US20050010016A1 - Resins based on ketones and aldehydes, having improved solubility properties and low color numbers - Google Patents
Resins based on ketones and aldehydes, having improved solubility properties and low color numbers Download PDFInfo
- Publication number
- US20050010016A1 US20050010016A1 US10/863,369 US86336904A US2005010016A1 US 20050010016 A1 US20050010016 A1 US 20050010016A1 US 86336904 A US86336904 A US 86336904A US 2005010016 A1 US2005010016 A1 US 2005010016A1
- Authority
- US
- United States
- Prior art keywords
- resin
- ketone
- phase transfer
- transfer catalyst
- aldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 0 [1*]C([2*])([3*])[4*].[Y-] Chemical compound [1*]C([2*])([3*])[4*].[Y-] 0.000 description 3
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G6/00—Condensation polymers of aldehydes or ketones only
- C08G6/02—Condensation polymers of aldehydes or ketones only of aldehydes with ketones
Definitions
- the ketone-aldehyde resins of the invention are soluble in virtually all organic solvents useful for coatings, including, in particular, mineral oils, white spirits, and aliphatics. They are likewise soluble in alcoholic solvents such as ethanol. This affords the possibility of formulating low-odor, environmentally unburdensome coating materials which are toxicologically unobjectionable.
- the resins relevant to the invention are able to increase the solids fraction of such products, thereby allowing the fraction of organic solvents to be reduced.
- the ketone-aldehyde resins relevant to the invention possess
- a mixed resin is prepared from trimethylcyclohexanone and cyclohexanone and also formaldehyde under the conditions described in EP 0 668 301 (incorporated herein by reference in its entirety) in the absence of a phase transfer catalyst (GL 269, 270, 271, 294 see Table 1 below).
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/342,612 US7812109B2 (en) | 2003-06-14 | 2008-12-23 | Resins based on ketones and aldehydes, having improved solubility properties and low color numbers |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10326893.6 | 2003-06-14 | ||
DE10326893A DE10326893A1 (de) | 2003-06-14 | 2003-06-14 | Harze auf Basis von Ketonen und Aldehyde mit verbesserten Löslichkeitseigenschaften und geringen Farbzahlen |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/342,612 Division US7812109B2 (en) | 2003-06-14 | 2008-12-23 | Resins based on ketones and aldehydes, having improved solubility properties and low color numbers |
Publications (1)
Publication Number | Publication Date |
---|---|
US20050010016A1 true US20050010016A1 (en) | 2005-01-13 |
Family
ID=33185794
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/863,369 Abandoned US20050010016A1 (en) | 2003-06-14 | 2004-06-09 | Resins based on ketones and aldehydes, having improved solubility properties and low color numbers |
US12/342,612 Expired - Fee Related US7812109B2 (en) | 2003-06-14 | 2008-12-23 | Resins based on ketones and aldehydes, having improved solubility properties and low color numbers |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/342,612 Expired - Fee Related US7812109B2 (en) | 2003-06-14 | 2008-12-23 | Resins based on ketones and aldehydes, having improved solubility properties and low color numbers |
Country Status (9)
Country | Link |
