US1041510A - Process of producing fast brown resists on vegetable fibers. - Google Patents
Process of producing fast brown resists on vegetable fibers. Download PDFInfo
- Publication number
- US1041510A US1041510A US66445011A US1911664450A US1041510A US 1041510 A US1041510 A US 1041510A US 66445011 A US66445011 A US 66445011A US 1911664450 A US1911664450 A US 1911664450A US 1041510 A US1041510 A US 1041510A
- Authority
- US
- United States
- Prior art keywords
- resists
- brown
- vegetable fibers
- producing fast
- fast brown
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 5
- 239000000835 fiber Substances 0.000 title description 4
- 235000013311 vegetables Nutrition 0.000 title description 4
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 7
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 4
- 240000007817 Olea europaea Species 0.000 description 3
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 2
- OETHQSJEHLVLGH-UHFFFAOYSA-N metformin hydrochloride Chemical compound Cl.CN(C)C(=N)N=C(N)N OETHQSJEHLVLGH-UHFFFAOYSA-N 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 description 1
- PCAXITAPTVOLGL-UHFFFAOYSA-N 2,3-diaminophenol Chemical class NC1=CC=CC(O)=C1N PCAXITAPTVOLGL-UHFFFAOYSA-N 0.000 description 1
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 1
- 229940018563 3-aminophenol Drugs 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- HFACYLZERDEVSX-UHFFFAOYSA-N benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 1
- 239000001049 brown dye Substances 0.000 description 1
- VRWKTAYJTKRVCU-UHFFFAOYSA-N iron(6+);hexacyanide Chemical compound [Fe+6].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] VRWKTAYJTKRVCU-UHFFFAOYSA-N 0.000 description 1
- 125000004401 m-toluyl group Chemical group [H]C1=C([H])C(=C([H])C(=C1[H])C([H])([H])[H])C(*)=O 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- QVRVXSZKCXFBTE-UHFFFAOYSA-N n-[4-(6,7-dimethoxy-3,4-dihydro-1h-isoquinolin-2-yl)butyl]-2-(2-fluoroethoxy)-5-methylbenzamide Chemical compound C1C=2C=C(OC)C(OC)=CC=2CCN1CCCCNC(=O)C1=CC(C)=CC=C1OCCF QVRVXSZKCXFBTE-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- -1 p-phenylene diamin Chemical compound 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229940080281 sodium chlorate Drugs 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
I To all whom it may concern STATES PATENT orFicEi.
CARI; PILZ, OF LIESING, NEAR VIENNA, AUSTRIA-HUNGARY.
, r'nocns's or i nonucme r'nsr BROWN RESISTS 0N VEGETABLE FIBERS.
Ito Drawing.
Specification of Letters Patent. Application fil ed December 7, 19111 serial-no. 664,450.
Patented Oct. 15, EH2.
'Be it known that I, CARL PILZ, a subject of the Austro-Hungarian Emperor, residing at Liesing, near Vienna, Austria-Hungary,
'have invented-certain new and useful Improvements in Processes of Producing Fast; Brown Resists in Vegetable Fibers, of which the following is a specification.
The'surp'rising observation has been made that easily oxidized aromatic amlns when printed on undeveloped anilinblack padding, prevent the oxidation of the anilin to 'black, and are themselves developed to fast brown dyes. If,' for example, thecotton material is padded in the usual manner with anilin salt, potassium 'ferrocyanid,' sodiumchlorate, 'and oso forth, dried, and printed on .with an aromatic amin, for example, m-aminophenol, the subsequent steaming in a Mather-Flatt will not produce black at the printed places, but an olive brown, while the ground appears black. I 1
' The resistive efiectoof the easily oxidized amins, aminophenols, diamins, triamins, and.
so forth, is so strong that even when printing a mixture of anilin with one of these aminophenols, and so forth-with the necessary oxidizing agents, the anilin remains unoxidized and only the brown color results from the oxidized aminophenol. I The easily oxidizabl'e amins', diamin's, triamins, 'aminophenols, diaminophenols, triamins of the benzohseri'es and naphthalene series may be utilized. These a-mi'ns areall embraced in the: generic class of easily oxidizable "aromatic amins. Some ofjthe'se'. amins give a great va rietyf -of shades, for ex-' ample m-ami'nophenol gives an olive brown,
o-aminophenol a red brown, m-phenylene 'diamin and m-toluyl'ene' diar'nin an olive and o-amidocresol a yellow brown; others how- 'by steammg. 1 4
2. The process of producing fast brown ever give less striking shades, such as p-phenylene diamin, benzidin, and so forth give very dark shades of brown.
It isof great importance that these brown resists may easily be reserved with the white and colored resists used habitually for aniiin -.black.' Thus, a large number of new combinations can be obtalned by means of the new process which could not be obtained till DOW.
my process: The material prepared in the usual manner-With anilin black padding and then dried, is printed .on with a print color, which apart from the thickening, without other resist, contains for every liter 40430 g.
printing on suchmaterialan easily oxidiz- The following is given as an exampletof able aromatic' amincapable of preventing the oxidization of the anilin' black and .developing thepadded'and printed material.
resists on vegetable fibers which comprises padding such materiai with anilin black and printing on such material an easily oxidize able aminophenoL-and developing thepaddedand printed material by steaming.
In testimony whereof I have affixed my signature in presence of two witnesses.
CARL PI-LZ.
Witnesses:
' RICHARD Rnrrz, AUGUST Fueenn.
re a tas
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66445011A US1041510A (en) | 1911-12-07 | 1911-12-07 | Process of producing fast brown resists on vegetable fibers. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66445011A US1041510A (en) | 1911-12-07 | 1911-12-07 | Process of producing fast brown resists on vegetable fibers. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1041510A true US1041510A (en) | 1912-10-15 |
Family
ID=3109785
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US66445011A Expired - Lifetime US1041510A (en) | 1911-12-07 | 1911-12-07 | Process of producing fast brown resists on vegetable fibers. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1041510A (en) |
-
1911
- 1911-12-07 US US66445011A patent/US1041510A/en not_active Expired - Lifetime
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