US20080090886A1 - Aqueous Fungicidal Composition And Use Thereof For Combating Harmful Micro Organisms - Google Patents
Aqueous Fungicidal Composition And Use Thereof For Combating Harmful Micro Organisms Download PDFInfo
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- US20080090886A1 US20080090886A1 US11/587,052 US58705206A US2008090886A1 US 20080090886 A1 US20080090886 A1 US 20080090886A1 US 58705206 A US58705206 A US 58705206A US 2008090886 A1 US2008090886 A1 US 2008090886A1
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- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 description 1
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/007—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process employing compositions comprising nanoparticles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/15—Impregnating involving polymerisation including use of polymer-containing impregnating agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
Definitions
- the present invention relates to aqueous fungicidal active substance compositions and to their use in the control of harmful microorganisms, in particular for the protection of cellulose-comprising materials, in particular wood, from infection by harmful fungi, in particular those harmful fungi which may be harmful to wood or cellulose.
- wood and also other cellulose-comprising materials can be attacked and in extreme cases destroyed by microorganisms and in particular fungi (subsequently harmful fungi) if they are exposed to environmental conditions which promote the growth and the development of such microorganisms.
- fungi subsequently harmful fungi
- wood is frequently treated with wood preservatives.
- fungicidal active substances which exhibit only a low solubility in water are frequently formulated in the form of aqueous suspensions or emulsions. While emulsions usually still comprise organic solvents, suspensions are usually formulated free from solvents. The active substance is present in these suspensions in the form of fine particles with particle sizes in the micrometer region. If wood is now treated with such a suspension, the active substance remains on the surface of the wood since it, because of the particle size, cannot penetrate into the pores of the wood. However, this is required if effective protection of the wood is to be achieved. In addition, the active substance is easily washed off the surface by the effects of the weather.
- Fungicidal transparent varnishes have also on several occasions been proposed as wood preservative.
- these are aqueous painting systems based on aqueous polymer latexes which comprise the active substance in suspended form.
- the protection of the wood is not satisfactory since the active substances do not penetrate into the wood but remain on the surface of the wood.
- Such a demixing can, for example, occur if the microemulsion becomes depleted in emulsifier because of a high affinity of the emulsifier for the wood or a depletion in solvent occurs, which can easily happen in the pressure impregnation.
- aqueous, fungicidally effective, composition of fungicidal active substances with low solubility in water i.e. a solubility in water of less than 5 g/l, in particular less than 1 g/l, at 25° C./1013 mbar, which is advantageously suitable for the protection of cellulose-comprising materials, in particular wood, from infection by harmful fungi.
- the composition should in particular comprise only small amounts of or no volatile organic compounds, such as organic solvents.
- the active substance should not, or not to a significant extent, be leached from the treated materials by the effect of water.
- the aqueous active substance compositions should exhibit a better stability than conventional suspensions or microemulsions.
- an aqueous active substance composition in which the fungicidal active substance which is insoluble in water or only slightly soluble in water is present in the polymer particles of a finely divided water-insoluble polymer, the polymer particles of which exhibit a average particle size of not more than 300 nm, and in which the polymer is formed from at least 60% by weight, based on the total amount of the monomers M, of at least one neutral monoethylenically unsaturated monomer M1 with a solubility in water of not more than 30 ⁇ l at 25° C. and up to 40% by weight, based on the total amount of the monomers M, of one or more ethylenically unsaturated monomers M2 other than the monomers M1.
- an aqueous active substance composition comprising:
- compositions according to the invention are stable aqueous preparations of fungicidal active substances which are insoluble in water or only slightly soluble in water, which in principle are suitable for all applications in which it is desired to achieve effective protection from infection by microorganisms, in particular harmful fungi.
- the rate of application of active substance necessary for effective protection is, surprisingly, not higher and in a few cases even lower than when conventional aqueous active substance preparations are used.
- the present invention also relates to the use of such aqueous compositions for the control of microorganisms, in particular for the control of harmful fungi.
- control comprises, here and subsequently, the prevention or avoidance of infection by microorganisms, in particular harmful fungi and also the destruction of microorganisms, in particular harmful fungi, in infected substrates.
- compositions according to the invention are particularly suitable for the control of microorganisms, in particular of harmful fungi, in wood and other cellulose materials and in particular for the protection of these materials from infection by microorganisms, in particular harmful fungi.
- a particular embodiment of the invention relates to the use of such compositions for the protection of cellulose-comprising materials from infection by microorganisms, in particular from infection by wood-destroying fungi.
- aqueous compositions according to the invention are also suitable for other applications in which control of microorganisms, in particular harmful fungi, is desired, for example in plant protection, for the control of phytotoxic microorganisms, in seed treatment, and also in the protection of materials, as in-can and film preservatives, for antifouling, and for the protection of leather and other organic materials from infection by harmful microorganisms.
- the particle sizes of the finely divided polymer given here are weight-average particle sizes, as can be determined by dynamic light scattering. Methods for this are familiar to a person skilled in the art, for example from H. Wiese in D. Distler, Wässrige Polymer dispersionen [Aqueous Polymer Dispersions], Wiley-VCH, 1999, chapter 4.2.1, p. 40ff and the literature cited therein, and also H. Auweter, D. Hom, J. Colloid Interf. Sci., 105 (1985), 399, D. Lilge, D. Hom, Colloid Polym. Sci., 269 (1991), 704, or H. Wiese, D. Hom, J. Chem. Phys., 94 (1991), 6429.
- the average particle size preferably ranges from 10 to 250 nm, in particular from 20 to 200 nm, particularly preferably from 30 to 150 nm and very particularly preferably from 30 to 100 nm.
