Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
  • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/60—Sugars; Derivatives thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
  • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
  • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q9/00—Preparations for removing hair or for aiding hair removal
  • A61Q9/04—Depilatories

Definitions

• This invention relates to an epilatory composition, its manufacture and use.
• compositions formed of viscoelastic materials are well known.
• the viscoelastic materials may in certain embodiments be rosinous materials. In other embodiments they may be sugar-based.
• the epilatory compositions may be supplied in the form of strips, retained between cellophane sheets.
• the cellophane sheets may have coatings of polyvinyl chloride, which acts as a barrier preventing the composition, or components of it, from migrating through the sheets; and also having the correct adhesive properties for use.
• the user peels away one of the cellophane sheets, presses the epilatory strip firmly onto the area to be plucked, then pulls one end of the remaining cellophane sheet sharply away from the area.
• the hairs trapped in the composition are removed from the treated area along with, optimally, all of the composition, still attached to the remaining backing strip.
• a composition may be warmed, and then applied to the skin by means of a spatula or other applicator. Strips of fabric are then applied so that they adhere to the epilatory composition. The strips are then pulled sharply to remove the epilatory material, and hair, from the skin.
• the rosinous materials have excellent viscoelastic properties for epilatory compositions of the type described above but may irritate the skin of some users, if they fail to follow the instructions given.
• an epilatory composition comprising a matrix material of the adhesive type, wherein the composition includes a branched polyalkene.
• the matrix material may comprise a tackifying polymeric material, for example a tackifying aliphatic or aromatic resin.
• the matrix material may comprise a sugar-based material.
• Examples of specifications describing epilatory compositions based on heating sugar(s) with acids (such as citric acid) are disclosed in GB 901624, GB 1242083, GB 2231494A, and GB 2157951A.
• the matrix material may comprise a rosinous material, for example a rosin ester and/or colophony.
• the branched polyalkene is suitably a polyalkene having C 1-4 alkyl groups, preferably methyl groups, projecting from a carbon backbone.
• the branched polyalkene comprises units derived from isobutene. These may have been homopolymerised, to form polyisobutene, or may have been copolymerised with other unsaturated materials, preferably other alkenes.
• the branched polyalkene used is fully saturated. Depending on the manufacturing process this may mean that it has been hydrogenated.
• the branched polyalkene may be regarded as a polymer having a carbon backbone carrying a proportion of pendent alkyl groups, preferably methyl groups.
• the carbon backbone carries both hydrogen atoms and pendent groups.
• the numerical ratio of pendent alkyl groups to hydrogen atoms on the backbone is suitably in the range 0.1:1-10:1, preferably 0.5:1-3:1, and most preferably 0.8:1-1.2:1 (such hydrogen atoms are directly on the backbone; hydrogen atoms within the pendent alkyl groups are not included).
• a ratio of substantially 1:1 as is obtained with homopolymeric isobutene.
• a preferred material is hydrogenated polyisobutene, a readily available material currently used in cosmetics. Grades are available under the trade marks POLYSYNLANE and PARLEAM, from Rossow Cosmetiques, France, or Nof Corporation, Japan.
• non-hydrogenated polyisobutene a readily available material currently used in cosmetics. Grades are available under the trade mark INDOPOL, from BP Chemicals, UK.
• the branched polyalkene provides up to 20% of the total weight of the composition, preferably up to 15%, more preferably up to 10%, and most preferably up to 5%. Especially preferred is an amount up to 3% of the total weight of the composition.
• the branched polyalkene provides at least 0.1% of the total weight of the composition, preferably at least 0.5%, most preferably at least 0.9%.
• the branched polyalkene has a weight average molecular weight in the range 1,000 to 100,000, preferably 3,000 to 30,000.
• the branched polyalkene is in the nature of a highly viscous liquid.
• the branched polyalkylene is in the nature of a waxy or tacky solid or semi-solid.
• the matrix material may comprise a sugar-based material and a rosinous material in admixture. The following paragraphs further define such mixtures.
• the epilatory composition of the present invention comprises greater than or equal to 70% by wt, preferably greater than or equal to 75% by wt, preferably greater than or equal to 80% by wt, preferably greater than or equal to 82% wt of sugar-based material.
