US20070284243A1 - Modular system for improving electro-metallurgical processes - Google Patents

Modular system for improving electro-metallurgical processes Download PDF

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Publication number
US20070284243A1
US20070284243A1 US11/802,672 US80267207A US2007284243A1 US 20070284243 A1 US20070284243 A1 US 20070284243A1 US 80267207 A US80267207 A US 80267207A US 2007284243 A1 US2007284243 A1 US 2007284243A1
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US
United States
Prior art keywords
modular system
cathode
nucleus
guide
anode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/802,672
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English (en)
Inventor
Pedro Aylwin
Andres Cardeon
Manuel Umana
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
New Tech Copper SA
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New Tech Copper SA
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Filing date
Publication date
Application filed by New Tech Copper SA filed Critical New Tech Copper SA
Publication of US20070284243A1 publication Critical patent/US20070284243A1/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/06Operating or servicing
    • C25C7/08Separating of deposited metals from the cathode

Definitions

  • a modular system for improving electro-metallurgical processes comprising a nucleus formed by upper and lower rectangular frames, the nucleus. At least one cathode guide is attached to at least one of longitudinal beams. The at least one cathode guide is operable to keep positive ions from reaching border or edge of the cathode. At least one anode guide is provided.
  • Another aspect of the disclosed teachings is a use of the system described above in a treatment of liquid waste or electroplating.
  • FIG. 01 . a is an isometric view of a subassembly of two cathode guide profiles according to an exemplary embodiment of the present invention.
  • FIG. 01 shows an enlarged isometric view of the upper part of a subassembly of two cathode guide profiles according to an exemplary embodiment of the present invention.
  • FIG. 02 . a shows an isometric view of an anode guide profile according to an exemplary embodiment of the present invention.
  • FIG. 02 shows an enlarged isometric view of the upper part of an anode guide profile according to an exemplary embodiment of the present invention.
  • FIG. 03 shows an isometric view of the Nucleus of the Modular System for Improving Electro-metallurgical Processes according to an exemplary embodiment of the present invention.
  • FIG. 04 shows an isometric view of a Horizontal Spacer according to an exemplary embodiment of the present invention.
  • FIG. 05 a - b show an isometric view of the Cathode type Nucleus Holder according to an exemplary embodiment of the present invention.
  • FIG. 06 shows an isometric view of the Anode Bracket type Nucleus Holder according to an exemplary embodiment of the present invention.
  • FIG. 07 shows an isometric view of the Head-type Nucleus Holder according to an exemplary embodiment of the present invention.
  • FIG. 08 shows an isometric view of the Nucleus positioned inside the cell, during the anode and cathode loading process according to an exemplary embodiment of the present invention.
  • FIG. 09 shows an isometric view of the Nucleus, with the cathode-type Nucleus holders, anode bracket type nucleus holders and head type nucleus holders installed in position according to an exemplary embodiment of the present invention.
  • An exemplary embodiment is of a modular system for improving electro-metallurgical processes is described in relation to FIGS. 1-8 . It is structured as of a Fundamental Module, known as a Nucleus, represented in FIG. 03 , to which other Modules or elements can be coupled or uncoupled to solve electro-metallurgical process problems such as those described previously in the Background section.
  • a Fundamental Module known as a Nucleus, represented in FIG. 03 , to which other Modules or elements can be coupled or uncoupled to solve electro-metallurgical process problems such as those described previously in the Background section.
  • the Nucleus of FIG. 03 is made up of an upper Frame formed by the left ( 6 ) and right ( 19 ) longitudinal holding beams and by the front or frontal ( 18 ) and rear ( 7 ) transversal supports, a lower Frame formed by the lower right longitudinal holding beams ( 11 ) and another equivalent one on the left side, and the lower beams of the Frontal heads ( 15 ) and their equivalent in the rear head.
  • Both Frames are joined by means of right hand corner pillars ( 8 ) and ( 14 ) and their equivalent on the left side, one or more Intermediate Pillars such as that designated with the number ( 12 ) and one or more diagonals on the right side like the one designated with the number ( 22 ) and its equivalent on the left side.
  • reinforcement Beams can be incorporated like the one designated with number ( 17 ), both in the frontal and in the rear head.
  • reinforcement Beams can be incorporated like the one designated with number ( 17 ), both in the frontal and in the rear head.
  • elements for resting on the floor of the cell such as that designated with the number ( 10 ).
  • the plastic stripping eliminator module is made up of a set of cathode guides ( 2 ) and optionally a set of anode guides ( 5 ) and/or a Spacer Module like the one shown in FIG. 04 .
  • Both the cathode guides ( 2 ) as well as the anode guides ( 5 ) can be installed, optionally, with their corresponding cathode aligners ( 1 ) and anode aligners ( 4 ), which are fixed in a vertical position on both interior sides of the Nucleus.