---|---|
US (2) | US20050010016A1 (de) |
EP (1) | EP1486520A1 (de) |
CN (1) | CN1315900C (de) |
AU (1) | AU2004202618A1 (de) |
BR (1) | BRPI0401930A (de) |
CA (1) | CA2471189A1 (de) |
DE (1) | DE10326893A1 (de) |
NO (1) | NO20042430L (de) |
TW (1) | TW200502275A (de) |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040129504A1 (en) * | 2001-05-31 | 2004-07-08 | Rene Kunz | Equipment for ascertaining the position of a rail-guided elevator car with a code carrier |
US20050043501A1 (en) * | 2003-08-22 | 2005-02-24 | Degussa Ag | Radiation-curable resins based on ketone-aldehyde and/or urea-aldehyde resins and a process for preparing them |
US20060074217A1 (en) * | 2003-08-22 | 2006-04-06 | Degussa Ag | Ketone-aldehyde resins having low water content, high thermal stability and yellowing resistance |
US20070123661A1 (en) * | 2004-02-03 | 2007-05-31 | Degussa Ag | Utilization of radiohardenable resins based on hydrogenated ketone and phenol aldehyde resins |
US20080027156A1 (en) * | 2004-04-27 | 2008-01-31 | Degussa Ag | Polymer Compositions of Carbonyl-Hydrated Ketone-Aldehyde Resins and Polyisocyanates in Reactive Solvents |
US20080039593A1 (en) * | 2005-01-19 | 2008-02-14 | Degussa Gmbh | Aqueous, Unsaturated, Amorphous Polyesters that are Modified so as to be Radiation Curable |
US20080045669A1 (en) * | 2004-08-12 | 2008-02-21 | Degussa Gmbh | Tin-Free, High-Melting Reaction Products of Carbonyl-Hydrogenated Ketone Aldehyde Resins, Hydrogenated Ketone Resins, and Carbonyl-Hydrogenated and Core-Hydrogenated Ketone Aldehyde Resins Based on Aromatic Ketones and Polyisocynates |
US20080146728A1 (en) * | 2004-07-01 | 2008-06-19 | Degussa Ag | Radiation Curable Composition Consisting of Unsaturated Amorphous Polyesters and Reactive Dilutant Agents |
US20080171816A1 (en) * | 2005-03-23 | 2008-07-17 | Degussa Gmbh | Low-Viscosity Uretdion Group-Containing Polyaddition Compounds, Method Of Production And Use Thereof |
US20080213515A1 (en) * | 2005-06-10 | 2008-09-04 | Evonik Degussa Gmbh | Backfixing of Artificial Turf Stock Material with Hotmelts Based on Amorphous Poly-Alpha-Olefins and/or Modified Amorphous Poly-Alpha-Olefins |
US20080306210A1 (en) * | 2006-01-03 | 2008-12-11 | Patrick Glockner | Compositions For Producing Universal Pigment Preparations |
US20090012245A1 (en) * | 2006-02-28 | 2009-01-08 | Evonik Degussa Gmbh | Carbonyl hydrogenated ketone aldehyde resins, devoid of formaldehyde, based on formaldehyde and associated production method |
US20090030113A1 (en) * | 2006-01-03 | 2009-01-29 | Evonil Degussa Gmbh | Universal pigment preparations |
US7759424B2 (en) | 2004-10-12 | 2010-07-20 | Evonik Degussa Gmbh | Radiation curable modified, unsaturated, amorphous polyesters |
US8288489B2 (en) | 2005-04-13 | 2012-10-16 | Evonik Degussa Gmbh | Use of a highly viscous largely amorphous polyolefin for the production of a film |
US20140289790A1 (en) * | 2013-03-22 | 2014-09-25 | Brendon Wilson | System and method for adaptive application of authentication policies |
US10870723B2 (en) | 2015-07-07 | 2020-12-22 | Evonik Operations Gmbh | Production of polyurethane foam |
US10961418B2 (en) | 2016-05-09 | 2021-03-30 | Evonik Operations Gmbh | Use of block copolymers in adhesives |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006000651A1 (de) * | 2006-01-03 | 2007-07-12 | Degussa Gmbh | Präparation aus Ionischen Flüssigkeiten und Harzen |
