US20060019201A1 - Post-dry etching cleaning liquid composition and process for fabricating semiconductor device - Google Patents
Post-dry etching cleaning liquid composition and process for fabricating semiconductor device Download PDFInfo
- Publication number
- US20060019201A1 US20060019201A1 US11/145,731 US14573105A US2006019201A1 US 20060019201 A1 US20060019201 A1 US 20060019201A1 US 14573105 A US14573105 A US 14573105A US 2006019201 A1 US2006019201 A1 US 2006019201A1
- Authority
- US
- United States
- Prior art keywords
- dry etching
- cleaning liquid
- liquid composition
- cleaning
- post
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 205
- 239000000203 mixture Substances 0.000 title claims abstract description 165
- 239000007788 liquid Substances 0.000 title claims abstract description 160
- 238000001312 dry etching Methods 0.000 title claims abstract description 112
- 238000000034 method Methods 0.000 title claims description 84
- 239000004065 semiconductor Substances 0.000 title claims description 44
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 claims abstract description 72
- 239000000758 substrate Substances 0.000 claims abstract description 62
- -1 organic acid salt Chemical class 0.000 claims abstract description 31
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims abstract description 28
- 150000002222 fluorine compounds Chemical class 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 9
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 9
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000005695 Ammonium acetate Substances 0.000 claims abstract description 7
- 235000019257 ammonium acetate Nutrition 0.000 claims abstract description 7
- 229940043376 ammonium acetate Drugs 0.000 claims abstract description 7
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims abstract description 6
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000010408 film Substances 0.000 claims description 213
- 239000010410 layer Substances 0.000 claims description 61
- 239000010949 copper Substances 0.000 claims description 58
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 38
- 229910052802 copper Inorganic materials 0.000 claims description 38
- 239000000463 material Substances 0.000 claims description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 32
- 238000004380 ashing Methods 0.000 claims description 26
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 26
- 239000011229 interlayer Substances 0.000 claims description 23
- 239000007769 metal material Substances 0.000 claims description 19
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 14
- 238000000059 patterning Methods 0.000 claims description 12
- 239000004020 conductor Substances 0.000 claims description 11
- 239000010409 thin film Substances 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 7
- 229910010272 inorganic material Inorganic materials 0.000 claims description 6
- 239000011147 inorganic material Substances 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- 238000005530 etching Methods 0.000 description 75
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical group [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 40
- 229920000642 polymer Polymers 0.000 description 38
- 238000005260 corrosion Methods 0.000 description 30
- 230000007797 corrosion Effects 0.000 description 30
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 26
- 239000001393 triammonium citrate Substances 0.000 description 22
- 235000011046 triammonium citrate Nutrition 0.000 description 22
- 230000004888 barrier function Effects 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 17
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 239000007864 aqueous solution Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 238000011156 evaluation Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 229910052581 Si3N4 Inorganic materials 0.000 description 8
- 238000001035 drying Methods 0.000 description 8
- 229920002120 photoresistant polymer Polymers 0.000 description 8
- 229920003209 poly(hydridosilsesquioxane) Polymers 0.000 description 8
- 229910021332 silicide Inorganic materials 0.000 description 8
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 8
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 238000000862 absorption spectrum Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 239000010703 silicon Substances 0.000 description 7
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 5
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 238000005229 chemical vapour deposition Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 238000004544 sputter deposition Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- 238000001459 lithography Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000011368 organic material Substances 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 238000010561 standard procedure Methods 0.000 description 3
