Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
  • A61K8/89—Polysiloxanes
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
  • A61K8/89—Polysiloxanes
  • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
  • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q5/00—Preparations for care of the hair
  • A61Q5/04—Preparations for permanent waving or straightening the hair
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
  • C08G77/04—Polysiloxanes
  • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
  • C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups

Definitions

• the present disclosure relates to a process for permanently reshaping keratin fibres, for example, hair.
• This process may be used, for example, in professional hairstyling salons, or privately via the marketing of kits.
• the expression “permanent reshaping process” means any long-lasting process for shaping, curling, straightening or relaxing the hair.
• keratin fibres means, for example, hair, eyelashes and eyebrows.
• One technique for obtaining a permanent reshaping of the hair comprises, in a first stage, opening the keratin —S—S—disulphide (cystine) bonds using a reducing composition comprising a reducing agent (reduction), followed, for example, after having rinsed the hair thus treated, by reconstituting, in a second stage, the disulphide bonds by applying to the hair, which has been placed under tension beforehand (for example, with curlers and the like), an oxidizing composition (oxidizing, also known as fixing) so as to finally give the hair the desired shape.
• This technique thus can make it equally possible either to make the hair wavy or to straighten or relax it.
• the new shape given to the hair by a chemical treatment such as above can be long-lasting and may, for example, withstand the action of washing with water and/or shampoos, as opposed to other techniques for temporary reshaping, such as hairsetting.
• the reducing composition that may be used to carry out the reduction of a permanent-waving process may comprise, as reducing agents, sulphites, bisulphites or thiols.
• thiols that may be mentioned are cysteine and its various derivatives, cysteamine and its derivatives, thiolactic acid, thioglycolic acid and its esters, such as glyceryl monothioglycolate, and thioglycerol.
• compositions based on aqueous hydrogen peroxide solution or alkali metal bromates may be used.
• One disadvantage of the permanent-waving techniques known to date is that applying them repeatedly to the hair may induce in the long term a gradual deterioration in the quality of the hair, for example, a gradual and pronounced deterioration in the sheen and the cosmetic properties of the hair, such as the softness of the fibres, which may have a tendency to become more and more coarse, and also as regards their disentangling, the hair may become more and more difficult to disentangle. This deterioration may be pronounced when the fixing of the permanent-waving process is carried out using a bromate.
• the present disclosure addresses at least one of these disadvantages by providing a process for permanently reshaping keratin fibres, such as hair, which can reduce the degree of mechanical and/or cosmetic degradation of the hair, while at the same time providing a satisfactory degree, quality and liveliness of curls.
• the inventors have discovered, surprisingly and unexpectedly, that by applying to the hair, before applying the reducing composition and/or after having applied the oxidizing composition, at least one pre-treatment and/or post-treatment cosmetic composition comprising at least one aminosilicone as defined below, it is possible to solve at least one of the problems.
• One new embodiment is a process for permanently reshaping keratin fibres, such as hair, comprising the following:
• the process also comprises applying to the keratin fibres, before (i) and/or after (ii), a pre-treatment and/or post-treatment cosmetic composition comprising, in a cosmetically acceptable medium, at least one aminosilicone in non-microemulsified form chosen from the following aminosilicones of formulae (I) and (II):
• n and n are numbers such that the sum (n+m) range, from 1 to 1 000, such as from 50 to 250 and further such as from 100 to 200;
• n is a number ranging from 0 to 999, and further, for example, from 49 to 249 and even further, for example, from 125 to 175;
• m is number ranging from 1 to 1 000, and further, for example, from 1 to 10, and even further, for example, from 1 to 5;
• R 1 , R 2 , R 3 which may be identical or different, are chosen from hydroxyl and C 1 -C 4 alkoxy radicals, wherein at least one of the radicals R 1 , R 2 and R 3 is chosen from C 1 -C 4 alkoxy radicals.
• the alkoxy radical is a methoxy radical.
• the hydroxyl/alkoxy molar ratio may range, for example, from 0.2:1 to 0.4:1 and further, for example, from 0.25:1 to 0.35:1, and even further, for example, is equal to 0.3:1.
• the aminosilicone of formula (I) can have a weight-average molecular mass ranging, for example, from 2 000 to 1 000 000, and further, for example, from 3 500 to 200 000.
