US20090188638A1 - Process for manufacturing a material in sheet form, comprising at least one fibrous layer and security and/or decorative elements - Google Patents

Process for manufacturing a material in sheet form, comprising at least one fibrous layer and security and/or decorative elements Download PDF

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Publication number
US20090188638A1
US20090188638A1 US12/298,986 US29898607A US2009188638A1 US 20090188638 A1 US20090188638 A1 US 20090188638A1 US 29898607 A US29898607 A US 29898607A US 2009188638 A1 US2009188638 A1 US 2009188638A1
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United States
Prior art keywords
security
fibrous layer
decorative elements
elements
spraying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
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US12/298,986
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English (en)
Inventor
Sandrine Chalaye
Robert Langley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ArjoWiggins Security SAS
Original Assignee
ArjoWiggins SAS
Arjo Wiggins Fine Papers Ltd
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Filing date
Publication date
Application filed by ArjoWiggins SAS, Arjo Wiggins Fine Papers Ltd filed Critical ArjoWiggins SAS
Assigned to ARJO WIGGINS FINE PAPERS LIMITED, ARJOWIGGINS reassignment ARJO WIGGINS FINE PAPERS LIMITED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: LANGLEY, ROBERT, CHALAYE, SANDRINE
Publication of US20090188638A1 publication Critical patent/US20090188638A1/en
Assigned to ARJOWIGGINS SECURITY reassignment ARJOWIGGINS SECURITY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ARJO WIGGINS FINE PAPERS LIMITED, ARJOWIGGINS
Assigned to ARJOWIGGINS SECURITY reassignment ARJOWIGGINS SECURITY CHANGE OF ADDRESS Assignors: ARJOWIGGINS SECURITY
Abandoned legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/40Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22Addition to the formed paper
    • D21H23/50Spraying or projecting

Definitions

  • One object of the present invention is, in particular, a process for manufacturing a sheet material comprising at least one fibrous layer.
  • Security elements may be introduced selectively into one of the lines for distributing the paper pulp.
  • U.S. Pat. No. 5,989,389 is a process for manufacturing a security paper such as a banknote, that consists in depositing, onto a rotating wire cylinder, two types of fibrous suspensions, one being intended to form opaque zones of the paper and the other substantially transparent zones.
  • the suspension of fibers that form the transparent zones may contain a filler, a binder or a transparentizing agent, and be distributed using a nozzle in contact with the papermaking wire.
  • Patent GB 2 309 710 is a single-ply security paper incorporating security elements such as metallic or magnetic particles.
  • the paper is formed in contact with a rotating wire cylinder and the particles are introduced into the fibrous layer being formed using nozzles spaced apart from one another and positioned at the location where the fibrous layer begins to be formed in contact with the papermaking wire.
  • Patent GB 696 673 is a process for manufacturing a paper, comprising the step that consists in injecting a material such as an ink, using a syringe, into the bulk of the fibrous layer being formed.
  • Patent Application EP 490 825 is a security paper such as a banknote comprising a plurality of adjacent strips each formed by a coating of an iridescent pigment.
  • the iridescent pigment is deposited by coating using a rotating roller:
  • a security paper such as a banknote comprising two adjacent iridescent strips deposited on the paper, for example using the process described in the aforementioned Application EP 498 825, or by coating, printing, photogravure, flexography or offset printing.
  • the paper also comprises an optically variable element such as a hologram deposited by hot pressing onto at least one of the iridescent strips.
  • an optically variable element such as a hologram deposited by hot pressing onto at least one of the iridescent strips.
  • security and/or valuable documents are known that comprise security elements that make it possible to protect these documents against forgery or counterfeiting attempts.
  • security elements some are detectable by the naked eye, in visible light, without the use of a specific device.
  • These security elements comprise, for example, colored planchettes or fibers.
  • security elements are detectable only using a relatively simple device such as a lamp that emits in the ultraviolet or infrared range.
  • These security elements comprise, for example, fibers, planchettes or particles.
  • These security elements may be visible to the naked eye or not, being, for example, luminescent under a Wood lamp that emits at a wavelength of 365 nm.
  • These elements may also be, for example, of the thermochromic or photochromic type.
  • security elements require, for their detection, a more sophisticated detection device.
  • These security elements are, for example, capable of generating a specific signal when they are subjected, simultaneously or not, to one or more sources of external excitation. The automatic detection of the signal makes it possible to authenticate, if necessary, the document.
  • These security elements comprise, for example, markers that are in the form of active material, of particles or of fibers, capable of generating a specific signal when these markers are subjected to an optoelectronic, electric, magnetic or electromagnetic excitation.
  • the security elements mentioned above may be incorporated into the bulk of the paper or at the surface of the latter.