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 2
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 240000007711 Peperomia pellucida Species 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- RYYVLZVUVIJVGH-UHFFFAOYSA-N caffeine Chemical compound CN1C(=O)N(C)C(=O)C2=C1N=CN2C RYYVLZVUVIJVGH-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 229920001795 coordination polymer Polymers 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 230000027756 respiratory electron transport chain Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- ILZHHPCAMLILSP-UHFFFAOYSA-N 2-(dimethylamino)ethanol;hydrofluoride Chemical compound [F-].C[NH+](C)CCO ILZHHPCAMLILSP-UHFFFAOYSA-N 0.000 description 1
- PTOKDFKDUYQOAK-UHFFFAOYSA-N 2-aminoethanol;hydrofluoride Chemical compound F.NCCO PTOKDFKDUYQOAK-UHFFFAOYSA-N 0.000 description 1
- 229930024421 Adenine Natural products 0.000 description 1
- GFFGJBXGBJISGV-UHFFFAOYSA-N Adenine Chemical compound NC1=NC=NC2=C1N=CN2 GFFGJBXGBJISGV-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- MPWRABSFFDBSMJ-UHFFFAOYSA-N F.CC(O)CN Chemical compound F.CC(O)CN MPWRABSFFDBSMJ-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- LPHGQDQBBGAPDZ-UHFFFAOYSA-N Isocaffeine Natural products CN1C(=O)N(C)C(=O)C2=C1N(C)C=N2 LPHGQDQBBGAPDZ-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical group CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical group N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 description 1
- TVWHNULVHGKJHS-UHFFFAOYSA-N Uric acid Natural products N1C(=O)NC(=O)C2NC(=O)NC21 TVWHNULVHGKJHS-UHFFFAOYSA-N 0.000 description 1
- VDRSDNINOSAWIV-UHFFFAOYSA-N [F].[Si] Chemical compound [F].[Si] VDRSDNINOSAWIV-UHFFFAOYSA-N 0.000 description 1
- 229960000643 adenine Drugs 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-O azanium;hydrofluoride Chemical compound [NH4+].F LDDQLRUQCUTJBB-UHFFFAOYSA-O 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229960001948 caffeine Drugs 0.000 description 1
- VJEONQKOZGKCAK-UHFFFAOYSA-N caffeine Natural products CN1C(=O)N(C)C(=O)C2=C1C=CN2C VJEONQKOZGKCAK-UHFFFAOYSA-N 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- LZCVHHFGMKXLBU-UHFFFAOYSA-N ethanamine;hydrofluoride Chemical compound [F-].CC[NH3+] LZCVHHFGMKXLBU-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- RRSMHQNLDRCPQG-UHFFFAOYSA-N methanamine;hydrofluoride Chemical compound [F-].[NH3+]C RRSMHQNLDRCPQG-UHFFFAOYSA-N 0.000 description 1
- MOVBJUGHBJJKOW-UHFFFAOYSA-N methyl 2-amino-5-methoxybenzoate Chemical compound COC(=O)C1=CC(OC)=CC=C1N MOVBJUGHBJJKOW-UHFFFAOYSA-N 0.000 description 1
- PJUIMOJAAPLTRJ-UHFFFAOYSA-N monothioglycerol Chemical group OCC(O)CS PJUIMOJAAPLTRJ-UHFFFAOYSA-N 0.000 description 1
- RUFLMLWJRZAWLJ-UHFFFAOYSA-N nickel silicide Chemical compound [Ni]=[Si]=[Ni] RUFLMLWJRZAWLJ-UHFFFAOYSA-N 0.000 description 1
- 229910021334 nickel silicide Inorganic materials 0.000 description 1
- ZVVSSOQAYNYNPP-UHFFFAOYSA-N olaflur Chemical class F.F.CCCCCCCCCCCCCCCCCCN(CCO)CCCN(CCO)CCO ZVVSSOQAYNYNPP-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000090 poly(aryl ether) Polymers 0.000 description 1
- DSISTIFLMZXDDI-UHFFFAOYSA-N propan-1-amine;hydrofluoride Chemical compound F.CCCN DSISTIFLMZXDDI-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- QSUJAUYJBJRLKV-UHFFFAOYSA-M tetraethylazanium;fluoride Chemical compound [F-].CC[N+](CC)(CC)CC QSUJAUYJBJRLKV-UHFFFAOYSA-M 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910021341 titanium silicide Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/304—Mechanical treatment, e.g. grinding, polishing, cutting
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
- C11D3/245—Organic compounds containing halogen containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/08—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02041—Cleaning
- H01L21/02057—Cleaning during device manufacture
- H01L21/0206—Cleaning during device manufacture during, before or after processing of insulating layers
- H01L21/02063—Cleaning during device manufacture during, before or after processing of insulating layers the processing being the formation of vias or contact holes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/22—Electronic devices, e.g. PCBs or semiconductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76802—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
- H01L21/76807—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics for dual damascene structures
- H01L21/76811—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics for dual damascene structures involving multiple stacked pre-patterned masks
Definitions
- copper and an alloy having copper as a main component have been used as new wiring materials for the purpose of reducing wiring resistance and inter-wiring capacitance.
