US491673A - Process of printing colors with aniline-black - Google Patents
Process of printing colors with aniline-black Download PDFInfo
- Publication number
- US491673A US491673A US491673DA US491673A US 491673 A US491673 A US 491673A US 491673D A US491673D A US 491673DA US 491673 A US491673 A US 491673A
- Authority
- US
- United States
- Prior art keywords
- aniline
- black
- colors
- printing colors
- aniline black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000767 polyaniline Polymers 0.000 title description 30
- 239000003086 colorant Substances 0.000 title description 24
- 238000000034 method Methods 0.000 title description 16
- 239000000463 material Substances 0.000 description 20
- 239000000203 mixture Substances 0.000 description 18
- 239000004744 fabric Substances 0.000 description 14
- 229920000742 Cotton Polymers 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 230000032683 aging Effects 0.000 description 6
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 6
- 238000010025 steaming Methods 0.000 description 6
- WBTCZEPSIIFINA-UHFFFAOYSA-J Antimony potassium tartrate Chemical compound O.O.O.[K+].[K+].O1C(=O)C2O[Sb-]1(OC1=O)OC1C(C(=O)O1)O[Sb-]31OC(=O)C2O3 WBTCZEPSIIFINA-UHFFFAOYSA-J 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
- 239000001263 FEMA 3042 Substances 0.000 description 4
- CXKWCBBOMKCUKX-UHFFFAOYSA-M Methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 4
- 229940042115 Methylene blue Drugs 0.000 description 4
- 229940033123 Tannic Acid Drugs 0.000 description 4
- LRBQNJMCXXYXIU-NRMVVENXSA-N Tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229960000907 methylthioninium chloride Drugs 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 235000015523 tannic acid Nutrition 0.000 description 4
- 229920002258 tannic acid Polymers 0.000 description 4
- 229940108066 Coal Tar Drugs 0.000 description 2
- FYGDTMLNYKFZSV-MRCIVHHJSA-N Dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M Potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 2
- 241000208225 Rhus Species 0.000 description 2
- 235000014220 Rhus chinensis Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000011280 coal tar Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- ORXDSIPBTFAEKJ-UHFFFAOYSA-N ferrocyanide Chemical compound N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N ORXDSIPBTFAEKJ-UHFFFAOYSA-N 0.000 description 2
- 238000010297 mechanical methods and process Methods 0.000 description 2
- 229940072033 potash Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- 235000015096 spirit Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Definitions
- PROCESS OF PRINTING COLORS WITH ANILINE-BLACKP SPECIFICATION forming part of Letters Patent No. 191,673, dated February 14, 1893.
- This invention relates to an improved proand then printing and fixing the color upon cess or combination of operations for the prosuch portions, in which operation the diffiduction and fixation of colors, in conjunction culty of exactly fitting the reserved white por- 1. with aniline black upon cotton materials.
- the range of colors which tallic salt, according to the usual known can be employed is comparatively limited bemethods of mordanting.
- the material thus sides lacking clearness, brilliancy and permordanted or prepared is then washed, dried manency; while by my improved process the and padded either upon one side, or upon colors are chemically fixed in the fabric,have both, with an aniline black mixture thickened great brilliancy, and the variety of colors and or otherwise, suitable for the production of shades of colors which may be employed is 8o 30 aniline black by the ordinary known methunlimited.
- Next pad (preferably on both sides) veloped by steaming or aging as usual, the with a solution prepared as follows: First coloring matters on the printed portions are dissolve six pounds of chlorate of potash in 5 at the same time fixed by the mordant or assix gallons of hot water, and fifteen pounds tringent matter and the resist in the colorof ferro-cyanide of potash, also in six gallons ing mixtures prevents the formation of the of hot water, and mix the two solutions toaniline black at those parts.
- the cloth thus padded is dried, print on the design with the following:Dissolve two ounces of, say, methylene blue in half a pint of methylated spirits and half a pint of hot water, and add seven pints of a thickened resist containing about four ounces and two-thirds of acetate of soda and two ounces and twothirds British gum to the half pint.