• the epilatory composition of the present invention comprises less than or equal to 95% by wt, preferably less than or equal to 92.5% by wt, preferably less than or equal to 90% by wt, more preferably less than 90% by wt, more preferably less than or equal to 88% by wt of sugar-based material.
• the epilatory composition of the present invention comprises greater than or equal to 5% by wt, preferably greater than or equal to 7.5% by wt, preferably greater than or equal to 10% by wt, more preferably greater than 10% by wt, most preferably greater than or equal to 12% by wt of rosinous material.
• the epilatory composition of the present invention comprises less than or equal to 30% by wt, preferably less than or equal to 25 by wt, preferably less than or equal to 20% by wt, most preferably less than or equal to 18% by wt of rosinous material.
• a particularly preferred epilatory composition of the present invention comprises greater than 10% by wt and less than 30% by wt, especially greater than or equal to 12% by wt and less than or equal to 20% by wt, of rosinous material.
• the adhesive properties of the sugar-based composition may be significantly enhanced while maintaining the water rinsability characteristics of the sugar-based composition.
• the weight ratio of sugar-based material to rosinous material in the epilatory composition of the present invention is less than or equal to 19:1, preferably less than or equal to 15:1, preferably less than or equal to 13:1, preferably less than or equal to 10:1, preferably less than or equal to 9:1, most preferably less than or equal to 7.5:1.
• the weight ratio of sugar-based material to rosinous material in the epilatory composition of the present invention is greater than or equal to 2.3:1, preferably greater than or equal to 3:1, more preferably greater than or equal to 4:1, most preferably greater than or equal to 5:1.
• a particularly preferred epilatory composition of the present invention comprises a weight ratio of sugar-based material to rosinous material of less than 9:1 and greater than or equal to 2.3:1, especially less than or equal to 7.5:1 and greater than or equal to 4:1.
• the rosinous material is in the form of droplets, which may be of any shape, dispersed within the matrix material.
• the droplets are spherical and/or ellipsoidal in shape.
• the average maximum cross-sectional dimension of the droplets of rosinous material is greater than or equal to 20 nm, more preferably greater than or equal to 30 nm, most preferably greater than or equal to 40 nm, especially greater than or equal to 50 nm.
• the average maximum cross-sectional dimension of the droplets of rosinous material is less than or equal to 5000 nm, preferably less than or equal to 1500 nm, preferably less than or equal to 1000 nm, most preferably less than or equal to 500 nm.
• the epilatory composition comprises at least 60% wt/wt of the matrix material, for example rosinous material and/or sugar-based material, preferably at least 70% wt/wt, more preferably at least 80% wt/wt.
• the epilatory composition is a so-called “cold” epilatory composition (that is, one which can be applied at ambient temperature without reheating).
• the epilatory composition comprises a particulate material in admixture with the matrix material.
• the particulate material is a colloidal material.
• it has particles of mean diameter 1-200 nm, more preferably 5-100 nm, and most preferably 10-50 nm.
• the particles when present in the epilatory composition, are in an amount of at least 1% wt on total weight of composition, more preferably at least 2%, and most preferably at least 3%. Suitably they are present in an amount up to 20% on total weight of composition, and preferably up to 10%.
• Preferred particulate materials for use in the present invention are siliceous materials. Especially preferred is fumed silica.
• Fumed silica is currently manufactured in a process that involves flame hydrolysis of silicon tetrachloride, in an oxy-hydrogen flame. It is a colloidal form of silica having silanol groups, able to participate in hydrogen bonding. Fumed silica typically comprises colloidal particles of mean diameter 1-200 nm. Preferably the fumed silica is of mean diameter 5-100 nm, more preferably 10-50 nm. The external surface area is typically in the range 15-380 m 2 /g. Fumed silicas are typically non-porous and thus have no internal surface area. They may be hydrophobic and of use in the present invention but preferred fumed silicas for use in the present invention are hydrophilic.
• the epilatory composition may suitably comprise up to 40%, preferably up to 20%, of other components, which may include one or more of a natural wax, a fragrance, a polymer, an essential oil, a silicone oil, a colorant, an anti-oxidant or a paraffin or mineral oil.