- Copper wiring is formed by, for example, a damascene process in which, after copper is embedded using sputtering or electro-plating in a trench formed as a wiring pattern in an interlayer insulating film, an unwanted copper film portion is removed using chemical mechanical polishing (CMP), etc.
- CMP chemical mechanical polishing
- the copper alloy there are examples in which it is used for wiring by a process analogous to the damascene process.
- a liquid containing an aliphatic polycarboxylic acid, a reducing material such as glyoxylic acid, and water has been disclosed by the present inventors.
- the aliphatic polycarboxylic acid is oxalic acid, malonic acid, tartaric acid, malic acid, succinic acid, or citric acid
- the reducing material is glyoxylic acid, ascorbic acid, glucose, or mannose (ref. JP, A, 2003-167360).
- a post-etching treatment can be carried out that is capable of removing the residue from the etched surface while maintaining the shape resulting from the etching process. Furthermore, forming the composition as an aqueous solution without using any organic solvent enables the burden on the environment to be reduced.
- FIG. 10 is a graph showing the etching rate for a silicon oxide film by each constitution of cleaning liquid composition.
- the above-mentioned cleaning liquid composition may contain a resist removal component.
- the resist removal component include TMAH (tetramethylammonium hydroxide) and MEA (monomethanolamine). This can give an effect in removing the resist residue in particular.
- a barrier layer 21 is formed from TaN, etc. on the entire surface above the semiconductor substrate 1 by, for example, a sputtering method as a conductive thin film for the purpose of preventing wiring metal from diffusing.
- a Cu thin film for plating is formed, and a conductive material 23 such as copper (Cu) is deposited within the wiring trench 19 by a plating method, thus filling in the wiring trench 19 .
- the first inorganic mask 41 a , the cap insulating film 39 , and the low dielectric constant insulating film 37 are dry etched through the second inorganic mask 43 a to which the wiring trench pattern has been transferred, and the etching is stopped at the stopper layer 35 .
- a wiring trench (trench pattern) 53 is formed.
- the stopper layer 35 and the low dielectric constant film 33 at the base of the aperture 51 are dry etched, and the etching is first stopped at the surface of the stopper layer 31 . By so doing, the aperture 51 is further dug down into while being connected to the wiring trench 53 .
- This cleaning liquid composition is an aqueous solution comprising a fluorine compound, glyoxylic acid, and an organic acid salt as described above, and post cleaning by use of this cleaning liquid composition enables the resist residue B to be removed sufficiently without corroding a silicide (source/drain plug 87 ), which is a metal material exposed on the etching surface. Moreover, since etching of the interlayer insulating film 77 is suppressed, an etched side wall is prevented from retreating. It is therefore possible to maintain the etched shape formed by dry etching as it is.
- the third embodiment describes an arrangement in which the cleaning liquid composition of the present invention is used for a cleaning posttreatment in the formation by dry etching of the via hole 81 extending to the source/drain 75 , which is covered by the silicide.
- the cleaning liquid composition of the present invention is used for a cleaning posttreatment in the formation by dry etching of the via hole 81 extending to the source/drain 75 , which is covered by the silicide.