- the polymer is, according to the invention, at least 60% by weight, based on the total amount of the monomers M forming the polymer, preferably 60 to 99.5% by weight and particularly preferably 70 to 99% by weight formed from neutral monoethylenically unsaturated monomers M1 with a solubility in water of not more than 30 ⁇ l at 25° C./1013 mbar.
- the solubility in water of the monomers M1 under these conditions is from 0.1 to 20 g/l.
- Suitable monomers M1 comprise vinylaromatic monomers, such as styrene, esters of monoethylenically unsaturated mono- and dicarboxylic acids with 3 to 8 and in particular 3 or 4 carbon atoms with C 1 -C 10 -alkanols or with C 5 -C 8 -cycloalkanols, in particular the esters of acrylic acid, of methacrylic acid or of crotonic acid, the diesters of maleic acid, of fumaric acid and of itaconic acid, and particularly preferably the esters of acrylic acid with C 2 -C 10 -alkanols ( ⁇ C 2 -C 10 -alkyl acrylates), such as ethyl acrylate, n-butyl acrylate, isobutyl acrylate, tert-butyl acrylate, n-hexyl acrylate, 2-ethylhexyl acrylate and 3-propylheptyl acrylate,
- Suitable monomers M1 are, in addition, vinyl and allyl esters of aliphatic carboxylic acids with 2 to 10 carbon atoms, for example vinyl acetate, vinyl propionate and the vinyl esters of Versatic® acids (vinyl versatate), vinyl halides, such as vinyl chloride and vinylidene chloride, conjugated diolefins, such as butadiene and isoprene, and C 2 -C 6 -olefins, such as ethylene, propene, 1-butene and n-hexene.
- vinyl and allyl esters of aliphatic carboxylic acids with 2 to 10 carbon atoms for example vinyl acetate, vinyl propionate and the vinyl esters of Versatic® acids (vinyl versatate), vinyl halides, such as vinyl chloride and vinylidene chloride, conjugated diolefins, such as butadiene and isoprene, and C 2 -C 6 -olefins, such as
- Preferred monomers M1 are vinylaromatic monomers, in particular styrene, C 2 -C 10 -alkyl acrylates, in particular C 2 -C 8 -alkyl acrylates, and C 1 -C 10 -alkyl methacrylates.
- the ethylenically unsaturated monomers M which form the polymer advantageously also comprise at least 0.5 to 40% by weight, in particular 1 to 30% by weight, of at least one ethylenically unsaturated monomer M2 other than the monomers M1.
- the monomers M2 include in particular monoethylenically unsaturated monomers M2a exhibiting at least one acid group or at least one anionic group, in particular monomers M2a exhibiting a sulfonic acid group, a phosphonic acid group or one or two carboxylic acid groups, and the salts of the monomers M2a, in particular the alkali metal salts, e.g. the sodium or potassium salts, and the ammonium salts.
- ethylenically unsaturated sulfonic acids in particular vinylsulfonic acid, 2-acrylamido-2-methylpropanesulfonic acid, 2-acryloxyethanesulfonic acid, 2-methacryloxyethanesulfonic acid, 3-acryloxy- and 3-methacryloxypropanesulfonic acid, vinylbenzenesulfonic acid and their salts, ethylenically unsaturated phosphonic acids, such as vinylphosphonic acid and vinylphosphonic acid dimethyl ester and their salts, and ⁇ , ⁇ -ethylenically unsaturated C 3 -C 8 -mono- and C 4 -C 8 -dicarboxylic acids, in particular acrylic acid, methacrylic acid, crotonic acid, maleic acid, fumaric acid and itaconic acid.
- the proportion of the monomers M2a will commonly come to not more than 35% by weight, preferably not more than 20% by weight, e.g. 0.1 to 20% by weight and in particular
- the monomers M2 additionally include monoethylenically unsaturated neutral monomers M2b exhibiting a solubility in water of at least 50 g/l at 25° C. and in particular of at least 100 ⁇ l at 25° C.
- monoethylenically unsaturated neutral monomers M2b exhibiting a solubility in water of at least 50 g/l at 25° C. and in particular of at least 100 ⁇ l at 25° C.
- these are the amides of the above-mentioned ethylenically unsaturated carboxylic acids, in particular acrylamide and methacrylamide, ethylenically unsaturated nitriles, such as methacrylonitrile and acrylonitrile, hydroxyalkyl esters of the abovementioned ⁇ , ⁇ -ethylenically unsaturated C 3 -C 8 -monocarboxylic acids and C 4 -C 8 -dicarboxylic acids, in particular hydroxyethy
- the monomers M2b furthermore include N-vinylamides, such as N-vinylformamide, N-vinylpyrrolidone, N-vinylimidazole and N-vinylcaprolactam.
- N-vinylamides such as N-vinylformamide, N-vinylpyrrolidone, N-vinylimidazole and N-vinylcaprolactam.
- the proportion of the monomers M2b will preferably come to not more than 20% and in particular not more than 10% by weight, e.g. 0.1 to 10 and in particular 0.5 to 5% by weight, based on the total amount of the monomers M.
- the monomers M2 furthermore include monoethylenically unsaturated monomers M2c exhibiting at least one cationic group and/or at least one group which can be protonated in the aqueous medium.
- the monomers M2c include in particular those exhibiting a protonatable amino group, a quaternary ammonium group, a protonatable imino group or a quaternized imino group. Examples of monomers with a protonatable imino group are N-vinylimidazole and vinylpyridines.
- Examples of monomers with a quaternized imino group are N-alkylvinylpyridinium salts and N-Alkyl-N′-vinylimidazolinium salts, such as N-methyl-N′-vinylimidazolinium chloride or methyl sulfate.
