US501156A - Oscar ostersetzer - Google Patents
Oscar ostersetzer Download PDFInfo
- Publication number
- US501156A US501156A US501156DA US501156A US 501156 A US501156 A US 501156A US 501156D A US501156D A US 501156DA US 501156 A US501156 A US 501156A
- Authority
- US
- United States
- Prior art keywords
- oscar
- ostersetzer
- grains
- red
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 241000501754 Astronotus ocellatus Species 0.000 title description 4
- 239000000975 dye Substances 0.000 description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 8
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-Naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 6
- 239000000987 azo dye Substances 0.000 description 6
- 229950011260 betanaphthol Drugs 0.000 description 6
- 150000004985 diamines Chemical class 0.000 description 6
- IOVCWXUNBOPUCH-UHFFFAOYSA-M nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 6
- 239000003638 reducing agent Substances 0.000 description 6
- 238000010025 steaming Methods 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- RSRNHSYYBLEMOI-UHFFFAOYSA-M Primuline Chemical compound [Na+].S1C2=C(S([O-])(=O)=O)C(C)=CC=C2N=C1C(C=C1S2)=CC=C1N=C2C1=CC=C(N)C=C1 RSRNHSYYBLEMOI-UHFFFAOYSA-M 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 238000009967 direct dyeing Methods 0.000 description 4
- 238000007599 discharging Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 235000011167 hydrochloric acid Nutrition 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- SOAAGHDAWFEEPP-JZJYNLBNSA-N (4Z)-4-[(2,4-dimethylphenyl)hydrazinylidene]-3-oxonaphthalene-2,7-disulfonic acid Chemical compound CC1=CC(C)=CC=C1N\N=C/1C2=CC=C(S(O)(=O)=O)C=C2C=C(S(O)(=O)=O)C\1=O SOAAGHDAWFEEPP-JZJYNLBNSA-N 0.000 description 2
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- FYGDTMLNYKFZSV-MRCIVHHJSA-N Dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- GEYOCULIXLDCMW-UHFFFAOYSA-N O-Phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N Resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000010446 mirabilite Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- -1 prirnuline Substances 0.000 description 2
- 210000001519 tissues Anatomy 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
- D06P5/155—Locally discharging the dyes with reductants
Definitions
- the object of this invention is to overcome this difficulty by developing the red on the fiber.
- red in its various shades but also yellow, orange, brown and other shades can be produced.
- This invention may be carried out as follows: Recently a series of direct dyeing cotton-dyes have been found, which can be diazotized on the fiber and developed to new dyestuffs, which latter not only differ in shade .from the original dyeing, but also show a greater resistance to the actions of light, alkalies and acids.
- These dyestuffs belong to two diiferent groups, the first one of which is characterized by the dyestuff, named primuline, (thiochromogene, polychromine,) the second one by diamineblack (diamineblueblack, Nyanza or tabora-black, diazurine, diazochromine). The first one of these groups is distinguished from the second one by its resistance against reducing agents.
- both the printed and the bottom colors can be perfectly fixed.
- developers I particularly name the following: phenole, resorcine, betanaphthol, Schaefferacid, ethylebeta -naphthylamine, phenylenediamine.
- the goods After steaming, in order to remove the zinc-dust, which would impair the formation of the new azodye, the goods are passed through diluted muriatic acid and then diazotized in a cold solution containing three hundred grains nitrite of soda and one liter muriatic acid of 21 Baum to two hundred liters water. Then the goods are entered in a bath containing four hundred grains of betanaphthol dissolved in one
- the thus produced patterns are of great fastness to washing and acids, but less fast to light than the known turkey red-indigo fabrics, against which my method has the advantage of cheapness.
Description
NITED STATES PATENT OFFIoE.
OSCAR OSTERSETZER, OF SAGAN, GERMANY.
PRINTING COTTON FABRICS.
SPECIFICATION forming part of Letters Patent No. 501,156, dated July 11, 1893.
Application filed February 17, 1893.
To a/ZZ whom it may concern: Be it known that I, OscAR Osrnesnrznn, subject of the Emperor of Austria-Hungary, and a resident of Sagan, Austria-Hungary, have invented certain new and useful Improvements in Methods of Discharging Red and other Azo Colors on Direct-Dyeing Cotton Dye-Stuffs, of which the following is a specification.