DE102014203231A1 (de) | 2014-02-24 | 2015-08-27 | Evonik Degussa Gmbh | Dispergierharze für Pigmentpräparationen mit geringem flüchtigem organischem Anteil |
EP3459984A1 (de) | 2017-09-25 | 2019-03-27 | Evonik Degussa GmbH | Herstellung von polyurethanschaum |
Citations (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3625918A (en) * | 1967-06-22 | 1971-12-07 | Ciba Ltd | Adducts of polyepoxides and cycloaliphatic diprimary diamines and as curing agents in epoxy resin compositions |
US3926636A (en) * | 1972-08-29 | 1975-12-16 | Basf Ag | Photocurable compositions |
US4083816A (en) * | 1976-06-25 | 1978-04-11 | The United States Of America As Represented By The Secretary Of Agriculture | Acetoxymethyl derivatives of polyunsaturated fatty triglycerides as primary plasticizers for polyvinylchloride |
US4731434A (en) * | 1983-07-06 | 1988-03-15 | Huels Aktiengesellschaft | Alkyl aryl ketone/formaldehyde resin having high softening point |
US5705597A (en) * | 1994-02-16 | 1998-01-06 | Huels Aktiengesellschaft | Ketone-aldehyde resin with wide compatibility, process for its preparation, and composition containing same |
US20020124780A1 (en) * | 2000-12-20 | 2002-09-12 | Vincent Promuto | Method and apparatus for drying and incineration of sewage sludge |
US6552154B1 (en) * | 1999-09-16 | 2003-04-22 | Degussa Ag | Catalyst and process for preparing color-reduced polyisocyanates containing isocyanurate groups |
US20040116604A1 (en) * | 2002-12-14 | 2004-06-17 | Degussa Ag | Polymer-modified resins |
US20040122172A1 (en) * | 2002-12-14 | 2004-06-24 | Degussa Ag | Polymer-modified resins |
US6794482B2 (en) * | 2002-09-12 | 2004-09-21 | Degussa Ag | Adhesion promoter additive comprising an unsaturated, amorphous polyester |
US6797787B2 (en) * | 2001-12-22 | 2004-09-28 | Degussa Ag | Epoxidized polyalkenylenes and method for their preparation |
US20050043501A1 (en) * | 2003-08-22 | 2005-02-24 | Degussa Ag | Radiation-curable resins based on ketone-aldehyde and/or urea-aldehyde resins and a process for preparing them |
US20050043499A1 (en) * | 2003-08-22 | 2005-02-24 | Degussa Ag | Ketone-aldehyde resins having low water content, high thermal stability and yellowing resistance |
US20050080222A1 (en) * | 2003-08-22 | 2005-04-14 | Degussa Ag | Preparation of ketone-formaldehyde resins |
US6881785B2 (en) * | 2002-12-24 | 2005-04-19 | Degussa Ag | Dispersions of amorphous unsaturated polyester resins based on particular Dicidol isomers |
US7005002B2 (en) * | 2003-05-19 | 2006-02-28 | Degussa Ag | Branched, amorphous, polyester-based macropolyols of narrow molecular weight distribution |
US7033522B2 (en) * | 2000-09-27 | 2006-04-25 | Degussa Ag | Pulverulent, water-dispersible, blocked polyisocyanate adducts, a process for the preparation and their use |
US7135522B2 (en) * | 2002-12-24 | 2006-11-14 | Degussa Ag | Dispersions of amorphous urethanized unsaturated polyester resins based on particular dicidol isomers |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
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US680014A (en) * | 1899-04-29 | 1901-08-06 | Joseph Arbes | Blind-stitch sewing-machine. |
US3909332A (en) | 1973-06-04 | 1975-09-30 | Gen Electric | Bonding process for dielectric isolation of single crystal semiconductor structures |