- Preference is given, among the monomers M2c, in particular to the monomers of the general formula (I) in which
- Examples of such monomers are 2-(N,N-dimethylamino)ethyl acrylate, 2-(N,N-dimethylamino)ethyl methacrylate, 2-(N,N-dimethylamino)ethylacrylamide, 3-(N,N-dimethylamino)propylacrylamide, 3-(N,N-dimethylamino)propylmethacrylamide, 2-(N,N-dimethylamino)ethylmethacrylamide, 2-(N,N,N-trimethylammonio)ethyl acrylate chloride, 2-(N,N,N-trimethylammonio)ethyl methacrylate chloride, 2-(N,N,N-trimethylammonio)ethylmethacrylamide chloride, 3-(N,N,N-trimethylammonio)propylacrylamide chloride, 3-(N,N,N-trimethylammonio)propylacrylamide chloride, 2-(N,N
- the monomers M which form the polymer comprise at least one monomer M2c.
- the proportion of the monomers M2c is then advantageously 0.1 to 20% by weight, in particular 0.5 to 10% by weight and particularly preferably 1 to 7% by weight, based on the total amount of the monomers M.
- the polymer exhibits a net cationic charge, i.e. the molar proportion of the monomers M2c is greater than the molar proportion of the monomers M2a in the polymer and is preferably 110 mol %, in particular at least 120 mol % and particularly preferably at least 150 mol %, based on the monomers M2a.
- the monomers M2 furthermore include all monomers which can conventionally be used in an emulsion polymerization.
- the proportion of monomers exhibiting two or more nonconjugated ethylenically unsaturated double bonds usually comes to not more than 5% by weight, in particular not more than 2% by weight, e.g. 0.01 to 2% by weight and in particular 0.05 to 1.5% by weight, based on the total amount of monomers.
- the polymer present in the compositions according to the invention has proved to be advantageous for the polymer present in the compositions according to the invention to exhibit a glass transition temperature T g of at least 10° C., preferably of at least 20° C. and in particular of at least 30° C. In particular, the glass transition temperature will not exceed a value of 180° C. and particularly preferably 130° C. If the active substance composition according to the invention comprises several polymers with different glass transition temperatures, be it in the form of step or core/shell polymers or in the form of blends of different polymers, the proportion of polymers with a glass transition temperature of at least 10° C., preferably at least 20° C. and in particular at least 30° C. is at least 40% by weight.
- glass transition temperature T g is to be understood here as the midpoint temperature determined by differential scanning calorimetry (DSC) according to ASTM D 3418-82 (cf. Ullmann's Encyclopedia of Industrial Chemistry, 5th edition, volume A 21, VCH, Weinheim, 1992, p. 169, and Zosel, Aid und Lack, 82 (1976), p. 125-134, see also DIN 53765).
- X n represent the mass fractions of the monomers 1, 2, . . . , n and T g 1 , T g 2 , . . . , T g n represent, in degrees Kelvin, the glass transition temperatures of the polymers formed in each case only from one of the monomers 1, 2, . . . , n.
- the latter are, e.g., known from Ullmann's Encyclopedia of Industrial Chemistry, VCH, Weinheim, Vol. A 21, (1992) p. 169, or from J. Brandrup, E. H. Immergut, Polymer Handbook, 3rd ed., J. Wiley, New York, 1989.
- All organic substances with low solubility in water which inhibit the growth or the propagation of harmful fungi or which destroy the latter are suitable in principle as active substances.
- Their solubility in water at 25° C./1013 mbar is generally not more than 5 g/l, frequently not more than 3 g/l and in particular not more than 1 g/l, e.g. 0.001 g/l to 1 g/l, in particular 0.002 to 0.5 g/l, at 25° C./1013 mbar.
- Suitable active substances are the compounds listed as fungicides in the Compendium of Pesticide Common Names: http://www.hclrss.demon.co.uk/class-fungicides.html (Index of common names). These include, for example:
- compositions according to the invention for the protection of cellulose-comprising materials from infection by microorganisms of relevance in wood preservation, mainly molds, wood-discoloring fungi and wood-destroying fungi, preference is given in particular to those fungicides which are effective, for example, against the following groups of microorganisms:
- Preferred active substances are hence selected from the group of the conazoles, the group of the morpholines, the group of the strobilurins, the group of the thiazoles, the group of the sulfenamides and the group of the iodine compounds.
- the aqueous active substance preparations according to the invention comprise the fungicidal active substance generally in an amount of 0.1 to 50% by weight, preferably in an amount of 0.2 to 30% by weight and in particular in an amount of 0.5 to 20% by weight, based on the polymer present in the composition or based on the total amount of the monomers M used to prepare the polymer.
- compositions according to the invention can also comprise one or more insecticidal active substances.
- insecticidal active substances together with the at least one fungicidal active substance, are present in the polymer particles.
- the insecticidal active substance is then preferably an organic active substance with a low solubility in water generally of not more than 5 g/l, preferably not more than 3 g/l and in particular not more than 1 g/l, e.g. 0.001 to 1 g/l or 0.002 to 0.5 g/l, at 25° C./1013 mbar.
- suitable insecticidal active substances are the compounds listed as insecticides in the Compendium of Pesticide Common Names: http://www.hclrss.demon.co.uk/class-insecticides.html (Index of common names). These include, for example:
- insecticidal active substances from the class of the pyrethroids include in particular the insecticidal active substances from the class of the pyrethroids, arthropod growth regulators, such as chitin biosynthesis inhibitors, ecdysone antagonists, juvenoids or lipid biosynthesis inhibitors, neonicotinoids, pyrazole insecticides and chlorfenapyr.
- arthropod growth regulators such as chitin biosynthesis inhibitors, ecdysone antagonists, juvenoids or lipid biosynthesis inhibitors, neonicotinoids, pyrazole insecticides and chlorfenapyr.
