US20100025217A1 - Centrally Controlled Coke Oven Aeration System for Primary and Secondary Air - Google Patents

Centrally Controlled Coke Oven Aeration System for Primary and Secondary Air Download PDF

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Publication number
US20100025217A1
US20100025217A1 US12/084,841 US8484106A US2010025217A1 US 20100025217 A1 US20100025217 A1 US 20100025217A1 US 8484106 A US8484106 A US 8484106A US 2010025217 A1 US2010025217 A1 US 2010025217A1
Authority
US
United States
Prior art keywords
locking elements
adjusting element
ventilation device
cokemaking
locking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/084,841
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English (en)
Inventor
Franz-Josef Schuecker
Ronald Kim
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Industrial Solutions AG
Original Assignee
Uhde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uhde GmbH filed Critical Uhde GmbH
Assigned to UHDE GMBH reassignment UHDE GMBH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KIM, RONALD, SCHUECKER, FRANZ-JOSEF
Publication of US20100025217A1 publication Critical patent/US20100025217A1/en
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B21/00—Heating of coke ovens with combustible gases
    • C10B21/10—Regulating and controlling the combustion
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B15/00—Other coke ovens
    • C10B15/02—Other coke ovens with floor heating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B21/00—Heating of coke ovens with combustible gases
    • C10B21/20—Methods of heating ovens of the chamber oven type
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B41/00—Safety devices, e.g. signalling or controlling devices for use in the discharge of coke

