US20060102563A1 - Treating slurries - Google Patents

Treating slurries Download PDF

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Publication number
US20060102563A1
US20060102563A1 US10/542,432 US54243205A US2006102563A1 US 20060102563 A1 US20060102563 A1 US 20060102563A1 US 54243205 A US54243205 A US 54243205A US 2006102563 A1 US2006102563 A1 US 2006102563A1
Authority
US
United States
Prior art keywords
slurry
tetrakis
hydroxymethyl
phosphonium
salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/542,432
Other languages
English (en)
Inventor
Christopher Jones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay Solutions UK Ltd
Original Assignee
Rhodia Consumer Specialties Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Consumer Specialties Ltd filed Critical Rhodia Consumer Specialties Ltd
Assigned to RHODIA CONSUMER SPECIALTIES LIMITED reassignment RHODIA CONSUMER SPECIALTIES LIMITED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: JONES, CHRISTOPHER RAYMOND
Publication of US20060102563A1 publication Critical patent/US20060102563A1/en
Priority to US13/586,012 priority Critical patent/US20120309718A1/en
Priority to US13/856,058 priority patent/US8772356B2/en
Priority to US14/285,973 priority patent/US20140256686A1/en
Priority to US15/412,800 priority patent/US20170127681A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/34Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-halogen bonds; Phosphonium salts
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02Compounds of alkaline earth metals or magnesium
    • C09C1/021Calcium carbonates
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/40Compounds of aluminium
    • C09C1/42Clays
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08Treatment with low-molecular-weight non-polymer organic compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/80Compositional purity

Definitions

  • This invention relates to a composition for treating inorganic slurries and to a method of treating inorganic slurries with the aforesaid composition so as to maintain the slurries in a substantially homogeneous phase.
  • inorganic slurries contain about 70% to 80% by weight of solids.
  • Many inorganic slurries are known to be susceptible to bacterial contamination and it has been the practice to add one or more biocidally-active materials to the slurries in order to minimise such contamination.
  • Phosphorus-containing compounds in particular tetrakis(hydroxyorgano)phosphonium salts (THP + salts) are known to be effective biocides.
  • THP + salts tetrakis(hydroxyorgano)phosphonium salts
  • Experimental work carried out by the applicants has shown, for example, that the addition of a solution of tetrakis(hydroxymethyl)phosphonium sulphate (THPS) to a calcium carbonate-based slurry can give rise to a reduction in bacterial count of 10 4 in 2 hours.
  • THPS tetrakis(hydroxymethyl)phosphonium sulphate
  • composition comprising a THP + salt and a dispersant will provide continuing preservation against bacterial contamination, while at the same time maintaining the slurry in a substantially homogeneous phase.
  • the present invention provides a composition for treating an inorganic slurry, the composition comprising:
  • the THP + salt is preferably tetrakis(hydroxymethyl)phosphonium sulphate.
  • the THP + salt may be tetrakis(hydroxymethyl)phosphonium chloride, phosphate, nitrate or oxalate.
  • a preferred example of a dispersant of the type (b)(i) is a compound having one tertiary nitrogen atom, such as a sodium salt of nitrilo-tris(methylene phosphate), particularly the tetra-sodium salt.
  • Preferred examples of dispersants of the type (b) (ii) include those oligomers having the general H(CH 2 OM.CH 2 OM).PO 3 M 3 , wherein M is a cationic species such that the oligomer is soluble in water and n is a number greater than 1.
  • a preferred example of a dispersant of the type (b)(iii) is a homopolymer of acrylic acid, especially a homopolymer having a molecular weight in the range 2000 to 5000.
  • Preferred examples of dispersants of the type b(iv) include sodium tripolyphosphate.
  • the present invention provides a method of treating an inorganic slurry to maintain the slurry in a substantially homogeneous phase, the method comprising the addition to the slurry of an effective amount of a composition according to the first aspect of the present invention.
  • the inorganic slurry may, for example, comprise a calcium carbonate-based slurry.
  • the inorganic slurry may comprise a pigment slurry, a clay slurry or a cement slurry.
  • the ratio of THP + salt to dispersant in the composition is about 2:1 (as active ingredients).
  • the composition may be added to the slurry in an amount in the range 10 ppm to 1000 ppm (by weight of the slurry), for example about 750 ppm (by weight of the slurry).