• p and q are numbers such that the sum (p+q) ranges, for example, from 1 to 1 000, such as from 50 to 350 and further such as from 150 to 250;
• p is a number ranging from 0 to 999, and further, for example, from 49 to 349, and even further, for example, from 159 to 239; and q is a number ranging from 1 to 1 000, and further, for example, from 1 to 10 and even further, for example, from 1 to 5;
• R 1 , R 2 which may be identical or different, are chosen from hydroxyl and C 1 -C 4 alkoxy radicals, wherein at least one of the radicals R 1 and R 2 is chosen from C 1 -C 4 alkoxy radicals.
• the alkoxy radical is a methoxy radical.
• the hydroxyl/alkoxy molar ratio may range, for example, from 1:0.8 to 1:1.1 and further, for example, from 1:0.9 to 1:1, and even further, for example, is equal to 1:0.95.
• the aminosilicone of formula (II) may have a weight-average molecular mass ranging, for example, from 2 000 to 200 000, and further, for example, from 5 000 to 100 000, and even further, for example, from 10 000 to 50 000.
• the weight-average molecular masses of these aminosilicones are measured by Gel Permeation Chromatography (GPC) at room temperature as polystyrene equivalent.
• the columns used are ⁇ styragel columns.
• the eluent is THF, the flow rate is 1 ml/min. 200 ⁇ l of a solution containing 0.5% by weight of silicone in THF are injected. The detection is made by refractometry and UVmetry.
• non-microemulsified means a silicone used as it is or in the form of an emulsion in the presence of at least one surfactant, the number-average size of the silicone particles in the emulsion being greater than 70 nm, ranging, for example, from 70 to 500 nm.
• One of ordinary skill in the art can measure such particle sizes by known methods. Such particle sizes are measured with a laser granulometer.
• the surfactant may be of any type, such as cationic and/or nonionic.
• kits for permanently reshaping keratin fibres comprising at least one compartment comprising a pre-treatment and/or post-treatment cosmetic composition comprising at least one aminosilicone as defined above.
• the commercial products corresponding to these aminosilicones of formula (I) or (II) may include in their composition at least one other aminosilicone whose structure is different from the formulae (I) and (II).
• the at least one aminosilicone chosen from formulae (I) and (II) is chosen such that the contact angle with water of hair treated with a composition comprising 2% AM (active materials) of the aminosilicone ranges, for example, from 90 to 180°, and such as from 90 to 130°.
• a range “from x to y” includes within the range the endpoints x and y.
• composition comprising at least one aminosilicone chosen from aminosilicones of formulae (I) and (II) is chosen such that the contact angle of hair treated with the composition ranges, for example, from 90 to 180° such as from 90 to 130°.
• the measurement of the contact angle is based on the immersion of hair in distilled water.
• the measurement includes evaluating the force exerted by the water on the hair during its immersion in distilled water and during its removal.
• the forces thus measured are directly linked to the contact angle ⁇ between the water and the surface of the hair.
• the hair is said to be hydrophilic when the angle ⁇ ranges from 0 to less than 90°, and hydrophobic when this angle ranges from 900 to 180°.
• Each mesh of 1 g is placed in a crystallizing dish 75 mm in diameter and then homogeneously coated with 5 ml of the formula to be tested. The lock is thus left for 15 minutes at room temperature and then rinsed for 30 seconds. The drained lock is left in the open air until it is completely dry.
• the perimeter of the hair (P) is measured via a microscopy observation.
• F is the wettability force expressed in Newtons
• P the perimeter of the hair in metres
• ⁇ lv the liquid/steam interfacial tension of the water in J/m 2
• ⁇ the contact angle
• the concentration of the at least one aminosilicone in the pre-treatment and/or post-treatment composition ranges, for example, from 0.05 to 10% by weight relative to the total weight of the composition, such as from 0.1 to 7% by weight relative to the total weight of the composition.
• the pre-treatment and/or post-treatment composition comprising at least one aminosilicone may further comprise at least one active agent chosen from water-soluble and liposoluble active agents, having cosmetic and/or dermopharmaceutical activity.
• active agents include vitamins and derivatives thereof such as vitamin E, vitamin E acetate, vitamin C and its esters, the B vitamins, vitamin A alcohol and retinol, vitamin A acid and retinoic acid and its derivatives, provitamins such as panthenol, vitamin A palmitate, niacinamide, ergocalciferol, antioxidants, essential oils, wetting agents, silicone and non-silicone sunscreens, preserving agents, sequestering agents, pearlescent agents, pigments, moisturizers, anti-dandruff agents, anti-seborrhoeic agents, plasticizers, hydroxy acids, electrolytes, solvents and fragrances.