  • the security elements When the security elements are incorporated into the bulk of the paper, their observation with the naked eye, when these are first-level security elements, or their detection, when these are third-level security elements, may be difficult or even impossible due to, for example, the presence of cellulose fibers or dyes which may act as a filter.
  • the present invention aims, in particular, to provide a novel process for manufacturing a sheet material having at least one fibrous layer that comprises security and/or decorative elements.
  • sheet material may denote, in the description and the claims, a fibrous sheet based on cellulose and/or synthetic fibers.
  • a sheet material may, for example, have a relatively small thickness, in particular less than or equal to 3 mm, for example equal to around 100 ⁇ m, and be at least partially, or even completely, flexible.
  • the sheet material may be of the single-ply or multi-ply type, in particular two-ply.
  • the sheet material may be packaged as a coil, especially before being cut to the desired format.
  • the subject of the invention is a process for manufacturing a sheet material comprising at least one fibrous layer and a plurality of security and/or decorative elements, the process comprising at least one of the following steps:
  • the amount of security and/or decorative elements used for manufacturing the sheet material may be relatively low.
  • the invention makes it possible to limit possible losses of material.
  • the spraying of the security and/or decorative elements onto the fibrous layer may be carried out in-line, downstream of a wet part of the papermaking machine that is used to form the fibrous layer, especially before passing into the press section, or even before passing into a drying assembly of the papermaking machine.
  • the deposition of the security and/or decorative elements may be facilitated since it is carried out on the papermaking machine itself, which in particular makes it possible to be able to locate the pattern or patterns of security and/or decorative elements relative to other security elements present in the fibrous layer, for example a security thread or a watermark.
  • the zones of the fibrous layer covered by the security and/or decorative elements may have a fuzzy or sharp contour, depending on the type of security and/or decorative elements deposited and the spraying method.
  • a fuzzy contour may make it possible to make an attempt to copy the sheet material by printing more difficult.
  • the security and/or decorative elements are previously dispersed in a fluid such as water, optionally with one or more additives, for example a binder or a retention agent, in order to facilitate the anchoring of the security and/or decorative elements to the fibrous layer or a dispersant in order to facilitate the dispersion of the security and/or decorative elements.
  • a fluid such as water
  • additives for example a binder or a retention agent
  • the mixture thus obtained may be sprayed onto the fibrous layer using a pressurized fluid, especially a pressurized gas such as compressed air.
  • the process according to the invention may comprise at least one of the following steps:
  • the spraying of the security and/or decorative elements may be carried out using a spraying system comprising one or more spray nozzles.
  • the spraying of the security and/or decorative elements may be carried out with several spray nozzles fed with security and/or decorative elements of different types to form adjacent or overlapping patterns.
  • the spraying system comprises, if desired, especially depending on the type of security and/or decorative elements, a device for atomizing the liquid medium in order to create very fine droplets.
  • the spraying system may comprise at least one nozzle that may be alternately fed by at least two reservoirs of security and/or decorative elements capable of alternately spraying the security and/or decorative elements originating from the two reservoirs.
  • the spraying system may comprise a jet divider arranged in order to divide, at the outlet of a nozzle, one jet into several jets, optionally with spaces between them in order to create one or more patterns.
  • the security and/or decorative elements are sprayed while forming at least one jet, the process comprising the following steps:
  • the invention makes it possible to produce a wide variety of patterns using security and/or decorative elements.
  • the security and/or decorative elements may be sprayed onto the fibrous layer continuously or, as a variant, intermittently, in particular periodically with a predetermined frequency.
  • the spraying system may, where necessary, be combined with a control system arranged in order to control the spraying of the security and/or decorative elements, especially the spraying frequency, the spraying direction, the spraying force of the security and/or decorative elements, the volume, the flow rate, and the shape and/or the dimensions of a jet of security and/or decorative elements.
  • the control system may comprise at least one of a pneumatic device and of a peristaltic device, or a combined pneumatic/peristaltic device, arranged in order to control the spraying frequency and volume.
  • a pneumatic pump may especially be arranged in order to be able to regulate the spraying frequency and volume via a system of compressed air, the flow rate and pressure of which may be easily controlled.
  • the spraying frequency and volume in a peristaltic pump depend, in particular, on the pump configuration (number of rotors that create the spraying pressure, for example).
  • the control system may comprise, if desired, a centrifugal pump or a mono pump, especially in the case of forming continuous patterns, allowing a control of the flow rates that is precise and regular, in particular reproducible and constant over time.
  • the security and/or decorative elements may be sprayed by forming at least one jet that has, in transverse cross section, a shape chosen from: a straight line segment, a corner such as a right-angled corner, a triangle, a rectangle or a square, a non-rectilinear curve such as an arc of a circle, a circle, an ellipse, an oval or S-shaped portion, a disk, or a wavy shape.
  • the jet may be hollow or solid.