Definitions

  • This invention relates to a device and a method for supplying combustion air for the combustion of coking gas in cokemaking chambers of coke ovens built in flat-type construction and arranged as a battery of coke ovens for the so-called non-recovery or heat-recovery process.
  • This device at least comprises a vent port for each cokemaking chamber, said vent port extending through the relevant coke oven door or its wall surrounding it, as well as vent ports for supplying secondary air into the heating flues.
  • a freely-supported locking element is provided for each vent port.
  • All locking elements are mechanically connected to at least one adjusting element controlled and driven from a central point.
  • the adjusting element continuously actuates the locking elements depending on the demand for combustion air in the cokemaking chamber.
  • the mechanical connection of each individual locking element with the central adjusting element can be effected separately, wherein especially the starting position of each individual locking element at the beginning of the cokemaking process of the pertaining cokemaking chamber can be adjusted independently of the other locking elements of the adjacent cokemaking chambers.
  • Heating of heat-recovery ovens is usually performed by combustion of gas evolving on cokemaking. Combustion is controlled in such a manner that part of the gas above the coal charge burns off with primary air in the oven chamber. This partly burnt gas is fed through channels that are also designated as “downcomers” to the heating flues in the oven chamber sole and completely burnt there by the addition of further combustion air, which is called secondary air.
  • This invention solves this task by providing a device for supplying combustion air for the combustion of coking gas in cokemaking chambers of coke ovens built in flat-type construction and arranged as a battery of coke ovens, wherein the venting device consists of at least one vent port for each cokemaking chamber, said vent port extending through the relevant coke oven door or through its wall surrounding it, and wherein a freely-supported locking element is provided for each vent port, wherein
  • connection between the locking element and the adjusting element as used hereunder shall be understood to mean that both elements may be connected to each other in a detachable way through a coupling element, for example a lever, rope tackle, chain, lever arm, etc. as well as combinations of these elements.
  • a coupling element for example a lever, rope tackle, chain, lever arm, etc. as well as combinations of these elements.
  • Advantageous embodiments provide for configuring the adjusting element as a rotating chain or as a steel cable.
  • Using a screw spindle as adjusting element is another suitable embodiment. All these adjusting elements permit a permanent actuation into one moving direction which is very advantageous for the continuous overall process.
  • the device embodying this invention can be configured in such a manner that locking plates are installed as locking elements, said locking plates being supported in such a way that when actuated by the coupling element they are moved mainly in parallel to the oven door.
  • vent port For a directed flow of primary gas it is of advantage for the vent port to be of a rotary-symmetrical shape. Therefore, the use of locking elements configured as upright standing locking plates and supported in vertically or horizontally rotatable arrangement around a central axle is advantageous.
  • the locking elements are formed by at least two overlapping and reciprocally slideable facettes, with both facettes ideally exposing a polygonal and point-symmetrical or nearly circular cross-section when partly opened.
  • a still advanced improvement resides in configuring the locking elements in conical shape, with the tip pointing towards the oven interior when built-in.
  • This embodiment can still be further optimised in such a way that the vent port has the same or a wider angle of aperture than the pertaining conical locking elements.
  • the aspirated air is whirled-up minimally in the area of the locking element as well as in the area of the vent port and shaped to a gas jet independently of the size of the exposed cross-section.
  • the conical locking element is moved via a lever structure and/or a spindle in the longitudinal direction of the vent port so that a circular ring gap is exposed when partly opened.
  • the ventilation device can be further improved by connecting the locking element with the adjusting element in such a way that it is automatically released from the adjusting element when being in the end position and when the vent port has been completely closed.
  • This invention furthermore comprises a device for supplying combustion air in coke ovens, in which the ventilation device embodying this invention as described before is implemented by one of its embodiment variants, with the sequence of the method being as set forth below:
  • An improved variant of this method is that the locking element being in the end position is automatically released from the adjusting element.
  • At least two central adjusting elements are provided for, wherein one adjusting element thereof actuates the locking elements for primary air and wherein the other central adjusting element actuates the locking elements for secondary air. Throughout the entire carbonisation time, the two adjusting elements are controllable completely independently of each other.
  • This invention also encompasses the use of the ventilation device embodying this invention in one of the embodiment variants outlined hereinabove with a method for supplying combustion air in cokemaking chambers of coke ovens built in flat-type construction and arranged as a battery of coke ovens.
  • FIG. 1 shows a coke oven 1 in a front view.
  • coke oven 1 has a coke oven door 2 in which two vent ports 3 for primary air are arranged.
  • heating flues 4 Located beneath said coke oven door 2 and illustrated by dotted lines are heating flues 4 extending under the oven space.
  • the vent ports 5 for supplying secondary air into these heating flues 4 are arranged near the bottom beneath said heating flues 4 .
  • FIG. 1 shows the locking elements 6 for said vent ports 3 of the primary air supply and the locking elements 7 for the vent ports 5 of the secondary air supply.
  • Each locking element mainly consists of a locking plate 9 and a lever arm 10 and it is supported at an axle 8 around which said locking element can be moved in rotating motion.
  • the lever arms 10 of said locking elements 6 are connected in a detachable way with a rotating chain 11 and the locking elements 7 are connected in a detachable way with a rotating chain 12 .
  • FIG. 2 shows the front view of two coke ovens 1 representing a major coke oven battery as indicated by the two arrows I and II. These two coke ovens 1 are at different stages of coal carbonisation.
  • the coke oven 1 shown on the right side is in the initial stage of coal carbonisation, and therefore the locking elements 6 hardly overlap the vent ports 3 .
  • the lever arm 10 is connected via a minor chain 15 to the rotating chain 11 .
  • the arrangement in the area of the vent ports 5 for secondary air is analogous.
  • the locking elements 7 and, respectively, their lever arms 10 are connected via minor chains 16 to the rotating chain 12 .
  • FIG. 3 A special embodiment variant of the locking elements 6 and 7 is illustrated in FIG. 3 .
  • a rotary-symmetrical locking element 6 having a locking head 17 in form of a truncated cone to which a cylindrical guiding rod 18 is fastened.
  • the guiding rod is firmly connected to a spring bridge 19 fastened to said coke oven door 2 .
  • the guiding rod 18 is guided in a guiding tube 20 and connected with its rear end via a small chain 15 to the rotating chain 11 .
  • the springs of the spring bridge 19 are pre-stressed by expansion so that the vent port 3 is largely open.
  • the spring bridge 19 is relieved, the locking element 6 is moved in the direction of the coke oven door 2 , and the locking head 17 is introduced into the conical vent port 3 .
  • the pre-stressing shall be chosen such that after relief of the chain 15 and spring bridge 19 a complete closure of vent port 3 is achieved.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Coke Industry (AREA)
  • Specific Sealing Or Ventilating Devices For Doors And Windows (AREA)
US12/084,841 2005-11-18 2006-10-11 Centrally Controlled Coke Oven Aeration System for Primary and Secondary Air Abandoned US20100025217A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102005055483A DE102005055483A1 (de) 2005-11-18 2005-11-18 Zentral gesteuertes Koksofenbelüftungssystem für Primär- und Sekundärluft
DE102005055483.0 2005-11-18
PCT/EP2006/009799 WO2007057076A1 (fr) 2005-11-18 2006-10-11 Systeme de ventilation de four a coke a controle central pour air primaire et secondaire