• composition may also comprise at least one solvent, such as C1-C8 lower alcohols such as ethanol.
• solvent such as C1-C8 lower alcohols such as ethanol.
• the pH of the pre-treatment and/or post-treatment composition comprising at least one aminosilicone ranges, for example, from 2 to 10, such as from 3 to 9.
• the pre-treatment composition comprising at least one aminosilicone as defined above is applied to the hair to be treated, which will optionally have been moistened beforehand.
• This application may be performed after the usual procedure of placing the hair under tension in a shape corresponding to the desired final shape for the hair (for example curls),
• This procedure itself can possibly be carried out by any means, such as a mechanical means, that is suitable and known per se for maintaining hair under tension, such as rollers, curlers and the like.
• the pre-treatment and/or post-treatment composition comprising at least one aminosilicone is left to act on the hair, at room temperature or under heat, for a period of time ranging from, for example, 1 to 60 minutes, such as from 3 to 30 minutes.
• the hair impregnated with the pre-treatment composition comprising at least one aminosilicone can be rinsed, wherein the rinsing can be carried out using water.
• a reducing composition is applied to the hair, wherein the reducing composition may comprise at least one thiol.
• the thiol in the reducing composition may be chosen from thiols known as reducing agents such as thioglycolic acid, glyceryl and glycol monothioglycolate, cysteamine and its C 1 -C 4 acyl derivatives such as N-acetylcysteamine or N-propionylcysteamine, cysteine, N-acetylcysteine, sugar N-mercaptoalkylamides such as N-(2-mercaptoethyl)gluconamide, 3-mercaptopropionic acid and its derivatives, thiolactic acid and its esters such as glyceryl monothiolactate, thiomalic acid, pantethine, thioglycerol, alkali metal and alkaline-earth metal sulphites and bisulphites, the N-(mercaptoalkyl)- ⁇ -hydroxyalkylamides described in patent application EP-A-354 835 and the N-mono- or
• thioglycolic acid, thiolactic acid and 3-mercaptopropionic acid are chosen for use.
• the reducing agent may be present in a concentration that may range, for example, from 1% to 20% by weight relative to the total weight of the reducing composition.
• the pH of the reducing composition may range, for example, from 6 to 10, and further, for example, from 7 to 9.
• the pH values of the reducing compositions may be conventionally adjusted by adding at least one basifying agent.
• basifying agents include aqueous ammonia, monoethanolamine, diethanolamine, triethanolamine, isopropanolamine, 1,3-propanediamine, ammonium and alkali metal carbonates and bicarbonates, primary, secondary and tertiary amine carbonates and bicarbonates and organic carbonates such as guanidine carbonate.
• the reducing composition may be in the form of a thickened or unthickened lotion, a cream, a gel, or any other suitable form, and may comprise additives known for their use in reducing compositions for permanently reshaping the hair.
• the reducing composition may also be of the exothermic type, i.e., the type causing a certain level of heating during application to the hair, affording a pleasant sensation to the person on whom the permanent-waving or straightening process is being performed.
• the reducing composition may also comprise a solvent such as ethanol, propanol, isopropanol and glycerol, in a maximum concentration of 20% by weight relative to the total weight of the composition.
• a solvent such as ethanol, propanol, isopropanol and glycerol
• the reducing composition may be, for example, in the form of a thickened cream so as to keep the hair as straight as possible.
• These creams are prepared in the form of “heavy” emulsions, for example, based on glyceryl stearate, glycol stearate, self-emulsifiable waxes, fatty alcohols, etc.
• compositions may also be in a “self-neutralizing” or “self-regulated” form and, in this case, the reducing agents used may be combined with at least one disulphide known for its use in a reducing composition for self-neutralizing permanent waving.
• the hair onto which the reducing composition has been applied is left to rest for a few minutes, such as ranging from 2 to 40 minutes and further such as ranging from 5 to 30 minutes, so as to allow the reducing agent sufficient time to act correctly on the hair.
• This waiting stage may be carried out by leaving the treated hair to rest in the open air (at room temperature or with heating). During this waiting stage, care may be taken to ensure that the hair does not dry out completely but instead remains humid.