• the epilatory composition is such that its elastic modulus exceeds its viscous modulus at all frequencies up to 0.1 rad/s at 50° C.
• the elastic modulus of the epilatory composition exceeds its viscous modulus at all frequencies up to 1 rad/s at 50° C., more preferably at all frequencies up to 2 rad/s at 50° C.
• the elastic modulus may exceed the viscous modulus at all frequencies up to 20 rad/s at 50° C.
• the elastic modulus Preferably at certain higher frequencies (representative of the rapid removal of the epilatory composition from the user's skin), the elastic modulus also exceeds the viscous modulus, at temperatures within the temperature range 20-50° C.
• the elastic modulus exceeds the viscous modulus (when measured at 35° C.) at a frequency of at least 10,000 rad/s, more preferably at a frequency at least 5,000 rad/s.
• the epilatory composition is such that, at ambient temperatures, at low frequencies of applied stress the elastic modulus exceeds the viscous modulus; at high frequencies of applied stress the elastic modulus exceeds the viscous modulus; and at moderate frequencies, in between, the viscous modulus exceeds the elastic modulus.
• the epilatory composition in transit and storage corresponds to the low frequency condition, and the non-viscous nature of the composition aids shape stability in storage and transit;
• the application of the epilatory composition to the skin corresponds to the moderate frequency condition, and the viscous nature of the composition aids application and good contact with hair and skin; and pulling the epilatory composition sharply from the skin corresponds to the high frequency condition, the non-viscous, glassy nature of the composition aiding effective hair removal.
• the transition between the low frequency condition and the moderate frequency condition is known as the gel point.
• the transition between the moderate frequency condition and the high strain rate condition is known as the glass transition.
• the elastic modulus G′ (sometimes known as the storage modulus) corresponds to the energy which can be stored and released by a bulk material.
• the viscous modulus G′′ (sometimes known as the loss modulus) corresponds to the energy dissipated by a bulk material due to friction between its macromolecules when it is deformed.
• ⁇ . is the stress amplitude
• ⁇ . the strain amplitude
• ⁇ is the out-of-phase coefficient.
• the measurements quoted later are based on studies carried out into the rheology of the viscoelastic compositions in order to obtain a better understanding of their adhesive behaviour and their suitability as epilatory materials. These studies involved subjecting the materials to dynamic investigations in which a sinusoidal strain at defined frequencies was applied to the materials and the resulting output force was measured. In these studies a stress control rheometer was used, the SR rheometer commercially available from the company Rheometrics, using parallel plate geometry of 25 mm in diameter. The output force was found to include an in-phase elastic component G′ and an out-of-phase viscous component G′′. The output force can be expressed as follows.
• G′ Within the linear stress-strain domain of the material G′ is desirably lower than G′′ at moderate frequency oscillation in order to prevent the material cracking and to ensure that the material has strong adhesion at the material/hair interface.
• the values of G′ and G′′ at moderate frequency oscillation are a measure of how readily the material wets the hairs. Moderate frequency oscillation is a long time process and corresponds to the time when the material is being applied to the skin. The lower values of G′ and G′′ at this moderate frequency, the better the material wets the hairs. Thus the hairs become well embedded in the material in a very short time (ie the time needed for spreading the material on the skin).
• G′ should be higher than G′′ at high frequency oscillation (which mimics the action of the user in rapidly pulling the strip from the body) in order to remove hairs efficiently. Also, at low frequency oscillation, or no oscillation, G′ is preferably higher than G′′, in accordance with this invention, in order to obtain the benefit of enhanced stability, even when warm.
• the composition is of an elastic nature when unstressed.
• the composition is of a viscous nature when moderately stressed, for example on application to the skin.
• the composition is of an elastic nature when highly stressed, for example on removal from the skin (as by abrupt pulling).
• the epilatory composition By ensuring that the epilatory composition satisfies the above parameters, it can be readily applied to the skin at body temperature, yet it is very efficient at removing hairs from the skin and, surprisingly, the user experiences less pain.
• references in this specification to a material not under applied stress are to a material in the form of a flat sheet, resting on a horizontal surface.
• the epilatory composition of the present invention may be provided in a container, from which the user removes it using, for example, a spatula or an applicator fitted to the container, and applies it to the skin.
