silicas such as colloids and/or sols. Examples of silicas include, but are not limited to, sodium silicate and/or borosilicates.
  • the composition may optionally and additionally include one or more pigments.
  • pigments include calcium carbonate, kaolin clay, calcined clay, aluminum trihydrate, titanium dioxide, talc, plastic pigment, ground calcium carbonate, precipitated calcium carbonate, amorphous silica, modified calcium carbonate, modified calcined clay, aluminum silicate, zeolite, aluminum oxide, colloidal silica, colloidal alumina slurry, modified calcium carbonate, modified ground calcium carbonate, modified precipitated calcium carbonate, or a mixture thereof.
  • the modified calcium carbonate is modified ground calcium carbonate, modified precipitated calcium carbonate, or a mixture thereof.
  • modified is sometimes referred to as “structured”. These types of pigments are known to those skilled in the papermaking art.
  • the cationic trivalent metal, salt thereof, or combination thereof is contacted with a composition comprising fluff pulp fibers and water at a first pH.
  • a composition comprising fluff pulp fibers and water at a first pH.
  • the order of contacting is not particularly limited.
  • the fluff pulp mixture may be formed into a single or multi-ply web on a papermaking machine such as a Fourdrinier machine or any other suitable papermaking machine known in the art.
  • the basic methodologies involved in making fluff pulp sheets on various papermaking machine configurations are well known to those of ordinary skill in the art and accordingly will not be described in detail herein.
  • the fluff pulp mixture or fluff pulp fibers may have the form of a relatively low consistency aqueous slurry of the pulp fibers optionally together with one or more additives.
  • the fluff pulp mixture or fluff pulp fibers slurry is ejected from a head box onto a table, e.g., a porous endless moving forming sheet or wire, where the liquid, e.g., water, is gradually drained through small openings in the wire, optionally with the aid of one or more suction boxes, until a mat of pulp fibers and optionally the other materials is formed on the wire.
  • the debonder surfactant is applied to the web and the pH is raised to a second pH, which is higher than the first pH.
  • the debonder surfactant is applied by spraying it from, for example, a formation shower at any point along the table.
  • the still-wet web is transferred from the wire to a wet press where more fiber-to-fiber consolidation occurs and the moisture is further decreased.
  • the web is then passed to a dryer section to remove a portion, most of or all of the retained moisture and further consolidate the fibers in the web.
  • the web or fluff pulp sheet may be further treated with one or more of the same or different debonder surfactant, or any combination thereof with a formation shower, spray boom, or the like. If desired, after the dried web or fluff pulp sheet exits the last drying section, additional debonder surfactant may be applied to the dried web or fluff pulp sheet.
  • the cationic trivalent metal, salt thereof, or combination thereof is contacted with the composition at a first pH in order to at least partially solublize the cationic trivalent metal, salt thereof, or combination thereof.
  • alum is added to the stock before the web is formed and spraying on the debonder surfactant.
  • the debonder surfactant and alum are present in the stock, the web is formed, and then additional debonder surfactant is applied.
  • Air pressure is set to 100 psi and the test time is set to 600 seconds.
  • a 5′′ ⁇ 12′′ fluff pulp sample was compressed to a density of 0.154 gms/cm3 using a Beloit Wheeler calendar roll.
  • a 1′′ diameter dosing tube weighing 1000 g was centered on top of the sample.
  • Timing began once the dosage started and ended when all of the saline solution was absorbed and the absorption time was recorded.
  • the Kamas hammermill is a simulation of commercial equipment manufactured and supplied by Kamas Industri AB for use in the production of fluff pulp products. Like the commercial equipment it has variable rotor speed, variable pulp feed speed and exchangeable screens. Pulp strips are hand fed into the mill and are defiberized with free swinging hammers until the resultant fluff is sufficiently broken up to pass through the screen holes.
  • Sample Preparation Condition pulp sheets in the testing room for at least 4 hours. For lab test sheets, trim about 1 ⁇ 2′′ from edges. Cut pulp sheets into strips, 5-10 strips/sample if available, 2 inches wide. Record weights. Clean dust bag if necessary. Ensure that milling chamber is clean and desired screen is properly inserted. Make sure the collection funnel/screen is securely in place. Set rotor to 3300 rpm, feed to 15 cm/sec and use 10 mm screen unless otherwise specified. Feed pulp strip into mill. The energy will be automatically measured and displayed. Make sure weight entry is correct. Collect the shredded pulp in the collection screen receptor below the shredding chamber—maximum capacity is 4-5 strips. Empty fluff into plastic bag. Mix by hand, then seal bag and shake vigorously to get a homogenous fluff mix.
  • a moving high velocity air stream disperses shredded pulp in a covered standard testing sieve while individual fibers are removed through the wire mesh by an applied vacuum.
  • the amount of fluff retained on the sieve wire is determined by weight.
  • the fiber is subjected to fractionation through a series of sieves with consecutively increasing hole openings. The fractions are calculated as a percentage of the original whole fluff weight.
  • Percent passing #200 is reported as Fines. Percent retained on #200 screen, but passing #50 is reported as Good. Percent retained on #50, but passing #14 is reported as Good (Total Good is sum of the two good fractions). Percent retained on #14 screen, but passing #8 screen is reported as Nits (fiber agglomerates). Percent retained on #8 screen is reported as Pieces.
  • SCAN Absorption Tester consisting of a test piece former, absorption unit and timing device.
  • a control was prepared using fully treated fluff with debonder surfactant add at wet-end; EKA 509 HA 4 lbs/ton.
  • a sample in accordance with one of the embodiments of the claimed subject matter was prepared by adding a debonder surfactant at the wet-end, forming and drying a web, and spraying on additional debonder surfactant F60 to the dried web (having a moisture content of about 6.3%); 2 lbs/ton EKA 509 HA and spray-on 2 lbs/ton F60. The results are shown in Table 1.