• the hair impregnated with the reducing composition may then be carefully rinsed, such as with water.
• a stage of heating at high temperature for a few seconds may be carried out.
• An oxidizing composition can then be applied to the hair thus rinsed, with the aim of fixing the new shape given to the hair. It may also be envisaged to leave the hair to be oxidized by the air.
• the oxidizing composition comprises an oxidizing agent that may be chosen from aqueous hydrogen peroxide solution, alkali metal bromates, persalts and polythionates.
• an oxidizing agent that may be chosen from aqueous hydrogen peroxide solution, alkali metal bromates, persalts and polythionates.
• the bromate concentration in the oxidizing composition ranges, for example, from 0.1 to 2 M.
• the hair onto which the oxidizing composition has been applied is then, left for a standing or waiting stage that may last a few minutes, for example, ranging from 3 to 30 minutes and further, for example, ranging from 5 to 15 minutes.
• the hair impregnated with the oxidizing composition is rinsed carefully, such as with water.
• the keratin fibres may be separated from the implement used for placing the keratin fibres under tension.
• the hair finally obtained can have good cosmetic properties: the hair can be shinier, softer and easier to disentangle or to style.
• the pre-treatment and/or post-treatment composition comprising at least one aminosilicone as defined above is applied according to at least one of the following variants:
• the process for permanently reshaping the hair is a straightening process
• a straightening agent such as a thiol agent or an alkaline agent.
• the process may be carried out, for example, by applying the pre-treatment and/or post-treatment composition comprising at least one aminosilicone as defined above according to at least one of the following variants:
• the process may be carried out, for example, by applying the pre-treatment and/or post-treatment composition comprising at least one aminosilicone as defined above to wet hair, after rinsing out neutralizing shampoo, by rinsing before drying the hair.
• the process can give lively curls, and the hair may be at least one of supple, light, silky and well separated.
• the process may afford control of the body of the hair, may make the hair smooth from the root to the tip and may give a more natural feel.
• This composition was applied to hair straightened with an alkaline straightening agent, after rinsing out the cleansing shampoo. The composition was left for 1 to 10 minutes on the hair before being rinsed out.
• composition described in 1) may be used as a pre-permanent-waving treatment. This composition was applied to wet hair before fitting curlers, and was not rinsed out before the application of the permanent-waving reducing agent. This composition could make it possible to limit the degradation of the hair due to permanent waving, while making it possible to obtain tonic curls.

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Citations (97)

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• 2001
  • 2001-11-08 FR FR0114478A patent/FR2831804B1/fr not_active Expired - Fee Related
• 2002
  • 2002-01-01 ZA ZA200208903A patent/ZA200208903B/xx unknown
  • 2002-10-31 AU AU2002301740A patent/AU2002301740B2/en not_active Ceased
  • 2002-11-05 BR BR0204919-8A patent/BR0204919A/pt not_active Application Discontinuation
  • 2002-11-06 KR KR1020020068448A patent/KR100570943B1/ko not_active IP Right Cessation
  • 2002-11-06 RU RU2002129800/15A patent/RU2002129800A/ru not_active Application Discontinuation
  • 2002-11-07 CN CNA200810109829XA patent/CN101305971A/zh active Pending
  • 2002-11-07 CN CN02149843A patent/CN1416795A/zh active Pending
  • 2002-11-07 PL PL02357003A patent/PL357003A1/xx not_active Application Discontinuation
  • 2002-11-07 CA CA2411471A patent/CA2411471C/fr not_active Expired - Fee Related
  • 2002-11-07 MX MXPA02010946A patent/MXPA02010946A/es unknown
  • 2002-11-07 DE DE60237573T patent/DE60237573D1/de not_active Expired - Lifetime
  • 2002-11-07 EP EP02292783A patent/EP1312338B1/fr not_active Revoked
  • 2002-11-07 AT AT02292783T patent/ATE480224T1/de not_active IP Right Cessation
  • 2002-11-07 AR ARP020104254A patent/AR037274A1/es unknown
  • 2002-11-08 JP JP2002325916A patent/JP2003146842A/ja not_active Withdrawn
  • 2002-11-08 US US10/290,189 patent/US20030118537A1/en not_active Abandoned
• 2006
  • 2006-09-21 US US11/524,512 patent/US7510705B2/en not_active Expired - Fee Related

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