- the insecticidal active substance is, if desired, usually present in the active substance composition according to the invention in an amount of 0.1 to 50% by weight, preferably in an amount of 0.2 to 30% by weight and in particular in an amount of 0.5 to 20% by weight, based on the monomers M which form the polymer.
- the total amount of active substance in the polymer of the compositions according to the invention is preferably 0.2 to 50% by weight, in particular 0.5 to 30% by weight and particularly preferably 1 to 20% by weight, based on the polymer or on the monomers M which form the polymer.
- the aqueous compositions according to the invention usually comprise surface-active substances in order to stabilize the polymer particles in the aqueous medium.
- surface-active substances include both protective colloids and low-molecular-weight emulsifiers, the latter, in contrast to the protective colloids, generally exhibiting a molecular weight of less than 2000 g/mol, in particular of less than 1000 g/mol (weight-average).
- the protective colloids and emulsfiers can be both cationic, anionic or neutral in nature and zwitterionic in nature.
- anionic surface-active substances are anionic emulsifiers, such as alkylphenylsulfonates, phenylsulfonates, alkyl sulfates, alkylsulfonates, alkyl ether sulfates, alkylphenol ether sulfates, alkyl polyglycol ether phosphates, alkyldiphenyl ether sulfonates, polyarylphenyl ether phosphates, alkyl sulfosuccinates, olefin sulfonates, paraffin sulfonates, petroleum sulfonates, taurides, sarcosides, fatty acids, alkylnaphthalenesulfonic acids or naphthalenesulfonic acids, including their alkali metal, alkaline earth metal, ammonium and amine salts.
- anionic emulsifiers such as alkylphenylsulfonates,
- anionic protective colloids examples include lignosulfonic acids, condensation products of sulfonated naphthalenes with formaldehyde or with formaldehyde and phenol and, if appropriate, urea, and also condensation products from phenolsulfonic acid, formaldehyde and urea, lignin sulfite waste liquor and lignosulfonates, and also polycarboxylates, such as polyacrylates, maleic anhydride/olefin copolymers (e.g. Sokalan® CP9, BASF), and also the alkali metal, alkaline earth metal, ammonium and amine salts of the above-mentioned protective colloids.
- lignosulfonic acids condensation products of sulfonated naphthalenes with formaldehyde or with formaldehyde and phenol and, if appropriate, urea, and also condensation products from phenolsulfonic acid, formaldehyde and urea,
- Nonionic emulsifiers are, for example, alkylphenol alkoxylates, alcohol alkoxylates, fatty amine alkoxylates, polyoxyethylene glycerol fatty acid esters, castor oil alkoxylates, fatty acid alkoxylates, fatty acid amide alkoxylates, fatty acid polydiethanolamides, lanolin ethoxylates, fatty acid polyglycol esters, isotridecyl alcohol, fatty acid amides, methylcellulose, fatty acid esters, silicone oils, alkylpolyglycosides and glycerol fatty acid esters.
- nonionic protective colloids are polyethylene glycol, polypropylene glycol, polyethylene glycol/polypropylene glycol block copolymers, polyethylene glycol alkyl ethers, polypropylene glycol alkyl ethers, polyethylene glycovpolypropylene glycol ether block copolymers, and their mixtures.
- cationic emulsifiers are quaternary ammonium salts, e.g. trimethyl- and triethyl(C 6 -C 30 -alkyl)ammonium salts, such as cocotrimethylammonium salts and trimethylcetylammonium salts, dimethyl- and diethyldi(C 4 -C 20 -alkyl)ammonium salts, such as didecyldimethylammonium salts and dicocodimethylammonium salts, methyl- and ethyltri(C 4 -C 20 -alkyl)ammonium salts, such as methyltrioctylammonium salts, (C 1 -C 20 -alkyl)di(C 1 -C 4 -alkyl)benzylammonium salts, such as triethylbenzylammonium salts and cocobenzyldimethylammonium salts, methyl- and ethyld
- didecylmethylpoly(oxyethyl)ammonium salts N—(C 6 -C 20 -alkyl)pyridinium salts, e.g. N-laurylpyridinium salts, N-methyl- and N-ethyl-N—(C 6 -C 2 -alkyl)morpholinium salts, and N-methyl- and N-ethyl-N′—C 6 -C 20 -alkyl)imidazolinium salts, in particular the halides, borates, carbonates, formates, acetates, propionates, hydrogencarbonates, sulfates and methyl sulfates.
- N—(C 6 -C 20 -alkyl)pyridinium salts e.g. N-laurylpyridinium salts
- N-methyl- and N-ethyl-N—(C 6 -C 2 -alkyl)morpholinium salts N-methyl- and N-e
- cationic protective colloids are homo- and copolymers of the abovementioned monomers M2c with a content of monomers M2c of at least 20% by weight, in particular at least 30% by weight of monomers M2c, for example homopolymers of N-vinyl-N-methylimidazolinium salts or of N-alkylvinylpyridinium salts and copolymers of these monomers with neutral monomers M2b which are preferably miscible with water.
- Zwitterionic emulsifiers are those with betaine structures. Such substances are known to a person skilled in the art and can be taken from the relevant state of the art (see, for example, R. Heusch, in Ullmann's Encyclopedia of Industrial Chemistry, 5th ed., on CD-ROM, Wiley-VCH, 1997, “Emulsions”, chapter 7, Table 4).
- compositions according to the invention usually comprise at least one emulsifier, preferably at least one ionic emulsifier and, if appropriate, one or more nonionic emulsifiers.
- emulsifier preferably at least one ionic emulsifier and, if appropriate, one or more nonionic emulsifiers.