DE2410863A1 (de) * | 1974-03-07 | 1975-09-18 | Bayer Ag | Neue stickstoffhaltige kondensationsprodukte aus cycloalkanonen und formaldehyd |
DE2831613C2 (de) * | 1978-07-19 | 1982-03-18 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Polykondensationsprodukten |
DE19748467A1 (de) | 1997-11-03 | 1999-05-06 | Huels Chemische Werke Ag | Beschichtungen auf Basis thermoplastischer Polyester und eines Zusatzharzes (Keton-Aldehyd-Kondensat) |
US7136465B2 (en) * | 2000-08-31 | 2006-11-14 | Lamson Holdings Llc | Voice activated, voice responsive product locator system, including product location method utilizing product bar code and product-situated, location-identifying bar code |
DE10212706A1 (de) | 2002-03-21 | 2003-10-02 | Degussa | Ungesättigte, amorphe Polyester auf Basis bestimmter Dicidolisomerer |
DE10338560A1 (de) | 2003-08-22 | 2005-03-17 | Degussa Ag | Strahlenhärtbare Harze auf Basis hydrierter Keton- und Phenol-Aldehydharze und ein Verfahren zu ihrer Herstellung |
DE102004005208A1 (de) | 2004-02-03 | 2005-08-11 | Degussa Ag | Verwendung strahlenhärtbarer Harze auf Basis hydrierter Keton- und Phenol-Aldehydharze |
DE102004020740A1 (de) | 2004-04-27 | 2005-11-24 | Degussa Ag | Polymerzusammensetzungen von carbonylhydrierten Keton-Aldehydharzen und Polylsocyanaten in reaktiven Lösemitteln |
-
2003
- 2003-06-14 DE DE10326893A patent/DE10326893A1/de not_active Withdrawn
-
2004
- 2004-04-21 EP EP04101655A patent/EP1486520A1/de not_active Withdrawn
- 2004-06-08 TW TW093116465A patent/TW200502275A/zh unknown
- 2004-06-09 US US10/863,369 patent/US20050010016A1/en not_active Abandoned
- 2004-06-09 BR BR0401930-0A patent/BRPI0401930A/pt not_active IP Right Cessation
- 2004-06-10 AU AU2004202618A patent/AU2004202618A1/en not_active Abandoned
- 2004-06-11 NO NO20042430A patent/NO20042430L/no not_active Application Discontinuation
- 2004-06-11 CA CA002471189A patent/CA2471189A1/en not_active Abandoned
- 2004-06-11 CN CN200410049037.XA patent/CN1315900C/zh not_active Expired - Fee Related
-
2008
- 2008-12-23 US US12/342,612 patent/US7812109B2/en not_active Expired - Fee Related
Patent Citations (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3625918A (en) * | 1967-06-22 | 1971-12-07 | Ciba Ltd | Adducts of polyepoxides and cycloaliphatic diprimary diamines and as curing agents in epoxy resin compositions |
US3926636A (en) * | 1972-08-29 | 1975-12-16 | Basf Ag | Photocurable compositions |
US4083816A (en) * | 1976-06-25 | 1978-04-11 | The United States Of America As Represented By The Secretary Of Agriculture | Acetoxymethyl derivatives of polyunsaturated fatty triglycerides as primary plasticizers for polyvinylchloride |
US4731434A (en) * | 1983-07-06 | 1988-03-15 | Huels Aktiengesellschaft | Alkyl aryl ketone/formaldehyde resin having high softening point |
US5705597A (en) * | 1994-02-16 | 1998-01-06 | Huels Aktiengesellschaft | Ketone-aldehyde resin with wide compatibility, process for its preparation, and composition containing same |
US6552154B1 (en) * | 1999-09-16 | 2003-04-22 | Degussa Ag | Catalyst and process for preparing color-reduced polyisocyanates containing isocyanurate groups |
US6730628B2 (en) * | 1999-09-16 | 2004-05-04 | Degussa Ag | Catalyst and process for preparing color-reduced polyisocyanates containing isocyanurate groups |