  • ranges are used as a short hand for describing each and every value that is within the range, including all subranges therein.
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110034891A1 (en) * 2009-08-05 2011-02-10 International Paper Company Dry Fluff Pulp Sheet Additive
US8465624B2 (en) 2010-07-20 2013-06-18 International Paper Company Composition containing a multivalent cationic metal and amine-containing anti-static agent and methods of making and using
US8613836B2 (en) 2009-08-05 2013-12-24 International Paper Company Composition containing a cationic trivalent metal and debonder and methods of making and using the same to enhance fluff pulp quality
US8871059B2 (en) * 2012-02-16 2014-10-28 International Paper Company Methods and apparatus for forming fluff pulp sheets
US8871054B2 (en) 2010-07-22 2014-10-28 International Paper Company Process for preparing fluff pulp sheet with cationic dye and debonder surfactant
US10190260B2 (en) * 2012-08-10 2019-01-29 International Paper Company Fluff pulp and high SAP loaded core
US10260201B2 (en) 2009-08-05 2019-04-16 International Paper Company Process for applying composition containing a cationic trivalent metal and debonder and fluff pulp sheet made from same

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9273432B2 (en) * 2011-03-25 2016-03-01 Nanopaper, Llc Volatile debonder formulations for papermaking
SE538956C2 (en) * 2015-05-22 2017-03-07 Innventia Ab Use of a paper or paperboard product as a middle layer in a paperboard
US11401662B2 (en) * 2017-12-15 2022-08-02 The Procter & Gamble Company Fibrous structures comprising a surfactant
BR112020005283B1 (pt) 2018-04-13 2021-08-03 Eldorado Brasil Celulose S/A Processo para a fabricação de um material de trama melhorado mediante a medição e o ajuste in-situ de concentrações de íons

Citations (88)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1704A (en) * 1840-07-21 Improvement in the construction of the common thumb-latch
US1909A (en) * 1840-12-17 Machinery for and manner of spinning silk
US3395708A (en) * 1966-11-09 1968-08-06 Riegel Textile Corp Method for improving a fluffed fibrous wood pulp batt for use in sanitary products and the products thereof
US3554862A (en) * 1968-06-25 1971-01-12 Riegel Textile Corp Method for producing a fiber pulp sheet by impregnation with a long chain cationic debonding agent
US3627630A (en) * 1969-12-04 1971-12-14 Beloit Corp Method of flash drying pulp
US3819470A (en) * 1971-06-18 1974-06-25 Scott Paper Co Modified cellulosic fibers and method for preparation thereof
US3903889A (en) * 1973-02-16 1975-09-09 First National Bank Of Nevada Disposable liquid absorbent products
US4022965A (en) * 1975-01-13 1977-05-10 Crown Zellerbach Corporation Process for producing reactive, homogeneous, self-bondable lignocellulose fibers
US4075136A (en) * 1974-01-25 1978-02-21 Calgon Corporation Functional ionene compositions and their use
US4081316A (en) * 1974-12-05 1978-03-28 Molnlycke Ab Method for producing fluffed pulp
US4089647A (en) * 1976-03-18 1978-05-16 Ciba-Geigy Ag Process for the dyeing of paper material
US4144122A (en) * 1976-10-22 1979-03-13 Berol Kemi Ab Quaternary ammonium compounds and treatment of cellulose pulp and paper therewith
US4166894A (en) * 1974-01-25 1979-09-04 Calgon Corporation Functional ionene compositions and their use
US4174417A (en) * 1975-10-14 1979-11-13 Kimberly-Clark Corporation Method of forming highly absorbent fibrous webs and resulting products
US4425186A (en) * 1981-03-24 1984-01-10 Buckman Laboratories, Inc. Dimethylamide and cationic surfactant debonding compositions and the use thereof in the production of fluff pulp
US4431481A (en) * 1982-03-29 1984-02-14 Scott Paper Co. Modified cellulosic fibers and method for preparation thereof
US4439271A (en) * 1980-06-05 1984-03-27 Mo Och Domsjo Aktiebolag Process for the oxygen bleaching of cellulose pulp
US4496427A (en) * 1980-01-14 1985-01-29 Hercules Incorporated Preparation of hydrophilic polyolefin fibers for use in papermaking
US4720383A (en) * 1986-05-16 1988-01-19 Quaker Chemical Corporation Softening and conditioning fibers with imidazolinium compounds
US4777736A (en) * 1987-07-01 1988-10-18 Thermo Electron - Web Systems, Inc. System for drying web material utilizing removable/adjustable nozzle
US4973382A (en) * 1988-07-26 1990-11-27 International Paper Company Filtration fabric produced by wet laid process
US4986882A (en) * 1989-07-11 1991-01-22 The Proctor & Gamble Company Absorbent paper comprising polymer-modified fibrous pulps and wet-laying process for the production thereof
US5049235A (en) * 1989-12-28 1991-09-17 The Procter & Gamble Company Poly(methyl vinyl ether-co-maleate) and polyol modified cellulostic fiber
US5061344A (en) * 1986-10-02 1991-10-29 Sunds Defibrator Aktiebolag Method of making soft paper
US5066009A (en) * 1990-08-09 1991-11-19 Brady David L Cue ball scratch indicator
US5160789A (en) * 1989-12-28 1992-11-03 The Procter & Gamble Co. Fibers and pulps for papermaking based on chemical combination of poly(acrylate-co-itaconate), polyol and cellulosic fiber
US5209953A (en) * 1989-08-03 1993-05-11 Kimberly-Clark Corporation Overall printing of tissue webs
US5225047A (en) * 1987-01-20 1993-07-06 Weyerhaeuser Company Crosslinked cellulose products and method for their preparation
US5231122A (en) * 1988-04-11 1993-07-27 Faricerca S.P.A. Fibrous composition for absorbent pads, a method for the manufacture of an absorbent material from such a composition, and an absorbent material produced by the method