- the compositions according to the invention it has proved worthwhile for the compositions according to the invention to comprise at least one cationic emulsifier, in particular if no monomers M2c are used to prepare the polymer.
- the amount of emulsifier usually ranges from 0.1 to 15% by weight, in particular from 0.2 to 12% by weight and particularly preferably from 0.7 to 10% by weight, based on the monomers M or on the polymer P.
- the amount of ionic emulsifier is preferably 0.3 to 10% by weight and in particular 0.5 to 8% by weight, based on the monomers M constituting the polymer.
- the amount of nonionic emulsifier preferably ranges from 0.2 to 12% by weight, in particular from 0.5 to 10% by weight, based on the monomers M constituting the polymer.
- the preparation of the aqueous compositions according to the invention comprises a radical aqueous emulsion polymerization of an oil-in-water emulsion of the monomers M, in which the monomer droplets of the emulsion comprise at least one fungicidal active substance and, if appropriate, an insecticidal active substance.
- the polymerization is carried out analogously to a conventional emulsion polymerization, with the difference that the monomer emulsion to be polymerized comprises the active substance dissolved in the monomer droplets.
- the oil-in-water emulsion of the active substance/monomer solution can be prepared in situ by addition of a solution of the active substance in the monomers M to be polymerized in the polymerization vessel placed under polymerization conditions.
- the active substance will be dissolved in the monomers M and the monomer solution thus obtained will be converted to an aqueous monomer emulsion, before the monomer/active substance emulsion thus obtained is fed to the polymerization reaction.
- the polymerization is generally carried out according to a “monomer feed process”, i.e. the greater part, preferably at least 70% and in particular at least 90%, of the solution of the active substance in the monomers M or the greater part, preferably at least 70% and in particular at least 90%, of the monomer/active substance emulsion is fed to the polymerization vessel in the course of the polymerization reaction.
- the addition of the monomer/active substance solution or emulsion is preferably carried out over a period of at least 0.5 h, preferably at least 1 h, e.g. 1 to 10 h and in particular 2 to 5 h.
- the addition of the monomer/active substance solution or emulsion can be carried out with a constant or variable addition rate, e.g.
- composition of the monomer/active substance solution or emulsion can remain constant during the addition or can be changed, it being possible for changes to be made both with regard to the monomer composition and with regard to the type of active substance or the concentration of the active substance.
- the monomer composition is changed in the course of the monomer addition in such a way that polymer regions with a different glass transition temperature are obtained in the polymer particles.
- This is achieved by a “step polymerization”.
- a first monomer/active substance solution or emulsion the monomer composition of which corresponds to a glass transition temperature T g 1
- a second monomer/active substance solution or emulsion the monomer composition of which corresponds to a glass transition temperature T g 2
- 2nd step 2nd step
- one or more additional monomer/active substance solutions or emulsions the monomer composition of which corresponds in each case to a glass transition temperature T g n , n being the respective step, is/are provided for this.
- the respective glass transition temperatures in polymers obtained in successive polymerization steps preferably differ by at least 10 K, in particular by at least 20 K and particularly preferably by at least 30 K, e.g. 30 K to 200 K, in particular 40 K to 160 K.
- the monomer amount polymerized in a monomer amount will come to at least 5% by weight, preferably at least 10% by weight, e.g. 5 to 95% by weight, in particular 10 to 90% by weight, in a 2-step polymerization and 5 to 90 or 5 to 85% by weight, in particular 10 to 80% by weight, in a polymerization with three or more steps.
- seed latex it is a finely divided polymer latex, the average particle size of which is usually not more than 100 nm, in particular not more than 80 nm and particularly preferably not more than 50 nm.
- the monomers constituting the seed latex are preferably to at least 90% by weight, in particular to at least 95% by weight and frequently to more than 99% by weight selected from the monomers M1, the seed latex also being able to comprise, for the stabilization, small amounts, e.g.
- the seed latex frequently exhibits a glass transition temperature of at least 10, in particular of at least 50 and frequently of at least 80° C.
- the amount of seed latex is usually 0.01 to 5% by weight, in particular 0.1 to 4% by weight, based on the monomers M1 to be polymerized.
- the bulk, and in particular all, of the seed latex is found, at the beginning of the polymerization, completely in the reaction vessel.
- the seed latex can also be generated in situ in the polymerization vessel by radical emulsion polymerization of the monomers which form the seed latex, the monomers which form the seed latex being selected from the abovementioned monomers M1 and M2 and in particular to at least 90% by weight from the monomers M1.
- the desired particle size of the seed latex can be controlled in a way known per se via the ratio of monomer to emulsifier.
- the initiators suitable for the emulsion polymerization according to the invention are the polymerization initiators suitable for and conventionally used for an emulsion polymerization which initiate a radical polymerization of the monomers M.
- These include azo compounds, such as 2,2′-azobisisobutyronitrile, 2,2′-azobis(2-methyl-butyronitrile), 2,2′-azobis[2-methyl-N-(2-hydroxyethyl)propionamide], 1,1′-azobis(1-cyclohexanecarbonitrile), 2,2′-azobis(2,4-dimethylvaleronitrile), 2,2′-azobis(N,N′-dimethyleneisobutyramidine) dihydrochloride and 2,2′-azobis(2-amidinopropane) dihydrochloride, organic or inorganic peroxides, such as diacetyl peroxide, di(tert-butyl)peroxide, diamyl peroxide, dioctanoyl
- Use is preferably made of water-soluble initiators, e.g. cationic azo compounds, such as azobis(dimethylamidinopropane), salts of peroxydisulfuric acid, in particular a sodium, potassium or ammonium salt, or a redox initiator system, which a salt of peroxydisulfuric acid, hydrogen peroxide or an organic peroxide, such as tert-butyl hydroperoxide, as oxidizing agent.