Publications (1)

Publication Number Publication Date
US20100025217A1 true US20100025217A1 (en) 2010-02-04

Family

ID=37387447

Family Applications (1)

Application Number Title Priority Date Filing Date
US12/084,841 Abandoned US20100025217A1 (en) 2005-11-18 2006-10-11 Centrally Controlled Coke Oven Aeration System for Primary and Secondary Air

Country Status (19)

Country Link
US (1) US20100025217A1 (fr)
EP (1) EP1948759A1 (fr)
JP (1) JP5114422B2 (fr)
KR (1) KR20080069170A (fr)
CN (1) CN101309996B (fr)
AP (1) AP2008004466A0 (fr)
AR (1) AR056158A1 (fr)
AU (1) AU2006314857B2 (fr)
BR (1) BRPI0618679A2 (fr)
CA (1) CA2628316C (fr)
DE (1) DE102005055483A1 (fr)
EG (1) EG25241A (fr)
HK (1) HK1122061A1 (fr)
MY (1) MY149240A (fr)
RU (1) RU2422490C2 (fr)
TW (1) TWI319432B (fr)
UA (1) UA91571C2 (fr)
WO (1) WO2007057076A1 (fr)
ZA (1) ZA200804138B (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090032382A1 (en) * 2006-01-31 2009-02-05 Franz-Josef Schuecker Coke Oven With Optimized Control and Method of Control
US20100065413A1 (en) * 2006-09-21 2010-03-18 Uhde Gmbh Coke oven comprising tertiary heating elements in the gas chamber
US20100300867A1 (en) * 2007-09-07 2010-12-02 Ronald Kim Device for feeding combustion air or gas influencing coal carbonization into the upper area of coke ovens
US20110023860A1 (en) * 2007-11-27 2011-02-03 Uhde Gmbh Mechanism for the autonomous latching of coke oven chamber doors for horzontal coke oven chambers
US20110048917A1 (en) * 2007-12-18 2011-03-03 Uhde Gmbh Controllable air ducts for feeding of additional combustion air into the area of flue gas channels of coke oven chambers
US20110192395A1 (en) * 2008-10-09 2011-08-11 Uhde Gmbh Air distributing device for primary air in coke ovens
US20110198206A1 (en) * 2008-09-29 2011-08-18 Uhde Gmbh Air proportioning system for secondary air in coke ovens depending on the vault vs. sole temperature ratio
US20120305381A1 (en) * 2009-12-29 2012-12-06 Research Institute Of Industrial Science & Technology Method for increasing amount of coke oven gas by using carbon dioxide
US8409405B2 (en) 2009-03-11 2013-04-02 Thyssenkrupp Uhde Gmbh Device and method for dosing or shutting off primary combustion air in the primary heating room of horizontal coke-oven chambers
US20210163823A1 (en) * 2015-01-02 2021-06-03 Suncoke Technology And Development Llc Integrated coke plant automation and optimization using advanced control and optimization techniques

