US409823A - Process of printing on aniline-black - Google Patents
Process of printing on aniline-black Download PDFInfo
- Publication number
- US409823A US409823A US409823DA US409823A US 409823 A US409823 A US 409823A US 409823D A US409823D A US 409823DA US 409823 A US409823 A US 409823A
- Authority
- US
- United States
- Prior art keywords
- aniline
- black
- cloth
- color
- resist
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000767 polyaniline Polymers 0.000 title description 36
- 238000000034 method Methods 0.000 title description 10
- 239000004744 fabric Substances 0.000 description 32
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 20
- 239000000203 mixture Substances 0.000 description 18
- 239000000049 pigment Substances 0.000 description 18
- 239000003086 colorant Substances 0.000 description 14
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 10
- 239000003513 alkali Substances 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 8
- 238000001035 drying Methods 0.000 description 8
- ORXDSIPBTFAEKJ-UHFFFAOYSA-N ferrocyanide Chemical compound N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N ORXDSIPBTFAEKJ-UHFFFAOYSA-N 0.000 description 8
- MMCPOSDMTGQNKG-UHFFFAOYSA-N Anilinium chloride Chemical compound Cl.NC1=CC=CC=C1 MMCPOSDMTGQNKG-UHFFFAOYSA-N 0.000 description 6
- 229920000591 gum Polymers 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229920002261 Corn starch Polymers 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000001448 anilines Chemical class 0.000 description 4
- 239000008120 corn starch Substances 0.000 description 4
- 229940099112 cornstarch Drugs 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000010025 steaming Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 210000004369 Blood Anatomy 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 241000322338 Loeseliastrum Species 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M Potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 2
- PXLIDIMHPNPGMH-UHFFFAOYSA-N Sodium chromate Chemical compound [Na+].[Na+].[O-][Cr]([O-])(=O)=O PXLIDIMHPNPGMH-UHFFFAOYSA-N 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 235000013601 eggs Nutrition 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical class [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Definitions
- My invention relates to an improved method of compounding, applying, and developing aniline-black with resists printed in patterns upon the cloth, and in developing and fastening the colors by the use of steam under pressure, or what is commonly termed live steam, su bstantiallyas hereinafter described and claimed.
- I proceed as follows: I take bleached cotton cloth prepared for printing to form calico in the usual way, and print thereon the resist mixture hereinafter described, in suitable patterns to form the figure or design desired.
- This resist mixture may be compounded with pigment colors when other than a white pattern is to be produced.
- I then dry the cloth upon steam drums or cans or in heated air, say at 160 Fahrenheit.
- the proportion of gum substitute or other suitable thickening may be varied to suit the printing, and the quantity of acetate of soda may also be varied.
- acetate of soda other soda or potash salts may be employed as the alkali of the resist, and in some of the pigments chromate of soda maybe used.
- the steam aniline -black color is compounded as follows: I mix, cold, twelve gallens of the ferro-cyanide paste, given below, with four gallons of the solution of anilinesalt crystals, given below, and add thereto four pints of aniline-oil, when the color is ready for use.
- the aniline-oil is added to neutralize any free acid which may exist in the aniline solution, and it may be omitted if that solution contain no free acid.
- This aniline color may be padded into the cloth or printed thereon, as desired.
- the ferro-cyanide paste is formed as follows: Take forty-five gallons of water and dissolve in it seventy pounds of ferro-cyanide-of-soda crystals and twenty-three and three-fourths pounds of chlorate of potash. Add twenty pounds of corn-starch and boil till thickened, and then cool. The corn-starch may be omitted or added in greater or less amount, as the printing, padding, or saturating of the cloth with the aniline color may require.
- aniline salt is prepared as follows: Dissolve sixty pounds of aniline-salt crystals in ten gallons of hot Water and cool. Instead of the salts of aniline, an equivalent amount of aniline-oil neutralized with hydrochloric acid may be employed.
- the proportion of the ferro-cyanide to the aniline salts in the above color may be varied, as I have only given the proportions I prefer to employ; but care should be taken that the proportion of the ferro-cyanide to the aniline shall never be less than eighty per cent. of the latter in any given quantity of color.