  • the transversal profile of the cathode guide can be shaped like an omega, or a U and/or V, its length being greater than the length of the cathode immersed in the electrolyte, the width of the channel of the omega or of the U and/or of the V profile must be slightly greater than the thickness of the cathode in use.
  • the cathode guides must be installed in such a way that the lower corners of the cathode, once the cathode is positioned in the cell, they are totally covered by the cathode guide.
  • the cathode guide can be reinforced with a shock absorber ( 3 ).
  • the transversal profile of the anode guide ( 5 ) corresponds to a channel whose distance between opposing faces must be slightly greater than the thickness of the anode that will be employed.
  • the aligners have the shape of a truncated cone or inverted truncated pyramid, open towards the center of the cell, and their function is to act as a funnel to facilitate the introduction of the cathodes and anodes respectively into the cell.
  • the cathode guides ( 1 ) may be used only with the anode guides ( 5 ), with or without aligners or the cathode guides only with a horizontal spacer module like the one in FIG. 04 , or the cathode guides together with the anode guides and the horizontal spacer module.
  • the installation in a Wet or in a Dry Cell can be executed by attaching elements to the Nucleus that make it easier to lift and transfer it with the help of the traveling crane of the EW plant. These elements can be located in positions occupied by cathodes, by anodes or at the ends of the Nucleus.
  • the version known as Cathode Type Nucleus Holder represented in FIG. 05 a - b consists of a bar ( 25 ) with two windows for the Crane hooks ( 23 ) and two coupling angles to be attached to the longitudinal support beam of the Upper Frame of the Nucleus ( 24 ). Two or more of these cathode type Nucleus holders attached in positions normally occupied by cathodes are needed.
  • the version known as Anode-type Bracket of the Nucleus Holder represented in FIG. 06 , consists of a Holder ( 26 ) joined to a Cube ( 27 ), to be attached by means of a bolt or other system, in two or more anode positions, in each one of the longitudinal support beams of the upper frame of the Nucleus.
  • the version known as Head-type Nucleus Holder, represented in FIG. 07 consists of one end that rests on the electrolytic cell upper head masonry ( 28 ) and one end that is attached to the Nucleus ( 29 ). These holding systems can be used independently one at a time or in any combination thereof.
  • these holders make it possible to lift, introduce and/or remove the Nucleus from the cell with all the cathodes and anodes in position, whether the cell is empty or full of electrolyte.
  • the Head Assembly Support Module consisting of four supports like the one shown in FIG. 07 may be installed. These supports are installed at the ends of the longitudinal support beams of the upper frame of the Nucleus ( 6 ) and ( 19 ), as shown in FIG. 09 , and their projecting head support ends of the masonry electrolytic cell ( 28 ) are located directly over the heads of the cell itself, preventing the lower frame of the Nucleus from resting on the bottom of the cell.
  • a module is being developed to facilitate the transversal circulation of the electrolyte.
  • the exemplary embodiments of the disclosed system is with such a module.
  • the Nucleus of the Modular System for Improving Electro-Metallurgical Processes similar to the one represented in FIG. 03 , was introduced into this cell.
  • the general dimensions of the Nucleus that was introduced into the Electrolytic Cell are 35 cm wide by 50 cm long and 35 cm high.
  • a module of five cathode guides ( 2 ) was coupled to each side on the left ( 6 ) and right ( 19 ) longitudinal support beams and on the lower right longitudinal support beam ( 11 ) and its lower equivalent on the left side. All this with its corresponding cathode aligners ( 1 ).
  • a Horizontal Spacer similar to the one shown in FIG. 04 , was coupled at the bottom of the cell, with six pairs of anode housing ( 20 ) and five pairs of cathode housing ( 21 ). The distance between anodes as well as that between cathodes was fixed at 100 mm, the same one used in the simulated Industrial Plant.
  • the cell was filled with copper sulfate electrolyte, having a composition equivalent to that of the simulated Industrial Plant, and the deposit was started at a potential of 2.6 Volts between anode and cathode, employing a current density of 300 Amperes per square meter.
  • the operational improvements include multiple benefits that arise from the absence of jacketed cathodes, absence of short-circuits and the ease with which the cathodes deposited can be loosened from the stainless cathode substrates with the Modular System for Improving Electro-Metallurgical Processes. The most important of these are: greater availability of equipment, reduction of human resources and reduction of raw materials costs. First, the factors that affect the greater availability of equipment are: 100% detaching in peeling machine, reduction of stripping frequency, increased useful life of the cathode, the anode and the cell, and increased availability of the traveling crane.
  • the reduction of the Human Resources corresponds to the reduced supervision of short-circuits, manual detachment of plates and rectification of short-circuited cathodes.
  • the cost reduction associated to other supplies used in the EW process relates to the elimination of plastic borders, the elimination of cathode/anode spacers and the consumption reduction of chemical reagents.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
US11/802,672 2006-05-30 2007-05-24 Modular system for improving electro-metallurgical processes Abandoned US20070284243A1 (en)