- reducing agent they preferably comprise a sulfur compound which is selected in particular from sodium hydrogensulfite, sodium hydroxymethanesulfinate and the hydrogensulfite adduct of acetone.
- Redox initiator systems can furthermore comprise the addition of small amounts of redox metal salts, such as iron salts, vanadium salts, copper salts, chromium salts or manganese salts, such as, for example, the redox initiator system ascorbic acid/iron(II) sulfate/sodium peroxydisulfate.
- redox metal salts such as iron salts, vanadium salts, copper salts, chromium salts or manganese salts, such as, for example, the redox initiator system ascorbic acid/iron(II) sulfate/sodium peroxydisulfate.
- the initiator is generally used in an amount of 0.02 to 2% by weight and in particular 0.05 to 1.5% by weight, based on the amount of the monomers M.
- the optimal amount of initiator naturally depends on the initiator system used and can be determined by a person skilled in the art by routine experiments.
- the initiator can be partially or completely introduced into the reaction vessel.
- the bulk of the initiator in particular at least 80%, e.g. 80 to 99.5%, of the initiator, is provided to the polymerization reactor in the course of the polymerization.
- the pressure and temperature are of secondary importance for the preparation of the active substance compositions according to the invention.
- the temperature naturally depends on the initiator system used and an optimal polymerization temperature can be determined by a person skilled in the art through routine experiments.
- the polymerization temperature usually ranges from 20 to 110° C., frequently from 50 to 95° C.
- the polymerization is usually carried out at standard pressure or ambient pressure. However, it can also be carried out under increased pressure, e.g. up to 3 bar, or under slightly reduced pressure, e.g. >800 mbar.
- the emulsifiers and protective colloids conventionally used for emulsion polymerization which have already been mentioned above as constituents of the active substance formulations according to the invention are suitable as surface-active substances.
- the amounts of surface-active substances conventionally used for an emulsion polymerization generally lie in the ranges given above, so that all or a portion of the surface-active substances in the compositions according to the invention is supplied via the emulsion polymerization.
- the molecular weight of the polymers can obviously be adjusted by addition of a small amount of regulators, e.g. 0.01 to 2% by weight, based on the monomers M which are being polymerized.
- regulators e.g. 0.01 to 2% by weight
- organic thio compounds and also allyl alcohols and aldehydes are suitable as regulator.
- aqueous polymer dispersions according to the invention may be necessary to substantially free the aqueous polymer dispersions according to the invention from odorous substances, such as residual monomers and other volatile organic constituents.
- this can be achieved physically by distillative removal (in particular via steam distillation) or by stripping with an inert gas.
- the residual monomers can be lowered chemically by radical postpolymerization, in particular under the effects of redox initiator systems, such as are listed, e.g., in DE-A 44 35 423, DE-A 44 19 518 and DE-A 44 35 422.
- the postpolymerization is preferably carried out with a redox initiator system composed of at least one organic peroxide and one organic sulfite.
- the polymer dispersions used are frequently, before their use according to the invention, adjusted to an alkaline value, preferably to pH values ranging from 7 to 10.
- Ammonia or organic amines, and also, preferably, hydroxides, such as sodium hydroxide, potassium hydroxide or calcium hydroxide, can be used for the neutralization.
- aqueous polymer dispersions which comprise, in the polymer particles of the dispersion, at least one fungicidal active substance, and, if appropriate, one or more insecticidal active substances.
- the dispersions thus obtained comprise the abovementioned surface-active substances.
- the active substance preparations thus obtained are characterized by a high stability and a low content of volatile organic compounds, which usually come to not more than 1% by weight, frequently not more than 0.1% by weight and in particular not more than 500 ppm, based on the total weight of the composition. Volatile compounds are, here and subsequently, all organic compounds which exhibit a boiling point of less than 200° C. at standard pressure.
- the solids content of the compositions according to the invention is determined to a first approximation by the active substance and the polymer and generally ranges from 10 to 60% by weight and in particular from 20 to 50% by weight.
- compositions according to the invention can be used directly as such or after diluting.
- compositions according to the invention can also comprise conventional additives, e.g. viscosity-modifying additives (thickeners), antifoam agents, bactericides and antifreeze agents.
- Suitable thickeners are compounds which confer a pseudoplastic flow behavior on the formulation, i.e. high viscosity at rest and low viscosity in the agitated state. Mention may be made, in this connection, for example, of polysaccharides or organic layered minerals, such as Xanthan Gum® (Keizan® from Kelco), Rhodopol® 23 (Rhône-Poulenc) or Veegum® (R.T. Vanderbilt), or Attaclay® (Engelhardt), Xanthan Gum® preferably being used.
- polysaccharides or organic layered minerals such as Xanthan Gum® (Keizan® from Kelco), Rhodopol® 23 (Rhône-Poulenc) or Veegum® (R.T. Vanderbilt), or Attaclay® (Engelhardt), Xanthan Gum® preferably being used.
- Silicone emulsions such as, e.g., Silicone SRE, from Wacker, or Rhodorsil® from Rhodia
- long-chain alcohols such as, e.g., Silicone SRE, from Wacker, or Rhodorsil® from Rhodia
- fatty acids such as, e.g., fatty acids, fluoroorganic compounds and their mixtures, for example, come into consideration as antifoam agents suitable for the dispersions according to the invention.
- Bactericides can be added to stabilize the compositions according to the invention from infection by microorganisms.
- Suitable bactericides are, for example, Proxel® from Avecia (or Arch) or Acticide® RS from Thor Chemie and Kathon® MK from Röhm & Haas.