• a fabric can then be used to pull the applied material in one piece from the skin.
• the epilatory composition is supplied in the form of strips, sandwiched between sheets, for example of cellophane, or paper or another non-woven material. In use, one sheet is removed from a strip of epilatory composition and that strip is then applied to the skin with the remaining sheet uppermost. The end of that sheet is grasped and pulled sharply, to remove the strip of epilatory composition from the skin, along with hairs with which it is in contact.
• an epilatory composition of the invention is mildly acidic, for example having a pH in the range 4.5-6.5, preferably 5-6.
• Preferred epilatory compositions of the present invention are such that residues are removable from the user's skin by normal water washing.
• a preferred epilatory composition of the present invention comprises, in accordance with the definitions given previously:
• An especially preferred epilatory composition of the present invention comprises, in accordance with the definitions given previously:
• an epilatory product for example a strip of such an epilatory composition or a dispenser containing such a composition, having an applicator to deposit a sheet thereof on the skin or a user; and a method of epilation, using such a composition or product.
• a composition was made with the following ingredients. Ingredients % wt/wt Inverted sugar base: Sugar (sucrose) 78.3 Citric acid monohydrate 1.3 DERMULSENE RA 405 1.5 Water 7.4 DERTOLINE RC2 rosinous material 7 HDK N20 fumed silica 2 PARLEAM SV polyisobutene 1 KOH (50% in water) 1.5 DERMULSENE RA 405 is a collophonium emulsion available from DRT-Granel. DERTOLINE RC2 is a colophonium derived resin, available from DRT-Granel. HDK N20 is a fumed silica powder available from Wacker.
• PARLEAM SV also called POLYSYNLANE SV, is an hydrogenated polyisobutene polymer available from Rossow Cosmetiques, France. The SV grade denotes the super high viscosity grade.
• Method of Manufacture 1. Preparation of an Inverted Sugar-Based Material:
• the resulting gel product could be formed in standard manner into water rinsable cold wax strips.
• the composition is particularly suitable for sensitive skin. To this end, it is predominantly sugar-based; the rosinous material content is low (but sufficient to promote good performance); and it contains PARLEAM SV.
• composition was made with the following ingredients: Ingredients % wt/wt Inverted sugar base (same as 95.5 Example 1) HDK N20 2 PARLEAM SV 1 KOH (50% in water) 1.5
• composition had the following properties:
• a composition for manufacture into an epilatory strip was made with the following ingredients. Ingredients % wt/wt Inverted sugar base: Sugar (sucrose) 77.6 Citric acid monohydrate 1.3 DERMULSENE RA 405 1.3 Water 7.4 TEG rosinate 4.84 DERTOLINE RC2 rosinous material 2.16 INDOPOL H2100 polyisobutene 1 KOH (50% in water) 1.4 TEG rosinate is triethylene glycol rosinate available from DRT-Granel. INDOPOL H2100 is non-hydrogenated polyisobutene, molecular weight approx. 2,000, available from BP. Being non-hydrogenated it has unsaturation at the polymer termini.
• the epilatory composition was prepared by the method described in Example 1, except:
• Step 1 the temperature was 65° C.
• Step 2 both rosinates and the polyisobutene were premixed in a separate tank and added to the inverted sugar material at 65° C. Homogenisation for 5 minutes using a high speed turbine operated at 1,000 rpm ensured good dispersion of the rosinates.
• Step 3a the fumed silica was blended in using a high speed rotor/stator mixer/pump operated at 1,000 rpm for 15 minutes.
• Step 3b the KOH was added in a single addition with stirring.
• the composition was then recirculated in the high speed rotor/stator mixer/pump. Friction increased the temperature to 80° C.
• the gel point of the Example 3 composition measured at 50° C., is 25 rad/s. Its viscosity, measured at 35° C., is 230 Pa ⁇ s. Its pH is 5.5.

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• Animal Behavior & Ethology (AREA)
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• Birds (AREA)
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• Oil, Petroleum & Natural Gas (AREA)
• Cosmetics (AREA)
• Medicinal Preparation (AREA)
• Adhesives Or Adhesive Processes (AREA)

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• 2002
  • 2002-02-13 GB GB0203396A patent/GB2385270B/en not_active Expired - Fee Related
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