Applications Claiming Priority (2)

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CL1300-2006 2006-05-30
CL200601300 2006-05-30

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US20070284243A1 true US20070284243A1 (en) 2007-12-13

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US (1) US20070284243A1 (es)
AU (1) AU2007201708B2 (es)
CA (1) CA2586149C (es)
PE (1) PE20071262A1 (es)
ZA (1) ZA200704426B (es)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2456196A (en) * 2008-01-07 2009-07-08 New Tech Copper S A Modular system for positioning electrodes in cells for the electrodeposition of metals
WO2016054755A1 (es) * 2014-10-06 2016-04-14 New Tech Copper Spa Sistema de sujeción de guías anódicas y catódicas
WO2016054753A1 (es) * 2014-10-06 2016-04-14 New Tech Copper Spa Guía de ánodo deslizable
WO2016054754A1 (es) * 2014-10-06 2016-04-14 New Tech Copper Spa Guía de cátodo deslizable
WO2020069630A1 (es) * 2018-10-05 2020-04-09 New Tech Copper Spa Sistema de estructura auto-soportante ensamblable por piezas y adaptable al espacio dispuesto para la electro-obtención de metales, tanto en una celda ya operativa o en una cuba, (sele ng); método de armado; y método de extracción de lodos

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050263392A1 (en) * 2004-05-12 2005-12-01 Casanova Manuel R U Cathode guidance and perimeter deposition control assembly in electro-metallurgy cathodes

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6746581B2 (en) * 2002-10-22 2004-06-08 William A. Ebert Edge protector systems for cathode plates and methods of making same

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050263392A1 (en) * 2004-05-12 2005-12-01 Casanova Manuel R U Cathode guidance and perimeter deposition control assembly in electro-metallurgy cathodes

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2456196A (en) * 2008-01-07 2009-07-08 New Tech Copper S A Modular system for positioning electrodes in cells for the electrodeposition of metals
EP2077342A2 (en) 2008-01-07 2009-07-08 New Tech Copper S.A. Set of Parts for Positioning Electrodes in Cells for the Electrodepositing of Metals
US20090173624A1 (en) * 2008-01-07 2009-07-09 New Tech Copper S.A. Set of parts for positioning electrodes in cells for the electrodepositing of metals
EP2077342A3 (en) * 2008-01-07 2009-10-21 New Tech Copper S.A. Set of Parts for Positioning Electrodes in Cells for the Electrodepositing of Metals
AU2008207601B2 (en) * 2008-01-07 2010-09-16 New Tech Copper S.A. Set of parts for positioning electrodes in cells for the electrodepositing of metals
ES2358651A1 (es) * 2008-01-07 2011-05-12 New Tech Copper, S.A. Sistema de guiado de ánodos y/o cátodos en celdas de producción de metales por electrolisis.
US7988837B2 (en) * 2008-01-07 2011-08-02 New Tech Copper S.A. Set of parts for positioning electrodes in cells for the electrodepositing of metals
GB2456196B (en) * 2008-01-07 2013-05-15 New Tech Copper S A Set of parts for positioning electrodes in cells for the electrodepositing of metals
WO2016054755A1 (es) * 2014-10-06 2016-04-14 New Tech Copper Spa Sistema de sujeción de guías anódicas y catódicas
WO2016054753A1 (es) * 2014-10-06 2016-04-14 New Tech Copper Spa Guía de ánodo deslizable
WO2016054754A1 (es) * 2014-10-06 2016-04-14 New Tech Copper Spa Guía de cátodo deslizable
WO2020069630A1 (es) * 2018-10-05 2020-04-09 New Tech Copper Spa Sistema de estructura auto-soportante ensamblable por piezas y adaptable al espacio dispuesto para la electro-obtención de metales, tanto en una celda ya operativa o en una cuba, (sele ng); método de armado; y método de extracción de lodos

Also Published As

Publication number Publication date
ZA200704426B (en) 2008-06-25
PE20071262A1 (es) 2008-01-07
CA2586149C (en) 2011-03-01
AU2007201708A1 (en) 2007-12-20
AU2007201708B2 (en) 2011-05-19
CA2586149A1 (en) 2007-11-30

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