  • the security and/or decorative elements are sprayed onto the fibrous layer so as to be dispersed over only one portion of the corresponding face of the fibrous layer, the elements not covering the entirety of this face.
  • the process may comprise, if desired, the following step:
  • the pattern or patterns made on the sheet material may define, if desired, an identification element of the sheet material.
  • the pattern or patterns may define, where appropriate, a decorative pattern or a specific trademark pattern.
  • Security and/or decorative elements of different types may, for example, have different colors, while being of identical nature.
  • This or these patterns comprise, for example, one of the following elements: an alphanumeric character, a symbol, a geometric shape, a logo, or a design, this list not being limiting.
  • This or these patterns may or may not be alternate, optionally with a predetermined step, and/or juxtaposed or superposed.
  • the process may comprise the following step:
  • One advantage of a mixture of security elements of different levels may be the possibility of locating the position of second- or third-level security elements owing to the presence of first-level security elements visible in daylight.
  • the authentication and/or identification of the sheet material may, where appropriate, rest on the verification of the set of zones formed by the security elements or on the verification of only some of these zones.
  • One at least of the zones formed by the security elements may define an inspection zone in order to analyze the security elements present in this inspection zone with a view to identifying the sheet material, on the basis, for example, of the spatial distribution of the security elements in the inspection zone.
  • This inspection zone corresponds, for example, to the intersection of two zones formed by security elements of different types and/or concentrations.
  • the security elements may comprise;
  • the security elements may comprise, if desired, at least one of the following elements:
  • the particles or pigments may have, for example, dimensions between 10 and 20 ⁇ m, even ranging up to 500 ⁇ m.
  • the fibers may have, for example, a length of 3 to 5 mm and a diameter of around 30 ⁇ m.
  • the decorative elements comprise, if desired, metallic particles and/or shiny or matt or colored particles, made of mineral or plastic material(s).
  • the sheet material may comprise at least one authentication and/or identification structure, the security and/or decorative elements covering a zone of the fibrous layer that may be superposed at least partially, or even perfectly, on the authentication and/or identification structure.
  • the latter may, if desired, cover the security and/or decorative elements.
  • the authentication and/or identification structure may comprise, for example, a foil or patch or a hologram applied to the fibrous layer, especially away from the papermaking machine.
  • the pattern or patterns defined by the security and/or decorative elements may be present in a security thread or a zone of reduced opacity or a watermark, for example.
  • the authentication and/or identification structure may be chosen from at least one of the following elements: a watermark, an optically variable element such as a hologram, a strip element, a foil, a patch, a security thread, or printing.
  • the variations in concentration may be used for authentication of the sheet material.
  • Another subject of the invention is a papermaking machine comprising:
  • the spraying system may comprise, where appropriate, at least one spraying device arranged in order to spray the security and/or decorative elements.
  • Another subject of the invention is a sheet material obtained, in particular, by the implementation of the process defined above.
  • the security and/or decorative elements may cover one portion only of one face of the fibrous layer and may, in particular, be dispersed at least partially in the bulk of the fibrous layer, over a thickness smaller than that of the fibrous layer.
  • the security and/or decorative elements may form a pattern having a succession of disjointed zones, in particular that are identical and/or repeated regularly.
  • the sheet material may comprise at least two types, for example three types, of security and/or decorative elements, the security elements of one given type in particular covering one portion only of the face of the fibrous layer.
  • the sheet material may comprise at least two zones formed respectively by security and/or decorative elements of different types, having for example different colors, these zones in particular being adjacent or at least partially superposed.
  • intersection zone of the aforementioned two zones may, where appropriate, have a color corresponding to the superposition of the two colors of said zones.
  • the sheet material may comprise security and/or decorative elements that form one at least of:
  • the continuous zone forms, for example, a pattern in the shape of a wavy strip or zigzag.
  • the continuous zone is a strip having parallel rectilinear edges.
  • the sheet material comprises at least one authentication and/or identification element chosen from at least one of the following elements: an element for illustrating a forgery, in particular that is visible and/or detectable using a specific detection device, an element having a variable, interference, in particular iridescent, and/or diffractive optical effect, a liquid crystal element, a magnetic coating, magnetic fibers, markers detectable by magnetic resonance, markers detectable by X-ray fluorescence, biomarkers, a varnish or an ink, luminescent (fluorescent or phosphorescent) markers, photochromic, thermochromic, electroluminescent, tribochromic and especially piezochromic compounds and/or compounds that change color in contact with one or more predetermined products (solvatochrome, ionochrome, etc.).