US5266250A (en) * 1990-05-09 1993-11-30 Kroyer K K K Method of modifying cellulosic wood fibers and using said fibers for producing fibrous products
US5350370A (en) * 1993-04-30 1994-09-27 Kimberly-Clark Corporation High wicking liquid absorbent composite
US5360420A (en) * 1990-01-23 1994-11-01 The Procter & Gamble Company Absorbent structures containing stiffened fibers and superabsorbent material
US5492759A (en) * 1989-09-27 1996-02-20 Molnlycke Ab Fibres of increased specific surface area, a method for their manufacture, fluff pulp consisting of such fibres and the use of the fibres as absorption material
US5496626A (en) * 1993-04-01 1996-03-05 Kao Corporation Absorbent paper and absorbent article provided therewith
US5516569A (en) * 1991-12-11 1996-05-14 Kimberly-Clark Corporation High absorbency composite
US5662773A (en) * 1995-01-19 1997-09-02 Eastman Chemical Company Process for preparation of cellulose acetate filters for use in paper making
US5667637A (en) * 1995-11-03 1997-09-16 Weyerhaeuser Company Paper and paper-like products including water insoluble fibrous carboxyalkyl cellulose
US5698688A (en) * 1996-03-28 1997-12-16 The Procter & Gamble Company Aldehyde-modified cellulosic fibers for paper products having high initial wet strength
US5720737A (en) * 1994-12-28 1998-02-24 Kao Corporation Absorbent sheet, process for producing the same, and absorbent article
US5731080A (en) * 1992-04-07 1998-03-24 International Paper Company Highly loaded fiber-based composite material
US5851672A (en) * 1994-02-17 1998-12-22 The Procter & Gamble Company Absorbent materials having modified surface characteristics and methods for making the same
US5865822A (en) * 1993-12-28 1999-02-02 Kao Corporation Crosslinked cellulose fibers, absorbent papers and absorbent members using the same, topsheets using the same, and absorbent articles using the same
US6020278A (en) * 1995-12-15 2000-02-01 Gatenholm; Paul Method for the production of highly absorbent hybrid fibers by ozoning and graft polymerizing and hybrid fibers produced through the method
US6059924A (en) * 1998-01-02 2000-05-09 Georgia-Pacific Corporation Fluffed pulp and method of production
US6074524A (en) * 1996-10-23 2000-06-13 Weyerhaeuser Company Readily defibered pulp products
US6086950A (en) * 1994-12-28 2000-07-11 Kao Corporation Absorbent sheet, process for producing the same, and absorbent article using the same
US6146494A (en) * 1997-06-12 2000-11-14 The Procter & Gamble Company Modified cellulosic fibers and fibrous webs containing these fibers
US6159335A (en) * 1997-02-21 2000-12-12 Buckeye Technologies Inc. Method for treating pulp to reduce disintegration energy
US6162329A (en) * 1997-10-01 2000-12-19 The Procter & Gamble Company Soft tissue paper having a softening composition containing an electrolyte deposited thereon
US6248879B1 (en) * 1996-09-26 2001-06-19 Bp Amoco Corporation Polyanhydride crosslinked fibrous cellulosic products and process for their preparation
US6340408B1 (en) * 1996-04-15 2002-01-22 Stora Kopparbergs Bergslags Aktiebolag (Publ) Method of preparation of a fluffed pulp to be used in absorbent products
US6361651B1 (en) * 1998-12-30 2002-03-26 Kimberly-Clark Worldwide, Inc. Chemically modified pulp fiber
US6417425B1 (en) * 2000-02-01 2002-07-09 Basf Corporation Absorbent article and process for preparing an absorbent article
US6419790B1 (en) * 1996-05-09 2002-07-16 Fort James Corporation Methods of making an ultra soft, high basis weight tissue and product produced thereby
US20020099347A1 (en) * 1997-03-21 2002-07-25 Fung-Jou Chen Dual-zoned absorbent webs
US6458343B1 (en) * 1999-05-07 2002-10-01 Goldschmidt Chemical Corporation Quaternary compounds, compositions containing them, and uses thereof
US6471824B1 (en) * 1998-12-29 2002-10-29 Weyerhaeuser Company Carboxylated cellulosic fibers
US20030000139A1 (en) * 2001-06-28 2003-01-02 Anderson James Lars Mesh-backed lawn sod and apparatus for producing the same
US6506282B2 (en) * 1998-12-30 2003-01-14 Kimberly-Clark Worldwide, Inc. Steam explosion treatment with addition of chemicals
US20030034137A1 (en) * 2002-07-19 2003-02-20 Neogi Amar N. Superabsorbent cellulosic fiber
US6533898B2 (en) * 1998-12-18 2003-03-18 Bki Holding Corporation Softened comminution pulp
US6592712B2 (en) * 2000-06-27 2003-07-15 International Paper Company Method to manufacture paper using fiber filler complexes
US6603054B2 (en) * 1998-05-22 2003-08-05 Kimberly-Clark Worldwide, Inc. Fibrous absorbent material and methods of making the same
US6667424B1 (en) * 1998-10-02 2003-12-23 Kimberly-Clark Worldwide, Inc. Absorbent articles with nits and free-flowing particles
US6692603B1 (en) * 1999-10-14 2004-02-17 Kimberly-Clark Worldwide, Inc. Method of making molded cellulosic webs for use in absorbent articles
US20040122389A1 (en) * 2002-12-23 2004-06-24 Mace Tamara Lee Use of hygroscopic treatments to enhance dryness in an absorbent article
US20040123483A1 (en) * 2001-10-30 2004-07-01 Vrbanac Michael David Process to produce dried singulated cellulose pulp fibers
US6770576B2 (en) * 1998-12-24 2004-08-03 Bki Holding Corporation Absorbent structures of chemically treated cellulose fibers
US6808790B2 (en) * 1994-09-21 2004-10-26 Kimberly-Clark Worldwide, Inc. Wet-resilient webs and disposable articles made therewith
US6811879B2 (en) * 2002-08-30 2004-11-02 Weyerhaeuser Company Flowable and meterable densified fiber flake
US6837970B2 (en) * 2001-12-18 2005-01-04 Kimberly-Clark Worldwide, Inc. Wood pulp fiber morphology modifications through thermal drying
US6893473B2 (en) * 2002-05-07 2005-05-17 Weyerhaeuser.Company Whitened fluff pulp