- the cleaning liquid composition of the present invention even when the surface of the source/drain 75 is not the silicide but is a semiconductor layer, by carrying out a cleaning posttreatment using the cleaning liquid composition of the present invention, it is possible to reliably remove the resist residue B. Because of this, it is possible to reliably connect the plug 87 and the source/drain 75 while maintaining the etched shape with good precision.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Cleaning Or Drying Semiconductors (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
- Drying Of Semiconductors (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/075,578 US20080188085A1 (en) | 2004-06-04 | 2008-03-11 | Post-dry etching cleaning liquid composition and process for fabricating semiconductor device |
US12/924,288 US8513140B2 (en) | 2004-06-04 | 2010-09-23 | Post-dry etching cleaning liquid composition and process for fabricating semiconductor device |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004-166571 | 2004-06-04 | ||
JP2004166571A JP2005347587A (ja) | 2004-06-04 | 2004-06-04 | ドライエッチング後の洗浄液組成物および半導体装置の製造方法 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/075,578 Division US20080188085A1 (en) | 2004-06-04 | 2008-03-11 | Post-dry etching cleaning liquid composition and process for fabricating semiconductor device |
US12/924,288 Division US8513140B2 (en) | 2004-06-04 | 2010-09-23 | Post-dry etching cleaning liquid composition and process for fabricating semiconductor device |
Publications (1)
Publication Number | Publication Date |
---|---|
US20060019201A1 true US20060019201A1 (en) | 2006-01-26 |
Family
ID=34937244
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/145,731 Abandoned US20060019201A1 (en) | 2004-06-04 | 2005-06-06 | Post-dry etching cleaning liquid composition and process for fabricating semiconductor device |
US12/075,578 Abandoned US20080188085A1 (en) | 2004-06-04 | 2008-03-11 | Post-dry etching cleaning liquid composition and process for fabricating semiconductor device |
US12/924,288 Active 2025-07-02 US8513140B2 (en) | 2004-06-04 | 2010-09-23 | Post-dry etching cleaning liquid composition and process for fabricating semiconductor device |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/075,578 Abandoned US20080188085A1 (en) | 2004-06-04 | 2008-03-11 | Post-dry etching cleaning liquid composition and process for fabricating semiconductor device |
US12/924,288 Active 2025-07-02 US8513140B2 (en) | 2004-06-04 | 2010-09-23 | Post-dry etching cleaning liquid composition and process for fabricating semiconductor device |
Country Status (7)
Country | Link |
---|---|
US (3) | US20060019201A1 (ja) |
EP (1) | EP1602714B1 (ja) |
JP (1) | JP2005347587A (ja) |
KR (1) | KR20060048205A (ja) |
CN (1) | CN100529039C (ja) |
DE (1) | DE602005000657T2 (ja) |
TW (1) | TWI407489B (ja) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050288199A1 (en) * | 2004-06-29 | 2005-12-29 | Kanto Kagaku Kabushiki Kaisha | Composition for removing photoresist residue and polymer residue |
US20060030158A1 (en) * | 2002-01-22 | 2006-02-09 | Cabot Microelectronics | Compositions and methods for tantalum CMP |
US20070178637A1 (en) * | 2006-01-31 | 2007-08-02 | Samsung Electronics Co., Ltd. | Method of fabricating gate of semiconductor device using oxygen-free ashing process |
US20080188084A1 (en) * | 2007-02-07 | 2008-08-07 | Siltronic Ag | Method For Reducing And Homogenizing The Thickness Of A Semiconductor Layer Which Lies On The Surface Of An Electrically Insulating Material |
WO2008144501A3 (en) * | 2007-05-17 | 2009-03-05 | Advanced Materials Technology | New antioxidants for post-cmp cleaning formulations |
US20090117736A1 (en) * | 2007-11-01 | 2009-05-07 | Applied Materials, Inc. | Ammonia-based plasma treatment for metal fill in narrow features |
US20090239777A1 (en) * | 2006-09-21 | 2009-09-24 | Advanced Technology Materials, Inc. | Antioxidants for post-cmp cleaning formulations |