- Another advantage of the above process is that the pigment colors, being first applied to the cloth in the form of a resist before the aniline-black color, enters the substance of the cloth more intimately than if it had been previously filled with the aniline color, and when the steaming sets the pigments it is done more perfectly because of such intimate con nection with the substance of the goods.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
UNITED STATES PATENT OFFICE.
JOHN BRACEIVELL, OF NORTH ADAMS, MASSACHUSETTS.
PROCESS OF PRINTING ON ANlLlNE-BLACK.
SPECIFICATION forming part of Letters Patent No. 409,823, dated August 27, 1889.
Application filed February 15, 1889- Serial No. 299,985. (No specimens.)
To all whom it may concern:
Be it known that 1, JOHN BRACEWELL, of North Adams, in the county of Berkshire and State of Massachusetts, have invented a new and useful Improvement in the Combination of Resists with Aniline-Black, of which the following is a specification.
My invention relates to an improved method of compounding, applying, and developing aniline-black with resists printed in patterns upon the cloth, and in developing and fastening the colors by the use of steam under pressure, or what is commonly termed live steam, su bstantiallyas hereinafter described and claimed.
In practicing my invention I proceed as follows: I take bleached cotton cloth prepared for printing to form calico in the usual way, and print thereon the resist mixture hereinafter described, in suitable patterns to form the figure or design desired. This resist mixture may be compounded with pigment colors when other than a white pattern is to be produced. I next dry the cloth, and then print on it a cover or other pattern; or I blotch or I pad on the face only, or on face and back, with the steam aniline-black color, hereinafter described, or any other equivalent steam aniline-black color that is, one which can be developed by steam under pressure. I then dry the cloth upon steam drums or cans or in heated air, say at 160 Fahrenheit. I then pass it through a continuous steamer, or put it into a steam-box under pressure, and thus develop the aniline-black, and if it contain pigment colorsin the pattern printed thereon set or fix the same into the fabric simultaneously therewith, making them practically fast colors. Then soap and wash the cloth in the usual manner. \Vhen the operation is completed, it will be found that the parts covered by the resist mixture have not been substantially affected by the aniline-black color, because the alkali of the resist arrested the oxidation of the aniline and prevented its development in the parts printed with the discharge, whether plain or colored. The rapid development of the aniline-black by the steam under pressure secures a distinct and bold definition of the patterns, white or colored, because the oxidation of the aniline color proceeds so rapidly that the alkali of the resist, especially if it be the white, cannot affect the line or shade of the black around is edges. If the resist employed is mixed with pigment colors, it will also be found that the steam under pressure has fixed these inthe fabric simultaneously with the development of the aniline, and both the pattern and anilineblack ground thus become practically fast colors.
I form the resist mixture above mentioned as follows: gum substitute, four pounds; acetate of soda, four pounds; water, eight pounds. Dissolve and mix thoroughly. If the resist is to be colored, mix with the acetate of soda, albumen, either blood or egg, in place of the gum substitute, or other suitable thickening, and the desired pigment in sufficient quantity to produce the shade required, which can only be determined by experiment. The proportion of gum substitute or other suitable thickening may be varied to suit the printing, and the quantity of acetate of soda may also be varied. Instead of acetate of soda other soda or potash salts may be employed as the alkali of the resist, and in some of the pigments chromate of soda maybe used.
The steam aniline -black color is compounded as follows: I mix, cold, twelve gallens of the ferro-cyanide paste, given below, with four gallons of the solution of anilinesalt crystals, given below, and add thereto four pints of aniline-oil, when the color is ready for use. The aniline-oil is added to neutralize any free acid which may exist in the aniline solution, and it may be omitted if that solution contain no free acid. This aniline color may be padded into the cloth or printed thereon, as desired.
The ferro-cyanide paste is formed as follows: Take forty-five gallons of water and dissolve in it seventy pounds of ferro-cyanide-of-soda crystals and twenty-three and three-fourths pounds of chlorate of potash. Add twenty pounds of corn-starch and boil till thickened, and then cool. The corn-starch may be omitted or added in greater or less amount, as the printing, padding, or saturating of the cloth with the aniline color may require.