- Suitable antifreeze agents are organic polyols, e.g. ethylene glycol, propylene glycol or glycerol. These are generally used in amounts of not more than 10% by weight, based on the total weight of the active substance composition.
- the active substance compositions according to the invention can, to regulate the pH, comprise 1 to 5% by weight of buffer, based on the total amounts of the formulation prepared, the amounts and the type of the buffer used depending on the chemical properties of the active substance or substances.
- buffers are alkali metal salts of weak inorganic or organic acids, such as, e.g., phosphoric acid, boric acid, acetic acid, propionic acid, citric acid, fumaric acid, tartaric acid, oxalic acid and succinic acid.
- aqueous compositions according to the invention can be formulated with conventional binders, for example aqueous polymer dispersions or water-soluble resins, for example water-soluble alkyd resins, or with waxes.
- conventional binders for example aqueous polymer dispersions or water-soluble resins, for example water-soluble alkyd resins, or with waxes.
- the aqueous active substance compositions according to the invention can also be formulated with conventional water-soluble wood preservatives, in particular with their aqueous solutions, in order to improve the overall effectiveness against wood-destroying organisms.
- these are, for example, aqueous preparations of conventional wood-protecting salts, for example of salts based on boric acid and alkali metal borates, salts based on quaternary ammonium compounds, e.g.
- trimethyl- and triethyl(C 6 -C 30 -alkyl)ammonium salts such as cocotrimethylammonium chloride or trimethylcetylammonium salts, dimethyl- and diethyldi(C 4 -C 20 -alkyl)ammonium salts, such as didecyldimethylammonium chloride, didecyldimethylammonium bromide or dicocodimethylammonium chloride, (C 1 -C 20 -alkyl)di(C 1 -C 4 -alkyl)benzylammonium salts, such as cocobenzyldimethylammonium chloride, or methyl- and ethyldi(C 4 -C 20 -alkyl)poly(oxyethyl)ammonium salts, e.g.
- aqueous active substance preparations can also be formulated with other aqueous fungicidal and insecticidal active substance compositions, for example with conventional emulsion concentrates, suspension concentrates or suspoemulsion concentrates of the abovementioned active substances, e.g.
- aqueous active substance composition according to the invention By mixing the aqueous active substance composition according to the invention with conventional aqueous preparations of the abovementioned active substances, a broadening in the spectrum of activity is first obtained, if the conventional preparation comprises a different active substance from the aqueous active substance composition according to the invention.
- the advantages of the active substance compositions according to the invention are not lost by formulating with conventional aqueous active substance preparations, in particular the improved adhesion to cellulose-comprising materials and especially to wood. Consequently, the application properties of a conventional aqueous active substance preparation can be improved by formulating with an aqueous active substance composition according to the invention of the same active substance.
- the active substance compositions according to the invention there are a number of advantages to the active substance compositions according to the invention.
- these are stable aqueous formulations of fungicidal active substances which are insoluble in water or are soluble in water only to a slight extent.
- the phase separation problems observed in conventional formulations and in micro- or nanodispersions of the active substances are not observed and settling of the active substance is not observed, even when drastic conditions are employed, such as occur in the processes employed for impregnating wood with fungicidal active substances.
- the content of volatile organic compounds is with conventional additivating lower than with comparable conventional formulations and, in comparison to micro- or nanodispersions of active substances, the proportion of emulsifier is simultaneously lower, based on the active substance used.
- the active substance is leached from the treated material, under the effect of water, to a markedly lesser extent in comparison with other formulations. Furthermore, interactions of the active substances with other formulation constituents or additional active substances, such as frequently occur with a conventional formulation, are not observed. Furthermore, the decomposition of the active substances by the effects of the substrate or environment, such as pH value of the medium or UV radiation, is slowed down or even completely halted. Surprisingly, a reduced effectiveness of the active substance through the incorporation in a polymer matrix is not observed.
- the present invention also relates to a process for the protection of cellulose-comprising materials, in particular wood, from infection by harmful fungi, in particular from infection by the abovementioned wood-destroying fungi, in which the cellulose-comprising material, in particular wood, is treated with a composition according to the invention.
- Cellulose-comprising materials are, in addition to wood and downstream products, e.g. wood blanks, plywood, chipboard, MOF panels or OSB panels, also pulps and intermediates in the manufacture of paper, fabrics based on cellulose, such as cotton, materials based on woody annuals, for example molded articles formed from rape shavings, bargasse panels, straw panels, and the like.
- the cellulose-comprising materials furthermore include articles formed from cellulose-comprising fiber materials, such as fabrics, formed fabrics, paper, board, heat-insulating materials, ropes, cables, and the like.
- Suitable fiber materials for the process according to the invention comprise textile fibers, such as flax, linen, hemp, jute, cotton and ramie, paper fibers, such as flax, linen or hemp, bamboo fibers, paper mulberry and lignocellulose fibers, and also nettle fiber, manila hemp, sisal, kenaf and coconut fiber.
- the treatment can be carried out in a way known per se, depending on the type of substrate, by spraying, painting, dipping or impregnating the substrate with an undiluted active substance composition according to the invention or an active substance composition according to the invention diluted with water or by flooding the substrate in an undiluted aqueous active substance composition according to the invention or an aqueous active substance composition according to the invention diluted with water.
- the compositions according to the invention can also be present in the manufacture of the cellulose-comprising material, for example as binder or as sizing agent.
- the substrate according to the invention is wood
- the treatment of such materials with the active substance compositions according to the invention can be carried out according to the processes conventional for this and will be adapted in a way known per se to the technical realities in each case.
- the application concentration and the incorporation depend in this connection on the degree of danger of the material and on the respective treatment process and usually range from 0.05 mg to 10 g of active substance per kg of material.