US6909028B1 (en) * 1997-09-15 2005-06-21 Kimberly-Clark Worldwide, Inc. Stable breathable elastic garments
US20050137547A1 (en) * 2003-12-19 2005-06-23 Didier Garnier Gil B. Highly wettable - highly flexible fluff fibers and disposable absorbent products made of those
US6918992B1 (en) * 1999-04-16 2005-07-19 Korsnas Ab Fluff pulp for absorption products
US20060118258A1 (en) * 2004-12-02 2006-06-08 Chmielewski Harry J Plasticizing formulation for fluff pulp and plasticized fluff pulp products made therefrom
US20060137838A1 (en) * 2004-12-29 2006-06-29 Mengkui Luo Method for making carboxyalkyl cellulose
US20060260773A1 (en) * 2005-05-02 2006-11-23 Zheng Tan Ligno cellulosic materials and the products made therefrom
US7175741B2 (en) * 2003-07-16 2007-02-13 Weyerhaeuser, Co. Reducing odor in absorbent products
US7252868B2 (en) * 2004-01-08 2007-08-07 Certainteed Corporation Reinforced fibrous insulation product and method of reinforcing same
US20070218256A1 (en) * 2006-03-16 2007-09-20 Fujifilm Corporation Image-receiving sheet for electrophotography and image forming process
US7334347B2 (en) * 2001-10-30 2008-02-26 Weyerhaeuser Company Process for producing dried, singulated fibers using steam and heated air
US7344593B2 (en) * 2001-03-09 2008-03-18 James Hardie International Finance B.V. Fiber reinforced cement composite materials using chemically treated fibers with improved dispersibility
US20080082069A1 (en) * 2006-10-02 2008-04-03 Jian Qin Absorbent articles comprising carboxyalkyl cellulose fibers having non-permanent and temporary crosslinks
US7407615B2 (en) * 2000-08-09 2008-08-05 Miscanthus-Holding, S.A. Method for producing concrete or mortar using a vegetal aggregate
US7442279B2 (en) * 2005-11-04 2008-10-28 Kimberly-Clark Worldwide, Inc. Method and apparatus for producing tissue paper
US20120073773A1 (en) * 2009-06-16 2012-03-29 Basf Se Method for increasing the dry strength of paper, paperboard, and cardboard
US20130139980A1 (en) * 2011-12-01 2013-06-06 Buckman Laboratories International, Inc. Method And System For Producing Market Pulp And Products Thereof

Family Cites Families (76)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB301682A (en) 1928-03-06 1928-12-06 Robert Mcneill A process and mixture for treating paper making fibres in the making of certain kinds of paper
NL133687C (ru) 1957-01-23
DE1130271B (de) * 1960-10-28 1962-05-24 Hoechst Ag Verfahren zur Verbesserung der Retention mineralischer Fuellstoffe bei der Bildung von Papiervliesen
US3617439A (en) 1969-01-02 1971-11-02 Buckeye Cellulose Corp Process for improving comminution pulp sheets and resulting air-laid absorbent products
JPS5020602B1 (ru) 1970-12-31 1975-07-16
US4036679A (en) 1975-12-29 1977-07-19 Crown Zellerbach Corporation Process for producing convoluted, fiberized, cellulose fibers and sheet products therefrom
US4394212A (en) 1979-10-26 1983-07-19 Scott Paper Company Bleed-fast cationic dyestuffs
US4432833A (en) 1980-05-19 1984-02-21 Kimberly-Clark Corporation Pulp containing hydrophilic debonder and process for its application
DE3111712A1 (de) 1981-03-25 1982-10-07 Basf Ag, 6700 Ludwigshafen Verfahren zum faerben von papier
SU1033616A1 (ru) 1982-04-27 1983-08-07 Центральный научно-исследовательский институт бумаги Мелованный материал
CA1230708A (en) * 1983-07-14 1987-12-29 The Procter & Gamble Company Process for making pulp sheets containing debonding agents
EP0184603A1 (en) * 1984-12-07 1986-06-18 Korsnäs-Marma Ab Process for preparing a fluff pulp
US4664843A (en) * 1985-07-05 1987-05-12 The Dow Chemical Company Mixed metal layered hydroxide-clay adducts as thickeners for water and other hydrophylic fluids
EP0225940A1 (en) 1985-12-20 1987-06-24 Maria Scamvougeras Process for the production of disposable hygienic goods and fluff pulp for using in this process
EP0302947B1 (en) 1987-03-02 1994-06-08 Seiko Epson Corporation Rare earth element-iron base permanent magnet and process for its production
SE462108B (sv) 1987-09-22 1990-05-07 Air Laid Tissue As Framstaellning av torrformat tissuepapper, varvid en faergad massa anvaendes
SE461472B (sv) 1988-06-29 1990-02-19 Mo Och Domsjoe Ab Lignocellulosamaterial med arkstruktur foer torrdesintegrering och foerfarande foer framstaellning daerav
FI87372C (fi) 1989-03-30 1992-12-28 Genencor Int Europ Foerfarande foer framstaellning av fluffmassa med foerbaettrad rivbarhet
ZA903296B (en) 1989-05-26 1991-02-27 Kimerly Clark Corp Vertical wicking structures from wet crosslinked cellulose fiber structures
SU1656032A1 (ru) 1989-06-06 1991-06-15 Киевский Политехнический Институт Им.50-Летия Великой Октябрьской Социалистической Революции Способ подготовки бумажной массы дл изготовлени конденсаторной бумаги
SE500871C2 (sv) 1989-09-27 1994-09-19 Sca Research Ab Aluminiumsaltimpregnerade fibrer, sätt att framställa dessa, absorptionsmaterial för användning i hygienartiklar och användning av fibrerna som absorptionsmaterial
SE469843B (sv) 1992-02-14 1993-09-27 Stora Kopparbergs Bergslags Ab Fluffmassa och sätt vid beredning av fluffmassa
US5547541A (en) 1992-08-17 1996-08-20 Weyerhaeuser Company Method for densifying fibers using a densifying agent
US5807364A (en) 1992-08-17 1998-09-15 Weyerhaeuser Company Binder treated fibrous webs and products
CA2140263C (en) 1992-08-17 2005-09-13 Michael R. Hansen Particle binders
DE4396289T1 (de) * 1992-11-25 1995-12-21 Helix Inc Verarbeiten von Pulpe oder Faserbrei
IT1260117B (it) 1992-12-30 1996-03-28 Procedimento di fabbricazione di pannelli di prodotti simili in materiale isolante e pannello o prodotto ottenuto mediante tale procedimento.