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DE102008025437B4 (de) * 2008-05-27 2014-03-20 Uhde Gmbh Vorrichtungen und Verfahren zur gerichteten Einleitung von primärer Verbrennungsluft in den Gasraum einer Koksofenbatterie
DE102012002963A1 (de) 2012-02-16 2013-08-22 Thyssenkrupp Uhde Gmbh Verfahren und Vorrichtung zur flächenoptimierten Zuführung von Verbrennungsluft in den Primärheizraum einer Koksofenkammer des Typs "Non-Recovery" oder "Heat-Recovery"
DE102012014741A1 (de) * 2012-07-26 2014-05-15 Thyssenkrupp Uhde Gmbh Vorrichtung und Verfahren zur gerichteten Einleitung von Verbrennungsluft in die Sekundärheizräume eines Koksofens vom Typ "Heat-Recovery"
US9359554B2 (en) 2012-08-17 2016-06-07 Suncoke Technology And Development Llc Automatic draft control system for coke plants
US9243186B2 (en) 2012-08-17 2016-01-26 Suncoke Technology And Development Llc. Coke plant including exhaust gas sharing
DE102012019746B3 (de) 2012-10-09 2013-12-24 Thyssenkrupp Uhde Gmbh Vorrichtung und Verfahren zur Erzeugung einer Mehrzahl an Dampf- oder Heißwasserströmen in einer Koksofenbank
US10047295B2 (en) 2012-12-28 2018-08-14 Suncoke Technology And Development Llc Non-perpendicular connections between coke oven uptakes and a hot common tunnel, and associated systems and methods
WO2014105063A1 (fr) 2012-12-28 2014-07-03 Suncoke Technology And Development Llc. Systèmes et procédés pour maintenir un lorry chaud dans une installation à coke
EP2938701B1 (fr) 2012-12-28 2019-12-18 SunCoke Technology and Development LLC Couvercles de colonne de ventilation et procédés associés
CN104902984B (zh) 2012-12-28 2019-05-31 太阳焦炭科技和发展有限责任公司 用于去除排放物中的汞的系统和方法
US9273250B2 (en) 2013-03-15 2016-03-01 Suncoke Technology And Development Llc. Methods and systems for improved quench tower design
EP3090034B1 (fr) 2013-12-31 2020-05-06 Suncoke Technology and Development LLC Procédés pour désencrasser des fours à coke, et systèmes et dispositifs associés
DE102014005899A1 (de) * 2014-04-25 2015-10-29 Thyssenkrupp Ag Luftjustierorgan
EP3186340B1 (fr) 2014-08-28 2021-01-06 Suncoke Technology and Development LLC Procédé et système d'optimisation du fonctionnement et de la production d'une installation de coke
RU2702546C2 (ru) 2014-09-15 2019-10-08 САНКОУК ТЕКНОЛОДЖИ ЭНД ДИВЕЛОПМЕНТ ЭлЭлСи Коксовые печи, имеющие конструкцию из монолитных компонентов
US10968395B2 (en) 2014-12-31 2021-04-06 Suncoke Technology And Development Llc Multi-modal beds of coking material
EP3397719B1 (fr) 2015-12-28 2020-10-14 Suncoke Technology and Development LLC Système de charge de manière dynamique d'un four à coke
KR102445523B1 (ko) 2016-06-03 2022-09-20 선코크 테크놀러지 앤드 디벨로프먼트 엘엘씨 산업 설비에서 교정 액션을 자동적으로 생성하기 위한 방법 및 시스템
CA3064430C (fr) 2017-05-23 2022-04-26 Suncoke Technology And Development Llc Systeme et procede de reparation d'un four a coke
WO2020140079A1 (fr) 2018-12-28 2020-07-02 Suncoke Technology And Development Llc Décarbonisation de fours à coke, et systèmes et procédés associés
WO2020140086A1 (fr) 2018-12-28 2020-07-02 Suncoke Technology And Development Llc Détection de particules d'installations industrielles et systèmes et procédés associés
WO2020140092A1 (fr) * 2018-12-28 2020-07-02 Suncoke Technology And Development Llc Fondation de four à récupération de chaleur
BR112021012500B1 (pt) 2018-12-28 2024-01-30 Suncoke Technology And Development Llc Duto coletor ascendente, sistema de gás de escape para um forno de coque, e forno de coque
CA3125187C (fr) 2018-12-28 2023-04-04 Suncoke Technology And Development Llc Detection de fuite de traceur gazeux
BR112021012511B1 (pt) 2018-12-28 2023-05-02 Suncoke Technology And Development Llc Sistema de forno de recuperação de calor carregado por mola e método
US11486572B2 (en) 2018-12-31 2022-11-01 Suncoke Technology And Development Llc Systems and methods for Utilizing flue gas
US11395989B2 (en) 2018-12-31 2022-07-26 Suncoke Technology And Development Llc Methods and systems for providing corrosion resistant surfaces in contaminant treatment systems
KR20230004855A (ko) 2020-05-03 2023-01-06 선코크 테크놀러지 앤드 디벨로프먼트 엘엘씨 고품질 코크스 제품
CA3211286A1 (fr) 2021-11-04 2023-05-11 John Francis Quanci Produits de coke de fonderie, systemes, dispositifs et procedes associes
US11946108B2 (en) 2021-11-04 2024-04-02 Suncoke Technology And Development Llc Foundry coke products and associated processing methods via cupolas