- the undiluted composition comprising the active substance is frequently used in wood downstream products and cellulose-comprising materials, for example together with the binder used, as cobinder. Obviously, separate treatment during or after the manufacture, for example the sizing, is also possible.
- the aqueous active substance composition according to the invention can also be used in other areas of material protection from infection by harmful fungi and, if appropriate, from infection by animal pests.
- skin, fur or leather can be effectively protected, with the aqueous compositions according to the invention, from infection by microorganisms, in particular from infection by the abovementioned harmful fungi, and animal pests.
- the aqueous compositions according to the invention can also be used as antifouling paints, for example in shipbuilding, or as algicidal paint systems for facades and roofing tiles, depending on the active substance present therein in each case.
- the compositions according to the invention can be used as in-can and film preservatives.
- the particle sizes given were determined by quasielastic light scattering according to the methods described above in diluted dispersions (0.01 to 0.1% by weight). The average diameter, determined by the cumulant analysis of the autocorrelation function measured, is given.
- the glass transition temperature was determined in accordance with ASTM D 3418 using differential scanning calorimetry.
- the dispersion obtained had a solids content of 38.7% by weight and a viscosity of 30 mPa ⁇ s.
- the glass transition temperature of the polymer was +16° C.
- the average particle size, determined by means of light scattering, was 146 nm.
- the dispersion obtained had a solids content of 39% by weight and a viscosity of 45 mPa ⁇ s.
- the glass transition temperature of the polymer was 31° C.
- the average particle size, determined by means of light scattering, was 151 nm.
- the dispersions obtained had a solids content of 45% by weight and a viscosity of 115 mPa ⁇ s.
- the polymer showed 2 glass transition temperatures at ⁇ 31 and +99° C. determined by means of DSC.
- Emulsifier solution E4 40% by weight aqueous solution of a cationic emulsifier obtained by successive ethoxylation of stearylamine with 4-5 mol of ethylene oxide and subsequent quaternization with dimethyl sulfate.
- Dispersion Active substance x [g] D9 Metconazole 61.8 D10 Cyproconazole 42.9 D11 Epoxiconazole 0.4 D12 Tebuconazole 19.0 D13 IPBC 18.2
- the dispersion obtained had a solids content of 29.5% by weight and a viscosity of 100 mPa ⁇ s.
- the polymer showed a glass transition temperature at 87° C. determined by means of DSC.
- the average particle size, determined by means of light scattering, was 157 to 175 nm.
- feed 1 and 10% by weight of feed 2 were heated to 80° C. After 10 min, the addition of the remaining amount of feed 2 and of feed 3 was begun. The feed time of feed 2 and feed was 3.5 h. After the end of the addition of the feeds, the mixture was maintained at 80° C. for a further 30 min and was then cooled down to ambient temperature.
- the dispersion obtained had a solids content of 29.8% by weight and a viscosity of 105 mPa ⁇ s.
- the polymer showed a glass transition temperature at 110° C. determined by means of DSC.
- the average particle size, determined by means of light scattering, was 155 to 175 nm.
- the limits of the effectiveness of the compositions according to the invention with regard to wood-destroying basidiomycetes were determined on wood test specimens of Pinus spp. (southern yellow pine) with the dimensions 40 ⁇ 15 ⁇ 4 mm 3 .
- the test method on comminuted wood test specimens known as the Bravery test, is closely based on EN 113 and is used to determine the preventive effect of wood preservatives against wood-destroying fungi (see in this connection A. F. Bravery, Intern. Res. Group Wood Pres., Doc. No. IRG/WP/2113, 5S., Sweden, 1978).
- the wood test specimens impregnated with the composition according to the invention were tested without or with the constraint of leaching according to EN 84.
- Wood test specimens which, for control purposes, were treated only with a dispersion free of active substance with otherwise an identical composition showed, under test conditions, serious damage to the wood substance by fungal infection which was only slightly less than with untreated wood test samples.
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US12/831,055 US8741968B2 (en) | 2004-04-26 | 2010-07-06 | Aqueous fungicidal composition and use thereof for combating harmful microorganisms |
US14/261,193 US20140234425A1 (en) | 2004-04-26 | 2014-04-24 | Aqueous fungicidal composition and use thereof for combating harmful microorganisms |
US15/397,555 US10420339B2 (en) | 2004-04-26 | 2017-01-03 | Aqueous fungicidal composition and use thereof for combating harmful micro organisms |
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PCT/EP2005/004423 WO2005102044A1 (de) | 2004-04-26 | 2005-04-25 | Wässrige, fungizide zusammensetzung und deren verwendung zur bekämpfung von schädlichen mikroorganismen |
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US11/587,052 Abandoned US20080090886A1 (en) | 2004-04-26 | 2005-04-25 | Aqueous Fungicidal Composition And Use Thereof For Combating Harmful Micro Organisms |
US12/831,055 Active 2026-08-20 US8741968B2 (en) | 2004-04-26 | 2010-07-06 | Aqueous fungicidal composition and use thereof for combating harmful microorganisms |
US14/261,193 Abandoned US20140234425A1 (en) | 2004-04-26 | 2014-04-24 | Aqueous fungicidal composition and use thereof for combating harmful microorganisms |
US15/397,555 Expired - Fee Related US10420339B2 (en) | 2004-04-26 | 2017-01-03 | Aqueous fungicidal composition and use thereof for combating harmful micro organisms |
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US14/261,193 Abandoned US20140234425A1 (en) | 2004-04-26 | 2014-04-24 | Aqueous fungicidal composition and use thereof for combating harmful microorganisms |
US15/397,555 Expired - Fee Related US10420339B2 (en) | 2004-04-26 | 2017-01-03 | Aqueous fungicidal composition and use thereof for combating harmful micro organisms |
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