NL9300789A (nl) 1993-05-10 1994-12-01 Jonker Johannes Cornelis Wegwerpluier.
US5447603A (en) * 1993-07-09 1995-09-05 The Dow Chemical Company Process for removing metal ions from liquids
US5402938A (en) 1993-09-17 1995-04-04 Exair Corporation Fluid amplifier with improved operating range using tapered shim
WO1995020066A1 (en) 1994-01-21 1995-07-27 Rayonier, Inc. Cold caustic extraction of pulps for absorbent products
WO1996002697A1 (en) 1994-07-14 1996-02-01 Union Camp Patent Holding, Inc. Improved bleaching of high consistency lignocellulosic pulp
US5780616A (en) 1994-11-10 1998-07-14 The Procter & Gamble Company Cationic polymer
BR9509869A (pt) 1994-12-09 1997-11-25 Procter & Gamble Composto absorvente e processo para produzir esse composto absorvente
US6228217B1 (en) 1995-01-13 2001-05-08 Hercules Incorporated Strength of paper made from pulp containing surface active, carboxyl compounds
US5518540A (en) 1995-06-07 1996-05-21 Materials Technology, Limited Cement treated with high-pressure CO2
US5698076A (en) 1996-08-21 1997-12-16 The Procter & Gamble Company Tissue paper containing a vegetable oil based quaternary ammonium compound
DE69719326T2 (de) 1996-06-10 2003-10-16 Korea Inst Sci & Tech Verfahren zur herstellung einer homogenen celluloselösung in n-methylmorpholin-n-oxid
US5776308A (en) * 1996-10-10 1998-07-07 Rayonier Research Center Method of softening pulp and pulp products produced by same
US5725736A (en) 1996-10-25 1998-03-10 Kimberly-Clark Worldwide, Inc. Tissue containing silicone betaines
USH1704H (en) 1996-12-13 1998-01-06 Kimberly-Clark Worldwide, Inc. Modified cellulose fiber having improved curl
EP0896045A1 (en) 1997-08-06 1999-02-10 Akzo Nobel N.V. A composition for treatment of cellulosic material
ZA987682B (en) 1997-09-15 1999-02-25 Kimberly Clark Co Stable breathable elastic articles
SE511857C2 (sv) 1998-04-28 1999-12-06 Sca Hygiene Prod Ab Absorberande struktur med förbättrade absorptionsegenskaper innehållande minst 50 vikts% superabsorberande material
RU21793U1 (ru) 2001-10-23 2002-02-20 Кукушкин Владимир Дмитриевич Стеновой кладочный элемент
US20030139716A1 (en) 2001-11-27 2003-07-24 Torgny Falk Absorbent product
DE60321329D1 (de) 2002-04-09 2008-07-10 Fpinnovations Geschwollene stärke-latex-zusammensetzungen zur anwendung bei der papierherstellung
US20050000669A1 (en) 2003-03-14 2005-01-06 Hugh West Saccharide treated cellulose pulp sheets
US7186318B2 (en) 2003-12-19 2007-03-06 Kimberly-Clark Worldwide, Inc. Soft tissue hydrophilic tissue products containing polysiloxane and having unique absorbent properties
SE0303511D0 (sv) 2003-12-22 2003-12-22 Sca Hygiene Prod Ab Method for adding a softening and/or debonding agent to a hydroentangled nonwoven material
RU2264453C2 (ru) 2003-12-30 2005-11-20 Ирина Борисовна Сорокулова Биопрепарат "ирилис" ветеринарного назначения
US7592391B2 (en) 2004-03-18 2009-09-22 Bostik, Inc. Process for preparing an aqueous dispersion of a quaternary ammonium salt containing vinyl copolymer
WO2006004464A1 (en) 2004-07-02 2006-01-12 Sca Hygiene Products Ab Absorbent layer structure
US20060008621A1 (en) 2004-07-08 2006-01-12 Gusky Robert I Textured air laid substrate
KR20070067138A (ko) 2004-10-13 2007-06-27 클라리언트 파이넌스 (비브이아이)리미티드 알칸올아민의 지방산 에스터 및 이의 연화제로서의 용도
US7670459B2 (en) 2004-12-29 2010-03-02 Kimberly-Clark Worldwide, Inc. Soft and durable tissue products containing a softening agent
RU2347030C1 (ru) 2004-12-30 2009-02-20 Акцо Нобель Н.В. Композиция
US20060173432A1 (en) 2005-02-01 2006-08-03 Laumer Jason M Absorbent articles comprising polyamine-coated superabsorbent polymers
US7312297B2 (en) 2005-02-16 2007-12-25 Rayonier Trs Holdings, Inc. Treatment composition for making acquisition fluff pulp in sheet form
US20060246186A1 (en) * 2005-04-28 2006-11-02 Nowak Michael J Polycarboxylated polymer, method of making, method of use, and superabsorbent compositions including the same
WO2007057043A1 (en) 2005-11-18 2007-05-24 Sca Hygiene Products Ab Absorbent articles comprising acidic superabsorber and an organic zinc salt
US7967948B2 (en) 2006-06-02 2011-06-28 International Paper Company Process for non-chlorine oxidative bleaching of mechanical pulp in the presence of optical brightening agents
US8728274B2 (en) 2006-09-22 2014-05-20 Akzo Nobel N.V. Treatment of pulp
AU2006350909B2 (en) 2006-11-17 2013-07-04 Sca Hygiene Products Ab Absorbent articles comprising acidic cellulosic fibers and an organic zinc salt
CN101349030A (zh) 2007-07-17 2009-01-21 梁永林 一种抗氧化防菌纸
CN101575820B (zh) 2009-06-08 2011-12-07 昆明理工大学 一种纸浆金属离子去除及漂白的方法
CA2765094C (en) 2009-06-09 2016-02-09 Buckeye Technologies Inc. Dyed cellulose comminution sheet, dyed nonwoven material, and processes for their production
CN101586287B (zh) 2009-06-17 2011-04-27 东华大学 一种湿巾材料的制造方法