US6800714B2 (en) * | 1999-09-16 | 2004-10-05 | Degussa Ag | Catalyst and process for preparing color-reduced polyisocyanates containing isocyanurate groups |
US7033522B2 (en) * | 2000-09-27 | 2006-04-25 | Degussa Ag | Pulverulent, water-dispersible, blocked polyisocyanate adducts, a process for the preparation and their use |
US20020124780A1 (en) * | 2000-12-20 | 2002-09-12 | Vincent Promuto | Method and apparatus for drying and incineration of sewage sludge |
US6797787B2 (en) * | 2001-12-22 | 2004-09-28 | Degussa Ag | Epoxidized polyalkenylenes and method for their preparation |
US6794482B2 (en) * | 2002-09-12 | 2004-09-21 | Degussa Ag | Adhesion promoter additive comprising an unsaturated, amorphous polyester |
US20040122172A1 (en) * | 2002-12-14 | 2004-06-24 | Degussa Ag | Polymer-modified resins |
US20040116604A1 (en) * | 2002-12-14 | 2004-06-17 | Degussa Ag | Polymer-modified resins |
US6881785B2 (en) * | 2002-12-24 | 2005-04-19 | Degussa Ag | Dispersions of amorphous unsaturated polyester resins based on particular Dicidol isomers |
US7135522B2 (en) * | 2002-12-24 | 2006-11-14 | Degussa Ag | Dispersions of amorphous urethanized unsaturated polyester resins based on particular dicidol isomers |
US7005002B2 (en) * | 2003-05-19 | 2006-02-28 | Degussa Ag | Branched, amorphous, polyester-based macropolyols of narrow molecular weight distribution |
US20050043501A1 (en) * | 2003-08-22 | 2005-02-24 | Degussa Ag | Radiation-curable resins based on ketone-aldehyde and/or urea-aldehyde resins and a process for preparing them |
US20050043499A1 (en) * | 2003-08-22 | 2005-02-24 | Degussa Ag | Ketone-aldehyde resins having low water content, high thermal stability and yellowing resistance |
US20050080222A1 (en) * | 2003-08-22 | 2005-04-14 | Degussa Ag | Preparation of ketone-formaldehyde resins |
US20060074217A1 (en) * | 2003-08-22 | 2006-04-06 | Degussa Ag | Ketone-aldehyde resins having low water content, high thermal stability and yellowing resistance |
US7101958B2 (en) * | 2003-08-22 | 2006-09-05 | Degussa Ag | Ketone-aldehyde resins having low water content, high thermal stability and yellowing resistance |
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040129504A1 (en) * | 2001-05-31 | 2004-07-08 | Rene Kunz | Equipment for ascertaining the position of a rail-guided elevator car with a code carrier |
US7329710B2 (en) | 2003-08-22 | 2008-02-12 | Degussa Ag | Radiation-curable resins based on ketone-aldehyde and/or urea-aldehyde resins and a process for preparing them |
US20050043501A1 (en) * | 2003-08-22 | 2005-02-24 | Degussa Ag | Radiation-curable resins based on ketone-aldehyde and/or urea-aldehyde resins and a process for preparing them |
US20060074217A1 (en) * | 2003-08-22 | 2006-04-06 | Degussa Ag | Ketone-aldehyde resins having low water content, high thermal stability and yellowing resistance |
US20070123661A1 (en) * | 2004-02-03 | 2007-05-31 | Degussa Ag | Utilization of radiohardenable resins based on hydrogenated ketone and phenol aldehyde resins |
US7700664B2 (en) | 2004-04-27 | 2010-04-20 | Degussa Ag | Polymer compositions of carbonyl-hydrated ketone-aldehyde resins and polyisocyanates in reactive solvents |
US20080027156A1 (en) * | 2004-04-27 | 2008-01-31 | Degussa Ag | Polymer Compositions of Carbonyl-Hydrated Ketone-Aldehyde Resins and Polyisocyanates in Reactive Solvents |