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Toxicology (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Paper (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Liquid Crystal Substances (AREA)
  • Threshing Machine Elements (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Treatment Of Sludge (AREA)
US10/542,432 2003-01-29 2004-01-12 Treating slurries Abandoned US20060102563A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US13/586,012 US20120309718A1 (en) 2003-01-29 2012-08-15 Methods for treating an inorganic slurry
US13/856,058 US8772356B2 (en) 2003-01-29 2013-04-03 Methods for treating an inorganic slurry
US14/285,973 US20140256686A1 (en) 2003-01-29 2014-05-23 Composition for treating an inorganic slurry
US15/412,800 US20170127681A1 (en) 2003-01-29 2017-01-23 Composition for treating an inorganic slurry

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB03019759 2003-01-29
GB0301975A GB0301975D0 (en) 2003-01-29 2003-01-29 Treating slurries
PCT/GB2004/000056 WO2004066731A1 (fr) 2003-01-29 2004-01-12 Traitement de boues

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2004/000056 A-371-Of-International WO2004066731A1 (fr) 2003-01-29 2004-01-12 Traitement de boues

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US13/586,012 Continuation US20120309718A1 (en) 2003-01-29 2012-08-15 Methods for treating an inorganic slurry

Publications (1)

Publication Number Publication Date
US20060102563A1 true US20060102563A1 (en) 2006-05-18

Family

ID=9951976

Family Applications (5)

Application Number Title Priority Date Filing Date
US10/542,432 Abandoned US20060102563A1 (en) 2003-01-29 2004-01-12 Treating slurries
US13/586,012 Abandoned US20120309718A1 (en) 2003-01-29 2012-08-15 Methods for treating an inorganic slurry
US13/856,058 Expired - Fee Related US8772356B2 (en) 2003-01-29 2013-04-03 Methods for treating an inorganic slurry
US14/285,973 Abandoned US20140256686A1 (en) 2003-01-29 2014-05-23 Composition for treating an inorganic slurry
US15/412,800 Abandoned US20170127681A1 (en) 2003-01-29 2017-01-23 Composition for treating an inorganic slurry

Family Applications After (4)

Application Number Title Priority Date Filing Date
US13/586,012 Abandoned US20120309718A1 (en) 2003-01-29 2012-08-15 Methods for treating an inorganic slurry
US13/856,058 Expired - Fee Related US8772356B2 (en) 2003-01-29 2013-04-03 Methods for treating an inorganic slurry
US14/285,973 Abandoned US20140256686A1 (en) 2003-01-29 2014-05-23 Composition for treating an inorganic slurry
US15/412,800 Abandoned US20170127681A1 (en) 2003-01-29 2017-01-23 Composition for treating an inorganic slurry

Country Status (14)

Country Link
US (5) US20060102563A1 (fr)
EP (1) EP1592303B1 (fr)
JP (1) JP4568269B2 (fr)
KR (1) KR101076579B1 (fr)
CN (2) CN1744820B (fr)
AT (1) ATE430476T1 (fr)
CA (1) CA2514400C (fr)
DE (1) DE602004020971D1 (fr)
DK (1) DK1592303T3 (fr)
ES (1) ES2324711T3 (fr)
GB (1) GB0301975D0 (fr)
TW (1) TWI334855B (fr)
WO (1) WO2004066731A1 (fr)
ZA (1) ZA200505601B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7838854B2 (en) 2005-02-25 2010-11-23 Cymer, Inc. Method and apparatus for EUV plasma source target delivery

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2433441T3 (es) * 2010-04-16 2013-12-11 Omya International Ag Procedimiento para preparar material mineral de superficie modificada, productos resultantes y usos del mismo
WO2012122708A1 (fr) * 2011-03-16 2012-09-20 Rhodia (China) Co., Ltd. Procédé pour le traitement biologique des eaux usées
CA3058628A1 (fr) * 2017-03-31 2018-10-04 Dow Global Technologies Llc Composition microbicide
CN111848015A (zh) * 2020-07-21 2020-10-30 蚌埠龙淮建筑科技有限公司 一种利用市政污泥制备发泡墙体材料的方法