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US690748A (en) * 1901-03-11 1902-01-07 Richard D Martin Coke-oven.
US1200952A (en) * 1916-03-22 1916-10-10 Dennis T Koch Regulator and indicator for furnace-drafts.
US1775999A (en) * 1929-09-18 1930-09-16 Haseloff Otto Self-adjustable valve
US4287024A (en) * 1978-06-22 1981-09-01 Thompson Buster R High-speed smokeless coke oven battery
US4357211A (en) * 1980-05-14 1982-11-02 Dr. C. Otto & Comp. G.M.B.H. Air control arrangement for regeneratively-heated coke ovens
US5114542A (en) * 1990-09-25 1992-05-19 Jewell Coal And Coke Company Nonrecovery coke oven battery and method of operation
US5928476A (en) * 1997-08-19 1999-07-27 Sun Coal Company Nonrecovery coke oven door

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GB1555400A (en) 1977-08-30 1979-11-07 Pennsylvania Coke Technology I Smokeless nonrecovery type coke oven
BE906160A (fr) * 1986-01-31 1987-07-01 Westinghouse Electric Corp Procede de production mixte de coke, ainsi que d'energie electrique au depart de vapeur d'eau.
US6596128B2 (en) * 2001-02-14 2003-07-22 Sun Coke Company Coke oven flue gas sharing