  • an element for illustrating a forgery in particular that is visible and/or detectable using a specific detection device
  • an element having a variable, interference, in particular iridescent, and/or diffractive optical effect a liquid crystal element
  • FIG. 1 represents, schematically and partially, a papermaking machine according to the invention
  • FIG. 2 illustrates, schematically and partially, two spray nozzles of a spraying system of the papermaking machine from FIG. 1 ;
  • FIG. 3 represents, schematically and partially, a spray nozzle fed by two reservoirs of security and/or decorative elements
  • FIGS. 4 and 5 illustrate, schematically and partially, examples of patterns obtained as a function of the method of spraying the security and/or decorative elements
  • FIGS. 6 to 17 illustrate, schematically and partially, various examples of patterns formed by the security and/or decorative elements.
  • FIG. 1 Represented in FIG. 1 is a papermaking machine 1 comprising a wet part 2 for forming the paper, a circuit of a take-up belt 3 , especially one made of felt, a drying assembly 4 and a size press 5 .
  • the papermaking machine 1 is of round shape.
  • the papermaking machine may be of the flat table type.
  • the papermaking machine may comprise a wire for a rotating cylinder (or “former”) and a device for injecting fibrous material onto this surface with a view to forming the fibrous layer.
  • the wet part 2 comprises a tank 11 containing a suspension 12 of fibers, for example cellulose fibers, in particular cotton linters and/or synthetic and/or artificial fibers, in which a rotating wire cylinder 13 is partially immersed, said wire cylinder defining a surface 14 upon contact with which a fibrous layer 20 is continuously formed.
  • a suspension 12 of fibers for example cellulose fibers, in particular cotton linters and/or synthetic and/or artificial fibers
  • the drying assembly 4 comprises a plurality of rotating cylinders 9 upon contact with which the fibrous layer 20 is displaced.
  • the sheet material may comprise at least two fibrous layers, in particular assembled in the wet phase, so as to form, for example, a two-ply paper.
  • the papermaking machine 1 also comprises a spraying system 21 comprising one or more spray nozzles 22 arranged to spray security and/or decorative elements onto the fibrous layer 20 while moving in the direction of the arrow F, as illustrated in FIG. 2 .
  • the system 21 may comprise a single nozzle or a plurality of spray nozzles.
  • the spraying system 21 is placed at a location of the papermaking machine 1 where the fibrous layer 20 is still wet.
  • the spraying system 21 is placed between the wet part 2 for forming the paper and the drying assembly 4 , as illustrated in FIG. 1 .
  • the spraying system 21 is placed, for example, between the drying assembly 4 and the size press assembly 5 .
  • the spraying of the suspension over the fibrous layer may be combined with an atomization of the suspension in order to reduce the size of the drops sprayed.
  • One of the nozzles may comprise, for this purpose, an atomization device 23 comprising, for example, one or more vortex channels.
  • the spraying may be carried out using a fluid carrier such as compressed air.
  • One of the nozzles 22 may be fed by at least two reservoirs of security and/or decorative elements 25 and 26 in order to alternately spray the security and/or decorative elements originating from the two reservoirs 25 and 26 , as illustrated in FIG. 3 .
  • the reservoirs 25 and 26 comprise, for example, security and/or decorative elements of different types.
  • the system 21 may comprise a jet divider arranged in order to divide, at the outlet of a nozzle, one jet into several jets.
  • the system 21 may comprise, if desired, two nozzles arranged to spray jets that are at least partially juxtaposed in order, for example, to form on the fibrous layer a zone having a relatively large surface area.
  • the spraying system 21 may be combined with a control system 28 arranged in order to control the spraying of the security and/or decorative elements by the spraying system, this control system 28 possibly controlling, for example, the spraying frequency (in particular the duration of one spraying operation and/or the duration between two successive spraying operations), the spraying direction, the spraying force, and the shape and/or the dimensions of a jet 29 of security and/or decorative elements.
  • this control system 28 possibly controlling, for example, the spraying frequency (in particular the duration of one spraying operation and/or the duration between two successive spraying operations), the spraying direction, the spraying force, and the shape and/or the dimensions of a jet 29 of security and/or decorative elements.
  • the control system 28 comprises, for example, at least one of a pneumatic device and of a peristaltic device, or a combined pneumatic/peristaltic device arranged in order to control the spraying frequency.
  • the control system 28 may be arranged, for example, in order to be able to move one of the jets 29 of security and/or decorative elements along a direction that is not parallel to the direction F of movement of the fibrous layer 20 .
  • the control system 28 may comprise, if desired, a centrifugal pump or a mono pump, especially in the case of forming continuous patterns, that allows a control of the flow rates that is precise and regular, in particular that is reproducible and constant over time.
  • the jet 29 may, for example, be moved in a direction transverse to the direction F, in an oscillating movement.
  • Each nozzle 22 may be arranged in order to spray a jet 29 of security and/or decorative elements that has, in transverse cross section, a circle shape as illustrated in FIG. 2 .