MY162376A (en) 2009-08-05 2017-06-15 Shell Int Research Method for monitoring a well
CN102472003B (zh) 2009-08-05 2014-10-29 国际纸业公司 用于施加包含阳离子三价金属和解胶剂的组合物的方法以及由该方法制造的绒毛浆片材
PT2462276E (pt) 2009-08-05 2015-02-12 Int Paper Co Aditivo para folha de polpa de felpa seca
US8115050B2 (en) 2009-12-07 2012-02-14 The Natural Baby Company, LLC Soaker pad for cloth diaper
US8328988B2 (en) 2010-03-15 2012-12-11 Weyerhaeuser Nr Company Reduction of the adsorption of quaternary ammonium salts onto cellulosic fibers
ES2952420T3 (es) 2010-07-20 2023-10-31 Int Paper Co Composición que contiene un metal catiónico multivalente y un agente antiestático que contiene amina y métodos de fabricación y uso
EP2596167B1 (en) 2010-07-22 2017-03-22 International Paper Company Process for preparing fluff pulp sheet with cationic dye and debonder surfactant and fluff pulp sheet made from same
US20120310186A1 (en) 2011-06-06 2012-12-06 Tyco Healthcare Group Lp Dressings and Related Methods Therefor

Patent Citations (98)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1704A (en) * 1840-07-21 Improvement in the construction of the common thumb-latch
US1909A (en) * 1840-12-17 Machinery for and manner of spinning silk
US3395708A (en) * 1966-11-09 1968-08-06 Riegel Textile Corp Method for improving a fluffed fibrous wood pulp batt for use in sanitary products and the products thereof
US3554862A (en) * 1968-06-25 1971-01-12 Riegel Textile Corp Method for producing a fiber pulp sheet by impregnation with a long chain cationic debonding agent
US3627630A (en) * 1969-12-04 1971-12-14 Beloit Corp Method of flash drying pulp
US3819470A (en) * 1971-06-18 1974-06-25 Scott Paper Co Modified cellulosic fibers and method for preparation thereof
US3903889A (en) * 1973-02-16 1975-09-09 First National Bank Of Nevada Disposable liquid absorbent products
US4166894A (en) * 1974-01-25 1979-09-04 Calgon Corporation Functional ionene compositions and their use
US4075136A (en) * 1974-01-25 1978-02-21 Calgon Corporation Functional ionene compositions and their use
US4081316A (en) * 1974-12-05 1978-03-28 Molnlycke Ab Method for producing fluffed pulp
US4022965A (en) * 1975-01-13 1977-05-10 Crown Zellerbach Corporation Process for producing reactive, homogeneous, self-bondable lignocellulose fibers
US4174417A (en) * 1975-10-14 1979-11-13 Kimberly-Clark Corporation Method of forming highly absorbent fibrous webs and resulting products
US4089647A (en) * 1976-03-18 1978-05-16 Ciba-Geigy Ag Process for the dyeing of paper material
US4144122A (en) * 1976-10-22 1979-03-13 Berol Kemi Ab Quaternary ammonium compounds and treatment of cellulose pulp and paper therewith
US4496427A (en) * 1980-01-14 1985-01-29 Hercules Incorporated Preparation of hydrophilic polyolefin fibers for use in papermaking
US4439271A (en) * 1980-06-05 1984-03-27 Mo Och Domsjo Aktiebolag Process for the oxygen bleaching of cellulose pulp
US4425186A (en) * 1981-03-24 1984-01-10 Buckman Laboratories, Inc. Dimethylamide and cationic surfactant debonding compositions and the use thereof in the production of fluff pulp
US4431481A (en) * 1982-03-29 1984-02-14 Scott Paper Co. Modified cellulosic fibers and method for preparation thereof
US4720383A (en) * 1986-05-16 1988-01-19 Quaker Chemical Corporation Softening and conditioning fibers with imidazolinium compounds
US5061344A (en) * 1986-10-02 1991-10-29 Sunds Defibrator Aktiebolag Method of making soft paper
US5225047A (en) * 1987-01-20 1993-07-06 Weyerhaeuser Company Crosslinked cellulose products and method for their preparation
US4777736A (en) * 1987-07-01 1988-10-18 Thermo Electron - Web Systems, Inc. System for drying web material utilizing removable/adjustable nozzle
US5231122A (en) * 1988-04-11 1993-07-27 Faricerca S.P.A. Fibrous composition for absorbent pads, a method for the manufacture of an absorbent material from such a composition, and an absorbent material produced by the method
US4973382A (en) * 1988-07-26 1990-11-27 International Paper Company Filtration fabric produced by wet laid process
US4986882A (en) * 1989-07-11 1991-01-22 The Proctor & Gamble Company Absorbent paper comprising polymer-modified fibrous pulps and wet-laying process for the production thereof
US5209953A (en) * 1989-08-03 1993-05-11 Kimberly-Clark Corporation Overall printing of tissue webs
US5492759A (en) * 1989-09-27 1996-02-20 Molnlycke Ab Fibres of increased specific surface area, a method for their manufacture, fluff pulp consisting of such fibres and the use of the fibres as absorption material
US5160789A (en) * 1989-12-28 1992-11-03 The Procter & Gamble Co. Fibers and pulps for papermaking based on chemical combination of poly(acrylate-co-itaconate), polyol and cellulosic fiber