The solution of aniline salt is prepared as follows: Dissolve sixty pounds of aniline-salt crystals in ten gallons of hot Water and cool. Instead of the salts of aniline, an equivalent amount of aniline-oil neutralized with hydrochloric acid may be employed.
The proportion of the ferro-cyanide to the aniline salts in the above color may be varied, as I have only given the proportions I prefer to employ; but care should be taken that the proportion of the ferro-cyanide to the aniline shall never be less than eighty per cent. of the latter in any given quantity of color.
The above steam aniline-black will not injure the fiber of the goods, even if they be so thoroughly impregnated by it in the fluid state as to be colored on both sides alike, as the composition of the color retards any violent action when subjected to steam under pressure, which would tender the cloth, and the proportions of ferro-eyanide to aniline should not be less than eighty per cent. in order to preserve this quality of it and allow the steaming to be effected as described. This color is the subject-matter of another application filed simultaneously herewith.
Heretofore the action of steam under pressure to develop aniline colors has tendered the goods and prevented the use of it, substantially as hereinbefore described.
Another advantage of the above process is that the pigment colors, being first applied to the cloth in the form of a resist before the aniline-black color, enters the substance of the cloth more intimately than if it had been previously filled with the aniline color, and when the steaming sets the pigments it is done more perfectly because of such intimate con nection with the substance of the goods.
\Vhat I claim as new and of my invention 1s 1. The described process of producing patterns on aniline-black grounds by the action of live steamthat is to say, first printing the pattern in an alkali resist upon the cloth and drying, then treating the cloth with the prepared solution of aniline-black, as described, and drying, and finally developing and fixing the aniline-black rapidly by the action of steam under pressure, substantially as described.
2. The described process of producing col- "ored patterns on aniline-black grounds by the action of live steamthat is to say, first printing the pattern in an alkali resist colored with pigments upon the cloth and drying, then treating the cloth with the prepared solution of aniline-black, as described, and drying, and finally developing and simultaneously fixing the aniline-black and resist pigment by the action of steam under pressure, substantially as described.
JOHN BRACEVVELL. l/Vitnesses:
DAVID HALL RICE, .N. P. OCKINGTON.
Publications (1)
Publication Number | Publication Date |
---|---|
US409823A true US409823A (en) | 1889-08-27 |
Family
ID=2478758
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US409823D Expired - Lifetime US409823A (en) | Process of printing on aniline-black |
Country Status (1)
Country | Link |
---|---|
US (1) | US409823A (en) |
-
0
- US US409823D patent/US409823A/en not_active Expired - Lifetime
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US409823A (en) | Process of printing on aniline-black | |
US617772A (en) | Fritz rettig | |
US409821A (en) | Process of printing aniline-black | |
US409820A (en) | Pigment-resist | |
US491951A (en) | Frank p | |
US1482076A (en) | Mercerization and finishing of textile fabrics | |
US409819A (en) | Aniline-black discharge | |
US409822A (en) | Aniline-black | |
US500558A (en) | Printing aniline-black | |
US505088A (en) | Process of fixing colors upon cottons | |
US1513370A (en) | Soda-print process | |
US2233609A (en) | Patterned fabric and process for producing same | |
US491961A (en) | George donald | |
US99105A (en) | Improved method of fixing pigments to fibrous and textile materials | |
US491673A (en) | Process of printing colors with aniline-black | |
US128302A (en) | Improvement in processes of printing fabrics | |
US499687A (en) | Resist-mordant | |
US499689A (en) | Aniline-black resist | |
US1870516A (en) | Printing on textile pabrics | |
US499692A (en) | Aniline-black resist | |
US139056A (en) | Improvement in dyeing madder colors | |
US499690A (en) | Zinc res ist-mordant | |
US192491A (en) | Improvement ih mordanting textile fabrics | |
US809068A (en) | Composition of matter. | |
US1313658A (en) | wiggin |