On account of the brilliancy of red-azodyes it has for a long time been tried to print the same with a discharge on bottoms dyed with so-called aniline colors, but this has hitherto not been possible, because all azodyos are destroyed by the means which are used for discharging the bottom.
The object of this inventionis to overcome this difficulty by developing the red on the fiber. Thus not only red in its various shades but also yellow, orange, brown and other shades can be produced.
This invention may be carried out as follows: Recently a series of direct dyeing cotton-dyes have been found, which can be diazotized on the fiber and developed to new dyestuffs, which latter not only differ in shade .from the original dyeing, but also show a greater resistance to the actions of light, alkalies and acids. These dyestuffs belong to two diiferent groups, the first one of which is characterized by the dyestuff, named primuline, (thiochromogene, polychromine,) the second one by diamineblack (diamineblueblack, Nyanza or tabora-black, diazurine, diazochromine). The first one of these groups is distinguished from the second one by its resistance against reducing agents. It therefore a printing paste which contains a dyestuff of the first group and a reducing agent is applied to a tissue dyed with a dyestuff of the second group, this latter after steaming will disappear on the printed spots while simultaneously the first. one is fixed on these spots, and a pattern can thus be produced, which however does not possess the usually desired fastness to washing. Whereas however such dyestufis are selected which by the well known method may be further diazotized and developed to shades fast to Washing, it results that by passing the goods through nitrite of soda Serial No. 462,762. (No specimens.)
and then through a bath containing a suitable phenole or amine, both the printed and the bottom colors can be perfectly fixed.
As developers I particularly name the following: phenole, resorcine, betanaphthol, Schaefferacid, ethylebeta -naphthylamine, phenylenediamine.
On bottoms dyed as above mentioned I ob tain by developing with betanaphthol-turkey red print on blue ground; by developing with Schaeffer acidscarlet print on blue ground; by developing with ethyle betanaphthylamineolaret red print on blue ground. By developing diamine black I obtain with phenylenediamine-red print on black ground; resorcine-orange print on black ground.
I give the following examples:
Ewample I.Turkey red shade on darkblue by means of betanaphthol. I dye for instance with five per cent. diamine blueblack E with the usual addition of glaubersalt and soda and then I print thereon the following printing paste: five hundred grains primuline, one thousand grains dextrine, two thousand grains water, twelve hundred grains zinc-dust, nine hundred grains bisulphite 30, one hundred and twenty grains glycerine, eighty grains ammonia. Then I steam during one hour. After steaming, in order to remove the zinc-dust, which would impair the formation of the new azodye, the goods are passed through diluted muriatic acid and then diazotized in a cold solution containing three hundred grains nitrite of soda and one liter muriatic acid of 21 Baum to two hundred liters water. Then the goods are entered in a bath containing four hundred grains of betanaphthol dissolved in one The thus produced patterns are of great fastness to washing and acids, but less fast to light than the known turkey red-indigo fabrics, against which my method has the advantage of cheapness.
What I claim as new, and desire to secure by Letters Patent, is-
The process of printing cotton fabrics which are dyed with a diazotizabie a'zo dye-stuif, such as diamine black, by means of a printing color consisting of a diazotizable but not reducible dye-stuff such as prirnuline, and a reducing agent, and 0f devolopin g the printed design by steaming, passing through an acidulated bath of nitrite of soda and passing through a second bath which contains a pile n01 or an amine, substantially as herein described.
In testimony that I claim the foregoing as my invention I have signed my name, in pres ence of two witnesses, this 22d day of January, 1893. v
OSCAR OSTERSETZER.
Witnesses:
ADOLF DEMUTH, O'rcro GOLDSCHMIEDT.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US501156A true US501156A (en) | 1893-07-11 |
Family
ID=2569991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US501156D Expired - Lifetime US501156A (en) | Oscar ostersetzer |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US501156A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100258567A1 (en) * | 2007-07-17 | 2010-10-14 | Colin Gibert Tobeck and Rosalie Bernadette Tobeck as Trutees of the Progressive Endeavours Trust | Fluid receiver with one-way check valve at inlet port |
-
0
- US US501156D patent/US501156A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100258567A1 (en) * | 2007-07-17 | 2010-10-14 | Colin Gibert Tobeck and Rosalie Bernadette Tobeck as Trutees of the Progressive Endeavours Trust | Fluid receiver with one-way check valve at inlet port |
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