US5443899A (en) * 1989-12-28 1995-08-22 The Procter & Gamble Company Fibers and pulps for papermaking based on chemical combination of poly(acrylate-co-itaconate), polyol and cellulosic fiber
US5049235A (en) * 1989-12-28 1991-09-17 The Procter & Gamble Company Poly(methyl vinyl ether-co-maleate) and polyol modified cellulostic fiber
US5698074A (en) * 1989-12-28 1997-12-16 The Procter & Gamble Company Fibers and pulps for papermaking based on chemical combination of poly (acrylate-co-itaconate), polyol and cellulosic fiber
US5360420A (en) * 1990-01-23 1994-11-01 The Procter & Gamble Company Absorbent structures containing stiffened fibers and superabsorbent material
US5531728A (en) * 1990-01-23 1996-07-02 The Procter & Gamble Company Absorbent structures containing thermally-bonded stiffened fibers and superabsorbent material
US5266250A (en) * 1990-05-09 1993-11-30 Kroyer K K K Method of modifying cellulosic wood fibers and using said fibers for producing fibrous products
US5066009A (en) * 1990-08-09 1991-11-19 Brady David L Cue ball scratch indicator
US5516569A (en) * 1991-12-11 1996-05-14 Kimberly-Clark Corporation High absorbency composite
US5731080A (en) * 1992-04-07 1998-03-24 International Paper Company Highly loaded fiber-based composite material
US5496626A (en) * 1993-04-01 1996-03-05 Kao Corporation Absorbent paper and absorbent article provided therewith
US5350370A (en) * 1993-04-30 1994-09-27 Kimberly-Clark Corporation High wicking liquid absorbent composite
US5865822A (en) * 1993-12-28 1999-02-02 Kao Corporation Crosslinked cellulose fibers, absorbent papers and absorbent members using the same, topsheets using the same, and absorbent articles using the same
US5851672A (en) * 1994-02-17 1998-12-22 The Procter & Gamble Company Absorbent materials having modified surface characteristics and methods for making the same
US6808790B2 (en) * 1994-09-21 2004-10-26 Kimberly-Clark Worldwide, Inc. Wet-resilient webs and disposable articles made therewith
US5720737A (en) * 1994-12-28 1998-02-24 Kao Corporation Absorbent sheet, process for producing the same, and absorbent article
US6086950A (en) * 1994-12-28 2000-07-11 Kao Corporation Absorbent sheet, process for producing the same, and absorbent article using the same
US5662773A (en) * 1995-01-19 1997-09-02 Eastman Chemical Company Process for preparation of cellulose acetate filters for use in paper making
US5667637A (en) * 1995-11-03 1997-09-16 Weyerhaeuser Company Paper and paper-like products including water insoluble fibrous carboxyalkyl cellulose
US6020278A (en) * 1995-12-15 2000-02-01 Gatenholm; Paul Method for the production of highly absorbent hybrid fibers by ozoning and graft polymerizing and hybrid fibers produced through the method
US5698688A (en) * 1996-03-28 1997-12-16 The Procter & Gamble Company Aldehyde-modified cellulosic fibers for paper products having high initial wet strength
US6340408B1 (en) * 1996-04-15 2002-01-22 Stora Kopparbergs Bergslags Aktiebolag (Publ) Method of preparation of a fluffed pulp to be used in absorbent products
US6419790B1 (en) * 1996-05-09 2002-07-16 Fort James Corporation Methods of making an ultra soft, high basis weight tissue and product produced thereby
US6248879B1 (en) * 1996-09-26 2001-06-19 Bp Amoco Corporation Polyanhydride crosslinked fibrous cellulosic products and process for their preparation
US6074524A (en) * 1996-10-23 2000-06-13 Weyerhaeuser Company Readily defibered pulp products
US6296737B1 (en) * 1996-10-23 2001-10-02 Weyerhaeuser Company Method of making readily debonded pulp products
US6159335A (en) * 1997-02-21 2000-12-12 Buckeye Technologies Inc. Method for treating pulp to reduce disintegration energy
US20020099347A1 (en) * 1997-03-21 2002-07-25 Fung-Jou Chen Dual-zoned absorbent webs
US6146494A (en) * 1997-06-12 2000-11-14 The Procter & Gamble Company Modified cellulosic fibers and fibrous webs containing these fibers
US6909028B1 (en) * 1997-09-15 2005-06-21 Kimberly-Clark Worldwide, Inc. Stable breathable elastic garments
US6162329A (en) * 1997-10-01 2000-12-19 The Procter & Gamble Company Soft tissue paper having a softening composition containing an electrolyte deposited thereon
US6059924A (en) * 1998-01-02 2000-05-09 Georgia-Pacific Corporation Fluffed pulp and method of production
US6603054B2 (en) * 1998-05-22 2003-08-05 Kimberly-Clark Worldwide, Inc. Fibrous absorbent material and methods of making the same
US6667424B1 (en) * 1998-10-02 2003-12-23 Kimberly-Clark Worldwide, Inc. Absorbent articles with nits and free-flowing particles
US7265258B2 (en) * 1998-10-02 2007-09-04 Kimberly-Clark Worldwide, Inc. Absorbent articles with nits and free-flowing particles
US6533898B2 (en) * 1998-12-18 2003-03-18 Bki Holding Corporation Softened comminution pulp