US20080146728A1 (en) * | 2004-07-01 | 2008-06-19 | Degussa Ag | Radiation Curable Composition Consisting of Unsaturated Amorphous Polyesters and Reactive Dilutant Agents |
US7687569B2 (en) | 2004-07-01 | 2010-03-30 | Evonik Degussa Gmbh | Radiation curable composition consisting of unsaturated amorphous polyesters and reactive dilutant agents |
US20080045669A1 (en) * | 2004-08-12 | 2008-02-21 | Degussa Gmbh | Tin-Free, High-Melting Reaction Products of Carbonyl-Hydrogenated Ketone Aldehyde Resins, Hydrogenated Ketone Resins, and Carbonyl-Hydrogenated and Core-Hydrogenated Ketone Aldehyde Resins Based on Aromatic Ketones and Polyisocynates |
US7781538B2 (en) | 2004-08-12 | 2010-08-24 | Evonik Degussa Gmbh | Tin-free, high-melting reaction products of carbonyl-hydrogenated ketone aldehyde resins, hydrogenated ketone resins, and carbonyl-hydrogenated and core-hydrogenated ketone aldehyde resins based on aromatic ketones and polyisocynates |
US7759424B2 (en) | 2004-10-12 | 2010-07-20 | Evonik Degussa Gmbh | Radiation curable modified, unsaturated, amorphous polyesters |
US20080039593A1 (en) * | 2005-01-19 | 2008-02-14 | Degussa Gmbh | Aqueous, Unsaturated, Amorphous Polyesters that are Modified so as to be Radiation Curable |
US20080171816A1 (en) * | 2005-03-23 | 2008-07-17 | Degussa Gmbh | Low-Viscosity Uretdion Group-Containing Polyaddition Compounds, Method Of Production And Use Thereof |
US8288489B2 (en) | 2005-04-13 | 2012-10-16 | Evonik Degussa Gmbh | Use of a highly viscous largely amorphous polyolefin for the production of a film |
US20080213515A1 (en) * | 2005-06-10 | 2008-09-04 | Evonik Degussa Gmbh | Backfixing of Artificial Turf Stock Material with Hotmelts Based on Amorphous Poly-Alpha-Olefins and/or Modified Amorphous Poly-Alpha-Olefins |
US7935203B2 (en) | 2005-06-10 | 2011-05-03 | Evonik Degussa Gmbh | Backfixing of artificial turf stock material with hotmelts based on amorphous poly-α-olefins and/or modified amorphous poly-α-olefins |
US20090030113A1 (en) * | 2006-01-03 | 2009-01-29 | Evonil Degussa Gmbh | Universal pigment preparations |
US20080306210A1 (en) * | 2006-01-03 | 2008-12-11 | Patrick Glockner | Compositions For Producing Universal Pigment Preparations |
US20090012245A1 (en) * | 2006-02-28 | 2009-01-08 | Evonik Degussa Gmbh | Carbonyl hydrogenated ketone aldehyde resins, devoid of formaldehyde, based on formaldehyde and associated production method |
US20140289790A1 (en) * | 2013-03-22 | 2014-09-25 | Brendon Wilson | System and method for adaptive application of authentication policies |
US10870723B2 (en) | 2015-07-07 | 2020-12-22 | Evonik Operations Gmbh | Production of polyurethane foam |
US10961418B2 (en) | 2016-05-09 | 2021-03-30 | Evonik Operations Gmbh | Use of block copolymers in adhesives |
Also Published As
Publication number | Publication date |
---|---|
DE10326893A1 (de) | 2004-12-30 |
CN1315900C (zh) | 2007-05-16 |
CA2471189A1 (en) | 2004-12-14 |
BRPI0401930A (pt) | 2005-01-25 |
AU2004202618A1 (en) | 2005-01-06 |
US7812109B2 (en) | 2010-10-12 |
NO20042430L (no) | 2004-12-15 |
EP1486520A1 (de) | 2004-12-15 |
CN1572807A (zh) | 2005-02-02 |
US20090105442A1 (en) | 2009-04-23 |
TW200502275A (en) | 2005-01-16 |
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Legal Events
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