US20090239369A1 (en) * | 2008-03-19 | 2009-09-24 | Samsung Electronics Co., Ltd. | Method of Forming Electrical Interconnects within Insulating Layers that Form Consecutive Sidewalls |
US20110143547A1 (en) * | 2008-08-25 | 2011-06-16 | Daikin Industries, Ltd. | Solution for removal of residue after semiconductor dry process and residue removal method using same |
US20110214688A1 (en) * | 2010-03-05 | 2011-09-08 | Lam Research Corporation | Cleaning solution for sidewall polymer of damascene processes |
US9074170B2 (en) | 2008-10-21 | 2015-07-07 | Advanced Technology Materials, Inc. | Copper cleaning and protection formulations |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPWO2007111126A1 (ja) * | 2006-03-27 | 2009-08-13 | 東京エレクトロン株式会社 | 基板処理方法、半導体装置の製造方法、基板処理装置、および記録媒体 |
US8759268B2 (en) | 2006-08-24 | 2014-06-24 | Daikin Industries, Ltd. | Solution for removing residue after semiconductor dry process and method of removing the residue using the same |
US7879783B2 (en) * | 2007-01-11 | 2011-02-01 | Air Products And Chemicals, Inc. | Cleaning composition for semiconductor substrates |
US8822396B2 (en) | 2007-08-22 | 2014-09-02 | Daikin Industries, Ltd. | Solution for removing residue after semiconductor dry process and method of removing the residue using the same |
JP5573138B2 (ja) * | 2009-12-09 | 2014-08-20 | 豊田合成株式会社 | 半導体発光素子の製造方法 |
KR20130101193A (ko) * | 2012-03-05 | 2013-09-13 | 삼성디스플레이 주식회사 | 패널의 세정장치 및 세정방법 |
US9012322B2 (en) * | 2013-04-05 | 2015-04-21 | Intermolecular, Inc. | Selective etching of copper and copper-barrier materials by an aqueous base solution with fluoride addition |
CN104795311B (zh) | 2014-01-21 | 2018-06-01 | 中芯国际集成电路制造(上海)有限公司 | 半导体器件的形成方法 |
EP3139402B1 (en) * | 2014-05-02 | 2018-08-15 | Mitsubishi Gas Chemical Company, Inc. | Semiconductor element cleaning liquid and cleaning method |
JP7322704B2 (ja) * | 2017-07-31 | 2023-08-08 | 三菱瓦斯化学株式会社 | コバルト、アルミナ、層間絶縁膜、窒化シリコンのダメージを抑制した組成液及びこれを用いた洗浄方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5630904A (en) * | 1994-03-28 | 1997-05-20 | Mitsubishi Gas Chemical Co., Inc. | Stripping and cleaning agent for removing dry-etching and photoresist residues from a semiconductor substrate, and a method for forming a line pattern using the stripping and cleaning agent |
US6593246B1 (en) * | 1999-03-15 | 2003-07-15 | Sony Corporation | Process for producing semiconductor device |
US6787293B2 (en) * | 2002-03-22 | 2004-09-07 | Kanto Kagaku Kabushiki Kaisha | Photoresist residue remover composition |
US6864044B2 (en) * | 2001-12-04 | 2005-03-08 | Kanto Kagaku Kabushiki Kaisha | Photoresist residue removing liquid composition |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6589882B2 (en) * | 2001-10-24 | 2003-07-08 | Micron Technology, Inc. | Copper post-etch cleaning process |
JP2003142443A (ja) * | 2001-10-31 | 2003-05-16 | Nippon Zeon Co Ltd | 基板の洗浄方法及びリンス液 |
US6773873B2 (en) * | 2002-03-25 | 2004-08-10 | Advanced Technology Materials, Inc. | pH buffered compositions useful for cleaning residue from semiconductor substrates |
JP2003313594A (ja) * | 2002-04-22 | 2003-11-06 | Nec Corp | 洗浄液および半導体装置の製造方法 |
JP4221191B2 (ja) * | 2002-05-16 | 2009-02-12 | 関東化学株式会社 | Cmp後洗浄液組成物 |
JP4443864B2 (ja) * | 2002-07-12 | 2010-03-31 | 株式会社ルネサステクノロジ | レジストまたはエッチング残さ物除去用洗浄液および半導体装置の製造方法 |
TW200413522A (en) * | 2002-11-08 | 2004-08-01 | Sumitomo Chemical Co | Washing liquid for semiconductor substrate |
JP2004342632A (ja) * | 2003-05-13 | 2004-12-02 | Matsushita Electric Ind Co Ltd | 半導体装置の製造方法 |
KR100536378B1 (ko) | 2003-11-19 | 2005-12-12 | 기아자동차주식회사 | 차량 전복 방지를 위한 이씨에스 장치의 동작 방법 |
-
2004
- 2004-06-04 JP JP2004166571A patent/JP2005347587A/ja active Pending
-
2005
- 2005-05-31 TW TW094117900A patent/TWI407489B/zh not_active IP Right Cessation
- 2005-06-04 DE DE602005000657T patent/DE602005000657T2/de active Active