  • each nozzle 22 may be arranged in order to spray a jet 29 that has, in transverse cross section, a shape chosen from: a straight line segment, a corner such as a right-angled corner, a rectangle or a square, a non-rectilinear curve such as an arc of a circle, an oval or ellipse or S-shaped portion, or a disk.
  • the jet 29 may be flat, for example, or as a variant substantially conical.
  • the nozzles 22 are arranged in order to spray security and/or decorative elements onto the fibrous layer 20 over one portion only of the corresponding face of this layer.
  • the spraying system 21 may make it possible to spray, simultaneously or alternately, security and/or decorative elements of at least two different types onto the fibrous layer 20 .
  • nozzles sold by Spraying Systems Co for example the nozzles sold under the names FLATJET® NOZZLE, VEEJET® NOZZLE, FLATJET® NOZZLE AIR ATOMIZING NOZZLE or GUNJET® SPRAY GUNS.
  • the security and/or decorative elements may comprise elements detectable to the naked eye, in reflection and/or through transparency, in visible light, or detectable to the touch.
  • the security and/or decorative elements may, where appropriate, comprise elements detectable to the naked eye, in reflection and/or through transparency, for example under predetermined lighting, especially ultraviolet lighting, the security elements especially being undetectable to the naked eye, in visible light.
  • the security elements may comprise elements arranged in order to emit a specific signal when they are subjected to an external excitation, especially an optoelectronic, electromagnetic, electric, magnetic, thermal or acoustic excitation.
  • the security element comprises, for example, at least one of the following elements:
  • the decorative elements comprise, if desired, metallic particles and/or shiny or matt or colored particles, made of mineral or plastic material(s).
  • FIG. 4( a ) Illustrated in FIG. 4( a ) is a fibrous layer 20 on which two types of different patterns are formed.
  • the first continuous pattern 30 is produced by spraying security and/or decorative elements onto the fibrous layer 20 using a first nozzle 22 operating continuously.
  • the pattern 30 is a continuous strip with rectilinear and parallel edges.
  • the pattern 31 is formed from a row of circles, parallel to the strip 30 .
  • the circles are formed by security and/or decorative elements sprayed as hollow jets onto the fibrous layer 20 using, for example, a pneumatic spray nozzle 22 .
  • the circles of the pattern 31 are formed using a pneumatic spray nozzle.
  • the space between two circles of the pattern 31 may be reduced or increased in order, for example, to have a row of circles that are closer to one another, as illustrated in FIG. 5( b ).
  • a strip 33 having a substantially sinusoidal or zigzag shape is formed on the fibrous layer 20 as illustrated in FIG. 6 .
  • the fibrous layer 20 comprises, in addition to the sinusoidal strip 33 , a continuous pattern 34 of a strip having parallel rectilinear edges.
  • the pattern 34 is formed, in particular, by a mixture of security elements of two different types; namely, for example, on the one hand, planchettes having a red color in daylight and a red fluorescence under radiation at 365 nm and, on the other hands fibers that are invisible in daylight and that have a yellow fluorescence under radiation at 365 nm.
  • the pattern 33 is formed, for example, of markers that are invisible in ambient light, such as TRACELESSTM markers sold by Creo.
  • markers may be detected by a specific detector comprising a CCD camera operating in the infrared and equipped to characterize the spatial distribution of the markers.
  • the signal emitted by the markers dispersed in a predetermined region of the pattern 33 corresponding, for example, to a portion of the sinusoidal curve 33 may be used for identifying the fibrous layer 20 .
  • the portion of the sinusoidal curve may be, for example, a period of the latter or a multiple of the latter.
  • the pattern 34 is thus formed from first- and second-level security elements, and the pattern 33 from third-level security elements.
  • the pattern 34 is used in particular for locating the pattern 33 .
  • the fibrous layer 20 comprises a pattern 35 formed from a row of identical individual patterns repeated regularly, each individual pattern being formed, for example, from two concentric rings.
  • These individual patterns are produced from second-level security elements, for example HILITETM particles that are invisible in daylight and that have an orange fluorescence under radiation at 365 nm, described for example in Application EP 226 367. These particles are agglomerates, having a dimension of around 200 ⁇ m, of finer fluorescent particles.
  • the fibrous layer 20 comprises a pattern 36 obtained by varying the width of the jet of security and/or decorative elements so that the width of the pattern 36 varies, in particular periodically.
  • the fibrous layer 20 comprises a pattern 38 formed from an alternation of adjacent discontinuous zones 38 a - 38 c that together define a general shape in the form of a continuous strip with parallel rectilinear edges.
  • zones 38 a - 38 c are each obtained, in particular, by discontinuous spraying of security and/or decorative elements of different types.
  • the zones 38 a may be formed from HILITETM particles that are invisible in daylight and that have a blue fluorescence under UV radiation.