US6770576B2 (en) * 1998-12-24 2004-08-03 Bki Holding Corporation Absorbent structures of chemically treated cellulose fibers
US6582557B2 (en) * 1998-12-29 2003-06-24 Weyerhaeuser Company Fibrous composition including carboxylated cellulosic fibers
US6579414B2 (en) * 1998-12-29 2003-06-17 Weyerhaeuser Company Method for enhancing the softness of a fibrous web
US6579415B2 (en) * 1998-12-29 2003-06-17 Weyerhaeuser Company Method of increasing the wet strength of a fibrous sheet
US6471824B1 (en) * 1998-12-29 2002-10-29 Weyerhaeuser Company Carboxylated cellulosic fibers
US6592717B2 (en) * 1998-12-29 2003-07-15 Weyerhaeuser Company Carboxylated cellulosic fibrous web and method of making the same
US6506282B2 (en) * 1998-12-30 2003-01-14 Kimberly-Clark Worldwide, Inc. Steam explosion treatment with addition of chemicals
US6361651B1 (en) * 1998-12-30 2002-03-26 Kimberly-Clark Worldwide, Inc. Chemically modified pulp fiber
US6918992B1 (en) * 1999-04-16 2005-07-19 Korsnas Ab Fluff pulp for absorption products
US6458343B1 (en) * 1999-05-07 2002-10-01 Goldschmidt Chemical Corporation Quaternary compounds, compositions containing them, and uses thereof
US6692603B1 (en) * 1999-10-14 2004-02-17 Kimberly-Clark Worldwide, Inc. Method of making molded cellulosic webs for use in absorbent articles
US6417425B1 (en) * 2000-02-01 2002-07-09 Basf Corporation Absorbent article and process for preparing an absorbent article
US6592712B2 (en) * 2000-06-27 2003-07-15 International Paper Company Method to manufacture paper using fiber filler complexes
US7407615B2 (en) * 2000-08-09 2008-08-05 Miscanthus-Holding, S.A. Method for producing concrete or mortar using a vegetal aggregate
US7344593B2 (en) * 2001-03-09 2008-03-18 James Hardie International Finance B.V. Fiber reinforced cement composite materials using chemically treated fibers with improved dispersibility
US20030000139A1 (en) * 2001-06-28 2003-01-02 Anderson James Lars Mesh-backed lawn sod and apparatus for producing the same
US20040123483A1 (en) * 2001-10-30 2004-07-01 Vrbanac Michael David Process to produce dried singulated cellulose pulp fibers
US7334347B2 (en) * 2001-10-30 2008-02-26 Weyerhaeuser Company Process for producing dried, singulated fibers using steam and heated air
US6837970B2 (en) * 2001-12-18 2005-01-04 Kimberly-Clark Worldwide, Inc. Wood pulp fiber morphology modifications through thermal drying
US6893473B2 (en) * 2002-05-07 2005-05-17 Weyerhaeuser.Company Whitened fluff pulp
US20030034137A1 (en) * 2002-07-19 2003-02-20 Neogi Amar N. Superabsorbent cellulosic fiber
US6811879B2 (en) * 2002-08-30 2004-11-02 Weyerhaeuser Company Flowable and meterable densified fiber flake
US20040122389A1 (en) * 2002-12-23 2004-06-24 Mace Tamara Lee Use of hygroscopic treatments to enhance dryness in an absorbent article
US7175741B2 (en) * 2003-07-16 2007-02-13 Weyerhaeuser, Co. Reducing odor in absorbent products
US20050137547A1 (en) * 2003-12-19 2005-06-23 Didier Garnier Gil B. Highly wettable - highly flexible fluff fibers and disposable absorbent products made of those
US7479578B2 (en) * 2003-12-19 2009-01-20 Kimberly-Clark Worldwide, Inc. Highly wettable—highly flexible fluff fibers and disposable absorbent products made of those
US7252868B2 (en) * 2004-01-08 2007-08-07 Certainteed Corporation Reinforced fibrous insulation product and method of reinforcing same
US20060118258A1 (en) * 2004-12-02 2006-06-08 Chmielewski Harry J Plasticizing formulation for fluff pulp and plasticized fluff pulp products made therefrom
US20060137838A1 (en) * 2004-12-29 2006-06-29 Mengkui Luo Method for making carboxyalkyl cellulose
US20060260773A1 (en) * 2005-05-02 2006-11-23 Zheng Tan Ligno cellulosic materials and the products made therefrom
US7442279B2 (en) * 2005-11-04 2008-10-28 Kimberly-Clark Worldwide, Inc. Method and apparatus for producing tissue paper
US20070218256A1 (en) * 2006-03-16 2007-09-20 Fujifilm Corporation Image-receiving sheet for electrophotography and image forming process
US20080082069A1 (en) * 2006-10-02 2008-04-03 Jian Qin Absorbent articles comprising carboxyalkyl cellulose fibers having non-permanent and temporary crosslinks
US20120073773A1 (en) * 2009-06-16 2012-03-29 Basf Se Method for increasing the dry strength of paper, paperboard, and cardboard
US20130139980A1 (en) * 2011-12-01 2013-06-06 Buckman Laboratories International, Inc. Method And System For Producing Market Pulp And Products Thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Smook, Gary A., Handbook of Pulp and Paper Terminology, Angus Wilde Publications, 1990, p 85. *
Smook, Gary A., Handbook of Pulp and Paper Terminology, Angus Wilde Publications, 1990, pp 90, 163, 171, 176, 195, 205 and 206. *

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