US1974889A - Preparation of hides or skins for tanning - Google Patents
Preparation of hides or skins for tanning Download PDFInfo
- Publication number
- US1974889A US1974889A US592187A US59218732A US1974889A US 1974889 A US1974889 A US 1974889A US 592187 A US592187 A US 592187A US 59218732 A US59218732 A US 59218732A US 1974889 A US1974889 A US 1974889A
- Authority
- US
- United States
- Prior art keywords
- skins
- tanning
- hides
- per cent
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 102000005600 Cathepsins Human genes 0.000 description 5
- 108010084457 Cathepsins Proteins 0.000 description 5
- 210000001557 animal structure Anatomy 0.000 description 5
- 239000000284 extract Substances 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 230000001603 reducing effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 102000011782 Keratins Human genes 0.000 description 2
- 108010076876 Keratins Proteins 0.000 description 2
- 239000006286 aqueous extract Substances 0.000 description 2
- 230000003554 catheptic effect Effects 0.000 description 2
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 2
- 239000007857 degradation product Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- GEHJBWKLJVFKPS-UHFFFAOYSA-N bromochloroacetic acid Chemical compound OC(=O)C(Cl)Br GEHJBWKLJVFKPS-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 208000020442 loss of weight Diseases 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
- 210000000952 spleen Anatomy 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- -1 sulphur compound Chemical class 0.000 description 1
- 229940071127 thioglycolate Drugs 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/06—Facilitating unhairing, e.g. by painting, by liming
- C14C1/065—Enzymatic unhairing
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
Definitions
- the usual process of preparing hides or skins for tanning consists either in first liming the softened hide or skin, then de-hairing it and finally bating it, or in conducting the removal of 5 hair with the aidof enzymes comprising as essential constituent tryptic ferments; in both cases a strong alkaline pre-treatment is necessary.
- the ore-treatment has great disadvantages; by partial degradation of the protein substances of the hide, there is a more or less considerable loss of weight. This, however, cannot be avoided, since tryptic ierments alone cannot loosen the hair. This last fact is understandable from the new investigations of Waldschmidt- Leitz and his co-workers, as well as of Grassmann and his coworkers (see Collegium 1931, Ref. page 157), for the tryptic ferments are greatly hindered in their action by the degradation products of the keratins concerned in the structure of hair.
- an alkaline pretreatment of the hide or skin is avoided by use of the catheptic ferments (see Waldschmidt-Leitz, Zeitschrift fiir physio strige Chemie 188, page 1? (1929/)) for the preparatory process, it having been found that these ferments are directly activated by the degradation products of the keratin so that the loosening of the hair and the hating may be conducted in a single operation.
- Other activators may also be added, such as substances having a reducing action, for example sulphur compounds of an inorganic or organic nature, such as sodium hydrosulphide, thiosulphuric acid, thioglycolic acid etc.
- a further advantage of the invention resides in the fact that the maximum effect of the catheptic ferments lies at a pH-value between 7 and 5, whereby the treatment becomes one which improves the skin and is practically unaccompanied by loss.
- a process for preparing with the use of ferments hides or skins for tanning consisting in treating the softened hide or skin with an aque ous extract of an animal organ containing cathepsin with addition of an activating substance having a reducing effect.
- a process for preparing with the use of ferments hides or skins for tanning consisting in treating the softened hide or skin with an aqueous extract of an animal organ containing cathepsin with addition of a sulphur compound having a reducing eifect.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB148549A DE579634C (de) | 1931-02-21 | 1931-02-21 | Verfahren zur Herstellung gerbfertiger Bloessen aus tierischen Haeuten und Fellen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1974889A true US1974889A (en) | 1934-09-25 |
Family
ID=89508730
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US592187A Expired - Lifetime US1974889A (en) | 1931-02-21 | 1932-02-10 | Preparation of hides or skins for tanning |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US1974889A (cs) |
| BE (1) | BE386467A (cs) |
| DE (1) | DE579634C (cs) |
| ES (1) | ES125660A1 (cs) |
| FR (1) | FR731445A (cs) |
| GB (1) | GB398524A (cs) |
-
1931
- 1931-02-21 DE DEB148549A patent/DE579634C/de not_active Expired
-
1932
- 1932-02-10 US US592187A patent/US1974889A/en not_active Expired - Lifetime
- 1932-02-15 GB GB4435/32A patent/GB398524A/en not_active Expired
- 1932-02-15 ES ES0125660A patent/ES125660A1/es not_active Expired
- 1932-02-16 FR FR731445D patent/FR731445A/fr not_active Expired
- 1932-02-19 BE BE386467A patent/BE386467A/fr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB398524A (en) | 1933-09-15 |
| BE386467A (cs) | 1932-03-31 |
| FR731445A (fr) | 1932-09-02 |
| ES125660A1 (es) | 1932-03-01 |
| DE579634C (de) | 1933-06-29 |
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