  • the zones 38 b may be formed, for example, from HILITETM particles that have a white fluorescence and the zones 38 c from HILITETM particles that have a red fluorescence under UV radiation.
  • the pattern 38 may appear as a succession of blue/white/red three-colored flags.
  • the zones 38 a - 38 c may be formed from TRACELESSTM markers from Creo, the concentration of which varies along the zones 38 a - 38 c. These zones may form, for example, a barcode.
  • the fibrous layer 20 comprises two continuous patterns 40 and 41 each having a shape in the form of a strip with parallel rectilinear edges, these patterns 40 and 41 being adjacent over their entire length.
  • the pattern 40 may, for example, be formed from security and/or decorative elements that are visible to the naked eye, under appropriate lighting. This pattern 40 may make it possible to locate the pattern 41 formed, for example, from security elements that are invisible to the naked eye and that are detectable only using a specific device.
  • the fibrous layer 20 comprises a pattern 42 having a shape in the form of a strip with parallel rectilinear edges, formed for example from security elements that are invisible to the naked eye.
  • This pattern 42 may be superposed over authentication and/or identification structures 43 that are visible to the naked eye, for example that comprise watermarks.
  • the authentication and/or identification structure 43 may, as a variant, comprise at least one security thread, an optically variable element such as a holographic foil or printing such as ink printing.
  • the structure 43 may be applied to the fibrous layer during or after the manufacture of this layer, during a conversion or printing operation for example.
  • the fibrous layer 20 may comprise a pattern 39 formed from a succession of discontinuous zones, for example of rectangular shape.
  • the pattern 39 is superposed over a strip or security thread 44 incorporated at least partially into the bulk of the fibrous layer 20 .
  • the pattern 39 is obtained, for example, by spraying a dye that has electromagnetic properties and forms a specific signature for the sheet material.
  • the dye may be of the SECUSYSTEM® type sold by Bsecure, mixed with particles that are invisible in daylight and that have a red fluorescence under radiation at 365 nm.
  • the sheet material 20 comprises first and second patterns 44 and 45 that each have a shape in the form of a strip with parallel rectilinear edges, these patterns being adjacent, and a third pattern 46 that has a shape in the form of a sinusoidal strip that is superposed over the patterns 44 and 45 .
  • the first pattern 44 may be formed by spraying fibers that have a red color in daylight and a red fluorescence under radiation at 365 nm.
  • the pattern 45 may be formed from security elements such as HILITETM particles that have a red color in daylight and a red fluorescence under radiation at 365 nm.
  • the pattern 46 is formed, for example, from HILITETM particles that are invisible in daylight and that have a yellow fluorescence under radiation at 365 nm.
  • the fibrous layer 20 comprises a first pattern in the form of a strip 47 , a second pattern in the form of a strip 48 formed within the first pattern 47 and a third discontinuous pattern 49 formed within the pattern 48 .
  • the pattern 49 is formed from discontinuous zones, these zones being, for example, disks or similar shapes obtained by solid conical jets.
  • the first pattern 47 may comprise second-level security elements, for example fibers that are invisible in ambient light and that have a blue fluorescence under radiation at 365 nm.
  • the second pattern 48 may be formed, for example, from security elements such as HILITETM particles that have a red color in daylight and a red fluorescence under radiation at 365 nm.
  • the third pattern 49 may be formed, for example, from TRACELESSTM markers.
  • the fibrous layer 20 comprises a first continuous pattern 50 that has a shape in the form of a strip and continuous second and third patterns 51 and 52 that also have a shape in the form of a strip and that are superposed over the first pattern 50 .
  • the second and third patterns 51 and 52 are spaced apart from one another.
  • the fibrous layer 20 comprises two patterns 53 and 54 that each have a shape in the form of a continuous strip with parallel rectilinear edges and that are partially superposed in an intersection zone 55 .
  • the first pattern 53 is formed by spraying a dye that has a yellow color in daylight and a yellow fluorescence under radiation at 365 nm.
  • the second pattern 54 is formed by spraying a dye that has a blue color in daylight and a blue fluorescence under radiation at 365 nm.
  • the intersection zone 55 has a color corresponding to the superposition of the yellow and blue colors of the patterns 53 and 54 so that the patterns 53 - 54 form, under UV radiation, three colors, in the style of a yellow/green/blue flag.
  • One of the nozzles may, for example, comprise a valve in order to interrupt the spraying jet.
  • One of the nozzles may be able to be moved on a support, for example in translation or in rotation, especially following an oscillating movement.
  • One of the nozzles may be able to be moved so as to vary the distance between this nozzle and the fibrous layer.
US12/298,986 2006-05-19 2007-05-18 Process for manufacturing a material in sheet form, comprising at least one fibrous layer and security and/or decorative elements Abandoned US20090188638A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0651860 2006-05-19
FR0651860A FR2901286B1 (fr) 2006-05-19 2006-05-19 Procede de fabrication d'un materiau en feuille comprenant au moins une couche fibreuse et des elements de securite et/ou decoratifs
PCT/FR2007/051302 WO2007135334A1 (fr) 2006-05-19 2007-05-18 Procede de fabrication d'un materiau en feuille comprenant au moins une couche fibreuse et des elements de securite et/ou decoratifs

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US20090188638A1 true US20090188638A1 (en) 2009-07-30

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US (1) US20090188638A1 (sl)
EP (1) EP2021544B1 (sl)
AT (1) ATE473322T1 (sl)
BR (1) BRPI0712592A2 (sl)
CA (1) CA2652572A1 (sl)
DE (1) DE602007007608D1 (sl)
ES (1) ES2348370T3 (sl)
FR (1) FR2901286B1 (sl)
MX (1) MX2008014521A (sl)
RU (1) RU2429138C2 (sl)
SI (1) SI2021544T1 (sl)
WO (1) WO2007135334A1 (sl)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110133442A1 (en) * 2008-06-12 2011-06-09 Crane Douglas A Method for increasing adhesion between a security element and a fibrous sheet material
US8289352B2 (en) 2010-07-15 2012-10-16 HJ Laboratories, LLC Providing erasable printing with nanoparticles
US9708773B2 (en) 2011-02-23 2017-07-18 Crane & Co., Inc. Security sheet or document having one or more enhanced watermarks
US10011141B2 (en) 2010-07-29 2018-07-03 Henri Rosset Security structure including phosphorescent and fluorescent compositions
GB2559364A (en) * 2017-02-02 2018-08-08 Portals De La Rue Ltd A method of manufacturing a security sheet
DE102017125618A1 (de) * 2017-11-02 2019-05-02 Bundesdruckerei Gmbh Verfahren zum Herstellen eines Sicherheitsmerkmals auf einem Sicherheitspapier und Verwendung
WO2019131083A1 (ja) * 2017-12-28 2019-07-04 コアレックス信栄株式会社 消臭紙の製造方法
US11221305B2 (en) * 2017-05-15 2022-01-11 Security Matters Ltd. Object marking system and method

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2992410A1 (fr) 2012-06-26 2013-12-27 Arjowiggins Security Article comportant un code a barres a signature electromagnetique.

Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US447336A (en) * 1891-03-03 James macdonougii
US1329130A (en) * 1917-09-07 1920-01-27 Kimberly Clark Company Apparatus for making ornamental paper
US1595207A (en) * 1926-05-01 1926-08-10 Paper Patents Co Ornamental paper and method of making same
US3451878A (en) * 1965-03-29 1969-06-24 Frederick S T Fung Laminated article with decorative dots dispersed therethrough
US3560334A (en) * 1965-09-27 1971-02-02 Mead Corp Apparatus for incorporating additive dispersions to wet webs of paper
US4504357A (en) * 1979-02-13 1985-03-12 Gao Gesellschaft Fuer Automation Und Organisation Mbh. Security with identifying marks printed in the substance of a paper layer
US5622599A (en) * 1994-06-28 1997-04-22 Sproule; Barry Method and apparatus for coating pulp products
US5897746A (en) * 1993-12-24 1999-04-27 Giesecke & Devrient, Gmbh Method for equipping papers of value with authenticity features
US5916416A (en) * 1996-05-15 1999-06-29 Cartiere Fedrigoni & C. S.P.A. Method and apparatus for manufacturing papers with watermarks or patterns and paper thus manufactured
US5989389A (en) * 1992-11-11 1999-11-23 Ab Tumba Bruk Method of producing visible, continuous streaks and/or delimited fields in paper
US6270625B1 (en) * 1999-06-29 2001-08-07 The Mead Corporation Method for manufacturing colored stripped paper
US20020166647A1 (en) * 2001-04-27 2002-11-14 Thomas Attenberger Method and apparatus for incorporating feature substances into a paper web
US6764577B2 (en) * 1998-12-30 2004-07-20 Kimberly-Clark Worldwide, Inc. Masking patterns to enhance apparent opacity of paper products
US7011729B2 (en) * 2003-11-12 2006-03-14 Corn Products International, Inc. Starch and fiber mixture for papermaking and methods of making paper with the mixture
US7819434B2 (en) * 2003-10-08 2010-10-26 Giesecke & Devrient Gmbh Value document

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9215830D0 (en) * 1992-07-24 1992-09-09 Wiggins Teape Group Ltd Security paper
FR2726586B1 (fr) * 1994-11-03 1996-12-06 Arjo Wiggins Sa Papier comprenant des concentrations variables, controlees d'elements de securite et son procede de fabrication

Patent Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US447336A (en) * 1891-03-03 James macdonougii
US1329130A (en) * 1917-09-07 1920-01-27 Kimberly Clark Company Apparatus for making ornamental paper
US1595207A (en) * 1926-05-01 1926-08-10 Paper Patents Co Ornamental paper and method of making same
US3451878A (en) * 1965-03-29 1969-06-24 Frederick S T Fung Laminated article with decorative dots dispersed therethrough
US3560334A (en) * 1965-09-27 1971-02-02 Mead Corp Apparatus for incorporating additive dispersions to wet webs of paper
US4504357A (en) * 1979-02-13 1985-03-12 Gao Gesellschaft Fuer Automation Und Organisation Mbh. Security with identifying marks printed in the substance of a paper layer
US5989389A (en) * 1992-11-11 1999-11-23 Ab Tumba Bruk Method of producing visible, continuous streaks and/or delimited fields in paper
US5897746A (en) * 1993-12-24 1999-04-27 Giesecke & Devrient, Gmbh Method for equipping papers of value with authenticity features
US5622599A (en) * 1994-06-28 1997-04-22 Sproule; Barry Method and apparatus for coating pulp products
US5916416A (en) * 1996-05-15 1999-06-29 Cartiere Fedrigoni & C. S.P.A. Method and apparatus for manufacturing papers with watermarks or patterns and paper thus manufactured
US6764577B2 (en) * 1998-12-30 2004-07-20 Kimberly-Clark Worldwide, Inc. Masking patterns to enhance apparent opacity of paper products
US6270625B1 (en) * 1999-06-29 2001-08-07 The Mead Corporation Method for manufacturing colored stripped paper
US20020166647A1 (en) * 2001-04-27 2002-11-14 Thomas Attenberger Method and apparatus for incorporating feature substances into a paper web
US20050230071A1 (en) * 2001-04-27 2005-10-20 Giesecke & Devrient Gmbh Method for incorporating feature substances into a paper web
US7819434B2 (en) * 2003-10-08 2010-10-26 Giesecke & Devrient Gmbh Value document
US7011729B2 (en) * 2003-11-12 2006-03-14 Corn Products International, Inc. Starch and fiber mixture for papermaking and methods of making paper with the mixture

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110133442A1 (en) * 2008-06-12 2011-06-09 Crane Douglas A Method for increasing adhesion between a security element and a fibrous sheet material
US8289352B2 (en) 2010-07-15 2012-10-16 HJ Laboratories, LLC Providing erasable printing with nanoparticles
US10011141B2 (en) 2010-07-29 2018-07-03 Henri Rosset Security structure including phosphorescent and fluorescent compositions
US10344431B2 (en) 2011-02-23 2019-07-09 Crane & Co., Inc. Security sheet or document having one or more enhanced watermarks
US9708773B2 (en) 2011-02-23 2017-07-18 Crane & Co., Inc. Security sheet or document having one or more enhanced watermarks
GB2559364A (en) * 2017-02-02 2018-08-08 Portals De La Rue Ltd A method of manufacturing a security sheet
US11221305B2 (en) * 2017-05-15 2022-01-11 Security Matters Ltd. Object marking system and method
WO2019086080A1 (de) * 2017-11-02 2019-05-09 Bundesdruckerei Gmbh Verfahren zum herstellen eines sicherheitsmerkmals auf einem sicherheitspapier und verwendung
DE102017125618A1 (de) * 2017-11-02 2019-05-02 Bundesdruckerei Gmbh Verfahren zum Herstellen eines Sicherheitsmerkmals auf einem Sicherheitspapier und Verwendung
WO2019131083A1 (ja) * 2017-12-28 2019-07-04 コアレックス信栄株式会社 消臭紙の製造方法
JP6553320B1 (ja) * 2017-12-28 2019-07-31 コアレックス信栄株式会社 消臭紙の製造方法
CN111344457A (zh) * 2017-12-28 2020-06-26 科亚列士信荣株式会社 除臭纸的制造方法
US11396727B2 (en) 2017-12-28 2022-07-26 Corelex Shin-Ei Co., Ltd. Deodorant-paper manufacturing method

Also Published As

Publication number Publication date
RU2429138C2 (ru) 2011-09-20
DE602007007608D1 (de) 2010-08-19
FR2901286B1 (fr) 2011-08-19
BRPI0712592A2 (pt) 2012-07-03
ATE473322T1 (de) 2010-07-15
FR2901286A1 (fr) 2007-11-23
RU2008149604A (ru) 2010-06-27
CA2652572A1 (fr) 2007-11-29
EP2021544B1 (fr) 2010-07-07
EP2021544A1 (fr) 2009-02-11
MX2008014521A (es) 2009-04-16
ES2348370T3 (es) 2010-12-03
WO2007135334A1 (fr) 2007-11-29
SI2021544T1 (sl) 2010-12-31

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