- 2005-06-04 KR KR1020050048096A patent/KR20060048205A/ko active IP Right Grant
- 2005-06-04 EP EP05012100A patent/EP1602714B1/en not_active Not-in-force
- 2005-06-06 CN CNB2005100755873A patent/CN100529039C/zh not_active Expired - Fee Related
- 2005-06-06 US US11/145,731 patent/US20060019201A1/en not_active Abandoned
-
2008
- 2008-03-11 US US12/075,578 patent/US20080188085A1/en not_active Abandoned
-
2010
- 2010-09-23 US US12/924,288 patent/US8513140B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5630904A (en) * | 1994-03-28 | 1997-05-20 | Mitsubishi Gas Chemical Co., Inc. | Stripping and cleaning agent for removing dry-etching and photoresist residues from a semiconductor substrate, and a method for forming a line pattern using the stripping and cleaning agent |
US6593246B1 (en) * | 1999-03-15 | 2003-07-15 | Sony Corporation | Process for producing semiconductor device |
US6864044B2 (en) * | 2001-12-04 | 2005-03-08 | Kanto Kagaku Kabushiki Kaisha | Photoresist residue removing liquid composition |
US6787293B2 (en) * | 2002-03-22 | 2004-09-07 | Kanto Kagaku Kabushiki Kaisha | Photoresist residue remover composition |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060030158A1 (en) * | 2002-01-22 | 2006-02-09 | Cabot Microelectronics | Compositions and methods for tantalum CMP |
US7316603B2 (en) * | 2002-01-22 | 2008-01-08 | Cabot Microelectronics Corporation | Compositions and methods for tantalum CMP |
US20050288199A1 (en) * | 2004-06-29 | 2005-12-29 | Kanto Kagaku Kabushiki Kaisha | Composition for removing photoresist residue and polymer residue |
US7563754B2 (en) * | 2004-06-29 | 2009-07-21 | Kanto Kagaku Kabushiki Kaisha | Composition for removing photoresist residue and polymer residue |
US20070178637A1 (en) * | 2006-01-31 | 2007-08-02 | Samsung Electronics Co., Ltd. | Method of fabricating gate of semiconductor device using oxygen-free ashing process |
USRE46427E1 (en) | 2006-09-21 | 2017-06-06 | Entegris, Inc. | Antioxidants for post-CMP cleaning formulations |
US20090239777A1 (en) * | 2006-09-21 | 2009-09-24 | Advanced Technology Materials, Inc. | Antioxidants for post-cmp cleaning formulations |
US9528078B2 (en) | 2006-09-21 | 2016-12-27 | Advanced Technology Materials, Inc. | Antioxidants for post-CMP cleaning formulations |
US8685909B2 (en) | 2006-09-21 | 2014-04-01 | Advanced Technology Materials, Inc. | Antioxidants for post-CMP cleaning formulations |
US7988876B2 (en) * | 2007-02-07 | 2011-08-02 | Siltronic Ag | Method for reducing and homogenizing the thickness of a semiconductor layer which lies on the surface of an electrically insulating material |
US20080188084A1 (en) * | 2007-02-07 | 2008-08-07 | Siltronic Ag | Method For Reducing And Homogenizing The Thickness Of A Semiconductor Layer Which Lies On The Surface Of An Electrically Insulating Material |
WO2008144501A3 (en) * | 2007-05-17 | 2009-03-05 | Advanced Materials Technology | New antioxidants for post-cmp cleaning formulations |
US8551880B2 (en) * | 2007-11-01 | 2013-10-08 | Applied Materials, Inc. | Ammonia-based plasma treatment for metal fill in narrow features |
US20090117736A1 (en) * | 2007-11-01 | 2009-05-07 | Applied Materials, Inc. | Ammonia-based plasma treatment for metal fill in narrow features |
US7687381B2 (en) * | 2008-03-19 | 2010-03-30 | Samsung Electronics Co., Ltd. | Method of forming electrical interconnects within insulating layers that form consecutive sidewalls including forming a reaction layer on the inner sidewall |
US20090239369A1 (en) * | 2008-03-19 | 2009-09-24 | Samsung Electronics Co., Ltd. | Method of Forming Electrical Interconnects within Insulating Layers that Form Consecutive Sidewalls |
US20110143547A1 (en) * | 2008-08-25 | 2011-06-16 | Daikin Industries, Ltd. | Solution for removal of residue after semiconductor dry process and residue removal method using same |