- a steam chamber in the usual way, which will develope the aniline black ground and at the same time fix'the methylene blue pattern by the astringent mordant, then wash and finish in the usual manner.
- designs in any of the great variety of brilliant colors, derived from coal-tar may be produced upon cotton materials in conjunction with aniline black, and with a variety of different colors in each design, which heretofore has not been accomplished by calico-printers.
- ingredients and proportions of ingredients in the several mixtures may be varied according to the formulas employed by each calico-printer.
- I claim as my invention The process of producting and fixing upon cotton, designs in colors, in conjunction with aniline-black, which consists in, first, applying to the material mordant formed by an astringent solution and a metallic salt; second,padding the material with an aniline mixture suitable for producing aniline black; third, printing upon the material in any desired designs a resist for aniline-black mixed with coloring matter which will enter into chemical combination with such mordant, and finally, steaming or aging the material so mordanted, padded and printed, to develop and fix the colors, substantially as described.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
i NI'IED STATES PATENT WILLIAM BROl/VNING, OF ACCRINGTON, ENGLAND, ASSIGNOR, BY DIRECT AND MESNE ASSIGNMENTS, TO THE ARNOLD PRINT IVORKS, OF NORTH ADAMS, MASSACHUSETTS.
PROCESS OF PRINTING COLORS WITH ANILINE-BLACKP SPECIFICATION forming part of Letters Patent No. 191,673, dated February 14, 1893. Application filed July 30, 1892. Serial No. 441,727. (Specimens.) Patented in England June 18, 1892, No. 11,416.
To all whom it may concern.- singly, but by combining the several opera- Be it known that 1, WILLIAM BROYVNING, a tions in the manner herein described the most subject of the Queen of Great Britain and be perfect effects can be obtained, and delicate, land, residing at Accrington, in the county brilliant, and elaborate patterns or designs 3'. of Lancaster, England, have invented an Imcan be produced upon aniline-black grounds proved Process for the Production and Fixawhich,heretofore,has not been accomplished. tion of Colors, in Conjunction with Aniline- My improved process is to be distinguished Black,upon Cotton, (for which I have obtained from that in which colored designs have been British Letters Patent No. 11,416, dated June produced in connection with aniline black 18, 1892,) of which the following is a specificagrounds by reserving white portions corretiOH- sponding to the design or pattern desired, This invention relates to an improved proand then printing and fixing the color upon cess or combination of operations for the prosuch portions, in which operation the diffiduction and fixation of colors, in conjunction culty of exactly fitting the reserved white por- 1. with aniline black upon cotton materials. tions has been so great and, in fact, almost According to this invention, the fabric or impossible in fine patterns, that the results other material is first mordanted, as by padhave been veryimperfect and unsatisfactory: ding with a solution of an astringent matter, it is also to be distinguished from the methods say, for example, tannic acid or other mateheretofore used for producing colored figures go rial possessing similar properties such as gall upon aniline-black grounds by fastening pigliquor, sumac extract, or other known astrinments upon the fabric, with albumen, which gent, which is then fixed by treatment with a is a wholly mechanical method. For in these solution of tartar emetic or other suitable mepigment methods, the range of colors which tallic salt, according to the usual known can be employed is comparatively limited bemethods of mordanting. The material thus sides lacking clearness, brilliancy and permordanted or prepared is then washed, dried manency; while by my improved process the and padded either upon one side, or upon colors are chemically fixed in the fabric,have both, with an aniline black mixture thickened great brilliancy, and the variety of colors and or otherwise, suitable for the production of shades of colors which may be employed is 8o 30 aniline black by the ordinary known methunlimited.
ods. Before, however, developing the aniline As a specific illustration of the use of my black by steaming or aging in the usual manimproved process, I will describe the producner, the material preparedas above is printed tion of a blue pattern on an aniline black in the desired pattern or design with colorground upon cotton cloth, First prepare or 35 ing matters (such as those ordinarily fixed mordant the cloth in the following manner:
with an astringent as above) dissolved and Make two separate solutions, one in the prothickened and mixed with suitable proporportion of one ounce of tannic acid dissolved l tions of acetate of soda or such other well in one gallon of water and the other one ounce v I known materials, commonly called resists, of tartar emetic to each gallon of water. Pass 40 as are used to prevent the formation or dethe cloth through each solution separately, velopment of aniline black upon the parts drying it between the two, then wash and so printed. W hen the aniline black is dedry. Next pad (preferably on both sides) veloped by steaming or aging as usual, the with a solution prepared as follows:First coloring matters on the printed portions are dissolve six pounds of chlorate of potash in 5 at the same time fixed by the mordant or assix gallons of hot water, and fifteen pounds tringent matter and the resist in the colorof ferro-cyanide of potash, also in six gallons ing mixtures prevents the formation of the of hot water, and mix the two solutions toaniline black at those parts. gether; when cool, add six quarts of aniline I do not claim as new any of the above deoil and six quarts of hydrochloric acid (at I00 50 scribed steps in this process when taken sepa- 82 Twaddle), which have been previously rately, for they have been heretofore used mixed and cooled. This is the standard mixture. YVhen required for use, add more hydrochloric acid in the proportion of about two ounces of the acid to each gallon of the above mixture. Then the cloth thus padded is dried, print on the design with the following:Dissolve two ounces of, say, methylene blue in half a pint of methylated spirits and half a pint of hot water, and add seven pints of a thickened resist containing about four ounces and two-thirds of acetate of soda and two ounces and twothirds British gum to the half pint. When dry, expose in a steam chamber in the usual way, which will develope the aniline black ground and at the same time fix'the methylene blue pattern by the astringent mordant, then wash and finish in the usual manner. In this manner designs in any of the great variety of brilliant colors, derived from coal-tar may be produced upon cotton materials in conjunction with aniline black, and with a variety of different colors in each design, which heretofore has not been accomplished by calico-printers.
It will be understood that the ingredients and proportions of ingredients in the several mixtures may be varied according to the formulas employed by each calico-printer.
I claim as my invention The process of producting and fixing upon cotton, designs in colors, in conjunction with aniline-black, which consists in, first, applying to the material mordant formed by an astringent solution and a metallic salt; second,padding the material with an aniline mixture suitable for producing aniline black; third, printing upon the material in any desired designs a resist for aniline-black mixed with coloring matter which will enter into chemical combination with such mordant, and finally, steaming or aging the material so mordanted, padded and printed, to develop and fix the colors, substantially as described.
In testimony whereof I have signed my name to this specification in the presence of two subscribing witnesses.
WILLIAM BROWNING. Vitnesses:
GEORGE DAVIES, J NO. HUGHES.
It is hereby certified that in Letters Patent No. 491,673, granted February 14, 1893, upon the application of \Villiam Browning, of Aocrington, England, for an improvement in Processes of Printing Colors with Aniline Black, an error appears in the printed specification requiring the following correction, viz.: In line 29, page 2, the word producting should read producing and that the said Letters Patent should be read with this correction therein that the same may conform to the record of the case in the Patent Office.
Signed, countersigned, and sealed this 28th day of February, A. D. 1893.
[SEAL] CYRUS BUSSEY, Assistant Secretary of the Interior.
Gountersigned W. E. SIMQNDS,
Oomtm'sstoner of Patents.
Publications (1)
Publication Number | Publication Date |
---|---|
US491673A true US491673A (en) | 1893-02-14 |
Family
ID=2560519
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US491673D Expired - Lifetime US491673A (en) | Process of printing colors with aniline-black |
Country Status (1)
Country | Link |
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US (1) | US491673A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060197509A1 (en) * | 2005-03-01 | 2006-09-07 | Takashi Kanamori | Method and apparatus for voltage regulation |
-
0
- US US491673D patent/US491673A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060197509A1 (en) * | 2005-03-01 | 2006-09-07 | Takashi Kanamori | Method and apparatus for voltage regulation |
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