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US690748A (en) * 1901-03-11 1902-01-07 Richard D Martin Coke-oven.
US1200952A (en) * 1916-03-22 1916-10-10 Dennis T Koch Regulator and indicator for furnace-drafts.
US1775999A (en) * 1929-09-18 1930-09-16 Haseloff Otto Self-adjustable valve
US4287024A (en) * 1978-06-22 1981-09-01 Thompson Buster R High-speed smokeless coke oven battery
US4344820A (en) * 1978-06-22 1982-08-17 Elk River Resources, Inc. Method of operation of high-speed coke oven battery
US4357211A (en) * 1980-05-14 1982-11-02 Dr. C. Otto & Comp. G.M.B.H. Air control arrangement for regeneratively-heated coke ovens
US5114542A (en) * 1990-09-25 1992-05-19 Jewell Coal And Coke Company Nonrecovery coke oven battery and method of operation
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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8465626B2 (en) * 2006-01-31 2013-06-18 Uhde Gmbh Coke oven with optimized control and method of control
US20090032382A1 (en) * 2006-01-31 2009-02-05 Franz-Josef Schuecker Coke Oven With Optimized Control and Method of Control
US20100065413A1 (en) * 2006-09-21 2010-03-18 Uhde Gmbh Coke oven comprising tertiary heating elements in the gas chamber
US8764944B2 (en) 2006-09-21 2014-07-01 Uhde Gmbh Coke oven comprising tertiary heating elements in the gas chamber
US20100300867A1 (en) * 2007-09-07 2010-12-02 Ronald Kim Device for feeding combustion air or gas influencing coal carbonization into the upper area of coke ovens
US8647476B2 (en) 2007-09-07 2014-02-11 Uhde Gmbh Device for feeding combustion air or gas influencing coal carbonization into the upper area of coke ovens
US20110023860A1 (en) * 2007-11-27 2011-02-03 Uhde Gmbh Mechanism for the autonomous latching of coke oven chamber doors for horzontal coke oven chambers
US20110048917A1 (en) * 2007-12-18 2011-03-03 Uhde Gmbh Controllable air ducts for feeding of additional combustion air into the area of flue gas channels of coke oven chambers
US9039869B2 (en) 2007-12-18 2015-05-26 Uhde Gmbh Controllable air ducts for feeding of additional combustion air into the area of flue gas channels of coke oven chambers
US8980063B2 (en) * 2008-09-29 2015-03-17 Uhde Gmbh Air proportioning system for secondary air in coke ovens depending on the vault vs. sole temperature ratio
US20110198206A1 (en) * 2008-09-29 2011-08-18 Uhde Gmbh Air proportioning system for secondary air in coke ovens depending on the vault vs. sole temperature ratio
US20110192395A1 (en) * 2008-10-09 2011-08-11 Uhde Gmbh Air distributing device for primary air in coke ovens
US9404043B2 (en) 2008-10-09 2016-08-02 Thyssenkrupp Industrial Suolutions Ag Air distributing device for primary air in coke ovens
US8409405B2 (en) 2009-03-11 2013-04-02 Thyssenkrupp Uhde Gmbh Device and method for dosing or shutting off primary combustion air in the primary heating room of horizontal coke-oven chambers
US20120305381A1 (en) * 2009-12-29 2012-12-06 Research Institute Of Industrial Science & Technology Method for increasing amount of coke oven gas by using carbon dioxide
US9255224B2 (en) * 2009-12-29 2016-02-09 Research Institute Of Industrial Science & Technology Method for increasing amount of coke oven gas by using carbon dioxide
US20210163823A1 (en) * 2015-01-02 2021-06-03 Suncoke Technology And Development Llc Integrated coke plant automation and optimization using advanced control and optimization techniques
US11788012B2 (en) * 2015-01-02 2023-10-17 Suncoke Technology And Development Llc Integrated coke plant automation and optimization using advanced control and optimization techniques

Also Published As

Publication number Publication date
AP2008004466A0 (en) 2008-06-30
CA2628316A1 (fr) 2007-05-24
AU2006314857A1 (en) 2007-05-24
ZA200804138B (en) 2009-03-25
JP5114422B2 (ja) 2013-01-09
KR20080069170A (ko) 2008-07-25
CN101309996A (zh) 2008-11-19
EP1948759A1 (fr) 2008-07-30
UA91571C2 (ru) 2010-08-10
RU2008124810A (ru) 2009-12-27
BRPI0618679A2 (pt) 2011-09-06
CA2628316C (fr) 2014-04-22
RU2422490C2 (ru) 2011-06-27
HK1122061A1 (en) 2009-05-08
AU2006314857B2 (en) 2011-05-26
JP2009516033A (ja) 2009-04-16
CN101309996B (zh) 2013-04-03
TWI319432B (en) 2010-01-11
MY149240A (en) 2013-07-31
WO2007057076A1 (fr) 2007-05-24
DE102005055483A1 (de) 2007-05-31
TW200720417A (en) 2007-06-01
EG25241A (en) 2011-11-20
AR056158A1 (es) 2007-09-19

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