US8747564B2 (en) | 2008-08-25 | 2014-06-10 | Daikin Industries, Ltd. | Solution for removal of residue after semiconductor dry process and residue removal method using same |
US9074170B2 (en) | 2008-10-21 | 2015-07-07 | Advanced Technology Materials, Inc. | Copper cleaning and protection formulations |
US20110214688A1 (en) * | 2010-03-05 | 2011-09-08 | Lam Research Corporation | Cleaning solution for sidewall polymer of damascene processes |
Also Published As
Publication number | Publication date |
---|---|
US20080188085A1 (en) | 2008-08-07 |
JP2005347587A (ja) | 2005-12-15 |
TWI407489B (zh) | 2013-09-01 |
CN100529039C (zh) | 2009-08-19 |
US20110014793A1 (en) | 2011-01-20 |
DE602005000657D1 (de) | 2007-04-19 |
EP1602714B1 (en) | 2007-03-07 |
KR20060048205A (ko) | 2006-05-18 |
TW200603262A (en) | 2006-01-16 |
EP1602714A1 (en) | 2005-12-07 |
US8513140B2 (en) | 2013-08-20 |
DE602005000657T2 (de) | 2007-11-29 |
CN1706925A (zh) | 2005-12-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8513140B2 (en) | Post-dry etching cleaning liquid composition and process for fabricating semiconductor device | |
EP1612611B1 (en) | Composition and process for removing photoresist residue and polymer residue | |
US6773873B2 (en) | pH buffered compositions useful for cleaning residue from semiconductor substrates | |
US8772214B2 (en) | Aqueous cleaning composition for removing residues and method using same | |
US7674755B2 (en) | Formulation for removal of photoresist, etch residue and BARC | |
EP1619557B1 (en) | Composition for removing photoresist and/or etching residue from a substrate and use thereof | |
US8231733B2 (en) | Aqueous stripping and cleaning composition | |
TWI416282B (zh) | 用以移除殘餘光阻及聚合物的組合物及使用該組合物的殘餘物移除製程 | |
US20090131295A1 (en) | Compositions for Removal of Metal Hard Mask Etching Residues from a Semiconductor Substrate | |
US7816312B2 (en) | Composition for photoresist stripping solution and process of photoresist stripping | |
US7816313B2 (en) | Photoresist residue remover composition and semiconductor circuit element production process employing the same | |
JP2007519942A (ja) | レジスト、barc、およびギャップフィル材料を剥離する化学物質ならびに方法 | |
KR100946636B1 (ko) | 포토레지스트 잔사제거액 조성물 | |
JP3389166B2 (ja) | レジスト用剥離液組成物 | |
JP7022100B2 (ja) | ポストエッチング残留物洗浄組成物及びその使用方法 | |
US11377624B2 (en) | Cleaning composition for post-etch or post ash residue removal from a semiconductor substrate and corresponding manufacturing process | |
US20210189298A1 (en) | IMIDAZOLIDINETHIONE-CONTAINING COMPOSITIONS FOR POST-ASH RESIDUE REMOVAL AND/OR FOR OXIDATIVE ETCHING OF A LAYER OR MASK COMPRISING TiN |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: TOSHIBA COPORATION KABUSHIKI KAISHA TOSHIBA, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MURAMATSU, MASAFUMI;ASADA, KAZUMI;HAGINO, YUKINO;AND OTHERS;REEL/FRAME:017075/0001;SIGNING DATES FROM 20050812 TO 20050831 Owner name: SONY CORPORATION, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MURAMATSU, MASAFUMI;ASADA, KAZUMI;HAGINO, YUKINO;AND OTHERS;REEL/FRAME:017075/0001;SIGNING DATES FROM 20050812 TO 20050831 Owner name: KANTO KAGAKU KABUSHIKI KAISHI, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MURAMATSU, MASAFUMI;ASADA, KAZUMI;HAGINO, YUKINO;AND OTHERS;REEL/FRAME:017075/0001;SIGNING DATES FROM 20050812 TO 20050831 |
|
AS | Assignment |
Owner name: KABUSHIKI KAISHA TOSHIBA, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MURAMATSU, MASAFUMI;ASADA, KAZUMI;HAGINO, YUKINO;AND OTHERS;REEL/FRAME:018182/0189;SIGNING DATES FROM 20060328 TO 20060412 Owner name: SONY CORPORATION, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MURAMATSU, MASAFUMI;ASADA, KAZUMI;HAGINO, YUKINO;AND OTHERS;REEL/FRAME:018182/0189;SIGNING DATES FROM 20060328 TO 20060412 Owner name: KANTO KAGAKU KABUSHIKI KAISHA, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MURAMATSU, MASAFUMI;ASADA, KAZUMI;HAGINO, YUKINO;AND OTHERS;REEL/FRAME:018182/0189;SIGNING DATES FROM 20060328 TO 20060412 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |