US1998544A - Agent for sizing textile fibers - Google Patents
Agent for sizing textile fibers Download PDFInfo
- Publication number
- US1998544A US1998544A US606284A US60628432A US1998544A US 1998544 A US1998544 A US 1998544A US 606284 A US606284 A US 606284A US 60628432 A US60628432 A US 60628432A US 1998544 A US1998544 A US 1998544A
- Authority
- US
- United States
- Prior art keywords
- parts
- polyvinyl
- sizing
- agent
- viscosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004513 sizing Methods 0.000 title description 24
- 239000003795 chemical substances by application Substances 0.000 title description 14
- 239000000835 fiber Substances 0.000 title description 8
- 239000004753 textile Substances 0.000 title description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 description 25
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 25
- 239000004372 Polyvinyl alcohol Substances 0.000 description 21
- 229920002554 vinyl polymer Polymers 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000000047 product Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 229920002955 Art silk Polymers 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 229920000297 Rayon Polymers 0.000 description 4
- 229920002301 cellulose acetate Polymers 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 229920002689 polyvinyl acetate Polymers 0.000 description 4
- 239000011118 polyvinyl acetate Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- -1 compounds compounds Chemical class 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- XJELOQYISYPGDX-UHFFFAOYSA-N ethenyl 2-chloroacetate Chemical compound ClCC(=O)OC=C XJELOQYISYPGDX-UHFFFAOYSA-N 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
Definitions
- the present invention relates to agents for sizing textile fibers.
- a similar efiect is produced when other polyvinyl compounds, provided they are soluble in water, are used, , such as the water-soluble derivatives of polyproduct of the reaction of an alkylene oxide on a polyvinyl alcohol.
- a polyvinyl alcohol of a high viscosity with a derivative of low viscosity obtained by causing a polyvinyl alcohol to react with ethylene oxide, it is possible to obtain a sizing agent which with regard to the sizing effect and the soft feel of the sized material is superior to an agent consisting of either component.
- a polyvinyl compound of alow viscosity penetrates very readily into the fiber and causes the 'various capillaries to unite with one another, thus producing a soft sized material.
- a polyvinyl compound of a igh viscosity does not penetrate into the thread but in the "form of "a film surrounds the surface of the thread, thus enclosing the various capillary threads; the sized material thus obtained is rather hard.
- polyvinyl compounds compounds of a high molecular weight containing hydroxylgroups for instance the polymeric products obtained by the condensation of polyhydric alcohols, particularly of filhyecerin; furthermore there may also be added water-soluble products obtained by chemical reaction or by degradation from carbohydrates, such' as methyl cellulose, dextrin, or the like.
- Sugar-like substances such as glucose and cane sugar, likewise have a favorable action-on the sizing eilect of the polyvinyl alcohol; likewise the degradation products. obtained by a catalytic reduction of carbohydrates, for instance dimethoxytrioxyhexane obtained from methylcellulose.
- the condensation products from urea and glycerin and other condensation products containing hydroxyl and nitrogen, such as triethanolamine, may likewise be used.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE399905X | 1931-05-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1998544A true US1998544A (en) | 1935-04-23 |
Family
ID=6397537
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US606284A Expired - Lifetime US1998544A (en) | 1931-05-16 | 1932-04-19 | Agent for sizing textile fibers |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US1998544A (is") |
| NL (1) | NL32562C (is") |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2439108A (en) * | 1943-09-11 | 1948-04-06 | Eastman Kodak Co | Coating with polyvinyl alcohol |
| US2595276A (en) * | 1948-03-29 | 1952-05-06 | Lowry Milton Lester | Polyvinyl alcohol lucrose hemostat |
| US2874023A (en) * | 1954-07-27 | 1959-02-17 | Union Carbide Corp | Static-resistant hydrophobic resin composition, shaped article thereof and method formaking the latter |
| US2917478A (en) * | 1955-11-18 | 1959-12-15 | Bayer Ag | Textile sizing copolymer compositions and process for applying the same |
| US3052652A (en) * | 1958-02-26 | 1962-09-04 | Borden Co | Alkoxylated polyvinyl alcohol |
-
0
- NL NL32562D patent/NL32562C/xx active
-
1932
- 1932-04-19 US US606284A patent/US1998544A/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2439108A (en) * | 1943-09-11 | 1948-04-06 | Eastman Kodak Co | Coating with polyvinyl alcohol |
| US2595276A (en) * | 1948-03-29 | 1952-05-06 | Lowry Milton Lester | Polyvinyl alcohol lucrose hemostat |
| US2874023A (en) * | 1954-07-27 | 1959-02-17 | Union Carbide Corp | Static-resistant hydrophobic resin composition, shaped article thereof and method formaking the latter |
| US2917478A (en) * | 1955-11-18 | 1959-12-15 | Bayer Ag | Textile sizing copolymer compositions and process for applying the same |
| US3052652A (en) * | 1958-02-26 | 1962-09-04 | Borden Co | Alkoxylated polyvinyl alcohol |
Also Published As
| Publication number | Publication date |
|---|---|
| NL32562C (is") |
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