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2877848A (en) * 1956-06-11 1959-03-17 Gulf Oil Corp Process for cleaning permeable formations
US3336221A (en) * 1964-11-05 1967-08-15 Calgon Corp Method of inhibiting precipitation and scale formation
US3597251A (en) * 1968-11-19 1971-08-03 Wyandotte Chemical Corp Calcium carbonate product
US3832302A (en) * 1972-01-17 1974-08-27 Halliburton Co Methods for inhibiting scale formation
US3945843A (en) * 1974-07-22 1976-03-23 Nalco Chemical Company Acrylic acid copolymer as pigment dispersant
US4673509A (en) * 1983-08-26 1987-06-16 Albright & Wilson Limited Biocidal water treatment
US4874526A (en) * 1981-05-30 1989-10-17 Ciba-Geigy Corporation Treatment of water
US5386038A (en) * 1990-12-18 1995-01-31 Albright & Wilson Limited Water treatment agent
US5741757A (en) * 1985-08-06 1998-04-21 Albright & Wilson Limited Biocidal mixture of tetrakis (hydroxymethyl) phosphonium salt and a surfactant
US6180056B1 (en) * 1998-12-10 2001-01-30 Buckman Laboratories International Inc. Method and compositions for minimizing biological and colloidal fouling
US6315867B1 (en) * 1996-11-02 2001-11-13 Imerys Minerals Limited Dispersing agents and their use
US6402824B1 (en) * 2000-05-26 2002-06-11 J. M. Huber Corporation Processes for preparing precipitated calcium carbonate compositions and the products thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2057822C (fr) * 1990-12-18 1998-04-21 Keith Philip Davis Agent de traitement de l'eau
NZ296363A (en) 1994-11-04 1999-04-29 Betzdearborn Inc Synergistic biocidal compositions containing an oxidant and a non-oxidizing microbiocide for controlling bacteria
AU736266B2 (en) * 1997-12-23 2001-07-26 Rhodia Consumer Specialties Limited Biocidal compositions and treatments
JP2002521313A (ja) * 1998-07-22 2002-07-16 カルゴン コーポレイション ペルオキシ酢酸およびリン化合物の相乗的抗菌組成物
GB0017675D0 (en) 2000-07-20 2000-09-06 Rhodia Cons Spec Ltd Treatment of iron sulphide deposits

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2877848A (en) * 1956-06-11 1959-03-17 Gulf Oil Corp Process for cleaning permeable formations
US3336221A (en) * 1964-11-05 1967-08-15 Calgon Corp Method of inhibiting precipitation and scale formation
US3597251A (en) * 1968-11-19 1971-08-03 Wyandotte Chemical Corp Calcium carbonate product
US3832302A (en) * 1972-01-17 1974-08-27 Halliburton Co Methods for inhibiting scale formation
US3945843A (en) * 1974-07-22 1976-03-23 Nalco Chemical Company Acrylic acid copolymer as pigment dispersant
US4874526A (en) * 1981-05-30 1989-10-17 Ciba-Geigy Corporation Treatment of water
US4673509A (en) * 1983-08-26 1987-06-16 Albright & Wilson Limited Biocidal water treatment
US5741757A (en) * 1985-08-06 1998-04-21 Albright & Wilson Limited Biocidal mixture of tetrakis (hydroxymethyl) phosphonium salt and a surfactant
US5386038A (en) * 1990-12-18 1995-01-31 Albright & Wilson Limited Water treatment agent
US5606105A (en) * 1990-12-18 1997-02-25 Albright & Wilson Limited Water treatment agent
US6315867B1 (en) * 1996-11-02 2001-11-13 Imerys Minerals Limited Dispersing agents and their use
US6180056B1 (en) * 1998-12-10 2001-01-30 Buckman Laboratories International Inc. Method and compositions for minimizing biological and colloidal fouling
US6402824B1 (en) * 2000-05-26 2002-06-11 J. M. Huber Corporation Processes for preparing precipitated calcium carbonate compositions and the products thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7838854B2 (en) 2005-02-25 2010-11-23 Cymer, Inc. Method and apparatus for EUV plasma source target delivery

Also Published As

Publication number Publication date
US20170127681A1 (en) 2017-05-11
DK1592303T3 (da) 2009-08-17
GB0301975D0 (en) 2003-02-26
ZA200505601B (en) 2006-04-26
TW200427637A (en) 2004-12-16
US20130225534A1 (en) 2013-08-29
DE602004020971D1 (de) 2009-06-18
US20120309718A1 (en) 2012-12-06
EP1592303A1 (fr) 2005-11-09
KR101076579B1 (ko) 2011-10-24
JP2006521194A (ja) 2006-09-21
US20140256686A1 (en) 2014-09-11
CA2514400A1 (fr) 2004-08-12
JP4568269B2 (ja) 2010-10-27
EP1592303B1 (fr) 2009-05-06
CA2514400C (fr) 2012-11-06
US8772356B2 (en) 2014-07-08
CN1744820A (zh) 2006-03-08
KR20050114610A (ko) 2005-12-06
CN101851439A (zh) 2010-10-06
ES2324711T3 (es) 2009-08-13
CN1744820B (zh) 2011-10-05
ATE430476T1 (de) 2009-05-15
CN101851439B (zh) 2015-08-19
TWI334855B (en) 2010-12-21
WO2004066731A1 (fr) 2004-08-12

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Legal Events

Date Code Title Description
AS Assignment

Owner name: RHODIA CONSUMER SPECIALTIES LIMITED, GREAT BRITAIN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:JONES, CHRISTOPHER RAYMOND;REEL/FRAME:017291/0309

Effective date: 20050909

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION